Floating zone growth of α-Na0.90MnO2 single crystals

Dally, Rebecca; Clement, Raphaele J.; Chisnell, Robin; Taylor, Stephanie; Butala, Megan M.; Doan-Nguyen, Vicky V. T.; Balasubramanian, Mahalingam; Lynn, Jeffrey W.; Grey, Clare P.; Wilson, Stephen D.

doi:10.1016/j.jcrysgro.2016.12.010

Title: Floating zone growth of α-Na_0.90MnO₂ single crystals

Abstract

Here, single crystal growth of α-Na_xMnO₂ (x=0.90) is reported via the floating zone technique. The conditions required for stable growth and intergrowth-free crystals are described along with the results of trials under alternate growth atmospheres. Chemical and structural characterizations of the resulting α-Na_0.90MnO₂ crystals are performed using ICP-AES NMR, XANES, XPS, and neutron diffraction measurements. As a layered transition metal oxide with large ionic mobility and strong correlation effects, α-Na_xMnO₂ is of interest to many communities, and the implications of large volume, high purity, single crystal growth are discussed.

Authors:

Dally, Rebecca ^[1]; Clement, Raphaele J. ^[2]; Chisnell, Robin ^[3]; Taylor, Stephanie ^[4]; Butala, Megan M. ^[4]; Doan-Nguyen, Vicky V. T. ^[4]; Balasubramanian, Mahalingam ^[5]; Lynn, Jeffrey W. ^[3]; Grey, Clare P. ^[2]; Wilson, Stephen D. ^[4]

Boston College, Chestnut Hill, MA (United States); Univ. of California, Santa Barbara, CA (United States)
Univ. of Cambridge, Cambridge (United Kingdom)
National Institute of Standards and Technology, Gaithersburg, MD (United States)
Univ. of California, Santa Barbara, CA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Sat Dec 03 00:00:00 EST 2016

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: U.S. Army Research Laboratory, U.S. Army Research Office (ARO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

OSTI Identifier:: 1372403

Alternate Identifier(s):: OSTI ID: 1396715

Grant/Contract Number:: AC02-06CH11357; AC02-05CH11231; 7057154

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Crystal Growth

Additional Journal Information:: Journal Volume: 459; Journal Issue: C; Journal ID: ISSN 0022-0248

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; A1 characterization; A2 floating zone technique; B1 manganites; A2 single crystal growth

Citation Formats


                    Dally, Rebecca, Clement, Raphaele J., Chisnell, Robin, Taylor, Stephanie, Butala, Megan M., Doan-Nguyen, Vicky V. T., Balasubramanian, Mahalingam, Lynn, Jeffrey W., Grey, Clare P., and Wilson, Stephen D. Floating zone growth of α-Na0.90MnO2 single crystals.  United States: N. p., 2016. 
Web.  doi:10.1016/j.jcrysgro.2016.12.010.

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                    Dally, Rebecca, Clement, Raphaele J., Chisnell, Robin, Taylor, Stephanie, Butala, Megan M., Doan-Nguyen, Vicky V. T., Balasubramanian, Mahalingam, Lynn, Jeffrey W., Grey, Clare P., & Wilson, Stephen D. Floating zone growth of α-Na0.90MnO2 single crystals.  United States.  https://doi.org/10.1016/j.jcrysgro.2016.12.010

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                    Dally, Rebecca, Clement, Raphaele J., Chisnell, Robin, Taylor, Stephanie, Butala, Megan M., Doan-Nguyen, Vicky V. T., Balasubramanian, Mahalingam, Lynn, Jeffrey W., Grey, Clare P., and Wilson, Stephen D. Sat .  
"Floating zone growth of α-Na0.90MnO2 single crystals".  United States.  https://doi.org/10.1016/j.jcrysgro.2016.12.010.  https://www.osti.gov/servlets/purl/1372403.

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@article{osti_1372403,

  title        = {Floating zone growth of α-Na0.90MnO2 single crystals},

  author       = {Dally, Rebecca and Clement, Raphaele J. and Chisnell, Robin and Taylor, Stephanie and Butala, Megan M. and Doan-Nguyen, Vicky V. T. and Balasubramanian, Mahalingam and Lynn, Jeffrey W. and Grey, Clare P. and Wilson, Stephen D.},

  abstractNote = {Here, single crystal growth of α-NaxMnO2 (x=0.90) is reported via the floating zone technique. The conditions required for stable growth and intergrowth-free crystals are described along with the results of trials under alternate growth atmospheres. Chemical and structural characterizations of the resulting α-Na0.90MnO2 crystals are performed using ICP-AES NMR, XANES, XPS, and neutron diffraction measurements. As a layered transition metal oxide with large ionic mobility and strong correlation effects, α-NaxMnO2 is of interest to many communities, and the implications of large volume, high purity, single crystal growth are discussed.},

  doi          = {10.1016/j.jcrysgro.2016.12.010},

  journal      = {Journal of Crystal Growth},

  number       = C,

  volume       = 459,

  place        = {United States},

  year         = {Sat Dec 03 00:00:00 EST 2016},

  month        = {Sat Dec 03 00:00:00 EST 2016}

}

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https://doi.org/10.1016/j.jcrysgro.2016.12.010

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Cited by: 6 works

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Works referenced in this record:

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Crystal growth of NaxCoO2 under different atmospheres
journal, October 2004

Prabhakaran, D.; Boothroyd, A. T.; Coldea, R.
Journal of Crystal Growth, Vol. 271, Issue 1-2
DOI: 10.1016/j.jcrysgro.2004.07.033

Multiple Twinning As a Structure Directing Mechanism in Layered Rock-Salt-Type Oxides: NaMnO ₂ Polymorphism, Redox Potentials, and Magnetism
journal, May 2014

Abakumov, Artem M.; Tsirlin, Alexander A.; Bakaimi, Ioanna
Chemistry of Materials, Vol. 26, Issue 10
DOI: 10.1021/cm5011696

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet
journal, January 2014

Zorko, A.; Adamopoulos, O.; Komelj, M.
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms4222

Ferromagnetic in-plane spin fluctuations in NaxCoO2 observed by neutron inelastic scattering
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Works referencing / citing this record:

Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2
journal, June 2018

Dally, Rebecca L.; Zhao, Yang; Xu, Zhijun
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-04601-1

Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2
journal, June 2018

Dally, Rebecca L.; Zhao, Yang; Xu, Zhijun
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-04601-1

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Title: Floating zone growth of α-Na0.90MnO2 single crystals

Abstract

Citation Formats

Electrochemical Properties of Monoclinic NaMnO2 journal, January 2011

Electrochemical intercalation and deintercalation of NaxMnO2 bronzes journal, May 1985

Direct visualization of the Jahn–Teller effect coupled to Na ordering in Na5/8MnO2 journal, May 2014

Hydrothermal synthesis and properties of Na MnO2 crystals journal, September 1981

Zur Kenntnis der NaCl-Strukturfamilie Die Kristallstruktur von NaMnO2 journal, July 1973

Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials journal, January 2015

Multiple Twinning As a Structure Directing Mechanism in Layered Rock-Salt-Type Oxides: NaMnO 2 Polymorphism, Redox Potentials, and Magnetism journal, May 2014

β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries journal, November 2014

Insights into the Nature and Evolution upon Electrochemical Cycling of Planar Defects in the β-NaMnO 2 Na-Ion Battery Cathode: An NMR and First-Principles Density Functional Theory Approach journal, November 2016

Crystal growth of NaxCoO2 under different atmospheres journal, October 2004

Single-crystal growth and investigation of N a x C o O 2 and N a x Co O 2 · y H 2 O journal, July 2004

Effect of rotation of feed and seed rods on the quality of Na0.75CoO2 single crystal grown by traveling solvent floating zone method journal, May 2011

Growth and characterization of high quality single crystals of NaxCoO2 journal, September 2007

Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet α − NaMnO 2 journal, December 2007

Magnetic interactions in α − Na Mn O 2 : Quantum spin-2 system on a spatially anisotropic two-dimensional triangular lattice journal, January 2008

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet journal, January 2014

One-Dimensional Magnetic Fluctuations in the Spin-2 Triangular Lattice α − NaMnO 2 journal, August 2009

Ferromagnetic In-Plane Spin Fluctuations in Na x CoO 2 Observed by Neutron Inelastic Scattering journal, May 2004

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

High resolution x‐ray absorption spectroscopy with absolute energy calibration for the determination of absorption edge energies journal, March 1996

Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction journal, March 1988

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR journal, January 2012

A pre-edge analysis of Mn K-edge XANES spectra to help determine the speciation of manganese in minerals and glasses journal, July 2008

Achieving electrochemical capacitor functionality from nanoscale LiMn2O4 coatings on 3-D carbon nanoarchitectures journal, January 2013

A study on the effect of lithium insertion–extraction on the local structure of lithium manganese oxides using X-ray absorption spectroscopy journal, September 1999

A Sodium Manganese Oxide Cathode by Facile Reduction for Sodium Batteries journal, April 2014

Romanechite-structured Na 0.31 MnO 1.9 nanofibers as high-performance cathode material for a sodium-ion battery journal, January 2015

Phase Stability and Electronic Structure of NaMnO[sub 2] journal, January 2003

A pre-edge analysis of Mn K-edge XANES spectra to help determine the speciation of manganese in minerals and glasses journal, July 2008

Crystal growth of NaxCoO2 under different atmospheres journal, October 2004

Multiple Twinning As a Structure Directing Mechanism in Layered Rock-Salt-Type Oxides: NaMnO 2 Polymorphism, Redox Potentials, and Magnetism journal, May 2014

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet journal, January 2014

Ferromagnetic in-plane spin fluctuations in NaxCoO2 observed by neutron inelastic scattering text, January 2003

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR journal, January 2012

Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2 journal, June 2018

Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2 journal, June 2018

Title: Floating zone growth of α-Na_0.90MnO₂ single crystals

Electrochemical Properties of Monoclinic NaMnO2
journal, January 2011

Electrochemical intercalation and deintercalation of NaxMnO2 bronzes
journal, May 1985

Direct visualization of the Jahn–Teller effect coupled to Na ordering in Na5/8MnO2
journal, May 2014

Hydrothermal synthesis and properties of Na MnO2 crystals
journal, September 1981

Zur Kenntnis der NaCl-Strukturfamilie Die Kristallstruktur von NaMnO2
journal, July 1973

Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015

Multiple Twinning As a Structure Directing Mechanism in Layered Rock-Salt-Type Oxides: NaMnO ₂ Polymorphism, Redox Potentials, and Magnetism
journal, May 2014

β-NaMnO ₂ : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014

Insights into the Nature and Evolution upon Electrochemical Cycling of Planar Defects in the β-NaMnO ₂ Na-Ion Battery Cathode: An NMR and First-Principles Density Functional Theory Approach
journal, November 2016

Crystal growth of NaxCoO2 under different atmospheres
journal, October 2004

Single-crystal growth and investigation of $N a_{x} C o O_{2}$ and $N a_{x} Co O_{2} \cdot y H_{2} O$
journal, July 2004

Effect of rotation of feed and seed rods on the quality of Na0.75CoO2 single crystal grown by traveling solvent floating zone method
journal, May 2011

Growth and characterization of high quality single crystals of NaxCoO2
journal, September 2007

Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet $α − {NaMnO}_{2}$
journal, December 2007

Magnetic interactions in $α − Na Mn O_{2}$ : Quantum spin-2 system on a spatially anisotropic two-dimensional triangular lattice
journal, January 2008

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet
journal, January 2014

One-Dimensional Magnetic Fluctuations in the Spin-2 Triangular Lattice $α − {NaMnO}_{2}$
journal, August 2009

Ferromagnetic In-Plane Spin Fluctuations in ${Na}_{x} {CoO}_{2}$ Observed by Neutron Inelastic Scattering
journal, May 2004

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

High resolution x‐ray absorption spectroscopy with absolute energy calibration for the determination of absorption edge energies
journal, March 1996

Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction
journal, March 1988

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR
journal, January 2012

A pre-edge analysis of Mn K-edge XANES spectra to help determine the speciation of manganese in minerals and glasses
journal, July 2008

Achieving electrochemical capacitor functionality from nanoscale LiMn2O4 coatings on 3-D carbon nanoarchitectures
journal, January 2013

A study on the effect of lithium insertion–extraction on the local structure of lithium manganese oxides using X-ray absorption spectroscopy
journal, September 1999

A Sodium Manganese Oxide Cathode by Facile Reduction for Sodium Batteries
journal, April 2014

Romanechite-structured Na _0.31 MnO _1.9 nanofibers as high-performance cathode material for a sodium-ion battery
journal, January 2015

Phase Stability and Electronic Structure of NaMnO[sub 2]
journal, January 2003

A pre-edge analysis of Mn K-edge XANES spectra to help determine the speciation of manganese in minerals and glasses
journal, July 2008

Crystal growth of NaxCoO2 under different atmospheres
journal, October 2004

Multiple Twinning As a Structure Directing Mechanism in Layered Rock-Salt-Type Oxides: NaMnO ₂ Polymorphism, Redox Potentials, and Magnetism
journal, May 2014

Frustration-induced nanometre-scale inhomogeneity in a triangular antiferromagnet
journal, January 2014

Ferromagnetic in-plane spin fluctuations in NaxCoO2 observed by neutron inelastic scattering
text, January 2003

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR
journal, January 2012

Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2
journal, June 2018

Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2
journal, June 2018