Unrivaled combination of surface area and pore volume in micelle-templated carbon for supercapacitor energy storage
Abstract
Here, we created Immense Surface Area Carbons (ISACs) by a novel heat treatment that stabilized the micelle structure in a biological based precursor prior to high temperature combined activation – pyrolysis. While displaying a morphology akin to that of commercial activated carbon, ISACs contain an unparalleled combination of electrochemically active surface area and pore volume (up to 4051 m2 g–1, total pore volume 2.60 cm3 g–1, 76% small mesopores). The carbons also possess the benefit of being quite pure (combined O and N: 2.6–4.1 at%), thus allowing for a capacitive response that is primarily EDLC. Tested at commercial mass loadings (~10 mg cm–2) ISACs demonstrate exceptional specific capacitance values throughout the entire relevant current density regime, with superior rate capability primarily due to the large fraction of mesopores. In the optimized ISAC, the specific capacitance (Cg) is 540 F g–1 at 0.2 A g–1, 409 F g–1 at 1 A g–1 and 226 F g–1 at a very high current density of 300 A g–1 (~0.15 second charge time). At intermediate and high currents, such capacitance values have not been previously reported for any carbon. Tested with a stable 1.8 V window in a 1 M Li2SO4 electrolyte, a symmetricmore »
- Authors:
-
[1];
[1];
- Clarkson Univ., Potsdam, NY (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- State Univ. of New York, Binghamton, NY (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
- Sponsoring Org.:
- USDOE Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1366417
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 26; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; energy storage; high power; aqueous battery; lithium ion battery; sodium ion battery; activated carbon; graphite; graphene; nanotube; two dimensional; sulfur; phosphorous; doped carbon; heteroatom
Citation Formats
Pokrzywinski, Jesse, Keum, Jong K., Ruther, Rose E., Self, Ethan C., Chi, Miaofang, Meyer, III, Harry M., Littrell, Kenneth C., Aulakh, Darpandeep, Marble, Sam, Ding, Jia, Wriedt, Mario, Nanda, Jagjit, and Mitlin, David. Unrivaled combination of surface area and pore volume in micelle-templated carbon for supercapacitor energy storage. United States: N. p., 2017.
Web. doi:10.1039/C7TA03655H.
Pokrzywinski, Jesse, Keum, Jong K., Ruther, Rose E., Self, Ethan C., Chi, Miaofang, Meyer, III, Harry M., Littrell, Kenneth C., Aulakh, Darpandeep, Marble, Sam, Ding, Jia, Wriedt, Mario, Nanda, Jagjit, & Mitlin, David. Unrivaled combination of surface area and pore volume in micelle-templated carbon for supercapacitor energy storage. United States. https://doi.org/10.1039/C7TA03655H
Pokrzywinski, Jesse, Keum, Jong K., Ruther, Rose E., Self, Ethan C., Chi, Miaofang, Meyer, III, Harry M., Littrell, Kenneth C., Aulakh, Darpandeep, Marble, Sam, Ding, Jia, Wriedt, Mario, Nanda, Jagjit, and Mitlin, David. Tue .
"Unrivaled combination of surface area and pore volume in micelle-templated carbon for supercapacitor energy storage". United States. https://doi.org/10.1039/C7TA03655H. https://www.osti.gov/servlets/purl/1366417.
@article{osti_1366417,
title = {Unrivaled combination of surface area and pore volume in micelle-templated carbon for supercapacitor energy storage},
author = {Pokrzywinski, Jesse and Keum, Jong K. and Ruther, Rose E. and Self, Ethan C. and Chi, Miaofang and Meyer, III, Harry M. and Littrell, Kenneth C. and Aulakh, Darpandeep and Marble, Sam and Ding, Jia and Wriedt, Mario and Nanda, Jagjit and Mitlin, David},
abstractNote = {Here, we created Immense Surface Area Carbons (ISACs) by a novel heat treatment that stabilized the micelle structure in a biological based precursor prior to high temperature combined activation – pyrolysis. While displaying a morphology akin to that of commercial activated carbon, ISACs contain an unparalleled combination of electrochemically active surface area and pore volume (up to 4051 m2 g–1, total pore volume 2.60 cm3 g–1, 76% small mesopores). The carbons also possess the benefit of being quite pure (combined O and N: 2.6–4.1 at%), thus allowing for a capacitive response that is primarily EDLC. Tested at commercial mass loadings (~10 mg cm–2) ISACs demonstrate exceptional specific capacitance values throughout the entire relevant current density regime, with superior rate capability primarily due to the large fraction of mesopores. In the optimized ISAC, the specific capacitance (Cg) is 540 F g–1 at 0.2 A g–1, 409 F g–1 at 1 A g–1 and 226 F g–1 at a very high current density of 300 A g–1 (~0.15 second charge time). At intermediate and high currents, such capacitance values have not been previously reported for any carbon. Tested with a stable 1.8 V window in a 1 M Li2SO4 electrolyte, a symmetric supercapacitor cell yields a flat energy–power profile that is fully competitive with those of organic electrolyte systems: 29 W h kg–1 at 442 W kg–1 and 17 W h kg–1 at 3940 W kg–1. The cyclability of symmetric ISAC cells is also exceptional due to the minimization of faradaic reactions on the carbon surface, with 80% capacitance retention over 100 000 cycles in 1 M Li2SO4 and 75 000 cycles in 6 M KOH.},
doi = {10.1039/C7TA03655H},
journal = {Journal of Materials Chemistry. A},
number = 26,
volume = 5,
place = {United States},
year = {Tue May 23 00:00:00 EDT 2017},
month = {Tue May 23 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 51 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density
journal, April 2011
- Fan, Zhuangjun; Yan, Jun; Wei, Tong
- Advanced Functional Materials, Vol. 21, Issue 12
Excellent energy–power characteristics from a hybrid sodium ion capacitor based on identical carbon nanosheets in both electrodes
journal, January 2016
- Wang, Huanlei; Mitlin, David; Ding, Jia
- Journal of Materials Chemistry A, Vol. 4, Issue 14
Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009
- Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
- Nature Materials, Vol. 8, Issue 8, p. 621-629
Electrode materials for aqueous asymmetric supercapacitors
journal, January 2013
- Wang, Faxing; Xiao, Shiying; Hou, Yuyang
- RSC Advances, Vol. 3, Issue 32
Disruption and sedimentation of casein micelles and casein micelle isolates under high-pressure homogenization
journal, January 2008
- Roach, Adrienne; Harte, Federico
- Innovative Food Science & Emerging Technologies, Vol. 9, Issue 1
Carbon materials for high volumetric performance supercapacitors: design, progress, challenges and opportunities
journal, January 2016
- Wang, Qian; Yan, Jun; Fan, Zhuangjun
- Energy & Environmental Science, Vol. 9, Issue 3
On the structural models of bovine casein micelles—review and possible improvements
journal, January 2011
- Dalgleish, Douglas G.
- Soft Matter, Vol. 7, Issue 6
White clover based nitrogen-doped porous carbon for a high energy density supercapacitor electrode
journal, January 2015
- Ma, Guofu; Zhang, Zhiguo; Sun, Kanjun
- RSC Advances, Vol. 5, Issue 130
3D micro-porous conducting carbon beehive by single step polymer carbonization for high performance supercapacitors: the magic of in situ porogen formation
journal, January 2014
- Puthusseri, Dhanya; Aravindan, Vanchiappan; Madhavi, Srinivasan
- Energy Environ. Sci., Vol. 7, Issue 2
Sulfur-rich carbon cryogels for supercapacitors with improved conductivity and wettability
journal, January 2014
- Zhou, Yao; Candelaria, Stephanie L.; Liu, Qian
- Journal of Materials Chemistry A, Vol. 2, Issue 22
Graphene hydrogels non-covalently functionalized with alizarin: an ideal electrode material for symmetric supercapacitors
journal, January 2015
- An, Ning; An, Yufeng; Hu, Zhongai
- Journal of Materials Chemistry A, Vol. 3, Issue 44
Electrospun Carbon Nanofibers/Carbon Nanotubes/Polyaniline Ternary Composites with Enhanced Electrochemical Performance for Flexible Solid-State Supercapacitors
journal, December 2015
- Miao, Fujun; Shao, Changlu; Li, Xinghua
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 3
Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films
journal, March 2010
- Wu, Qiong; Xu, Yuxi; Yao, Zhiyi
- ACS Nano, Vol. 4, Issue 4, p. 1963-1970
Materials for electrochemical capacitors
journal, November 2008
- Simon, Patrice; Gogotsi, Yury
- Nature Materials, Vol. 7, Issue 11
Human hair-derived carbon flakes for electrochemical supercapacitors
journal, January 2014
- Qian, Wenjing; Sun, Fengxia; Xu, Yanhui
- Energy & Environmental Science, Vol. 7, Issue 1, p. 379-386
Safe, high-energy supercapacitors based on solvent-free ionic liquid electrolytes
journal, December 2008
- Arbizzani, Catia; Biso, Maurizio; Cericola, Dario
- Journal of Power Sources, Vol. 185, Issue 2
Functionalization of chemically derived graphene for improving its electrocapacitive energy storage properties
journal, January 2016
- Lei, Zhibin; Zhang, Jintao; Zhang, Li Li
- Energy & Environmental Science, Vol. 9, Issue 6
Formation of Carbon Nanosheets via Simultaneous Activation and Catalytic Carbonization of Macroporous Anion-Exchange Resin for Supercapacitors Application
journal, November 2014
- Peng, Hui; Ma, Guofu; Sun, Kanjun
- ACS Applied Materials & Interfaces, Vol. 6, Issue 23
Casein Interactions: Casting Light on the Black Boxes, the Structure in Dairy Products
journal, March 1998
- Horne, David S.
- International Dairy Journal, Vol. 8, Issue 3
High voltage supercapacitor built with seaweed carbons in neutral aqueous electrolyte
journal, December 2010
- Bichat, M. P.; Raymundo-Piñero, E.; Béguin, F.
- Carbon, Vol. 48, Issue 15
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015
- Suo, L.; Borodin, O.; Gao, T.
- Science, Vol. 350, Issue 6263
The Effect of Crystallinity on the Rapid Pseudocapacitive Response of Nb2O5
journal, December 2011
- Kim, Jong Woung; Augustyn, Veronica; Dunn, Bruce
- Advanced Energy Materials, Vol. 2, Issue 1
Organohalide lead perovskites for photovoltaic applications
journal, January 2014
- Gao, Peng; Grätzel, Michael; Nazeeruddin, Mohammad K.
- Energy Environ. Sci., Vol. 7, Issue 8
WO3-x@Au@MnO2 Core-Shell Nanowires on Carbon Fabric for High-Performance Flexible Supercapacitors
journal, January 2012
- Lu, Xihong; Zhai, Teng; Zhang, Xianghui
- Advanced Materials, Vol. 24, Issue 7
Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions
journal, January 2015
- Yu, Zenan; Tetard, Laurene; Zhai, Lei
- Energy & Environmental Science, Vol. 8, Issue 3
Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors
journal, January 2016
- Li, Yiju; Wang, Guiling; Wei, Tong
- Nano Energy, Vol. 19
A core-shell model of calcium phosphate nanoclusters stabilized by beta-casein phosphopeptides, derived from sedimentation equilibrium and small-angle X-ray and neutron-scattering measurements
journal, February 1998
- Holt, Carl; Timmins, Peter A.; Errington, Neil
- European Journal of Biochemistry, Vol. 252, Issue 1
Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors
journal, January 2013
- Li, Zhi; Xu, Zhanwei; Tan, Xuehai
- Energy & Environmental Science, Vol. 6, Issue 3
A Controllable Synthesis of Rich Nitrogen-Doped Ordered Mesoporous Carbon for CO 2 Capture and Supercapacitors
journal, December 2012
- Wei, Jing; Zhou, Dandan; Sun, Zhenkun
- Advanced Functional Materials, Vol. 23, Issue 18
Microporous Carbon Nanoplates from Regenerated Silk Proteins for Supercapacitors
journal, February 2013
- Yun, Young Soo; Cho, Se Youn; Shim, Jinyong
- Advanced Materials, Vol. 25, Issue 14
Production and adsorption characteristics of MAXSORB: High-surface-area active carbon
journal, January 1993
- Otowa, Toshiro; Tanibata, Ritsuo; Itoh, Masao
- Gas Separation & Purification, Vol. 7, Issue 4
Exploring the large voltage range of carbon/carbon supercapacitors in aqueous lithium sulfate electrolyte
journal, January 2012
- Gao, Qiang; Demarconnay, Laurent; Raymundo-Piñero, Encarnación
- Energy & Environmental Science, Vol. 5, Issue 11
Supercapacitors based on carbons with tuned porosity derived from paper pulp mill sludge biowaste
journal, June 2013
- Wang, Huanlei; Li, Zhi; Tak, Jin Kwon
- Carbon, Vol. 57
A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries
journal, January 2015
- Han, Man Huon; Gonzalo, Elena; Singh, Gurpreet
- Energy & Environmental Science, Vol. 8, Issue 1
Interconnected Carbon Nanosheets Derived from Hemp for Ultrafast Supercapacitors with High Energy
journal, May 2013
- Wang, Huanlei; Xu, Zhanwei; Kohandehghan, Alireza
- ACS Nano, Vol. 7, Issue 6, p. 5131-5141
True Performance Metrics in Electrochemical Energy Storage
journal, November 2011
- Gogotsi, Y.; Simon, P.
- Science, Vol. 334, Issue 6058
Capacitive Energy Storage in Nanostructured Carbon–Electrolyte Systems
journal, June 2012
- Simon, P.; Gogotsi, Y.
- Accounts of Chemical Research, Vol. 46, Issue 5
Carbon Nanocages as Supercapacitor Electrode Materials
journal, December 2011
- Xie, Ke; Qin, Xingtai; Wang, Xizhang
- Advanced Materials, Vol. 24, Issue 3
Carbon-based materials as supercapacitor electrodes
journal, January 2009
- Zhang, Li Li; Zhao, X. S.
- Chemical Society Reviews, Vol. 38, Issue 9
Effect of activation on the surface chemistry of carbons from polymer precursors
journal, July 2001
- László, Krisztina; Tombácz, Etelka; Josepovits, Katalin
- Carbon, Vol. 39, Issue 8
Manganese oxide-based materials as electrochemical supercapacitor electrodes
journal, January 2011
- Wei, Weifeng; Cui, Xinwei; Chen, Weixing
- Chem. Soc. Rev., Vol. 40, Issue 3
Formation of Onion-Like NiCo 2 S 4 Particles via Sequential Ion-Exchange for Hybrid Supercapacitors
journal, November 2016
- Guan, Bu Yuan; Yu, Le; Wang, Xiao
- Advanced Materials, Vol. 29, Issue 6
Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors
journal, January 2012
- Zhang, Li Li; Zhao, Xin; Stoller, Meryl D.
- Nano Letters, Vol. 12, Issue 4
Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2 composites for asymmetric supercapacitor application
journal, January 2015
- Salunkhe, Rahul R.; Lin, Jianjian; Malgras, Victor
- Nano Energy, Vol. 11
From Allergens to Battery Anodes: Nature-Inspired, Pollen Derived Carbon Architectures for Room- and Elevated- Temperature Li-ion Storage
journal, February 2016
- Tang, Jialiang; Etacheri, Vinodkumar; Pol, Vilas G.
- Scientific Reports, Vol. 6, Issue 1
Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors
journal, January 2013
- Qie, Long; Chen, Weimin; Xu, Henghui
- Energy & Environmental Science, Vol. 6, Issue 8
A reversible Br 2 /Br − redox couple in the aqueous phase as a high-performance catholyte for alkali-ion batteries
journal, January 2014
- Zhao, Yu; Ding, Yu; Song, Jie
- Energy Environ. Sci., Vol. 7, Issue 6
From Industrially Weavable and Knittable Highly Conductive Yarns to Large Wearable Energy Storage Textiles
journal, April 2015
- Huang, Yan; Hu, Hong; Huang, Yang
- ACS Nano, Vol. 9, Issue 5
An efficient preparation of N-doped mesoporous carbon derived from milk powder for supercapacitors and fuel cells
journal, April 2016
- Jia, Shaopei; Wang, Yanhui; Xin, Guoxiang
- Electrochimica Acta, Vol. 196
KOH Activation of Needle Coke to Develop Activated Carbons for High-Performance EDLC
journal, July 2006
- Qiao, Wenming; Yoon, Seong-Ho; Mochida, Isao
- Energy & Fuels, Vol. 20, Issue 4
High Rate Electrochemical Capacitors from Three-Dimensional Arrays of Vanadium Nitride Functionalized Carbon Nanotubes
journal, November 2011
- Zhang, Li; Holt, Chris M. B.; Luber, Erik J.
- The Journal of Physical Chemistry C, Vol. 115, Issue 49
High Hydrogen Storage Capacity of Porous Carbons Prepared by Using Activated Carbon
journal, May 2009
- Wang, Huanlei; Gao, Qiuming; Hu, Juan
- Journal of the American Chemical Society, Vol. 131, Issue 20
Heteroatom enhanced sodium ion capacity and rate capability in a hydrogel derived carbon give record performance in a hybrid ion capacitor
journal, May 2016
- Ding, Jia; Li, Zhi; Cui, Kai
- Nano Energy, Vol. 23
Supercapacitors Performance Evaluation
journal, December 2014
- Zhang, Sanliang; Pan, Ning
- Advanced Energy Materials, Vol. 5, Issue 6
Construction of Complex CoS Hollow Structures with Enhanced Electrochemical Properties for Hybrid Supercapacitors
journal, July 2016
- Hu, Han; Guan, Bu Yuan; Lou, Xiong Wen (David)
- Chem, Vol. 1, Issue 1
Advanced Materials for Energy Storage
journal, February 2010
- Liu, Chang; Li, Feng; Ma, Lai-Peng
- Advanced Materials, Vol. 22, Issue 8
Construction of High-Capacitance 3D CoO@Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor
journal, April 2013
- Zhou, Cheng; Zhang, Yangwei; Li, Yuanyuan
- Nano Letters, Vol. 13, Issue 5
Surfactant-Free Assembly of Mesoporous Carbon Hollow Spheres with Large Tunable Pore Sizes
journal, April 2016
- Zhang, Hongwei; Noonan, Owen; Huang, Xiaodan
- ACS Nano, Vol. 10, Issue 4
Supercapacitive carbon nanotube-cobalt molybdate nanocomposites prepared via solvent-free microwave synthesis
journal, January 2012
- Xu, Zhanwei; Li, Zhi; Tan, Xuehai
- RSC Advances, Vol. 2, Issue 7
Scalable fabrication of MnO 2 nanostructure deposited on free-standing Ni nanocone arrays for ultrathin, flexible, high-performance micro-supercapacitor
journal, January 2014
- Su, Zijin; Yang, Cheng; Xie, Binghe
- Energy Environ. Sci., Vol. 7, Issue 8
KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organisation
journal, January 2005
- Raymundo-Piñero, E.; Azaïs, P.; Cacciaguerra, T.
- Carbon, Vol. 43, Issue 4
Carbonized Chicken Eggshell Membranes with 3D Architectures as High-Performance Electrode Materials for Supercapacitors
journal, March 2012
- Li, Zhi; Zhang, Li; Amirkhiz, Babak Shalchi
- Advanced Energy Materials, Vol. 2, Issue 4
Pseudocapacitance and excellent cyclability of 2,5-dimethoxy-1,4-benzoquinone on graphene
journal, January 2016
- Boota, Muhammad; Chen, Chi; Bécuwe, Matthieu
- Energy & Environmental Science, Vol. 9, Issue 8
Functionalized graphene aerogel composites for high-performance asymmetric supercapacitors
journal, January 2015
- Yu, Zenan; McInnis, Matthew; Calderon, Jean
- Nano Energy, Vol. 11
Maximizing the Value of Milk Through Separation Technologies
journal, October 1999
- Huffman, Lee M.; James Harper, W.
- Journal of Dairy Science, Vol. 82, Issue 10
Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials
journal, March 2015
- Acerce, Muharrem; Voiry, Damien; Chhowalla, Manish
- Nature Nanotechnology, Vol. 10, Issue 4
Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
journal, January 2015
- Ding, Jia; Wang, Huanlei; Li, Zhi
- Energy & Environmental Science, Vol. 8, Issue 3, p. 941-955
KOH activation of carbon-based materials for energy storage
journal, January 2012
- Wang, Jiacheng; Kaskel, Stefan
- Journal of Materials Chemistry, Vol. 22, Issue 45
Supercapacitive Properties of Hydrothermally Synthesized Co 3 O 4 Nanostructures
journal, August 2011
- Wang, Huatao; Zhang, Li; Tan, Xuehai
- The Journal of Physical Chemistry C, Vol. 115, Issue 35
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014
- Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
- Energy & Environmental Science, Vol. 7, Issue 5
Flexible Asymmetric Supercapacitors Based upon Co 9 S 8 Nanorod//Co 3 O 4 @RuO 2 Nanosheet Arrays on Carbon Cloth
journal, May 2013
- Xu, Jing; Wang, Qiufan; Wang, Xiaowei
- ACS Nano, Vol. 7, Issue 6
Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation
journal, April 2010
- Liou, Tzong-Horng
- Chemical Engineering Journal, Vol. 158, Issue 2
Multifunctional g-C 3 N 4 Nanofibers: A Template-Free Fabrication and Enhanced Optical, Electrochemical, and Photocatalyst Properties
journal, December 2013
- Tahir, Muhammad; Cao, Chuanbao; Mahmood, Nasir
- ACS Applied Materials & Interfaces, Vol. 6, Issue 2
Carbon activation with KOH as explored by temperature programmed techniques, and the effects of hydrogen
journal, November 2007
- Lozano-Castelló, D.; Calo, J. M.; Cazorla-Amorós, D.
- Carbon, Vol. 45, Issue 13
Bacterial-Cellulose-Derived Carbon Nanofiber@MnO 2 and Nitrogen-Doped Carbon Nanofiber Electrode Materials: An Asymmetric Supercapacitor with High Energy and Power Density
journal, May 2013
- Chen, Li-Feng; Huang, Zhi-Hong; Liang, Hai-Wei
- Advanced Materials, Vol. 25, Issue 34
Self-Assembled Graphene/Carbon Nanotube Hybrid Films for Supercapacitors
journal, December 2009
- Yu, Dingshan; Dai, Liming
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 2
Nitrogen-doped Porous Carbon Derived from Rapeseed residues for High-performance Supercapacitors
journal, June 2016
- Sun, Kanjun
- International Journal of Electrochemical Science
Synthesis of porous graphene/activated carbon composite with high packing density and large specific surface area for supercapacitor electrode material
journal, July 2014
- Zheng, Chao; Zhou, Xufeng; Cao, Hailiang
- Journal of Power Sources, Vol. 258
Three-Dimensional Graphene-Based Macro- and Mesoporous Frameworks for High-Performance Electrochemical Capacitive Energy Storage
journal, November 2012
- Wu, Zhong-Shuai; Sun, Yi; Tan, Yuan-Zhi
- Journal of the American Chemical Society, Vol. 134, Issue 48
Nitrogen-Doped Porous Carbon Superstructures Derived from Hierarchical Assembly of Polyimide Nanosheets
journal, January 2016
- Xu, Zhixiao; Zhuang, Xiaodong; Yang, Chongqing
- Advanced Materials, Vol. 28, Issue 10
Porous Structure of Activated Carbon Prepared from Cherry Stones by Chemical Activation with Phosphoric Acid
journal, September 2007
- Olivares-Marín, M.; Fernández-González, C.; Macías-García, A.
- Energy & Fuels, Vol. 21, Issue 5
High-Performance One-Body Core/Shell Nanowire Supercapacitor Enabled by Conformal Growth of Capacitive 2D WS 2 Layers
journal, October 2016
- Choudhary, Nitin; Li, Chao; Chung, Hee-Suk
- ACS Nano, Vol. 10, Issue 12
Graphene with three-dimensional architecture for high performance supercapacitor
journal, February 2014
- Hu, Juan; Kang, Zhuang; Li, Fei
- Carbon, Vol. 67
In-situ Molten Salt Template Strategy for Hierarchical 3D Porous Carbon from Palm Shells as Advanced Electrochemical Supercapacitors
journal, July 2016
- Ma , Jing; Dong , You-zhen; Wang, Lei
- ChemistrySelect, Vol. 1, Issue 10
Far-infrared reduced graphene oxide as high performance electrodes for supercapacitors
journal, August 2014
- Xiang, Feng; Zhong, Jing; Gu, Ningyu
- Carbon, Vol. 75
Shape-controlled porous nanocarbons for high performance supercapacitors
journal, January 2014
- Chen, Wei; Rakhi, R. B.; Hedhili, M. N.
- Journal of Materials Chemistry A, Vol. 2, Issue 15
High energy density supercapacitors from lignin derived submicron activated carbon fibers in aqueous electrolytes
journal, December 2014
- Hu, Sixiao; Zhang, Sanliang; Pan, Ning
- Journal of Power Sources, Vol. 270
Sustainable Low-Cost Green Electrodes with High Volumetric Capacitance for Aqueous Symmetric Supercapacitors with High Energy Density
journal, December 2015
- Xie, Qinxing; Bao, Rongrong; Zheng, Anran
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 3
Exceptional energy and new insight with a sodium–selenium battery based on a carbon nanosheet cathode and a pseudographite anode
journal, January 2017
- Ding, Jia; Zhou, Hui; Zhang, Hanlei
- Energy & Environmental Science, Vol. 10, Issue 1
Porous carbon with high capacitance and graphitization through controlled addition and removal of sulfur-containing compounds
journal, March 2015
- Zhou, Yao; Candelaria, Stephanie L.; Liu, Qian
- Nano Energy, Vol. 12
Tunable, Functional Carbon Spheres Derived from Rapid Synthesis of Resorcinol-Formaldehyde Resins
journal, June 2014
- Pol, Vilas G.; Shrestha, Lok Kumar; Ariga, Katsuhiko
- ACS Applied Materials & Interfaces, Vol. 6, Issue 13
Nanoporous carbons through direct carbonization of a zeolitic imidazolate framework for supercapacitor electrodes
journal, January 2012
- Chaikittisilp, Watcharop; Hu, Ming; Wang, Hongjing
- Chemical Communications, Vol. 48, Issue 58
Elemental superdoping of graphene and carbon nanotubes
journal, March 2016
- Liu, Yuan; Shen, Yuting; Sun, Litao
- Nature Communications, Vol. 7, Issue 1
3D carbon based nanostructures for advanced supercapacitors
journal, January 2013
- Jiang, Hao; Lee, Pooi See; Li, Chunzhong
- Energy Environ. Sci., Vol. 6, Issue 1
Generation of B-Doped Graphene Nanoplatelets Using a Solution Process and Their Supercapacitor Applications
journal, December 2012
- Han, Jongwoo; Zhang, Li Li; Lee, Seungjun
- ACS Nano, Vol. 7, Issue 1
A new Guinier–Porod model
journal, May 2010
- Hammouda, Boualem
- Journal of Applied Crystallography, Vol. 43, Issue 4
Studies and characterisations of various activated carbons used for carbon/carbon supercapacitors
journal, October 2001
- Gamby, J.; Taberna, P. L.; Simon, P.
- Journal of Power Sources, Vol. 101, Issue 1
Self-supported formation of hierarchical NiCo 2 O 4 tetragonal microtubes with enhanced electrochemical properties
journal, January 2016
- Ma, Fei-Xiang; Yu, Le; Xu, Cheng-Yan
- Energy & Environmental Science, Vol. 9, Issue 3
Centrifugal dewatering of acid casein curd: Effect of casein manufacturing and centrifugation variables on curd compression in a laboratory centrifuge
journal, October 1988
- Munro, P. A.; Van Til, H. J.
- Biotechnology and Bioengineering, Vol. 32, Issue 9
Template-Assisted Low Temperature Synthesis of Functionalized Graphene for Ultrahigh Volumetric Performance Supercapacitors
journal, April 2014
- Yan, Jun; Wang, Qian; Wei, Tong
- ACS Nano, Vol. 8, Issue 5
High-performance flexible asymmetric supercapacitors based on a new graphene foam/carbon nanotube hybrid film
journal, January 2014
- Liu, Jilei; Zhang, Lili; Wu, Hao Bin
- Energy Environ. Sci., Vol. 7, Issue 11
Design and synthesis of NiCo2O4–reduced graphene oxide composites for high performance supercapacitors
journal, January 2011
- Wang, Huan-Wen; Hu, Zhong-Ai; Chang, Yan-Qin
- Journal of Materials Chemistry, Vol. 21, Issue 28
Carbon-Based Supercapacitors Produced by Activation of Graphene
journal, May 2011
- Zhu, Y.; Murali, S.; Stoller, M. D.
- Science, Vol. 332, Issue 6037, p. 1537-1541
Carbon materials for the electrochemical storage of energy in capacitors
journal, May 2001
- Frackowiak, Elzbieta; Béguin, François
- Carbon, Vol. 39, Issue 6, p. 937-950
Physiology of Mastitis and Factors Affecting Somatic Cell Counts
journal, July 1994
- Harmon, R. J.
- Journal of Dairy Science, Vol. 77, Issue 7
Ultrahigh Surface Area Three-Dimensional Porous Graphitic Carbon from Conjugated Polymeric Molecular Framework
journal, May 2015
- To, John W. F.; Chen, Zheng; Yao, Hongbin
- ACS Central Science, Vol. 1, Issue 2
Activated Graphene-Based Carbons as Supercapacitor Electrodes with Macro- and Mesopores
journal, July 2013
- Kim, TaeYoung; Jung, Gyujin; Yoo, Seonmi
- ACS Nano, Vol. 7, Issue 8
Preparation of Highly Conductive Graphene Hydrogels for Fabricating Supercapacitors with High Rate Capability
journal, August 2011
- Zhang, Li; Shi, Gaoquan
- The Journal of Physical Chemistry C, Vol. 115, Issue 34
Crumpled Nitrogen-Doped Graphene Nanosheets with Ultrahigh Pore Volume for High-Performance Supercapacitor
journal, August 2012
- Wen, Zhenhai; Wang, Xinchen; Mao, Shun
- Advanced Materials, Vol. 24, Issue 41
Graphene-nickel cobaltite nanocomposite asymmetrical supercapacitor with commercial level mass loading
journal, August 2012
- Wang, Huanlei; Holt, Chris M. B.; Li, Zhi
- Nano Research, Vol. 5, Issue 9
Bio-inspired beehive-like hierarchical nanoporous carbon derived from bamboo-based industrial by-product as a high performance supercapacitor electrode material
journal, January 2015
- Tian, Weiqian; Gao, Qiuming; Tan, Yanli
- Journal of Materials Chemistry A, Vol. 3, Issue 10
Synthesis of Nitrogen-Doped Porous Carbon Nanofibers as an Efficient Electrode Material for Supercapacitors
journal, July 2012
- Chen, Li-Feng; Zhang, Xu-Dong; Liang, Hai-Wei
- ACS Nano, Vol. 6, Issue 8
A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage
journal, January 2015
- Zhao, Yu; Ding, Yu; Li, Yutao
- Chemical Society Reviews, Vol. 44, Issue 22
Graphene-based materials for high-voltage and high-energy asymmetric supercapacitors
journal, January 2017
- Zheng, Shuanghao; Wu, Zhong-Shuai; Wang, Sen
- Energy Storage Materials, Vol. 6
Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors
journal, February 2014
- Wang, Qian; Yan, Jun; Wang, Yanbo
- Carbon, Vol. 67
Nitrogen-Doped Carbon Networks for High Energy Density Supercapacitors Derived from Polyaniline Coated Bacterial Cellulose
journal, March 2014
- Long, Conglai; Qi, Dongping; Wei, Tong
- Advanced Functional Materials, Vol. 24, Issue 25
Hierarchical MnMoO4/CoMoO4 heterostructured nanowires with enhanced supercapacitor performance
journal, July 2011
- Mai, Li-Qiang; Yang, Fan; Zhao, Yun-Long
- Nature Communications, Vol. 2, Issue 1
Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage
journal, December 2015
- Lin, T.; Chen, I. -W.; Liu, F.
- Science, Vol. 350, Issue 6267
Enhanced electrochemical performance of ordered mesoporous carbons by a one-step carbonization/activation treatment
journal, December 2015
- Lin, Gaoxin; Wang, Fan; Wang, Yiliang
- Journal of Electroanalytical Chemistry, Vol. 758
Capacitive Energy Storage from −50 to 100 °C Using an Ionic Liquid Electrolyte
journal, September 2011
- Lin, Rongying; Taberna, Pierre-Louis; Fantini, Sébastien
- The Journal of Physical Chemistry Letters, Vol. 2, Issue 19
From dead leaves to high energy density supercapacitors
journal, January 2013
- Biswal, Mandakini; Banerjee, Abhik; Deo, Meenal
- Energy & Environmental Science, Vol. 6, Issue 4, p. 1249-1259
Colossal pseudocapacitance in a high functionality–high surface area carbon anode doubles the energy of an asymmetric supercapacitor
journal, January 2014
- Li, Zhi; Xu, Zhanwei; Wang, Huanlei
- Energy Environ. Sci., Vol. 7, Issue 5
Gastronomic cosmopolitanism: Supermarket products in France and the United Kingdom
journal, June 2016
- Maxwell, Rahsaan; DeSoucey, Michaela
- Poetics, Vol. 56
Works referencing / citing this record:
Hybrid Graphene Ribbon/Carbon Electrodes for High‐Performance Energy Storage
journal, October 2018
- Farquhar, Anna K.; Supur, Mustafa; Smith, Scott R.
- Advanced Energy Materials, Vol. 8, Issue 35
Ethane-selective carbon composites CPDA@A-ACs with high uptake and its enhanced ethane/ethylene adsorption selectivity
journal, April 2018
- Liang, Wanwen; Wu, Ying; Xiao, Huiyu
- AIChE Journal, Vol. 64, Issue 9
Mesoporous Carbons Templated by PEO‐PCL Block Copolymers as Electrode Materials for Supercapacitors
journal, July 2019
- Li, Jheng‐Guang; Ho, Ya‐Fan; Ahmed, Mahmoud M. M.
- Chemistry – A European Journal, Vol. 25, Issue 44
Improved capacity of redox-active functional carbon cathodes by dimension reduction for hybrid supercapacitors
journal, January 2018
- Liu, Tianyuan; Lee, Byeongyong; Lee, Michael J.
- Journal of Materials Chemistry A, Vol. 6, Issue 8
Unravelling the role of temperature in a redox supercapacitor composed of multifarious nanoporous carbon@hydroquinone
journal, January 2020
- Barua, Aditi; Paul, Amit
- RSC Advances, Vol. 10, Issue 3
CH 4 /N 2 Adsorptive Separation on Zeolite X/AC Composites
journal, January 2019
- Xue, Cai Long; Cheng, Wen Ping; Hao, Wen Ming
- Journal of Chemistry, Vol. 2019
One-Pot Synthesis of CuS Nanoflower-Decorated Active Carbon Layer for High-Performance Asymmetric Supercapacitors
journal, June 2018
- Wang, Guoxiang; Zhang, Mingyuan; Lu, Lu
- ChemNanoMat, Vol. 4, Issue 9
Casein‐Derived Activated Carbon: Turning Expired Milk into Active Material for Electrochemical Capacitors
journal, December 2019
- Schütter, Christoph; Varzi, Alberto; Lodovico, Lucas
- Energy Technology, Vol. 8, Issue 3