Orientation-resolved domain mapping in tetragonal SrTiO3 using polarized Raman spectroscopy

Gray, Jr., Dodd J.; Merz, Tyler A.; Hikita, Yasuyuki; Hwang, Harold Y.; Mabuchi, Hideo

doi:10.1103/PhysRevB.94.214107

Title: Orientation-resolved domain mapping in tetragonal ${SrTiO}_{3}$ using polarized Raman spectroscopy

Abstract

Here, we present microscopically resolved, polarized spectroscopy of Raman scattering collected from tetragonal SrTiO₃. The anisotropic response of first-order Raman peaks within a single tetragonal domain has been measured. From these data, we assign symmetries to the phonons seen in the first-order Raman spectrum which is normally complicated by uncontrolled domain structure. Using a translation stage, we map the local domain orientation of a 3–μm³ crystal volume near the laser focus and compare it to wide-field polarized images. This technique can be performed with readily available instruments and is relevant to the study of a wide range of related materials, interfaces, and devices.

Authors:

Gray, Jr., Dodd J. ^[1]; Merz, Tyler A. ^[1]; Hikita, Yasuyuki ^[2]; Hwang, Harold Y. ^[3]; Mabuchi, Hideo ^[1]

Stanford Univ., Stanford, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Publication Date:: Fri Dec 16 00:00:00 EST 2016

Research Org.:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1361076

Alternate Identifier(s):: OSTI ID: 1336852

Grant/Contract Number:: N66001-11-1-4106; AC02-76SF00515; DGE-114747

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 94; Journal Issue: 21; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Gray, Jr., Dodd J., Merz, Tyler A., Hikita, Yasuyuki, Hwang, Harold Y., and Mabuchi, Hideo. Orientation-resolved domain mapping in tetragonal SrTiO3 using polarized Raman spectroscopy.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.94.214107.

Copy to clipboard


                    Gray, Jr., Dodd J., Merz, Tyler A., Hikita, Yasuyuki, Hwang, Harold Y., & Mabuchi, Hideo. Orientation-resolved domain mapping in tetragonal SrTiO3 using polarized Raman spectroscopy.  United States.  https://doi.org/10.1103/PhysRevB.94.214107

Copy to clipboard


                    Gray, Jr., Dodd J., Merz, Tyler A., Hikita, Yasuyuki, Hwang, Harold Y., and Mabuchi, Hideo. Fri .  
"Orientation-resolved domain mapping in tetragonal SrTiO3 using polarized Raman spectroscopy".  United States.  https://doi.org/10.1103/PhysRevB.94.214107.  https://www.osti.gov/servlets/purl/1361076.

Copy to clipboard


                    
@article{osti_1361076,

  title        = {Orientation-resolved domain mapping in tetragonal SrTiO3 using polarized Raman spectroscopy},

  author       = {Gray, Jr., Dodd J. and Merz, Tyler A. and Hikita, Yasuyuki and Hwang, Harold Y. and Mabuchi, Hideo},

  abstractNote = {Here, we present microscopically resolved, polarized spectroscopy of Raman scattering collected from tetragonal SrTiO3. The anisotropic response of first-order Raman peaks within a single tetragonal domain has been measured. From these data, we assign symmetries to the phonons seen in the first-order Raman spectrum which is normally complicated by uncontrolled domain structure. Using a translation stage, we map the local domain orientation of a 3–μm3 crystal volume near the laser focus and compare it to wide-field polarized images. This technique can be performed with readily available instruments and is relevant to the study of a wide range of related materials, interfaces, and devices.},

  doi          = {10.1103/PhysRevB.94.214107},

  journal      = {Physical Review B},

  number       = 21,

  volume       = 94,

  place        = {United States},

  year         = {Fri Dec 16 00:00:00 EST 2016},

  month        = {Fri Dec 16 00:00:00 EST 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevB.94.214107

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 7 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Local electrostatic imaging of striped domain order in LaAlO3/SrTiO3
journal, November 2013

Honig, M.; Sulpizio, J. A.; Drori, J.
Nature Materials, Vol. 12, Issue 12
DOI: 10.1038/nmat3810

Scanning Probe Manipulation of Magnetism at the LaAlO ₃ /SrTiO ₃ Heterointerface
journal, July 2012

Kalisky, Beena; Bert, Julie A.; Bell, Christopher
Nano Letters, Vol. 12, Issue 8
DOI: 10.1021/nl301451e

Birefringence of SrTiO ₃ at the ferroelastic phase transition
journal, May 2004

Geday, M. A.; Glazer, A. M.
Journal of Physics: Condensed Matter, Vol. 16, Issue 20
DOI: 10.1088/0953-8984/16/20/001

Locally enhanced conductivity due to the tetragonal domain structure in LaAlO3/SrTiO3 heterointerfaces
journal, September 2013

Kalisky, Beena; Spanton, Eric M.; Noad, Hilary
Nature Materials, Vol. 12, Issue 12
DOI: 10.1038/nmat3753

Depth resolved domain mapping in tetragonal SrTiO3 by micro-Laue diffraction
journal, May 2016

Merz, T. A.; Noad, H.; Xu, R.
Applied Physics Letters, Vol. 108, Issue 18
DOI: 10.1063/1.4948351

Dielectric, infrared, and Raman response of undoped ${SrTiO}_{3}$ ceramics: Evidence of polar grain boundaries
journal, October 2001

Petzelt, J.; Ostapchuk, T.; Gregora, I.
Physical Review B, Vol. 64, Issue 18
DOI: 10.1103/PhysRevB.64.184111

Raman study of oxygen reduced and re-oxidized strontium titanate
journal, July 2007

Tenne, D. A.; Gonenli, I. E.; Soukiassian, A.
Physical Review B, Vol. 76, Issue 2
DOI: 10.1103/PhysRevB.76.024303

First‐ and Second‐Order Raman Scattering of SrTiO ₃
journal, April 1967

Schaufele, R. F.; Weber, M. J.
The Journal of Chemical Physics, Vol. 46, Issue 7
DOI: 10.1063/1.1841140

Influence of electric field and domain structure on the low-temperature Raman spectra of SrTiO ₃
journal, December 2014

Gibhardt, H.; Leist, J.; Eckold, G.
Materials Research Express, Vol. 2, Issue 1
DOI: 10.1088/2053-1591/2/1/015005

Domain-wall orientations in ferroelastics
journal, December 1975

Sapriel, J.
Physical Review B, Vol. 12, Issue 11
DOI: 10.1103/PhysRevB.12.5128

Interface Physics in Complex Oxide Heterostructures
journal, March 2011

Zubko, Pavlo; Gariglio, Stefano; Gabay, Marc
Annual Review of Condensed Matter Physics, Vol. 2, Issue 1
DOI: 10.1146/annurev-conmatphys-062910-140445

DIRECT OBSERVATION OF SINGLE‐DOMAIN SrTiO ₃
journal, September 1970

Chang, T. S.; Holzrichter, J. F.; Imbusch, G. F.
Applied Physics Letters, Vol. 17, Issue 6
DOI: 10.1063/1.1653388

Bilbao Crystallographic Server: I. Databases and crystallographic computing programs
journal, January 2006

Aroyo, Mois Ilia; Perez-Mato, Juan Manuel; Capillas, Cesar
Zeitschrift für Kristallographie - Crystalline Materials, Vol. 221, Issue 1
DOI: 10.1524/zkri.2006.221.1.15

Monodomain strontium titanate
journal, April 1970

Müller, K. A.; Berlinger, W.; Capizzi, M.
Solid State Communications, Vol. 8, Issue 7
DOI: 10.1016/0038-1098(70)90302-9

Dielectric Properties of Strontium Titanate at Low Temperature
journal, August 1970

Saifi, M. A.; Cross, L. E.
Physical Review B, Vol. 2, Issue 3
DOI: 10.1103/PhysRevB.2.677

Normal mode determination of perovskite crystal structures with octahedral rotations: theory and applications
journal, April 2013

Islam, Mohammad A.; Rondinelli, James M.; Spanier, Jonathan E.
Journal of Physics: Condensed Matter, Vol. 25, Issue 17
DOI: 10.1088/0953-8984/25/17/175902

Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups
journal, March 2006

Aroyo, Mois I.; Kirov, Asen; Capillas, Cesar
Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 2
DOI: 10.1107/S0108767305040286

Variation in superconducting transition temperature due to tetragonal domains in two-dimensionally doped ${SrTiO}_{3}$
journal, November 2016

Noad, Hilary; Spanton, Eric M.; Nowack, Katja C.
Physical Review B, Vol. 94, Issue 17
DOI: 10.1103/PhysRevB.94.174516

The classification of tilted octahedra in perovskites
journal, November 1972

Glazer, A. M.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11
DOI: 10.1107/S0567740872007976

Emergent phenomena at oxide interfaces
journal, January 2012

Hwang, H. Y.; Iwasa, Y.; Kawasaki, M.
Nature Materials, Vol. 11, Issue 2
DOI: 10.1038/nmat3223

Temperature Dependence of the Raman Spectrum of SrTiO ₃ and KTaO ₃
journal, September 1967

Perry, C. H.; Fertel, Jeanne H.; McNelly, T. F.
The Journal of Chemical Physics, Vol. 47, Issue 5
DOI: 10.1063/1.1712142

Ferroelectric quantum criticality
journal, March 2014

Rowley, S. E.; Spalek, L. J.; Smith, R. P.
Nature Physics, Vol. 10, Issue 5
DOI: 10.1038/nphys2924

Soft Phonon Modes and the 110°K Phase Transition in SrTi $O_{3}$
journal, July 1968

Fleury, P. A.; Scott, J. F.; Worlock, J. M.
Physical Review Letters, Vol. 21, Issue 1
DOI: 10.1103/PhysRevLett.21.16

SrTi $O_{3}$ : An intrinsic quantum paraelectric below 4 K
journal, April 1979

Müller, K. A.; Burkard, H.
Physical Review B, Vol. 19, Issue 7
DOI: 10.1103/PhysRevB.19.3593

Bilbao Crystallographic Server : Useful Databases and Tools for Phase-Transition Studies
journal, January 2003

Kroumova, E.; Aroyo, M. I.; Perez-Mato, J. M.
Phase Transitions, Vol. 76, Issue 1-2
DOI: 10.1080/0141159031000076110

A Raman scattering study of the phase transitions in SrTiO ₃ and in the mixed system (Sr _{1- x} Ca _x )TiO ₃ at ambient pressure from T = 300 K down to 8 K
journal, February 2002

Ouillon, R.; Pinan-Lucarre, J-P; Ranson, P.
Journal of Physics: Condensed Matter, Vol. 14, Issue 8
DOI: 10.1088/0953-8984/14/8/333

Phonon calculations in cubic and tetragonal phases of SrTiO $_{3}$ : A comparative LCAO and plane-wave study
journal, April 2011

Evarestov, Robert A.; Blokhin, Evgeny; Gryaznov, Denis
Physical Review B, Vol. 83, Issue 13
DOI: 10.1103/PhysRevB.83.134108

Tetragonal SrTiO3 revisited: The effect of impurities on the Raman spectrum
journal, September 1979

Taylor, W.; Murray, A. F.
Solid State Communications, Vol. 31, Issue 12
DOI: 10.1016/0038-1098(79)90005-X

Works referencing / citing this record:

Carrier density and disorder tuned superconductor-metal transition in a two-dimensional electron system
journal, October 2018

Chen, Zhuoyu; Swartz, Adrian G.; Yoon, Hyeok
Nature Communications, Vol. 9, Issue 1
DOI: 10.1038/s41467-018-06444-2

Physics of SrTiO ₃ -based heterostructures and nanostructures: a review
journal, February 2018

Pai, Yun-Yi; Tylan-Tyler, Anthony; Irvin, Patrick
Reports on Progress in Physics, Vol. 81, Issue 3
DOI: 10.1088/1361-6633/aa892d

Physics of SrTiO$_3$-based heterostructures and nanostructures: a review
text, January 2017

Pai, Yun-Yi; Tylan-Tyler, Anthony; Irvin, Patrick
arXiv
DOI: 10.48550/arxiv.1702.07690

Similar Records in DOE PAGES and OSTI.GOV collections:

Variation in superconducting transition temperature due to tetragonal domains in two-dimensionally doped ${SrTiO}_{3}$

Journal Article Noad, Hilary ; Spanton, Eric M. ; Nowack, Katja C. ; ... - Physical Review B

Strontium titanate is a low-temperature, non–Bardeen-Cooper-Schrieffer superconductor that superconducts to carrier concentrations lower than in any other system and exhibits avoided ferroelectricity at low temperatures. Neither the mechanism of superconductivity in strontium titanate nor the importance of the structure and dielectric properties for the superconductivity are well understood. We studied the effects of twin structure on superconductivity in a 5.5-nm-thick layer of niobium-doped SrTiO₃ embedded in undoped SrTiO₃. We used a scanning superconducting quantum interference device susceptometer to image the local diamagnetic response of the sample as a function of temperature. We observed regions that exhibited a superconducting transition temperaturemore »« less
Cited by 26
https://doi.org/10.1103/PhysRevB.94.174516

Full Text Available
Spatially modulated magnetic structure of EuS due to the tetragonal domain structure of ${SrTiO}_{3}$

Journal Article Rosenberg, Aaron J. ; Katmis, Ferhat ; Kirtley, John R. ; ... - Physical Review Materials

The combination of ferromagnets with topological superconductors or insulators allows for new phases of matter that support excitations such as chiral edge modes and Majorana fermions. EuS, a wide-bandgap ferromagnetic insulator with a Curie temperature around 16K, and SrTiO₃ (STO), an important substrate for engineering heterostructures, may support these phases. We present scanning superconducting quantum interference device measurements of EuS grown epitaxially on STO that reveal micron-scale variations in ferromagnetism and paramagnetism. These variations are oriented along the STO crystal axes and only change their configuration upon thermal cycling above the STO cubic-to-tetragonal structural transition temperature at 105 K, indicatingmore »« less
Cited by 3
https://doi.org/10.1103/physrevmaterials.1.074406

Full Text Available
Ferroelectricity in [111]-oriented epitaxially strained ${SrTiO}_{3}$ from first principles

Journal Article Reyes-Lillo, Sebastian E. ; Rabe, Karin M. ; Neaton, Jeffrey B. - Physical Review Materials

We use first-principles density-functional theory calculations to investigate the effect of biaxial strain in the low-temperature structural and ferroelectric properties of [111]-oriented SrTiO₃. In this work we find that [111] biaxial strain, achievable by coherent epitaxial growth along the [111] direction, induces structural distortions in SrTiO₃ that are not present in either bulk or [001]-oriented SrTiO₃. Under [111] biaxial strain, SrTiO₃ displays ferroelectricity at tensile strain, and paraelectricity at compressive strain. We compute the phonon spectrum and macroscopic polarization of SrTiO₃ as a function of [111] biaxial strain, and relate our results to the predictions of the free-energy phenomenological modelmore » of Pertsev, Tagantsev, and Setter« less
Cited by 10
https://doi.org/10.1103/PhysRevMaterials.3.030601

Full Text Available
Variation in superconducting transition temperature due to tetragonal domains in two-dimensionally doped ${SrTiO}_{3}$

Journal Article Noad, Hilary ; Spanton, Eric M. ; Nowack, Katja C. ; ... - Physical Review B

Strontium titanate is a low-temperature, non-Bardeen-Cooper-Schrieffer superconductor that superconducts to carrier concentrations lower than in any other system and exhibits avoided ferroelectricity at low temperatures. Neither the mechanism of superconductivity in strontium titanate nor the importance of the structure and dielectric properties for the superconductivity are well understood. We studied the effects of twin structure on superconductivity in a 5.5-nm-thick layer of niobium-doped SrTiO3 embedded in undoped SrTiO3. We used a scanning superconducting quantum interference device susceptometer to image the local diamagnetic response of the sample as a function of temperature. We observed regions that exhibited a superconducting transition temperaturemore »« less
https://doi.org/10.1103/PhysRevB.94.174516
Strain-induced tetragonal distortions and multiferroic properties in polycrystalline ${Sr}_{1 - x} B a_{x} Mn O_{3}$ ( $x = 0.43 - 0.45$ ) perovskites

Journal Article Somaily, H. ; Kolesnik, S. ; Mais, J. ; ... - Physical Review Materials

Here, we report a comprehensive structure-property phase diagram of unique single-ion type-1 multiferroic pseudocubic Sr_1-xBa_xMnO₃ perovskites. Employing a specially designed multi-step reduction-oxidation synthesis technique, we describe the successful synthesis of previously unknown Sr_1-xBa_xMnO₃ compositions in their polycrystalline form with a significantly extended Ba solubility limit that is only rivaled by a very limited number of crystals and thin films grown under non-equilibrium conditions. Understanding the multiferroic interplay with structure in Sr_1-xBa_xMnO₃ is of great importance as it opens the door wide to the development of newer materials from the parent (AA’)(BB’) O₃ system with enhanced properties. To this end, usingmore »« less
Cited by 6
https://doi.org/10.1103/PhysRevMaterials.2.054408

Full Text Available

Similar Records

Title: Orientation-resolved domain mapping in tetragonal SrTiO 3 using polarized Raman spectroscopy

Abstract

Citation Formats

Local electrostatic imaging of striped domain order in LaAlO3/SrTiO3 journal, November 2013

Scanning Probe Manipulation of Magnetism at the LaAlO 3 /SrTiO 3 Heterointerface journal, July 2012

Birefringence of SrTiO 3 at the ferroelastic phase transition journal, May 2004

Locally enhanced conductivity due to the tetragonal domain structure in LaAlO3/SrTiO3 heterointerfaces journal, September 2013

Depth resolved domain mapping in tetragonal SrTiO3 by micro-Laue diffraction journal, May 2016

Dielectric, infrared, and Raman response of undoped SrTiO 3 ceramics: Evidence of polar grain boundaries journal, October 2001

Raman study of oxygen reduced and re-oxidized strontium titanate journal, July 2007

First‐ and Second‐Order Raman Scattering of SrTiO 3 journal, April 1967

Influence of electric field and domain structure on the low-temperature Raman spectra of SrTiO 3 journal, December 2014

Domain-wall orientations in ferroelastics journal, December 1975

Interface Physics in Complex Oxide Heterostructures journal, March 2011

DIRECT OBSERVATION OF SINGLE‐DOMAIN SrTiO 3 journal, September 1970

Bilbao Crystallographic Server: I. Databases and crystallographic computing programs journal, January 2006

Monodomain strontium titanate journal, April 1970

Dielectric Properties of Strontium Titanate at Low Temperature journal, August 1970

Normal mode determination of perovskite crystal structures with octahedral rotations: theory and applications journal, April 2013

Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups journal, March 2006

Variation in superconducting transition temperature due to tetragonal domains in two-dimensionally doped SrTiO 3 journal, November 2016

The classification of tilted octahedra in perovskites journal, November 1972

Emergent phenomena at oxide interfaces journal, January 2012

Temperature Dependence of the Raman Spectrum of SrTiO 3 and KTaO 3 journal, September 1967

Ferroelectric quantum criticality journal, March 2014

Soft Phonon Modes and the 110°K Phase Transition in SrTi O 3 journal, July 1968

SrTi O 3 : An intrinsic quantum paraelectric below 4 K journal, April 1979

Bilbao Crystallographic Server : Useful Databases and Tools for Phase-Transition Studies journal, January 2003

A Raman scattering study of the phase transitions in SrTiO 3 and in the mixed system (Sr 1- x Ca x )TiO 3 at ambient pressure from T = 300 K down to 8 K journal, February 2002

Phonon calculations in cubic and tetragonal phases of SrTiO 3 : A comparative LCAO and plane-wave study journal, April 2011

Tetragonal SrTiO3 revisited: The effect of impurities on the Raman spectrum journal, September 1979

Carrier density and disorder tuned superconductor-metal transition in a two-dimensional electron system journal, October 2018

Physics of SrTiO 3 -based heterostructures and nanostructures: a review journal, February 2018

Physics of SrTiO$_3$-based heterostructures and nanostructures: a review text, January 2017

Title: Orientation-resolved domain mapping in tetragonal ${SrTiO}_{3}$ using polarized Raman spectroscopy

Local electrostatic imaging of striped domain order in LaAlO3/SrTiO3
journal, November 2013

Scanning Probe Manipulation of Magnetism at the LaAlO ₃ /SrTiO ₃ Heterointerface
journal, July 2012

Birefringence of SrTiO ₃ at the ferroelastic phase transition
journal, May 2004

Locally enhanced conductivity due to the tetragonal domain structure in LaAlO3/SrTiO3 heterointerfaces
journal, September 2013

Depth resolved domain mapping in tetragonal SrTiO3 by micro-Laue diffraction
journal, May 2016

Dielectric, infrared, and Raman response of undoped ${SrTiO}_{3}$ ceramics: Evidence of polar grain boundaries
journal, October 2001

Raman study of oxygen reduced and re-oxidized strontium titanate
journal, July 2007

First‐ and Second‐Order Raman Scattering of SrTiO ₃
journal, April 1967

Influence of electric field and domain structure on the low-temperature Raman spectra of SrTiO ₃
journal, December 2014

Domain-wall orientations in ferroelastics
journal, December 1975

Interface Physics in Complex Oxide Heterostructures
journal, March 2011

DIRECT OBSERVATION OF SINGLE‐DOMAIN SrTiO ₃
journal, September 1970

Bilbao Crystallographic Server: I. Databases and crystallographic computing programs
journal, January 2006

Monodomain strontium titanate
journal, April 1970

Dielectric Properties of Strontium Titanate at Low Temperature
journal, August 1970

Normal mode determination of perovskite crystal structures with octahedral rotations: theory and applications
journal, April 2013

Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups
journal, March 2006

Variation in superconducting transition temperature due to tetragonal domains in two-dimensionally doped ${SrTiO}_{3}$
journal, November 2016

The classification of tilted octahedra in perovskites
journal, November 1972

Emergent phenomena at oxide interfaces
journal, January 2012

Temperature Dependence of the Raman Spectrum of SrTiO ₃ and KTaO ₃
journal, September 1967

Ferroelectric quantum criticality
journal, March 2014

Soft Phonon Modes and the 110°K Phase Transition in SrTi $O_{3}$
journal, July 1968

SrTi $O_{3}$ : An intrinsic quantum paraelectric below 4 K
journal, April 1979

Bilbao Crystallographic Server : Useful Databases and Tools for Phase-Transition Studies
journal, January 2003

A Raman scattering study of the phase transitions in SrTiO ₃ and in the mixed system (Sr _{1- x} Ca _x )TiO ₃ at ambient pressure from T = 300 K down to 8 K
journal, February 2002

Phonon calculations in cubic and tetragonal phases of SrTiO $_{3}$ : A comparative LCAO and plane-wave study
journal, April 2011

Tetragonal SrTiO3 revisited: The effect of impurities on the Raman spectrum
journal, September 1979

Carrier density and disorder tuned superconductor-metal transition in a two-dimensional electron system
journal, October 2018

Physics of SrTiO ₃ -based heterostructures and nanostructures: a review
journal, February 2018

Physics of SrTiO$_3$-based heterostructures and nanostructures: a review
text, January 2017