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Title: Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions

Abstract

Here, iron-incorporated nickel-based materials show promise as catalysts for the oxygen evolution reac-tion (OER) half-reaction of water electrolysis. Nickel has also exhibited high catalytic activity for methanol oxidation, particularly when in the form of a bimetallic catalyst. In this work, bimetallic iron-nickel nanoparticles were synthesized using a multi-step procedure in water under ambient conditions. When compared to monometallic iron and nickel nanoparticles, Fe-Ni nanoparticles show enhanced catalytic activity for both OER and methanol oxidation under alkaline conditions. At 1 mA/cm2, the overpotential for monometallic iron and nickel nanoparticles was 421 mV and 476 mV, respectively, while the bimetallic Fe-Ni nanoparticles had a greatly reduced overpotential of 256 mV. At 10 mA/cm2, bimetallic Fe-Ni nanoparticles had an overpotential of 311 mV. Spec-troscopy characterization suggests that the primary phase of nickel in Fe-Ni nanoparticles is the more disordered alpha phase of nickel hydroxide.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3];  [2];  [4];  [4];  [4];  [5];  [5];  [6];  [3]; ORCiD logo [3]; ORCiD logo [7]
+ Show Author Affiliations
  1. National Institute of Standard and Technology, Boulder, CO (United States)
  2. Univ. of Notre Dame, Notre Dame, IN (United States)
  3. Colorado School of Mines, Golden, CO (United States)
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
  5. Univ. of Massachusetts, Amherst, MA (United States)
  6. Colorado School of Mines, Golden, CO (United States); Northwestern Univ., Evanston, IL (United States)
  7. National Institute of Standard and Technology, Boulder, CO (United States); Univ. of Arkansas, Fayetteville, AR (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Institute of Standards and Technology (NIST); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); U.S. Army Research Laboratory, U.S. Army Research Office (ARO)
OSTI Identifier:
1363813
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; alcohol oxidation; core-shell nanoparticles; electrocatalyst; fuel cell; non-precious metal; oxygen evolution reaction

Citation Formats

Candelaria, Stephanie L., Bedford, Nicholas M., Woehl, Taylor J., Rentz, Nikki S., Showalter, Allison R., Pylypenko, Svitlana, Bunker, Bruce A., Lee, Sungsik, Reinhart, Benjamin, Ren, Yang, Ertem, S. Piril, Coughlin, E. Bryan, Sather, Nicholas A., Horan, James L., Herring, Andrew M., and Greenlee, Lauren F. Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions. United States: N. p., 2016. Web. doi:10.1021/acscatal.6b02552.
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Candelaria, Stephanie L., Bedford, Nicholas M., Woehl, Taylor J., Rentz, Nikki S., Showalter, Allison R., Pylypenko, Svitlana, Bunker, Bruce A., Lee, Sungsik, Reinhart, Benjamin, Ren, Yang, Ertem, S. Piril, Coughlin, E. Bryan, Sather, Nicholas A., Horan, James L., Herring, Andrew M., & Greenlee, Lauren F. Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions. United States. https://doi.org/10.1021/acscatal.6b02552
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Candelaria, Stephanie L., Bedford, Nicholas M., Woehl, Taylor J., Rentz, Nikki S., Showalter, Allison R., Pylypenko, Svitlana, Bunker, Bruce A., Lee, Sungsik, Reinhart, Benjamin, Ren, Yang, Ertem, S. Piril, Coughlin, E. Bryan, Sather, Nicholas A., Horan, James L., Herring, Andrew M., and Greenlee, Lauren F. Tue . "Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions". United States. https://doi.org/10.1021/acscatal.6b02552. https://www.osti.gov/servlets/purl/1363813.
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@article{osti_1363813,
title = {Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions},
author = {Candelaria, Stephanie L. and Bedford, Nicholas M. and Woehl, Taylor J. and Rentz, Nikki S. and Showalter, Allison R. and Pylypenko, Svitlana and Bunker, Bruce A. and Lee, Sungsik and Reinhart, Benjamin and Ren, Yang and Ertem, S. Piril and Coughlin, E. Bryan and Sather, Nicholas A. and Horan, James L. and Herring, Andrew M. and Greenlee, Lauren F.},
abstractNote = {Here, iron-incorporated nickel-based materials show promise as catalysts for the oxygen evolution reac-tion (OER) half-reaction of water electrolysis. Nickel has also exhibited high catalytic activity for methanol oxidation, particularly when in the form of a bimetallic catalyst. In this work, bimetallic iron-nickel nanoparticles were synthesized using a multi-step procedure in water under ambient conditions. When compared to monometallic iron and nickel nanoparticles, Fe-Ni nanoparticles show enhanced catalytic activity for both OER and methanol oxidation under alkaline conditions. At 1 mA/cm2, the overpotential for monometallic iron and nickel nanoparticles was 421 mV and 476 mV, respectively, while the bimetallic Fe-Ni nanoparticles had a greatly reduced overpotential of 256 mV. At 10 mA/cm2, bimetallic Fe-Ni nanoparticles had an overpotential of 311 mV. Spec-troscopy characterization suggests that the primary phase of nickel in Fe-Ni nanoparticles is the more disordered alpha phase of nickel hydroxide.},
doi = {10.1021/acscatal.6b02552},
journal = {ACS Catalysis},
number = 1,
volume = 7,
place = {United States},
year = {Tue Nov 29 00:00:00 EST 2016},
month = {Tue Nov 29 00:00:00 EST 2016}
}
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    journal, January 2018

    • Kim, Ju Seong; Kim, Byunghoon; Kim, Hyunah
    • Advanced Energy Materials, Vol. 8, Issue 11
    • DOI: 10.1002/aenm.201702774

    Ultralow Fe III Ion Doping Triggered Generation of Ni 3 S 2 Ultrathin Nanosheet for Enhanced Oxygen Evolution Reaction
    journal, March 2019

    Highly Active Ternary Nickel–Iron oxide as Bifunctional Catalyst for Electrochemical Water Splitting
    journal, July 2019

    • Dalai, Namita; Mohanty, Bishnupad; Mitra, Arijit
    • ChemistrySelect, Vol. 4, Issue 27
    • DOI: 10.1002/slct.201901465

    Facile fabrication of bimetallic Cu–Ag binary hybrid nanoparticles and their application in catalysis
    journal, January 2019

    • Meng, Yuxi; Gao, Hanyu; Li, Shuang
    • New Journal of Chemistry, Vol. 43, Issue 17
    • DOI: 10.1039/c9nj00816k

    Colloidal Ni–Co–Sn nanoparticles as efficient electrocatalysts for the methanol oxidation reaction
    journal, January 2018

    • Li, Junshan; Luo, Zhishan; He, Feng
    • Journal of Materials Chemistry A, Vol. 6, Issue 45
    • DOI: 10.1039/c8ta08242a

    Bifunctional CoNi/CoFe 2 O 4 /Ni foam electrodes for efficient overall water splitting at a high current density
    journal, January 2018

    • Li, Shasha; Sirisomboonchai, Suchada; Yoshida, Akihiro
    • Journal of Materials Chemistry A, Vol. 6, Issue 39
    • DOI: 10.1039/c8ta08223e

    Effects of Incorporated Iron or Cobalt on the Ethanol Oxidation Activity of Nickel (Oxy)Hydroxides in Alkaline Media
    journal, April 2019

    A facile, one-step electroless deposition of NiFeOOH nanosheets onto photoanodes for highly durable and efficient solar water oxidation
    journal, January 2018

    • Suryawanshi, Mahesh P.; Shin, Seung Wook; Ghorpade, Uma V.
    • Journal of Materials Chemistry A, Vol. 6, Issue 42
    • DOI: 10.1039/c8ta07343k

    Ultrathin Two-Dimensional Nanostructured Materials for Highly Efficient Water Oxidation
    journal, June 2017

    Ultrathin trimetallic metal–organic framework nanosheets for highly efficient oxygen evolution reaction
    journal, January 2019

    • Ding, Mengmeng; Chen, Jing; Jiang, Meiwen
    • Journal of Materials Chemistry A, Vol. 7, Issue 23
    • DOI: 10.1039/c9ta00708c

    Synergistic Supports Beyond Carbon Black for Polymer Electrolyte Fuel Cell Anodes
    journal, September 2018

    Chemical Structure of Fe–Ni Nanoparticles for Efficient Oxygen Evolution Reaction Electrocatalysis
    journal, October 2019

    Rapid Synthesis and Correlative Measurements of Electrocatalytic Nickel/Iron Oxide Nanoparticles
    journal, March 2018

    • Jeerage, Kavita M.; Candelaria, Stephanie L.; Stavis, Samuel M.
    • Scientific Reports, Vol. 8, Issue 1
    • DOI: 10.1038/s41598-018-22609-x
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