Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries
Abstract
The corrosion of aluminum current collectors and the oxidation of solvents at a relatively high potential have been widely investigated with an aim to stabilize the electrochemical performance of lithium-ion batteries using such components. The corrosion behavior of aluminum current collectors was revisited using a home-build high-precision electrochemical measurement system, and the impact of electrolyte components and the surface protection layer on aluminum foil was systematically studied. The electrochemical results showed that the corrosion of aluminum foil was triggered by the electrochemical oxidation of solvent molecules, like ethylene carbonate, at a relative high potential. The organic radical cations generated from the electrochemical oxidation are energetically unstable, and readily undergo a deprotonation reaction that generates protons and promote the dissolution of Al3+ from the aluminum foil. Finally, this new reaction mechanism can also shed light on the dissolution of transitional metal at high potentials.
- Authors:
-
- Univ. of Rochester, Rochester, NY (United States); Argonne National Lab. (ANL), Lemont, IL (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Tsinghua Univ., Beijing (China)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Univ. of Rochester, Rochester, NY (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1372064
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry Letters
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 5; Journal ID: ISSN 1948-7185
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; aluminum foil; corrosion reactions; lithium-ion batteries; non-aqueous electrolyte
Citation Formats
Ma, Tianyuan, Xu, Gui -Liang, Li, Yan, Wang, Li, He, Xiangming, Zheng, Jianming, Liu, Jun, Engelhard, Mark H., Zapol, Peter, Curtiss, Larry A., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries. United States: N. p., 2017.
Web. doi:10.1021/acs.jpclett.6b02933.
Ma, Tianyuan, Xu, Gui -Liang, Li, Yan, Wang, Li, He, Xiangming, Zheng, Jianming, Liu, Jun, Engelhard, Mark H., Zapol, Peter, Curtiss, Larry A., Jorne, Jacob, Amine, Khalil, & Chen, Zonghai. Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries. United States. https://doi.org/10.1021/acs.jpclett.6b02933
Ma, Tianyuan, Xu, Gui -Liang, Li, Yan, Wang, Li, He, Xiangming, Zheng, Jianming, Liu, Jun, Engelhard, Mark H., Zapol, Peter, Curtiss, Larry A., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. Thu .
"Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries". United States. https://doi.org/10.1021/acs.jpclett.6b02933. https://www.osti.gov/servlets/purl/1372064.
@article{osti_1372064,
title = {Revisiting the Corrosion of the Aluminum Current Collector in Lithium-Ion Batteries},
author = {Ma, Tianyuan and Xu, Gui -Liang and Li, Yan and Wang, Li and He, Xiangming and Zheng, Jianming and Liu, Jun and Engelhard, Mark H. and Zapol, Peter and Curtiss, Larry A. and Jorne, Jacob and Amine, Khalil and Chen, Zonghai},
abstractNote = {The corrosion of aluminum current collectors and the oxidation of solvents at a relatively high potential have been widely investigated with an aim to stabilize the electrochemical performance of lithium-ion batteries using such components. The corrosion behavior of aluminum current collectors was revisited using a home-build high-precision electrochemical measurement system, and the impact of electrolyte components and the surface protection layer on aluminum foil was systematically studied. The electrochemical results showed that the corrosion of aluminum foil was triggered by the electrochemical oxidation of solvent molecules, like ethylene carbonate, at a relative high potential. The organic radical cations generated from the electrochemical oxidation are energetically unstable, and readily undergo a deprotonation reaction that generates protons and promote the dissolution of Al3+ from the aluminum foil. Finally, this new reaction mechanism can also shed light on the dissolution of transitional metal at high potentials.},
doi = {10.1021/acs.jpclett.6b02933},
journal = {Journal of Physical Chemistry Letters},
number = 5,
volume = 8,
place = {United States},
year = {Thu Feb 16 00:00:00 EST 2017},
month = {Thu Feb 16 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Aluminum corrosion in electrolyte of Li-ion battery
journal, July 2002
- Zhang, S. S.; Jow, T. R.
- Journal of Power Sources, Vol. 109, Issue 2
Self-discharge of Li/LixMn2O4 batteries in relation to corrosion of aluminum cathode substrates
journal, December 2001
- Zhang, Shengshui; Ding, Michael S.; Jow, T. Richard
- Journal of Power Sources, Vol. 102, Issue 1-2
Comparative study of EC/DMC LiTFSI and LiPF6 electrolytes for electrochemical storage
journal, November 2011
- Dahbi, Mouad; Ghamouss, Fouad; Tran-Van, François
- Journal of Power Sources, Vol. 196, Issue 22
Factors That Influence Formation of AlF[sub 3] Passive Film on Aluminum in Li-Ion Battery Electrolytes with LiPF[sub 6]
journal, January 2006
- Zhang, Xueyuan; Devine, T. M.
- Journal of The Electrochemical Society, Vol. 153, Issue 9
Identity of Passive Film Formed on Aluminum in Li-Ion Battery Electrolytes with LiPF[sub 6]
journal, January 2006
- Zhang, Xueyuan; Devine, T. M.
- Journal of The Electrochemical Society, Vol. 153, Issue 9
Study of LiBF[sub 4] as an Electrolyte Salt for a Li-Ion Battery
journal, January 2002
- Zhang, S. S.; Xu, K.; Jow, T. R.
- Journal of The Electrochemical Society, Vol. 149, Issue 5
Methyl Difluoroacetate Inhibits Corrosion of Aluminum Cathode Current Collector for Lithium Ion Cells
journal, January 2005
- Kawamura, Tetsuya; Tanaka, Takaaki; Egashira, Minato
- Electrochemical and Solid-State Letters, Vol. 8, Issue 9
Inhibition of anodic corrosion of aluminum cathode current collector on recharging in lithium imide electrolytes
journal, May 2000
- Wang, Xianming; Yasukawa, Eiki; Mori, Shoichiro
- Electrochimica Acta, Vol. 45, Issue 17
Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms
journal, January 2014
- McOwen, Dennis W.; Seo, Daniel M.; Borodin, Oleg
- Energy Environ. Sci., Vol. 7, Issue 1
Corrosion Prevention Mechanism of Aluminum Metal in Superconcentrated Electrolytes
journal, July 2015
- Yamada, Yuki; Chiang, Ching Hua; Sodeyama, Keitaro
- ChemElectroChem, Vol. 2, Issue 11
Corrosion of Aluminum Current Collectors in Lithium-Ion Batteries with Electrolytes Containing LiPF[sub 6]
journal, January 2005
- Zhang, Xueyuan; Winget, Bryon; Doeff, Marca
- Journal of The Electrochemical Society, Vol. 152, Issue 11
Corrosion of Aluminum Current Collectors in High-Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles
journal, January 2007
- Hyams, Tzipi Cohen; Go, John; Devine, Thomas M.
- Journal of The Electrochemical Society, Vol. 154, Issue 8
Mechanism of Anodic Dissolution of the Aluminum Current Collector in 1 M LiTFSI EC:DEC 3:7 in Rechargeable Lithium Batteries
journal, December 2012
- Krämer, Elisabeth; Schedlbauer, Tanja; Hoffmann, Björn
- Journal of The Electrochemical Society, Vol. 160, Issue 2
Kinetic Study of Parasitic Reactions in Lithium-Ion Batteries: A Case Study on LiNi 0.6 Mn 0.2 Co 0.2 O 2
journal, January 2016
- Zeng, Xiaoqiao; Xu, Gui-Liang; Li, Yan
- ACS Applied Materials & Interfaces, Vol. 8, Issue 5
Oxidation induced decomposition of ethylene carbonate from DFT calculations – importance of explicitly treating surrounding solvent
journal, January 2012
- Xing, Lidan; Borodin, Oleg
- Physical Chemistry Chemical Physics, Vol. 14, Issue 37
Theoretical Investigations on Oxidative Stability of Solvents and Oxidative Decomposition Mechanism of Ethylene Carbonate for Lithium Ion Battery Use
journal, December 2009
- Xing, Lidan; Li, Weishan; Wang, Chaoyang
- The Journal of Physical Chemistry B, Vol. 113, Issue 52
Transition metal dissolution and deposition in Li-ion batteries investigated by operando X-ray absorption spectroscopy
journal, January 2016
- Wandt, Johannes; Freiberg, Anna; Thomas, Rowena
- Journal of Materials Chemistry A, Vol. 4, Issue 47
Study of Thermal Decomposition of Li 1-x (Ni 1/3 Mn 1/3 Co 1/3 ) 0.9 O 2 Using In-Situ High-Energy X-Ray Diffraction
journal, March 2013
- Chen, Zonghai; Ren, Yang; Lee, Eungje
- Advanced Energy Materials, Vol. 3, Issue 6
Works referencing / citing this record:
Interphases in Electroactive Suspension Systems: Where Chemistry Meets Mesoscale Physics
journal, April 2019
- Shukla, Garima; Franco, Alejandro A.
- Batteries & Supercaps, Vol. 2, Issue 7
Oxygen Release and Its Effect on the Cycling Stability of LiNi x Mn y Co z O 2 (NMC) Cathode Materials for Li-Ion Batteries
journal, January 2017
- Jung, Roland; Metzger, Michael; Maglia, Filippo
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Identifying Contact Resistances in High-Voltage Cathodes by Impedance Spectroscopy
journal, January 2019
- Pritzl, Daniel; Bumberger, Andreas E.; Wetjen, Morten
- Journal of The Electrochemical Society, Vol. 166, Issue 4
Solid-State Lithium/Selenium-Sulfur Chemistry Enabled via a Robust Solid-Electrolyte Interphase
journal, November 2018
- Xu, Gui-Liang; Sun, Hui; Luo, Chao
- Advanced Energy Materials, Vol. 9, Issue 2
A Review of Inactive Materials and Components of Flexible Lithium-Ion Batteries
journal, September 2017
- Foreman, Evan; Zakri, Waleed; Hossein Sanatimoghaddam, Mohammad
- Advanced Sustainable Systems, Vol. 1, Issue 11
Fluor und Lithium: Ideale Partner für Elektrolyte in wiederaufladbaren Hochleistungsbatterien
journal, July 2019
- Aspern, N.; Röschenthaler, G. ‐V.; Winter, M.
- Angewandte Chemie, Vol. 131, Issue 45
The Investigation of Electrolyte Oxidation and Film Deposition Characteristics at High Potentials in a Carbonate-Based Electrolyte Using Pt Electrode
journal, January 2018
- Yoon, Taeho; Lee, Taejin; Soon, Jiyong
- Journal of The Electrochemical Society, Vol. 165, Issue 5
Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery
journal, September 2018
- Zhang, Tong; Paillard, Elie
- Frontiers of Chemical Science and Engineering, Vol. 12, Issue 3
Mechanism of Gases Generation during Lithium-Ion Batteries Cycling
journal, January 2019
- Galushkin, N. Е.; Yazvinskaya, N. N.; Galushkin, D. N.
- Journal of The Electrochemical Society, Vol. 166, Issue 6
Advances in sodium secondary batteries utilizing ionic liquid electrolytes
journal, January 2019
- Matsumoto, Kazuhiko; Hwang, Jinkwang; Kaushik, Shubham
- Energy & Environmental Science, Vol. 12, Issue 11
Building Better Batteries in the Solid State: A Review
journal, November 2019
- Mauger, Alain; Julien, Christian M.; Paolella, Andrea
- Materials, Vol. 12, Issue 23, p. 3892
An organic–inorganic semi-interpenetrating network ionogel electrolyte for high-voltage lithium metal batteries
journal, January 2020
- Su, Anyu; Guo, Panlong; Li, Jian
- Journal of Materials Chemistry A, Vol. 8, Issue 9
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes
journal, November 2019
- Aspern, N.; Röschenthaler, G. ‐V.; Winter, M.
- Angewandte Chemie International Edition, Vol. 58, Issue 45
Biomass‐Derived Poly(Furfuryl Alcohol)–Protected Aluminum Anode for Lithium‐Ion Batteries
journal, April 2019
- Ling, Han Yeu; Su, Zhong; Chen, Hao
- Energy Technology
Interphases in Electroactive Suspension Systems: Where Chemistry Meets Mesoscale Physics
journal, July 2019
- Shukla, Garima; Franco, Alejandro A.
- Batteries & Supercaps, Vol. 2, Issue 7
Toward Low-Cost All-Organic and Biodegradable Li-Ion Batteries
journal, March 2020
- Delaporte, N.; Lajoie, G.; Collin-Martin, S.
- Scientific Reports, Vol. 10, Issue 1
Building Better Batteries in the Solid State: A Review
journal, November 2019
- Mauger, Alain; Julien, Christian M.; Paolella, Andrea
- Materials, Vol. 12, Issue 23, p. 3892