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Title: Ionization Study of Isomeric Molecules in Strong-field Laser Pulses

Abstract

Through the use of the technique of time-of-flight mass spectroscopy, we obtain strong-field ionization yields for randomly oriented 1,2-dichloroethylene (1,2-DCE) (C2H2Cl2) and 2-butene (C4H8). Here, we are interested in studying the effect of conformal structure in strong-field ionization and, in particular, the role of molecular polarity. That is, we can perform strong-field ionization studies in polar vs non-polar molecules that have the same chemical composition. Here, we report our findings through the ionization yields and the ratio (trans/cis) of each stereoisomer pair as a function of intensity.

Authors:
 [1];  [1];  [1];  [1]
  1. Kansas State Univ., Manhattan, KS (United States). Dept. of Physics
Publication Date:
Research Org.:
Kansas State Univ., Manhattan, KS (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1366468
Grant/Contract Number:  
FG02-86ER13491
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; atomic and molecular interactions with photons; chemical physics; electronic structure of atoms and molecules

Citation Formats

Zigo, Stefan, Le, Anh-Thu, Timilsina, Pratap, and Trallero-Herrero, Carlos A. Ionization Study of Isomeric Molecules in Strong-field Laser Pulses. United States: N. p., 2017. Web. doi:10.1038/srep42149.
Zigo, Stefan, Le, Anh-Thu, Timilsina, Pratap, & Trallero-Herrero, Carlos A. Ionization Study of Isomeric Molecules in Strong-field Laser Pulses. United States. https://doi.org/10.1038/srep42149
Zigo, Stefan, Le, Anh-Thu, Timilsina, Pratap, and Trallero-Herrero, Carlos A. Fri . "Ionization Study of Isomeric Molecules in Strong-field Laser Pulses". United States. https://doi.org/10.1038/srep42149. https://www.osti.gov/servlets/purl/1366468.
@article{osti_1366468,
title = {Ionization Study of Isomeric Molecules in Strong-field Laser Pulses},
author = {Zigo, Stefan and Le, Anh-Thu and Timilsina, Pratap and Trallero-Herrero, Carlos A.},
abstractNote = {Through the use of the technique of time-of-flight mass spectroscopy, we obtain strong-field ionization yields for randomly oriented 1,2-dichloroethylene (1,2-DCE) (C2H2Cl2) and 2-butene (C4H8). Here, we are interested in studying the effect of conformal structure in strong-field ionization and, in particular, the role of molecular polarity. That is, we can perform strong-field ionization studies in polar vs non-polar molecules that have the same chemical composition. Here, we report our findings through the ionization yields and the ratio (trans/cis) of each stereoisomer pair as a function of intensity.},
doi = {10.1038/srep42149},
journal = {Scientific Reports},
number = ,
volume = 7,
place = {United States},
year = {Fri Feb 10 00:00:00 EST 2017},
month = {Fri Feb 10 00:00:00 EST 2017}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 7 works
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Figures / Tables:

Figure 1 Figure 1: Ionization yields of the first ion of (a) 2-butene and (b) 1, 2-DCE (35–35 isotope) as a function of intensity (log-log).

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