Magnetic properties of the honeycomb oxide Na2Co2TeO6

Lefrançois, E.; Songvilay, M.; Robert, J.; Nataf, G.; Jordan, E.; Chaix, L.; Colin, C. V.; Lejay, P.; Hadj-Azzem, A.; Ballou, R.; Simonet, V.

doi:10.1103/PhysRevB.94.214416

Title: Magnetic properties of the honeycomb oxide ${Na}_{2} {Co}_{2} {TeO}_{6}$

Abstract

We have studied the magnetic properties of Na₂ Co₂ TeO ₆ , which features a honeycomb lattice of magnetic Co ^{2 +} ions, through macroscopic characterization and neutron diffraction on a powder sample. We also show that this material orders in a zigzag antiferromagnetic structure. Additionally by allowing a linear magnetoelectric coupling, this magnetic arrangement displays very peculiar spatial magnetic correlations, larger in the honeycomb planes than between the planes, which do not evolve with the temperature. We have investigated this behavior by classical Monte Carlo calculations using the J ₁ - J ₂ - J ₃ model on a honeycomb lattice with a small interplane interaction. Furthermore, our model reproduces the experimental neutron structure factor, although its absence of temperature evolution must be due to additional ingredients, such as chemical disorder or quantum fluctuations enhanced by the proximity to a phase boundary.

Authors:

Lefrançois, E. ^[1]; Songvilay, M. ^[2]; Robert, J. ^[1]; Nataf, G. ^[3]; Jordan, E. ^[4]; Chaix, L. ^[5]; Colin, C. V. ^[1]; Lejay, P. ^[1]; Hadj-Azzem, A. ^[1]; Ballou, R. ^[1]; Simonet, V. ^[1]

National Center For Scientific Research (CNRS), Grenoble (France). Neel Inst.; Univ. of Grenoble (France)
National Center For Scientific Research (CNRS), Grenoble (France). Neel Inst.; Univ. of Grenoble (France); Alternative Energies and Atomic Energy Commission (CEA), Saclay (France)
National Center For Scientific Research (CNRS), Grenoble (France). Neel Inst.; Univ. of Grenoble (France); Luxembourg Inst. of Science and Technology, Belvaux (Luxembourg). Materials Research and Technology Dept. ; Univ. of Paris Saclay (France)
National Center For Scientific Research (CNRS), Grenoble (France). Neel Inst.; Univ. of Grenoble (France); Institute of Microelectronics Electromagnetism and Photonics and the Hyperspectral and Characterization (IMEP-LAHC) Lab., Grenoble (France)
National Center For Scientific Research (CNRS), Grenoble (France). Neel Inst.; Univ. of Grenoble (France); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Inst. for Materials and Energy Sciences

Publication Date:: Wed Dec 14 00:00:00 EST 2016

Research Org.:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1361058

Grant/Contract Number:: ANR-13-BS04-0013-01; AC02-76SF00515

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 94; Journal Issue: 21; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Lefrançois, E., Songvilay, M., Robert, J., Nataf, G., Jordan, E., Chaix, L., Colin, C. V., Lejay, P., Hadj-Azzem, A., Ballou, R., and Simonet, V. Magnetic properties of the honeycomb oxide Na2Co2TeO6.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.94.214416.

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                    Lefrançois, E., Songvilay, M., Robert, J., Nataf, G., Jordan, E., Chaix, L., Colin, C. V., Lejay, P., Hadj-Azzem, A., Ballou, R., & Simonet, V. Magnetic properties of the honeycomb oxide Na2Co2TeO6.  United States.  https://doi.org/10.1103/PhysRevB.94.214416

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                    Lefrançois, E., Songvilay, M., Robert, J., Nataf, G., Jordan, E., Chaix, L., Colin, C. V., Lejay, P., Hadj-Azzem, A., Ballou, R., and Simonet, V. Wed .  
"Magnetic properties of the honeycomb oxide Na2Co2TeO6".  United States.  https://doi.org/10.1103/PhysRevB.94.214416.  https://www.osti.gov/servlets/purl/1361058.

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@article{osti_1361058,

  title        = {Magnetic properties of the honeycomb oxide Na2Co2TeO6},

  author       = {Lefrançois, E. and Songvilay, M. and Robert, J. and Nataf, G. and Jordan, E. and Chaix, L. and Colin, C. V. and Lejay, P. and Hadj-Azzem, A. and Ballou, R. and Simonet, V.},

  abstractNote = {We have studied the magnetic properties of Na 2 Co 2 TeO 6 , which features a honeycomb lattice of magnetic Co 2 + ions, through macroscopic characterization and neutron diffraction on a powder sample. We also show that this material orders in a zigzag antiferromagnetic structure. Additionally by allowing a linear magnetoelectric coupling, this magnetic arrangement displays very peculiar spatial magnetic correlations, larger in the honeycomb planes than between the planes, which do not evolve with the temperature. We have investigated this behavior by classical Monte Carlo calculations using the J 1 - J 2 - J 3 model on a honeycomb lattice with a small interplane interaction. Furthermore, our model reproduces the experimental neutron structure factor, although its absence of temperature evolution must be due to additional ingredients, such as chemical disorder or quantum fluctuations enhanced by the proximity to a phase boundary.},

  doi          = {10.1103/PhysRevB.94.214416},

  journal      = {Physical Review B},

  number       = 21,

  volume       = 94,

  place        = {United States},

  year         = {Wed Dec 14 00:00:00 EST 2016},

  month        = {Wed Dec 14 00:00:00 EST 2016}

}

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Works referencing / citing this record:

Spin Correlations and Short‐Range Magnetic Order in the Honeycomb‐Layered Na ₂ Ni ₂ TeO ₆
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Korshunov, Artem; Safiulina, Irina; Kurbakov, Alexander
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Ground state and low-temperature magnetism of the quasi-two-dimensional honeycomb compound ${InCu}_{2 / 3} V_{1 / 3} O_{3}$
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Title: Magnetic properties of the honeycomb oxide Na 2 Co 2 TeO 6

Abstract

Citation Formats

Classical Spin Liquid on the Maximally Frustrated Honeycomb Lattice journal, October 2016

Phase diagram of a frustrated quantum antiferromagnet on the honeycomb lattice: Magnetic order versus valence-bond crystal formation journal, July 2011

Anyons in an exactly solved model and beyond journal, January 2006

Monoclinic crystal structure of α − RuCl 3 and the zigzag antiferromagnetic ground state journal, December 2015

Ground-state phases of the spin- 1 J 1 − J 2 Heisenberg antiferromagnet on the honeycomb lattice journal, June 2016

Magnetic properties of the layered nickel compounds BaNi2(PO4)2 and BaNi2(AsO4)2 journal, January 1980

Review on structural and chemical properties of transition metal phosphorous trisulfides MPS3 journal, December 1986

Synthesis of Li3Cu2SbO6, a New Partially Ordered Rock Salt Structure journal, June 1997

Magnetic order in α − RuCl 3 : A honeycomb-lattice quantum magnet with strong spin-orbit coupling journal, April 2015

Orbital Order and Fluctuations in Mott Insulators journal, January 2005

Symmetry-Based Computational Tools for Magnetic Crystallography journal, July 2015

Structure and basic magnetic properties of the honeycomb lattice compounds Na2Co2TeO6 and Na3Co2SbO6 journal, March 2007

Zigzag antiferromagnetic quantum ground state in monoclinic honeycomb lattice antimonates A 3 N i 2 Sb O 6 ( A = Li , Na ) journal, October 2015

An investigation of the quantum J 1 - J 2 - J 3 model on the honeycomb lattice journal, March 2001

Studies on solid solutions based on layered honeycomb-ordered phases P2-Na2M2TeO6 (M=Co, Ni, Zn) journal, December 2012

Frustrated Heisenberg antiferromagnet on the honeycomb lattice: Spin gap and low-energy parameters journal, December 2015

Spin-Gap Behavior of Na 3 Cu 2 SbO 6 with Distorted Honeycomb Structure journal, August 2006

Monoclinic honeycomb-layered compound Li3Ni2SbO6: preparation, crystal structure and magnetic properties journal, January 2012

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Neutron Diffraction Study on MnPS 3 and FePS 3 journal, November 1983

Magnetism in the layered transition-metal thiophosphates M PS 3 ( M =Mn, Fe, and Ni) journal, September 1992

Crystal growth and magnetic ordering of Na 2 Ni 2 TeO 6 with honeycomb layers and Na 2 Cu 2 TeO 6 with Cu spin dimers journal, January 2014

Spin Waves and Revised Crystal Structure of Honeycomb Iridate Na 2 IrO 3 journal, March 2012

Quantum spin liquid emerging in two-dimensional correlated Dirac fermions journal, April 2010

Superconductivity in two-dimensional CoO2 layers journal, March 2003

Phase diagram of the J 1 − J 2 − J 3 Heisenberg model on the honeycomb lattice: A series expansion study journal, September 2011

Tenth-order high-temperature expansion for the susceptibility and the specific heat of spin- s Heisenberg models with arbitrary exchange patterns: Application to pyrochlore and kagome magnets journal, January 2014

New Layered Compounds with Honeycomb Ordering: Li 3 Ni 2 BiO 6 , Li 3 NiM′BiO 6 (M′ = Mg, Cu, Zn), and the Delafossite Ag 3 Ni 2 BiO 6 journal, April 2012

Structure and Magnetic Properties of the α-NaFeO 2 -Type Honeycomb Compound Na 3 Ni 2 BiO 6 journal, November 2013

Zig-zag magnetic ordering in honeycomb-layered Na3Co2SbO6 journal, November 2016

Frustrated Heisenberg antiferromagnet on the honeycomb lattice with spin quantum number s ≥ 1 journal, March 2016

Ground-state phases of the frustrated spin- 1 2 J 1 – J 2 – J 3 Heisenberg ferromagnet ( J 1 < 0 ) on the honeycomb lattice with J 3 = J 2 > 0 journal, February 2012

Direct evidence of a zigzag spin-chain structure in the honeycomb lattice: A neutron and x-ray diffraction investigation of single-crystal Na 2 IrO 3 journal, May 2012

Magnetic structure of the quasi-two-dimensional antiferromagnet NiPS 3 journal, December 2015

Electronic Texture of the Thermoelectric Oxide Na 0.75 CoO 2 journal, March 2008

Magnetic order and paramagnetic phases in the quantum J 1 - J 2 - J 3 honeycomb model journal, July 2011

Some symmetry aspects of ferroics and single phase multiferroics * journal, October 2008

Overrelaxation and Monte Carlo simulation journal, July 1987

Magnetic and electrode properties, structure and phase relations of the layered triangular-lattice tellurate Li4NiTeO6 journal, May 2015

Non-simple magnetic order for simple Hamiltonians journal, July 1979

Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models journal, January 2009

Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na 2 Cu 2 TeO 6 journal, July 2005

X-Ray Diffraction in Random Layer Lattices journal, May 1941

Solid solution studies of layered honeycomb-ordered phases O3–Na3M2SbO6 (M=Cu, Mg, Ni, Zn) journal, May 2013

Low-temperature crystal and magnetic structure of α − RuCl 3 journal, April 2016

Semiclassical spin dynamics of the antiferromagnetic Heisenberg model on the kagome lattice journal, August 2014

Superconductivity in Two-Dimensional CoO2 Layers. journal, June 2003

Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na2Cu2TeO6. journal, October 2005

Structure and Basic Magnetic Properties of the Honeycomb Lattice Compounds Na2Co2TeO6 and Na3Co2SbO6. journal, December 2007

Quantum spin-liquid emerging in two-dimensional correlated Dirac fermions text, January 2010

Phase Diagram of a Frustrated Quantum Antiferromagnet on the Honeycomb Lattice: Magnetic Order versus Valence-Bond Crystal formation text, January 2011

Frustrated Heisenberg antiferromagnet on the honeycomb lattice: Spin gap and low-energy parameters text, January 2015

Classical spin-liquid on the maximally frustrated honeycomb lattice text, January 2015

Anyons in an exactly solved model and beyond text, January 2005

Spin Correlations and Short‐Range Magnetic Order in the Honeycomb‐Layered Na 2 Ni 2 TeO 6 journal, August 2019

Ground state and low-temperature magnetism of the quasi-two-dimensional honeycomb compound InCu 2 / 3 V 1 / 3 O 3 journal, October 2019

Weak-field induced nonmagnetic state in a Co-based honeycomb journal, January 2020

The magnetic properties and structure of the quasi-two-dimensional antiferromagnet CoPS$_3$ text, January 2017

Role of quantum fluctuations on spin liquids and ordered phases in the Heisenberg model on the honeycomb lattice text, January 2018

Title: Magnetic properties of the honeycomb oxide ${Na}_{2} {Co}_{2} {TeO}_{6}$

Classical Spin Liquid on the Maximally Frustrated Honeycomb Lattice
journal, October 2016

Phase diagram of a frustrated quantum antiferromagnet on the honeycomb lattice: Magnetic order versus valence-bond crystal formation
journal, July 2011

Anyons in an exactly solved model and beyond
journal, January 2006

Monoclinic crystal structure of $α - {RuCl}_{3}$ and the zigzag antiferromagnetic ground state
journal, December 2015

Ground-state phases of the spin- $1 J_{1} − J_{2}$ Heisenberg antiferromagnet on the honeycomb lattice
journal, June 2016

Magnetic properties of the layered nickel compounds BaNi2(PO4)2 and BaNi2(AsO4)2
journal, January 1980

Review on structural and chemical properties of transition metal phosphorous trisulfides MPS3
journal, December 1986

Synthesis of Li3Cu2SbO6, a New Partially Ordered Rock Salt Structure
journal, June 1997

Magnetic order in $α - {RuCl}_{3}$ : A honeycomb-lattice quantum magnet with strong spin-orbit coupling
journal, April 2015

Orbital Order and Fluctuations in Mott Insulators
journal, January 2005

Symmetry-Based Computational Tools for Magnetic Crystallography
journal, July 2015

Structure and basic magnetic properties of the honeycomb lattice compounds Na2Co2TeO6 and Na3Co2SbO6
journal, March 2007

Zigzag antiferromagnetic quantum ground state in monoclinic honeycomb lattice antimonates $A_{3} N i_{2} Sb O_{6} (A = Li, Na)$
journal, October 2015

An investigation of the quantum J 1 - J 2 - J 3 model on the honeycomb lattice
journal, March 2001

Studies on solid solutions based on layered honeycomb-ordered phases P2-Na2M2TeO6 (M=Co, Ni, Zn)
journal, December 2012

Frustrated Heisenberg antiferromagnet on the honeycomb lattice: Spin gap and low-energy parameters
journal, December 2015

Spin-Gap Behavior of Na ₃ Cu ₂ SbO ₆ with Distorted Honeycomb Structure
journal, August 2006

Monoclinic honeycomb-layered compound Li3Ni2SbO6: preparation, crystal structure and magnetic properties
journal, January 2012

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Neutron Diffraction Study on MnPS ₃ and FePS ₃
journal, November 1983

Magnetism in the layered transition-metal thiophosphates M ${PS}_{3}$ ( M =Mn, Fe, and Ni)
journal, September 1992

Crystal growth and magnetic ordering of Na ₂ Ni ₂ TeO ₆ with honeycomb layers and Na ₂ Cu ₂ TeO ₆ with Cu spin dimers
journal, January 2014

Spin Waves and Revised Crystal Structure of Honeycomb Iridate ${Na}_{2} {IrO}_{3}$
journal, March 2012

Quantum spin liquid emerging in two-dimensional correlated Dirac fermions
journal, April 2010

Superconductivity in two-dimensional CoO2 layers
journal, March 2003

Phase diagram of the $J_{1} - J_{2} - J_{3}$ Heisenberg model on the honeycomb lattice: A series expansion study
journal, September 2011

Tenth-order high-temperature expansion for the susceptibility and the specific heat of spin- $s$ Heisenberg models with arbitrary exchange patterns: Application to pyrochlore and kagome magnets
journal, January 2014

New Layered Compounds with Honeycomb Ordering: Li ₃ Ni ₂ BiO ₆ , Li ₃ NiM′BiO ₆ (M′ = Mg, Cu, Zn), and the Delafossite Ag ₃ Ni ₂ BiO ₆
journal, April 2012

Structure and Magnetic Properties of the α-NaFeO ₂ -Type Honeycomb Compound Na ₃ Ni ₂ BiO ₆
journal, November 2013

Zig-zag magnetic ordering in honeycomb-layered Na3Co2SbO6
journal, November 2016

Frustrated Heisenberg antiferromagnet on the honeycomb lattice with spin quantum number s ≥ 1
journal, March 2016

Ground-state phases of the frustrated spin- $\frac{1}{2}$ $J_{1}$ – $J_{2}$ – $J_{3}$ Heisenberg ferromagnet ( $J_{1} < 0$ ) on the honeycomb lattice with $J_{3} = J_{2} > 0$
journal, February 2012

Direct evidence of a zigzag spin-chain structure in the honeycomb lattice: A neutron and x-ray diffraction investigation of single-crystal Na $_{2}$ IrO $_{3}$
journal, May 2012

Magnetic structure of the quasi-two-dimensional antiferromagnet ${NiPS}_{3}$
journal, December 2015

Electronic Texture of the Thermoelectric Oxide ${Na}_{0.75} {CoO}_{2}$
journal, March 2008

Magnetic order and paramagnetic phases in the quantum $J_{1}$ - $J_{2}$ - $J_{3}$ honeycomb model
journal, July 2011

Some symmetry aspects of ferroics and single phase multiferroics ^*
journal, October 2008

Overrelaxation and Monte Carlo simulation
journal, July 1987

Magnetic and electrode properties, structure and phase relations of the layered triangular-lattice tellurate Li4NiTeO6
journal, May 2015

Non-simple magnetic order for simple Hamiltonians
journal, July 1979

Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models
journal, January 2009

Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na ₂ Cu ₂ TeO ₆
journal, July 2005

X-Ray Diffraction in Random Layer Lattices
journal, May 1941

Solid solution studies of layered honeycomb-ordered phases O3–Na3M2SbO6 (M=Cu, Mg, Ni, Zn)
journal, May 2013

Low-temperature crystal and magnetic structure of $α - {RuCl}_{3}$
journal, April 2016

Semiclassical spin dynamics of the antiferromagnetic Heisenberg model on the kagome lattice
journal, August 2014

Superconductivity in Two-Dimensional CoO2 Layers.
journal, June 2003

Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na2Cu2TeO6.
journal, October 2005

Structure and Basic Magnetic Properties of the Honeycomb Lattice Compounds Na2Co2TeO6 and Na3Co2SbO6.
journal, December 2007

Quantum spin-liquid emerging in two-dimensional correlated Dirac fermions
text, January 2010

Phase Diagram of a Frustrated Quantum Antiferromagnet on the Honeycomb Lattice: Magnetic Order versus Valence-Bond Crystal formation
text, January 2011

Frustrated Heisenberg antiferromagnet on the honeycomb lattice: Spin gap and low-energy parameters
text, January 2015

Classical spin-liquid on the maximally frustrated honeycomb lattice
text, January 2015

Anyons in an exactly solved model and beyond
text, January 2005

Spin Correlations and Short‐Range Magnetic Order in the Honeycomb‐Layered Na ₂ Ni ₂ TeO ₆
journal, August 2019

Ground state and low-temperature magnetism of the quasi-two-dimensional honeycomb compound ${InCu}_{2 / 3} V_{1 / 3} O_{3}$
journal, October 2019

Weak-field induced nonmagnetic state in a Co-based honeycomb
journal, January 2020

The magnetic properties and structure of the quasi-two-dimensional antiferromagnet CoPS$_3$
text, January 2017

Role of quantum fluctuations on spin liquids and ordered phases in the Heisenberg model on the honeycomb lattice
text, January 2018