Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide
Abstract
Increasing the conversion efficiency of thermoelectric materials is a key scientific driver behind a worldwide effort to enable heat to electricity power generation at competitive cost. Here we report an increased performance for antimony-doped lead selenide with a thermoelectric figure of merit of ~1.5 at 800 K. This is in sharp contrast to bismuth doped lead selenide, which reaches a figure of merit of <1. Substituting antimony or bismuth for lead achieves maximum power factors between ~23–27μW cm–1 K–2 at temperatures above 400 K. The addition of small amounts (~0.25 mol%) of antimony generates extensive nanoscale precipitates, whereas comparable amounts of bismuth results in very few or no precipitates. The antimony-rich precipitates are endotaxial in lead selenide, and appear remarkably effective in reducing the lattice thermal conductivity. As a result, the corresponding bismuth-containing samples exhibit smaller reduction in lattice thermal conductivity.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States)
- Univ. of Michigan, Ann Arbor, MI (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Materials Sciences and Engineering Division; National Science Foundation (NSF); W.M. Keck Foundation; Northwestern University
- OSTI Identifier:
- 1355912
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 5; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; thermoelectrics
Citation Formats
Lee, Yeseul, Lo, Shih -Han, Chen, Changqiang, Sun, Hui, Chung, Duck -Young, Chasapis, Thomas C., Uher, Ctirad, Dravid, Vinayak P., and Kanatzidis, Mercouri G. Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide. United States: N. p., 2014.
Web. doi:10.1038/ncomms4640.
Lee, Yeseul, Lo, Shih -Han, Chen, Changqiang, Sun, Hui, Chung, Duck -Young, Chasapis, Thomas C., Uher, Ctirad, Dravid, Vinayak P., & Kanatzidis, Mercouri G. Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide. United States. https://doi.org/10.1038/ncomms4640
Lee, Yeseul, Lo, Shih -Han, Chen, Changqiang, Sun, Hui, Chung, Duck -Young, Chasapis, Thomas C., Uher, Ctirad, Dravid, Vinayak P., and Kanatzidis, Mercouri G. Fri .
"Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide". United States. https://doi.org/10.1038/ncomms4640. https://www.osti.gov/servlets/purl/1355912.
@article{osti_1355912,
title = {Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide},
author = {Lee, Yeseul and Lo, Shih -Han and Chen, Changqiang and Sun, Hui and Chung, Duck -Young and Chasapis, Thomas C. and Uher, Ctirad and Dravid, Vinayak P. and Kanatzidis, Mercouri G.},
abstractNote = {Increasing the conversion efficiency of thermoelectric materials is a key scientific driver behind a worldwide effort to enable heat to electricity power generation at competitive cost. Here we report an increased performance for antimony-doped lead selenide with a thermoelectric figure of merit of ~1.5 at 800 K. This is in sharp contrast to bismuth doped lead selenide, which reaches a figure of merit of <1. Substituting antimony or bismuth for lead achieves maximum power factors between ~23–27μW cm–1 K–2 at temperatures above 400 K. The addition of small amounts (~0.25 mol%) of antimony generates extensive nanoscale precipitates, whereas comparable amounts of bismuth results in very few or no precipitates. The antimony-rich precipitates are endotaxial in lead selenide, and appear remarkably effective in reducing the lattice thermal conductivity. As a result, the corresponding bismuth-containing samples exhibit smaller reduction in lattice thermal conductivity.},
doi = {10.1038/ncomms4640},
journal = {Nature Communications},
number = ,
volume = 5,
place = {United States},
year = {Fri May 02 00:00:00 EDT 2014},
month = {Fri May 02 00:00:00 EDT 2014}
}
Web of Science
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