Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon
Abstract
Research on lithium (Li) metal chemistry has been rapidly gaining momentum nowadays not only because of the appealing high theoretical capacity, but also its indispensable role in the next-generation Li–S and Li–air batteries. However, two root problems of Li metal, namely high reactivity and infinite relative volume change during cycling, bring about numerous other challenges that impede its practical applications. In the past, extensive studies have targeted these two root causes by either improving interfacial stability or constructing a stable host. However, efficient surface passivation on three-dimensional (3D) Li is still absent. Here in this paper, we develop a conformal LiF coating technique on Li surface with commercial Freon R134a as the reagent. In contrast to solid/liquid reagents, gaseous Freon exhibits not only nontoxicity and well-controlled reactivity, but also much better permeability that enables a uniform LiF coating even on 3D Li. By applying a LiF coating onto 3D layered Li-reduced graphene oxide (Li-rGO) electrodes, highly reduced side reactions and enhanced cycling stability without overpotential augment for over 200 cycles were proven in symmetric cells. Furthermore, Li–S cells with LiF protected Li-rGO exhibit significantly improved cyclability and Coulombic efficiency, while excellent rate capability (~800 mAh g-1 at 2 C) canmore »
- Authors:
-
[1];
[1];
[1];
[2];
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering and California NanoSystems Inst.
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1369411
- Grant/Contract Number:
- AC02-76SF00515; EE0006828
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 17; Journal Issue: 6; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; artificial SEI; interface passivation; Lithium metal anodes; stable host; three-dimensional Li
Citation Formats
Lin, Dingchang, Liu, Yayuan, Chen, Wei, Zhou, Guangmin, Liu, Kai, Dunn, Bruce, and Cui, Yi. Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon. United States: N. p., 2017.
Web. doi:10.1021/acs.nanolett.7b01020.
Lin, Dingchang, Liu, Yayuan, Chen, Wei, Zhou, Guangmin, Liu, Kai, Dunn, Bruce, & Cui, Yi. Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon. United States. https://doi.org/10.1021/acs.nanolett.7b01020
Lin, Dingchang, Liu, Yayuan, Chen, Wei, Zhou, Guangmin, Liu, Kai, Dunn, Bruce, and Cui, Yi. Tue .
"Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon". United States. https://doi.org/10.1021/acs.nanolett.7b01020. https://www.osti.gov/servlets/purl/1369411.
@article{osti_1369411,
title = {Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon},
author = {Lin, Dingchang and Liu, Yayuan and Chen, Wei and Zhou, Guangmin and Liu, Kai and Dunn, Bruce and Cui, Yi},
abstractNote = {Research on lithium (Li) metal chemistry has been rapidly gaining momentum nowadays not only because of the appealing high theoretical capacity, but also its indispensable role in the next-generation Li–S and Li–air batteries. However, two root problems of Li metal, namely high reactivity and infinite relative volume change during cycling, bring about numerous other challenges that impede its practical applications. In the past, extensive studies have targeted these two root causes by either improving interfacial stability or constructing a stable host. However, efficient surface passivation on three-dimensional (3D) Li is still absent. Here in this paper, we develop a conformal LiF coating technique on Li surface with commercial Freon R134a as the reagent. In contrast to solid/liquid reagents, gaseous Freon exhibits not only nontoxicity and well-controlled reactivity, but also much better permeability that enables a uniform LiF coating even on 3D Li. By applying a LiF coating onto 3D layered Li-reduced graphene oxide (Li-rGO) electrodes, highly reduced side reactions and enhanced cycling stability without overpotential augment for over 200 cycles were proven in symmetric cells. Furthermore, Li–S cells with LiF protected Li-rGO exhibit significantly improved cyclability and Coulombic efficiency, while excellent rate capability (~800 mAh g-1 at 2 C) can still be retained.},
doi = {10.1021/acs.nanolett.7b01020},
journal = {Nano Letters},
number = 6,
volume = 17,
place = {United States},
year = {Tue May 23 00:00:00 EDT 2017},
month = {Tue May 23 00:00:00 EDT 2017}
}
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