Finite-sized one-dimensional silica microstructures (rods): Synthesis, assembly, and applications
Abstract
Abstract Colloidal silica structures are very important for applications such as superhydrophobic, oleophobic, icephobic, and anti‐biofouling coatings, polymer–ceramic or metal–matrix composites, photon management, catalyst support, and drug delivery. In addition to various types of silica structures, a unique structure—silica rods—has been synthesized by employing the emulsion droplets made by adding water and citrate to polyvinylpyrrolidone pentanol solution. While significant progress has been made in modifying rod shape and chemistry, in rod assembly, and in rod applications, however, no review article has discussed the progress in this field. This Focus Review intends to highlight the developments in the synthesis, assembly, and application of these rods, and discuss the remaining challenges for precise control of size and shape, possible solutions, and potential applications.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Building Technologies Office
- OSTI Identifier:
- 1356908
- Alternate Identifier(s):
- OSTI ID: 1401753
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemNanoMat
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2199-692X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; silica rods; assembly; hierachical; particles; microstructures; one-dimensional; self-assembly; synthesis
Citation Formats
Sharma, Jaswinder. Finite-sized one-dimensional silica microstructures (rods): Synthesis, assembly, and applications. United States: N. p., 2017.
Web. doi:10.1002/cnma.201700001.
Sharma, Jaswinder. Finite-sized one-dimensional silica microstructures (rods): Synthesis, assembly, and applications. United States. https://doi.org/10.1002/cnma.201700001
Sharma, Jaswinder. Sat .
"Finite-sized one-dimensional silica microstructures (rods): Synthesis, assembly, and applications". United States. https://doi.org/10.1002/cnma.201700001. https://www.osti.gov/servlets/purl/1356908.
@article{osti_1356908,
title = {Finite-sized one-dimensional silica microstructures (rods): Synthesis, assembly, and applications},
author = {Sharma, Jaswinder},
abstractNote = {Abstract Colloidal silica structures are very important for applications such as superhydrophobic, oleophobic, icephobic, and anti‐biofouling coatings, polymer–ceramic or metal–matrix composites, photon management, catalyst support, and drug delivery. In addition to various types of silica structures, a unique structure—silica rods—has been synthesized by employing the emulsion droplets made by adding water and citrate to polyvinylpyrrolidone pentanol solution. While significant progress has been made in modifying rod shape and chemistry, in rod assembly, and in rod applications, however, no review article has discussed the progress in this field. This Focus Review intends to highlight the developments in the synthesis, assembly, and application of these rods, and discuss the remaining challenges for precise control of size and shape, possible solutions, and potential applications.},
doi = {10.1002/cnma.201700001},
journal = {ChemNanoMat},
number = 4,
volume = 3,
place = {United States},
year = {Sat Jan 28 00:00:00 EST 2017},
month = {Sat Jan 28 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 6 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Anti-reflective coatings: A critical, in-depth review
journal, January 2011
- Raut, Hemant Kumar; Ganesh, V. Anand; Nair, A. Sreekumaran
- Energy & Environmental Science, Vol. 4, Issue 10
Synthesis and Liquid-Crystal Behavior of Bent Colloidal Silica Rods
journal, December 2015
- Yang, Yang; Chen, Guangdong; Martinez-Miranda, Luz J.
- Journal of the American Chemical Society, Vol. 138, Issue 1
Step-by-Step Growth of Complex Oxide Microstructures
journal, June 2015
- Datskos, Panos; Cullen, David A.; Sharma, Jaswinder
- Angewandte Chemie, Vol. 127, Issue 31
Synthesis of Hollow Mesoporous Silica Nanorods with Controllable Aspect Ratios for Intracellular Triggered Drug Release in Cancer Cells
journal, August 2016
- Yang, Xue; He, Dinggeng; He, Xiaoxiao
- ACS Applied Materials & Interfaces, Vol. 8, Issue 32
Gold Nanoparticle Coated Silica Nanorods for Sensitive Visual Detection of microRNA on a Lateral Flow Strip Biosensor
journal, January 2016
- Takalkar, Sunitha; Xu, Hui; Chen, Jiao
- Analytical Sciences, Vol. 32, Issue 6
New pickering emulsions stabilized by silica nanowires
journal, October 2015
- Yan, Han; Zhao, Bin; Long, Yue
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 482
Deposition of silver nanoparticles on silica spheres and rods
journal, October 2012
- Choma, Jerzy; Jamioła, Dominik; Ludwinowicz, Jowita
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 411
Multisegmented One-Dimensional Nanorods Prepared by Hard-Template Synthetic Methods
journal, April 2006
- Hurst, Sarah J.; Payne, Emma Kathryn; Qin, Lidong
- Angewandte Chemie International Edition, Vol. 45, Issue 17
Additive manufacturing of multi-directional preforms for composites: opportunities and challenges
journal, November 2015
- Quan, Zhenzhen; Wu, Amanda; Keefe, Michael
- Materials Today, Vol. 18, Issue 9
Au-Induced Polyvinylpyrrolidone Aggregates with Bound Water for the Highly Shape-Selective Synthesis of Silica Nanostructures
journal, May 2008
- Zhang, Jianhui; Liu, Huaiyong; Wang, Zhenlin
- Chemistry - A European Journal, Vol. 14, Issue 14
Sol-gel chemistry
journal, January 1992
- Livage, J.; Sanchez, C.
- Journal of Non-Crystalline Solids, Vol. 145
A review of nanowire growth promoted by alloys and non-alloying elements with emphasis on Au-assisted III–V nanowires
journal, September 2008
- Dick, Kimberly A.
- Progress in Crystal Growth and Characterization of Materials, Vol. 54, Issue 3-4
Disposable Nucleic Acid Biosensors Based on Gold Nanoparticle Probes and Lateral Flow Strip
journal, February 2009
- Mao, Xun; Ma, Yunqing; Zhang, Aiguo
- Analytical Chemistry, Vol. 81, Issue 4
Synthesis of Segmented Silica Rods by Regulation of the Growth Temperature
journal, November 2013
- Datskos, Panos; Sharma, Jaswinder
- Angewandte Chemie International Edition, Vol. 53, Issue 2
Stimuli-Responsive Controlled-Release Delivery System Based on Mesoporous Silica Nanorods Capped with Magnetic Nanoparticles
journal, August 2005
- Giri, Supratim; Trewyn, Brian G.; Stellmaker, Michael P.
- Angewandte Chemie, Vol. 117, Issue 32
Anisotrope Gold-Nanopartikel: Synthese, Eigenschaften, Anwendungen und Toxizität
journal, January 2014
- Li, Na; Zhao, Pengxiang; Astruc, Didier
- Angewandte Chemie, Vol. 126, Issue 7
Template-mediated Synthesis of Hollow Microporous Organic Nanorods with Tunable Aspect Ratio
journal, August 2016
- Li, Qingyin; Jin, Shangbin; Tan, Bien
- Scientific Reports, Vol. 6, Issue 1
One-Dimensional Titanium Dioxide Nanomaterials: Nanowires, Nanorods, and Nanobelts
journal, April 2014
- Wang, Xudong; Li, Zhaodong; Shi, Jian
- Chemical Reviews, Vol. 114, Issue 19
Understanding silica-supported metal catalysts: Pd/silica as a case study
journal, October 2003
- Min, B. K.; Santra, A. K.; Goodman, D. W.
- Catalysis Today, Vol. 85, Issue 2-4
Emulsions Stabilized by Silica Rods via Arrested Demixing
journal, June 2015
- Daware, Santosh Vasant; Basavaraj, Madivala G.
- Langmuir, Vol. 31, Issue 24
Antireflective surfaces based on biomimetic nanopillared arrays
journal, April 2010
- Li, Yunfeng; Zhang, Junhu; Yang, Bai
- Nano Today, Vol. 5, Issue 2
Electrochemical Liquid–Liquid–Solid (ec-LLS) Crystal Growth: A Low-Temperature Strategy for Covalent Semiconductor Crystal Growth
journal, June 2015
- Fahrenkrug, Eli; Maldonado, Stephen
- Accounts of Chemical Research, Vol. 48, Issue 7
Chemotaxis of catalytic silica–manganese oxide “matchstick” particles
journal, January 2014
- Morgan, Adam R.; Dawson, Alan B.; Mckenzie, Holly S.
- Mater. Horiz., Vol. 1, Issue 1
Preparation of hollow silica microspheres in W/O emulsions with polymers
journal, October 2003
- Park, Jae-Hyung; Oh, Chul; Shin, Seung-Il
- Journal of Colloid and Interface Science, Vol. 266, Issue 1
Growth behavior of Al-doped zinc oxide microrods with times
journal, September 2015
- Kim, Kyung Ho; Umakoshi, Tomoyuki; Abe, Yoshio
- Superlattices and Microstructures, Vol. 85
Addressable morphology control of silica structures by manipulating the reagent addition time
journal, January 2014
- Datskos, P.; Chen, J.; Sharma, J.
- RSC Adv., Vol. 4, Issue 5
Solution–Liquid–Solid Synthesis, Properties, and Applications of One-Dimensional Colloidal Semiconductor Nanorods and Nanowires
journal, March 2016
- Wang, Fudong; Dong, Angang; Buhro, William E.
- Chemical Reviews, Vol. 116, Issue 18
Synthesis of Monodisperse, Rodlike Silica Colloids with Tunable Aspect Ratio
journal, March 2011
- Kuijk, Anke; van Blaaderen, Alfons; Imhof, Arnout
- Journal of the American Chemical Society, Vol. 133, Issue 8
Mechanistic Insight into the Synthesis of Silica-Based “Matchstick” Colloids
journal, August 2015
- Longbottom, Brooke W.; Rochford, Luke A.; Beanland, Richard
- Langmuir, Vol. 31, Issue 33
Modification of colloidal particles by unidirectional silica deposition for urchin-like morphologies
journal, January 2016
- Zhao, Bin; Li, Dongzhi; Long, Yue
- RSC Advances, Vol. 6, Issue 39
Catalytic growth of nanowires: Vapor–liquid–solid, vapor–solid–solid, solution–liquid–solid and solid–liquid–solid growth
journal, June 2006
- Kolasinski, Kurt W.
- Current Opinion in Solid State and Materials Science, Vol. 10, Issue 3-4, p. 182-191
Anisotropic Gold Nanoparticles: Synthesis, Properties, Applications, and Toxicity
journal, January 2014
- Li, Na; Zhao, Pengxiang; Astruc, Didier
- Angewandte Chemie International Edition, Vol. 53, Issue 7
Positioning growth of scalable silica nanorods on the interior and exterior surfaces of porous composites
journal, January 2015
- Li, Wenle; Chen, Bo; Walz, John Y.
- Journal of Materials Chemistry A, Vol. 3, Issue 5
Fabrication and directed assembly of magnetic Janus rods
journal, January 2016
- Zhao, Bin; Zhou, Hui; Liu, Chuanyong
- New Journal of Chemistry, Vol. 40, Issue 8
Preparation of silver decorated silica nanocomposite rods for catalytic and surface-enhanced Raman scattering applications
journal, January 2015
- Zhao, Kai; Wu, Chengjiao; Deng, Ziwei
- RSC Advances, Vol. 5, Issue 65
Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles
journal, November 2002
- Dinsmore, A. D.; Hsu, M. F.; Nikolaides, M. G.
- Science, Vol. 298, Issue 5595, p. 1006-1009
Synthesis of Discrete Alkyl-Silica Hybrid Nanowires and Their Assembly into Nanostructured Superhydrophobic Membranes
journal, June 2016
- Yi, Deliang; Xu, Chenglong; Tang, Ruidie
- Angewandte Chemie, Vol. 128, Issue 29
Wet-Chemical Synthesis of Amphiphilic Rodlike Silica Particles and their Molecular Mimetic Assembly in Selective Solvents
journal, February 2012
- He, Jie; Yu, Binyu; Hourwitz, Matt J.
- Angewandte Chemie, Vol. 124, Issue 15
Template Growth of ZnO Nanorods and Microrods with Controllable Densities
journal, July 2008
- Yan, Xiaodong; Li, Zhengwei; Chen, Ruiqun
- Crystal Growth & Design, Vol. 8, Issue 7
Synthesis of Monodisperse High-Aspect-Ratio Colloidal Silicon and Silica Rods
journal, December 2004
- van Kats, Carlos M.; Johnson, Patrick M.; van den Meerakker, Jan E. A. M.
- Langmuir, Vol. 20, Issue 25
Colloidal ribbons and rings from Janus magnetic rods
journal, February 2013
- Yan, Jing; Chaudhary, Kundan; Chul Bae, Sung
- Nature Communications, Vol. 4, Issue 1
Janus Colloidal Matchsticks
journal, July 2012
- Chaudhary, Kundan; Chen, Qian; Juárez, Jaime J.
- Journal of the American Chemical Society, Vol. 134, Issue 31
Germanium-Catalyzed Growth of Zinc Oxide Nanowires: A Semiconductor Catalyst for Nanowire Synthesis
journal, January 2005
- Pan, Zheng Wei; Dai, Sheng; Rouleau, Christopher M.
- Angewandte Chemie, Vol. 117, Issue 2
One-pot facile synthesis of Janus particles with tailored shape and functionality
journal, January 2011
- He, Jie; Hourwitz, Matt J.; Liu, Yijing
- Chemical Communications, Vol. 47, Issue 46
Self-Organization of Anisotropic and Binary Colloids in Thermo-Switchable 1D Microconfinement
journal, October 2014
- de Folter, Julius W. J.; Liu, Ping; Jiang, Lingxiang
- Particle & Particle Systems Characterization, Vol. 32, Issue 3
Step-by-Step Growth of Complex Oxide Microstructures
journal, June 2015
- Datskos, Panos; Cullen, David A.; Sharma, Jaswinder
- Angewandte Chemie International Edition, Vol. 54, Issue 31
Simple Synthesis Route to Monodispersed SBA-15 Silica Rods
journal, November 2004
- Sayari, Abdelhamid; Han, Bao-Hang; Yang, Yong
- Journal of the American Chemical Society, Vol. 126, Issue 44
Colloidosome like structures: self-assembly of silica microrods
journal, January 2016
- Datskos, P.; Polizos, G.; Bhandari, M.
- RSC Advances, Vol. 6, Issue 32
Foam Superstabilization by Polymer Microrods
journal, November 2004
- Alargova, Rossitza G.; Warhadpande, Devdutta S.; Paunov, Vesselin N.
- Langmuir, Vol. 20, Issue 24
Effect of external electric fields on the phase behavior of colloidal silica rods
journal, January 2014
- Kuijk, Anke; Troppenz, Thomas; Filion, Laura
- Soft Matter, Vol. 10, Issue 33
Visual detection of microRNA with lateral flow nucleic acid biosensor
journal, April 2014
- Gao, Xuefei; Xu, Hui; Baloda, Meenu
- Biosensors and Bioelectronics, Vol. 54
Vielsegmentige Nanostäbe: Templatsynthese und Eigenschaften
journal, April 2006
- Hurst, Sarah J.; Payne, Emma Kathryn; Qin, Lidong
- Angewandte Chemie, Vol. 118, Issue 17
Site-specific growth of polymers on silica rods
journal, January 2014
- Peng, Bo; Soligno, Giuseppe; Kamp, Marlous
- Soft Matter, Vol. 10, Issue 48
Obtaining silicon carbide from rice husks
journal, September 1991
- Vlasov, A. S.; Zakharov, A. I.; Sarkisyan, O. A.
- Refractories, Vol. 32, Issue 9-10
Synthesis of Discrete Alkyl-Silica Hybrid Nanowires and Their Assembly into Nanostructured Superhydrophobic Membranes
journal, June 2016
- Yi, Deliang; Xu, Chenglong; Tang, Ruidie
- Angewandte Chemie International Edition, Vol. 55, Issue 29
Micron-scale rod-like scattering particles for light trapping in nanostructured thin film solar cells
journal, January 2015
- Byranvand, M. Malekshahi; Taghavinia, N.; Kharat, A. Nemati
- RSC Advances, Vol. 5, Issue 105
Hybrid Organic−Inorganic, Rod-Shaped Nanoresistors and Diodes
journal, September 2004
- Park, Sungho; Chung, Sung-Wook; Mirkin, Chad A.
- Journal of the American Chemical Society, Vol. 126, Issue 38
Synthesis of Segmented Silica Rods by Regulation of the Growth Temperature
journal, November 2013
- Datskos, Panos; Sharma, Jaswinder
- Angewandte Chemie, Vol. 126, Issue 2
Controlled growth of zinc oxide microrods by hydrothermal process on porous ceramic supports for catalytic application
journal, February 2014
- Danwittayakul, Supamas; Dutta, Joydeep
- Journal of Alloys and Compounds, Vol. 586
CXCVI.—Emulsions
journal, January 1907
- Pickering, Spencer Umfreville
- J. Chem. Soc., Trans., Vol. 91, Issue 0
A Strong Integrated Strength and Toughness Artificial Nacre Based on Dopamine Cross-Linked Graphene Oxide
journal, August 2014
- Cui, Wei; Li, Mingzhu; Liu, Jiyang
- ACS Nano, Vol. 8, Issue 9
Wet-Chemical Synthesis of Amphiphilic Rodlike Silica Particles and their Molecular Mimetic Assembly in Selective Solvents
journal, February 2012
- He, Jie; Yu, Binyu; Hourwitz, Matt J.
- Angewandte Chemie International Edition, Vol. 51, Issue 15
Synthesis of Cone-Shaped Colloids from Rod-Like Silica Colloids with a Gradient in the Etching Rate
journal, April 2016
- Hagemans, Fabian; van der Wee, Ernest B.; van Blaaderen, Alfons
- Langmuir, Vol. 32, Issue 16
Confinement Induced Plastic Crystal-to-Crystal Transitions in Rodlike Particles with Long-Ranged Repulsion
journal, August 2015
- Liu, Bing; Besseling, Thijs H.; van Blaaderen, Alfons
- Physical Review Letters, Vol. 115, Issue 7
Stimuli-Responsive Controlled-Release Delivery System Based on Mesoporous Silica Nanorods Capped with Magnetic Nanoparticles
journal, August 2005
- Giri, Supratim; Trewyn, Brian G.; Stellmaker, Michael P.
- Angewandte Chemie International Edition, Vol. 44, Issue 32, p. 5038-5044
Synthesis of rod-like silica–gold core-shell structures
journal, January 2012
- Choma, Jerzy; Jamioła, Dominik; Nyga, Piotr
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 393
Gold-Nanoparticle-Decorated Silica Nanorods for Sensitive Visual Detection of Proteins
journal, July 2014
- Xu, Hui; Chen, Jiao; Birrenkott, Joseph
- Analytical Chemistry, Vol. 86, Issue 15
Nanomaterials: A Membrane-Based Synthetic Approach
journal, December 1994
- Martin, C. R.
- Science, Vol. 266, Issue 5193
Germanium-Catalyzed Growth of Zinc Oxide Nanowires: A Semiconductor Catalyst for Nanowire Synthesis
journal, January 2005
- Pan, Zheng Wei; Dai, Sheng; Rouleau, Christopher M.
- Angewandte Chemie International Edition, Vol. 44, Issue 2
Synthesis of very small diameter silica nanofibers using sound waves
journal, January 2014
- Datskos, Panos; Chen, Jihua; Sharma, Jaswinder
- Chem. Commun., Vol. 50, Issue 55
Switching plastic crystals of colloidal rods with electric fields
journal, January 2014
- Liu, Bing; Besseling, Thijs H.; Hermes, Michiel
- Nature Communications, Vol. 5, Issue 1
Nanostructures for photon management in solar cells
journal, January 2013
- Narasimhan, Vijay Kris; Cui, Yi
- Nanophotonics, Vol. 2, Issue 3
Works referencing / citing this record:
Shaping Silica Rods by Tuning Hydrolysis and Condensation of Silica Precursors
journal, December 2018
- Hagemans, Fabian; Pujala, Ravi Kumar; Hotie, Danisha S.
- Chemistry of Materials, Vol. 31, Issue 2
Seeded-Growth of Silica Rods from Silica-Coated Particles
journal, October 2019
- Hayden, Douglas R.; Kennedy, Chris L.; Velikov, Krassimir P.
- Langmuir, Vol. 35, Issue 46