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Title: X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111)

Abstract

Here, we present X-ray crystal truncation rods measurements of Pt(111) surface under electrochemical conditions. Analyses of crystal truncation rods reveal that surface oxide formation buckles the top surface layer of platinum to two different heights at the potential (0.95 V vs RHE) below the so-called place-exchange potential. While the anti-Bragg intensity, sensitive to the top surface layer, drops in response to the anodic charge transfers, its responses to the cathodic charge transfers are significantly delayed. Implications to the surface oxidation and reduction behaviors are discussed.

Authors:
 [1];  [1];  [2];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)
  2. Safarik Univ., Kosice (Slovakia)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1352615
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 120; Journal Issue: 29; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Liu, Yihua, Barbour, Andi, Komanicky, Vladimir, and You, Hoydoo. X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111). United States: N. p., 2016. Web. doi:10.1021/acs.jpcc.6b00492.
Liu, Yihua, Barbour, Andi, Komanicky, Vladimir, & You, Hoydoo. X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111). United States. https://doi.org/10.1021/acs.jpcc.6b00492
Liu, Yihua, Barbour, Andi, Komanicky, Vladimir, and You, Hoydoo. Fri . "X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111)". United States. https://doi.org/10.1021/acs.jpcc.6b00492. https://www.osti.gov/servlets/purl/1352615.
@article{osti_1352615,
title = {X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111)},
author = {Liu, Yihua and Barbour, Andi and Komanicky, Vladimir and You, Hoydoo},
abstractNote = {Here, we present X-ray crystal truncation rods measurements of Pt(111) surface under electrochemical conditions. Analyses of crystal truncation rods reveal that surface oxide formation buckles the top surface layer of platinum to two different heights at the potential (0.95 V vs RHE) below the so-called place-exchange potential. While the anti-Bragg intensity, sensitive to the top surface layer, drops in response to the anodic charge transfers, its responses to the cathodic charge transfers are significantly delayed. Implications to the surface oxidation and reduction behaviors are discussed.},
doi = {10.1021/acs.jpcc.6b00492},
journal = {Journal of Physical Chemistry. C},
number = 29,
volume = 120,
place = {United States},
year = {Fri Feb 26 00:00:00 EST 2016},
month = {Fri Feb 26 00:00:00 EST 2016}
}

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Works referenced in this record:

Just a Dream—or Future Reality?
journal, April 2009


Shape-Dependent Activity of Platinum Array Catalyst
journal, April 2009

  • Komanicky, Vladimir; Iddir, Hakim; Chang, Kee-Chul
  • Journal of the American Chemical Society, Vol. 131, Issue 16
  • DOI: 10.1021/ja900459w

Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007

  • Stamenkovic, V. R.; Fowler, B.; Mun, B. S.
  • Science, Vol. 315, Issue 5811, p. 493-497
  • DOI: 10.1126/science.1135941

Surface x-ray-scattering measurements of the substrate-induced spatial modulation of an incommensurate adsorbed monolayer
journal, September 1990

  • Toney, Michael F.; Gordon, Joseph G.; Samant, Mahesh G.
  • Physical Review B, Vol. 42, Issue 9
  • DOI: 10.1103/PhysRevB.42.5594

In situ x-ray reflectivity and diffraction studies of the Au(001) reconstruction in an electrochemical cell
journal, September 1990


Structure of Au(111) and Au(100) Single-Crystal Electrode Surfaces at Various Potentials in Sulfuric Acid Solution Determined by In Situ Surface X-ray Scattering
journal, September 2007

  • Kondo, Toshihiro; Morita, Jun; Hanaoka, Kazuya
  • The Journal of Physical Chemistry C, Vol. 111, Issue 35
  • DOI: 10.1021/jp072601j

Applications of surface X-ray scattering to electrochemistry problems
journal, July 2002


Voltage-dependent ordering of water molecules at an electrode–electrolyte interface
journal, March 1994

  • Toney, Michael F.; Howard, Jason N.; Richer, Jocelyn
  • Nature, Vol. 368, Issue 6470
  • DOI: 10.1038/368444a0

In-Situ X-ray Diffraction and STM Studies of Bromide Adsorption on Au(111) Electrodes
journal, January 1996

  • Magnussen, O. M.; Ocko, B. M.; Wang, J. X.
  • The Journal of Physical Chemistry, Vol. 100, Issue 13
  • DOI: 10.1021/jp953281j

In situ structural study on underpotential deposition of Ag on Au(111) electrode using surface X-ray scattering technique
journal, September 2002

  • Kondo, Toshihiro; Morita, Jun; Okamura, Masayuki
  • Journal of Electroanalytical Chemistry, Vol. 532, Issue 1-2
  • DOI: 10.1016/S0022-0728(02)00705-2

Commensurate Water Monolayer at the RuO 2 ( 110 ) /Water Interface
journal, April 2001


In‐situ x‐ray reflectivity study of incipient oxidation of Pt(111) surface in electrolyte solutions
journal, March 1994

  • You, H.; Zurawski, D. J.; Nagy, Z.
  • The Journal of Chemical Physics, Vol. 100, Issue 6
  • DOI: 10.1063/1.466254

Anomalous lattice expansion of the electrodeposited Ag bilayer on Pt(111)
journal, February 1998


Surface electrochemistry of CO on Pt(): anion effects
journal, March 2002


In Situ Surface X-Ray Scattering Observation of Long-Range Ordered ( 19 × 19 )R23.4°-13CO Structure on Pt(111) in Aqueous Electrolytes
journal, January 2004

  • Tolmachev, Yuriy V.; Menzel, Andreas; Tkachuk, Andrei V.
  • Electrochemical and Solid-State Letters, Vol. 7, Issue 3
  • DOI: 10.1149/1.1645354

Effect of Temperature on Surface Processes at the Pt(111)−Liquid Interface:  Hydrogen Adsorption, Oxide Formation, and CO Oxidation
journal, October 1999

  • Marković, N. M.; Schmidt, T. J.; Grgur, B. N.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 40
  • DOI: 10.1021/jp991826u

On the voltammetry of curves of Pt (111) in aqueous solutions
journal, March 1986

  • Jaaf-Golze, K. Al; Kolb, D. M.; Scherson, D.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 200, Issue 1-2
  • DOI: 10.1016/0022-0728(86)90067-7

First-principles diffusion-barrier calculation for atomic oxygen on Pt(111)
journal, February 1998

  • Bogicevic, Alexander; Strömquist, Johan; Lundqvist, Bengt I.
  • Physical Review B, Vol. 57, Issue 8
  • DOI: 10.1103/PhysRevB.57.R4289

A low-energy electron diffraction study of oxygen, water and ice adsorption on Pt(111)
journal, May 1993


X-ray-reflectivity study of the copper-water interface in a transmission geometry under in situ electrochemical control
journal, May 1992


LEED and voltammetry of carbon monoxide electrosorbed on platinum(111)
journal, March 1990

  • Zurawski, D.; Wasberg, M.; Wieckowski, Andrzej.
  • The Journal of Physical Chemistry, Vol. 94, Issue 5
  • DOI: 10.1021/j100368a064

Orientational epitaxy and lateral structure of the hexagonally reconstructed Pt(001) and Au(001) surfaces
journal, April 1992


Long-range structural effects in the anomalous voltammetry on ultra-high vacuum prepared Pt (111)
journal, August 1988

  • Wagner, F. T.; Ross, P. N.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 250, Issue 2
  • DOI: 10.1016/0022-0728(88)85172-6

Water dissociation on well-defined platinum surfaces: The electrochemical perspective
journal, March 2013


In Situ and Real-Time Monitoring of Oxide Growth in a Few Monolayers at Surfaces of Platinum Nanoparticles in Aqueous Media
journal, May 2009

  • Imai, Hideto; Izumi, Koichi; Matsumoto, Masashi
  • Journal of the American Chemical Society, Vol. 131, Issue 17
  • DOI: 10.1021/ja810036h

Electrocatalytic activity of surface oxides on platinum nanofacets and surfaces
journal, October 2013


Thermodynamics and Hysteresis of Oxide Formation and Removal on Platinum (111) Surfaces
journal, April 2012

  • Holby, Edward F.; Greeley, Jeff; Morgan, Dane
  • The Journal of Physical Chemistry C, Vol. 116, Issue 18
  • DOI: 10.1021/jp210805z

Works referencing / citing this record:

Correlation of surface site formation to nanoisland growth in the electrochemical roughening of Pt(111)
journal, February 2018


Towards identifying the active sites on RuO 2 (110) in catalyzing oxygen evolution
journal, January 2017

  • Rao, Reshma R.; Kolb, Manuel J.; Halck, Niels Bendtsen
  • Energy & Environmental Science, Vol. 10, Issue 12
  • DOI: 10.1039/c7ee02307c

Oscillations in the Electro-Oxidation of Thiourea on Platinum Electrode Studied by On-Line HPLC
journal, January 2019

  • Zhang, W.; Liu, Y.; Luo, H.
  • Journal of The Electrochemical Society, Vol. 166, Issue 14
  • DOI: 10.1149/2.1361914jes

Thermodynamics of the formation of surface PtO 2 stripes on Pt(111) in the absence of subsurface oxygen
journal, January 2020

  • Hanselman, Selwyn; McCrum, Ian T.; Rost, Marcel J.
  • Physical Chemistry Chemical Physics, Vol. 22, Issue 19
  • DOI: 10.1039/c9cp05107d

Atomic-Scale Identification of the Electrochemical Roughening of Platinum
journal, November 2019