Alumina-supported sub-nanometer Pt10 clusters: Amorphization and role of the support material in a highly active CO oxidation catalyst
Abstract
Catalytic CO oxidation is unveiled on size-selected Pt10 clusters deposited on two very different ultrathin (≈0.5–0.7 nm thick) alumina films: (i) a highly ordered alumina obtained under ultra-high vacuum (UHV) by oxidation of the NiAl(110) surface and (ii) amorphous alumina obtained by atomic layer deposition (ALD) on a silicon chip that is a close model of real-world supports. Notably, when exposed to realistic reaction conditions, the Pt10/UHV-alumina system undergoes a morphological transition in both the clusters and the substrate, and becomes closely akin to Pt10/ALD-alumina, thus reconciling UHV-type surface-science and real-world experiments. The Pt10 clusters, thoroughly characterized via combined experimental techniques and theoretical analysis, exhibit among the highest CO oxidation activity per Pt atom reported for CO oxidation catalysts, due to the interplay of ultra-small size and support effects. Lastly, a coherent interdisciplinary picture then emerges for this catalytic system.
- Authors:
-
[3];
[7];
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Consiglio Nazionale delle Ricerche, Pisa (Italy)
- Toyota Central R&D Labs. Inc., Nagakute (Japan)
- Univ. Rostock, Rostock (Germany)
- Toyota Motor Corp., Susono (Japan)
- Bhabha Atomic Research Centre, Mumbai (India)
- Consiglio Nazionale delle Ricerche, Pisa (Italy); California Inst. of Technology (CalTech), Pasadena, CA (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1352556
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 10; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; CO oxidation; DFT calculations; HV and atmospheric pressure conditions; amorphous and crystalline alumina; subnanometer Pt clusters
Citation Formats
Yin, Chunrong, Negreiros, Fabio R., Barcaro, Giovanni, Beniya, Atsushi, Sementa, Luca, Tyo, Eric C., Bartling, Stephan, Meiwes-Broer, Karl-Heinz, Seifert, Sönke, Hirata, Hirohito, Isomura, Noritake, Nigam, Sandeep, Majumder, Chiranjib, Watanabe, Yoshihide, Fortunelli, Alessandro, and Vajda, Stefan. Alumina-supported sub-nanometer Pt10 clusters: Amorphization and role of the support material in a highly active CO oxidation catalyst. United States: N. p., 2017.
Web. doi:10.1039/c6ta10989f.
Yin, Chunrong, Negreiros, Fabio R., Barcaro, Giovanni, Beniya, Atsushi, Sementa, Luca, Tyo, Eric C., Bartling, Stephan, Meiwes-Broer, Karl-Heinz, Seifert, Sönke, Hirata, Hirohito, Isomura, Noritake, Nigam, Sandeep, Majumder, Chiranjib, Watanabe, Yoshihide, Fortunelli, Alessandro, & Vajda, Stefan. Alumina-supported sub-nanometer Pt10 clusters: Amorphization and role of the support material in a highly active CO oxidation catalyst. United States. https://doi.org/10.1039/c6ta10989f
Yin, Chunrong, Negreiros, Fabio R., Barcaro, Giovanni, Beniya, Atsushi, Sementa, Luca, Tyo, Eric C., Bartling, Stephan, Meiwes-Broer, Karl-Heinz, Seifert, Sönke, Hirata, Hirohito, Isomura, Noritake, Nigam, Sandeep, Majumder, Chiranjib, Watanabe, Yoshihide, Fortunelli, Alessandro, and Vajda, Stefan. Fri .
"Alumina-supported sub-nanometer Pt10 clusters: Amorphization and role of the support material in a highly active CO oxidation catalyst". United States. https://doi.org/10.1039/c6ta10989f. https://www.osti.gov/servlets/purl/1352556.
@article{osti_1352556,
title = {Alumina-supported sub-nanometer Pt10 clusters: Amorphization and role of the support material in a highly active CO oxidation catalyst},
author = {Yin, Chunrong and Negreiros, Fabio R. and Barcaro, Giovanni and Beniya, Atsushi and Sementa, Luca and Tyo, Eric C. and Bartling, Stephan and Meiwes-Broer, Karl-Heinz and Seifert, Sönke and Hirata, Hirohito and Isomura, Noritake and Nigam, Sandeep and Majumder, Chiranjib and Watanabe, Yoshihide and Fortunelli, Alessandro and Vajda, Stefan},
abstractNote = {Catalytic CO oxidation is unveiled on size-selected Pt10 clusters deposited on two very different ultrathin (≈0.5–0.7 nm thick) alumina films: (i) a highly ordered alumina obtained under ultra-high vacuum (UHV) by oxidation of the NiAl(110) surface and (ii) amorphous alumina obtained by atomic layer deposition (ALD) on a silicon chip that is a close model of real-world supports. Notably, when exposed to realistic reaction conditions, the Pt10/UHV-alumina system undergoes a morphological transition in both the clusters and the substrate, and becomes closely akin to Pt10/ALD-alumina, thus reconciling UHV-type surface-science and real-world experiments. The Pt10 clusters, thoroughly characterized via combined experimental techniques and theoretical analysis, exhibit among the highest CO oxidation activity per Pt atom reported for CO oxidation catalysts, due to the interplay of ultra-small size and support effects. Lastly, a coherent interdisciplinary picture then emerges for this catalytic system.},
doi = {10.1039/c6ta10989f},
journal = {Journal of Materials Chemistry. A},
number = 10,
volume = 5,
place = {United States},
year = {Fri Feb 03 00:00:00 EST 2017},
month = {Fri Feb 03 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 59 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters
journal, March 2011
- Allian, Ayman D.; Takanabe, Kazuhiro; Fujdala, Kyle L.
- Journal of the American Chemical Society, Vol. 133, Issue 12
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Catalytic CO oxidation reaction studies on lithographically fabricated platinum nanowire arrays with different oxide supports
journal, October 2006
- Contreras, A. M.; Yan, X. -M.; Kwon, S.
- Catalysis Letters, Vol. 111, Issue 1-2
Molecular Studies of Catalytic Reactions on Crystal Surfaces at High Pressures and High Temperatures by Infrared−Visible Sum Frequency Generation (SFG) Surface Vibrational Spectroscopy
journal, March 1999
- Somorjai, Gabor A.; Rupprechter, Günther
- The Journal of Physical Chemistry B, Vol. 103, Issue 10
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO2 Surfaces
journal, November 2009
- Kaden, W. E.; Wu, T.; Kunkel, W. A.
- Science, Vol. 326, Issue 5954
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
New Material Needs for Hydrocarbon Fuel Processing: Generating Hydrogen for the PEM Fuel Cell
journal, August 2003
- Farrauto, R.; Hwang, S.; Shore, L.
- Annual Review of Materials Research, Vol. 33, Issue 1
Fischer–Tropsch Synthesis at a Low Pressure on Subnanometer Cobalt Oxide Clusters: The Effect of Cluster Size and Support on Activity and Selectivity
journal, January 2015
- Lee, Sungsik; Lee, Byeongdu; Seifert, Sönke
- The Journal of Physical Chemistry C, Vol. 119, Issue 20
Size and pressure independent kinetics of CO oxidation on alumina-supported iridium nanoparticles
journal, December 2008
- Sushchikh, Michael; Cameron, Lucas; Metiu, Horia
- International Journal of Chemical Kinetics, Vol. 40, Issue 12
Catalysis by clusters with precise numbers of atoms
journal, July 2015
- Tyo, Eric C.; Vajda, Stefan
- Nature Nanotechnology, Vol. 10, Issue 7
Size-Dependent Subnanometer Pd Cluster (Pd 4 , Pd 6 , and Pd 17 ) Water Oxidation Electrocatalysis
journal, June 2013
- Kwon, Gihan; Ferguson, Glen A.; Heard, Christopher J.
- ACS Nano, Vol. 7, Issue 7
A first-principles theoretical approach to heterogeneous nanocatalysis
journal, January 2012
- Negreiros, Fabio R.; Aprà, Edoardo; Barcaro, Giovanni
- Nanoscale, Vol. 4, Issue 4
Molecular beam experiments on model catalysts
journal, July 2005
- Libuda, J.; Freund, H. -J.
- Surface Science Reports, Vol. 57, Issue 7-8
Catalytic Oxidation of Carbon Monoxide on Monodispersed Platinum Clusters: Each Atom Counts
journal, April 1999
- Heiz, U.; Sanchez, A.; Abbet, S.
- Journal of the American Chemical Society, Vol. 121, Issue 13
Infrared study of the oxidation of carbon monoxide over Pt/Al2O3
journal, January 1992
- Anderson, James A.
- Journal of the Chemical Society, Faraday Transactions, Vol. 88, Issue 8
Generating Highly Active Partially Oxidized Platinum during Oxidation of Carbon Monoxide over Pt/Al 2 O 3 : In Situ, Time-Resolved, and High-Energy-Resolution X-Ray Absorption Spectroscopy
journal, October 2008
- Singh, Jagdeep; Alayon, Evalyn M. C.; Tromp, Moniek
- Angewandte Chemie International Edition, Vol. 47, Issue 48
Steady-state oxidation of carbon monoxide over supported noble metals with particular reference to platinum
journal, October 1978
- Cant, N.
- Journal of Catalysis, Vol. 54, Issue 3
Adsorption of O2 and oxidation of CO at Au nanoparticles supported by TiO2(110)
journal, April 2004
- Molina, L. M.; Rasmussen, M. D.; Hammer, B.
- The Journal of Chemical Physics, Vol. 120, Issue 16
Catalytic oxidation of CO by platinum group metals: from ultrahigh vacuum to elevated pressures
journal, August 2002
- Santra, A. K.; Goodman, D. W.
- Electrochimica Acta, Vol. 47, Issue 22-23
Catalysts for automobile emission control
journal, January 1980
- Kummer, J. T.
- Progress in Energy and Combustion Science, Vol. 6, Issue 2
Systematic study on novel catalytic activity of CO oxidation driven by strong electronic interaction between the monatomic-layered Pt 30 cluster disk and the Si substrate
journal, January 2014
- Yasumatsu, Hisato; Fukui, Nobuyuki
- Phys. Chem. Chem. Phys., Vol. 16, Issue 48
Atomic structure of surface defects in alumina studied by dynamic force microscopy: strain-relief-, translation- and reflection-related boundaries, including their junctions
journal, December 2011
- Simon, G. H.; König, T.; Heinke, L.
- New Journal of Physics, Vol. 13, Issue 12
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Ordered Arrays of Size-Selected Oxide Nanoparticles
journal, May 2012
- Gragnaniello, Luca; Ma, Teng; Barcaro, Giovanni
- Physical Review Letters, Vol. 108, Issue 19
Temperature Dependent CO Oxidation Mechanisms on Size-Selected Clusters
journal, December 2009
- Kunz, Sebastian; Schweinberger, Florian F.; Habibpour, Vahideh
- The Journal of Physical Chemistry C, Vol. 114, Issue 3
Structure of the Ultrathin Aluminum Oxide Film on NiAl(110)
journal, June 2005
- Kresse, G.
- Science, Vol. 308, Issue 5727
A Single-Site Platinum CO Oxidation Catalyst in Zeolite KLTL: Microscopic and Spectroscopic Determination of the Locations of the Platinum Atoms
journal, July 2014
- Kistler, Joseph D.; Chotigkrai, Nutchapon; Xu, Pinghong
- Angewandte Chemie International Edition, Vol. 53, Issue 34
Size-dependent catalytic activity and geometries of size-selected Pt clusters on TiO2(110) surfaces
journal, January 2011
- Watanabe, Yoshihide; Wu, Xingyang; Hirata, Hirohito
- Catalysis Science & Technology, Vol. 1, Issue 8, p. 1490-1495
Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015
- Ding, K.; Gulec, A.; Johnson, A. M.
- Science, Vol. 350, Issue 6257
Fabrication of Dense Arrays of Platinum Nanowires on Silica, Alumina, Zirconia and Ceria Surfaces as 2-D Model Catalysts
journal, December 2005
- Yan, X. -M.; Kwon, S.; Contreras, A. M.
- Catalysis Letters, Vol. 105, Issue 3-4
Magic Number Pt 13 and Misshapen Pt 12 Clusters: Which One is the Better Catalyst?
journal, August 2013
- Imaoka, Takane; Kitazawa, Hirokazu; Chun, Wang-Jae
- Journal of the American Chemical Society, Vol. 135, Issue 35
Stable Subnanometer Cobalt Oxide Clusters on Ultrananocrystalline Diamond and Alumina Supports: Oxidation State and the Origin of Sintering Resistance
journal, November 2012
- Ferguson, Glen A.; Yin, Chunrong; Kwon, Gihan
- The Journal of Physical Chemistry C, Vol. 116, Issue 45
Structural characterization of a model catalyst: Pt/Al2O3/NiAl(110)
journal, July 1995
- Bertrams, Th.; Winkelmann, F.; Uttich, Th.
- Surface Science, Vol. 331-333
Formation of a well-ordered aluminium oxide overlayer by oxidation of NiAl(110)
journal, December 1991
- Jaeger, R. M.; Kuhlenbeck, H.; Freund, H. -J.
- Surface Science, Vol. 259, Issue 3
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
Novel Powder-Supported Size-Selected Clusters for Heterogeneous Catalysis under Realistic Reaction Conditions
journal, December 2012
- Habibpour, V.; Song, M. Y.; Wang, Z. W.
- The Journal of Physical Chemistry C, Vol. 116, Issue 50
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au8 Clusters on MgO
journal, January 2005
- Yoon, Bokwon; Häkkinen, Hannu; Landman, Uzi
- Science, Vol. 307, Issue 5708, p. 403-407
Density-functional global optimization of gold nanoclusters
journal, May 2006
- Aprà, Edoardo; Ferrando, Riccardo; Fortunelli, Alessandro
- Physical Review B, Vol. 73, Issue 20
Morphology and chemical states of size-selected Pt n clusters on an aluminium oxide film on NiAl(110)
journal, January 2014
- Beniya, Atsushi; Isomura, Noritake; Hirata, Hirohito
- Phys. Chem. Chem. Phys., Vol. 16, Issue 48
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Structure of Ag Clusters Grown on Fs-Defect Sites of an MgO(1 0 0) Surface
journal, July 2007
- Barcaro, Giovanni; Aprà, Edoardo; Fortunelli, Alessandro
- Chemistry - A European Journal, Vol. 13, Issue 22
Catalysis by Gold
journal, January 1999
- Bond, Geoffrey C.; Thompson, David T.
- Catalysis Reviews, Vol. 41, Issue 3-4
Atomic resolution on small three-dimensional metal clusters by STM
journal, November 1997
- Piednoir, A.; Perrot, E.; Granjeaud, S.
- Surface Science, Vol. 391, Issue 1-3
Reactivity of supported platinum nanoclusters studied by in situ GISAXS: clusters stability under hydrogen
journal, October 2006
- Winans, Randall E.; Vajda, Stefan; Ballentine, Gregory E.
- Topics in Catalysis, Vol. 39, Issue 3-4
Bias dependent apparent height of an Al2O3 thin film on NiAl(110), and of supported Pd clusters
journal, March 2001
- Højrup Hansen, K.; Worren, T.; Lægsgaard, E.
- Surface Science, Vol. 475, Issue 1-3
CO oxidation trends on Pt-group metals from ultrahigh vacuum to near atmospheric pressures: A combined in situ PM-IRAS and reaction kinetics study
journal, January 2009
- Gao, F.; McClure, S. M.; Cai, Y.
- Surface Science, Vol. 603, Issue 1
CO oxidation over supported Pt clusters at different CO coverage
journal, February 2016
- Zhou, Hu; Chen, Xianlang; Wang, Jianguo
- International Journal of Quantum Chemistry, Vol. 116, Issue 12
Interaction of oxygen with palladium deposited on a thin alumina film
journal, April 2002
- Shaikhutdinov, Sh.; Heemeier, M.; Hoffmann, J.
- Surface Science, Vol. 501, Issue 3
Hydroxylation-induced modifications of the Al2O3/NiAl(001) surface at low water vapour pressure
journal, April 2005
- Maurice, Vincent; Frémy, Nicolas; Marcus, Philippe
- Surface Science, Vol. 581, Issue 1
Heterogeneous catalysis: Enigmas, illusions, challenges, realities, and emergent strategies of design
journal, May 2008
- Thomas, John Meurig
- The Journal of Chemical Physics, Vol. 128, Issue 18
The origin of apparent deactivation during the oxidation of carbon monoxide over silica-supported platinum at moderate temperatures
journal, January 1986
- Cant, N.
- Journal of Catalysis, Vol. 97, Issue 1
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism
journal, April 1990
- Vanderbilt, David
- Physical Review B, Vol. 41, Issue 11, p. 7892-7895
Utilizing Quantitative in Situ FTIR Spectroscopy To Identify Well-Coordinated Pt Atoms as the Active Site for CO Oxidation on Al 2 O 3 -Supported Pt Catalysts
journal, July 2016
- Kale, Matthew J.; Christopher, Phillip
- ACS Catalysis, Vol. 6, Issue 8
Growth pattern and bonding trends in Pt (n= 2–13) clusters: Theoretical investigation based on first principle calculations
journal, October 2007
- Bhattacharyya, Kaustava; Majumder, Chiranjib
- Chemical Physics Letters, Vol. 446, Issue 4-6
A new experimental setup for high-pressure catalytic activity measurements on surface deposited mass-selected Pt clusters
journal, September 2009
- Watanabe, Yoshihide; Isomura, Noritake
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 27, Issue 5
Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters
journal, February 2012
- Bonanni, Simon; Aït-Mansour, Kamel; Harbich, Wolfgang
- Journal of the American Chemical Society, Vol. 134, Issue 7, p. 3445-3450
Mechanism of the CO oxidation reaction on O-precovered Pt(111) surfaces studied with near-edge x-ray absorption fine structure spectroscopy
journal, April 2005
- Nakai, I.; Kondoh, H.; Amemiya, K.
- The Journal of Chemical Physics, Vol. 122, Issue 13
Effect of metal dispersion in CO oxidation on supported Pt catalysts
journal, April 1982
- Herskowitz, M.
- Journal of Catalysis, Vol. 74, Issue 2
Support-dependent Performance of Size-selected Subnanometer Cobalt Cluster-based Catalysts in the Dehydrogenation of Cyclohexene
journal, August 2012
- Lee, Sungsik; Di Vece, Marcel; Lee, Byeongdu
- ChemCatChem, Vol. 4, Issue 10
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008
- Herzing, A. A.; Kiely, C. J.; Carley, A. F.
- Science, Vol. 321, Issue 5894
Simultaneous measurement of X-ray small angle scattering, absorption and reactivity: A continuous flow catalysis reactor
journal, September 2011
- Lee, Sungsik; Lee, Byeongdu; Seifert, Soenke
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009
- Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P.
- Nature Materials, Vol. 8, Issue 3
CO Oxidation by Subnanometer Ag x Au 3– x Supported Clusters via Density Functional Theory Simulations
journal, July 2012
- Negreiros, F. R.; Sementa, L.; Barcaro, G.
- ACS Catalysis, Vol. 2, Issue 9
Works referencing / citing this record:
Origin of the High CO Oxidation Activity on CeO 2 Supported Pt Nanoparticles: Weaker Binding of CO or Facile Oxygen Transfer from the Support?
journal, March 2020
- Lu, Yubing; Thompson, Coogan; Kunwar, Deepak
- ChemCatChem, Vol. 12, Issue 6
Bifunctional CO oxidation over Mn-mullite anchored Pt sub-nanoclusters via atomic layer deposition
journal, January 2018
- Liu, Xiao; Tang, Yuanting; Shen, Meiqing
- Chemical Science, Vol. 9, Issue 9
Computational screening of a single transition metal atom supported on the C 2 N monolayer for electrochemical ammonia synthesis
journal, January 2018
- Wang, Zhongxu; Yu, Zhigang; Zhao, Jingxiang
- Physical Chemistry Chemical Physics, Vol. 20, Issue 18
Single atom alloy catalyst for SO 3 decomposition: enhancement of platinum catalyst's performance by Ag atom embedding
journal, January 2018
- Nigam, Sandeep; Majumder, Chiranjib
- Nanoscale, Vol. 10, Issue 44
Tuning the structure of bifunctional Pt/SmMn 2 O 5 interfaces for promoted low-temperature CO oxidation activity
journal, January 2019
- Liu, Xiao; Yang, Jiaqiang; Shen, Gurong
- Nanoscale, Vol. 11, Issue 17
2D oxides on metal materials: concepts, status, and perspectives
journal, January 2019
- Barcaro, Giovanni; Fortunelli, Alessandro
- Physical Chemistry Chemical Physics, Vol. 21, Issue 22
γ-Alumina-supported Pt 17 cluster: controlled loading, geometrical structure, and size-specific catalytic activity for carbon monoxide and propylene oxidation
journal, January 2020
- Negishi, Yuichi; Shimizu, Nobuyuki; Funai, Kanako
- Nanoscale Advances, Vol. 2, Issue 2
Atmosphere-dependent stability and mobility of catalytic Pt single atoms and clusters on γ-Al 2 O 3
journal, January 2019
- Dessal, Caroline; Sangnier, Alexis; Chizallet, Céline
- Nanoscale, Vol. 11, Issue 14
Perspective: Size selected clusters for catalysis and electrochemistry
journal, March 2018
- Halder, Avik; Curtiss, Larry A.; Fortunelli, Alessandro
- The Journal of Chemical Physics, Vol. 148, Issue 11
Geometry control of size selected Pt clusters bound to Si substrate surface by cluster impact deposition
journal, December 2019
- Fukui, Nobuyuki; Yasumatsu, Hisato
- The Journal of Chemical Physics, Vol. 151, Issue 22
Active Sites in Heterogeneous Catalytic Reaction on Metal and Metal Oxide: Theory and Practice
journal, October 2018
- Pan, Yanbo; Shen, Xiaochen; Yao, Libo
- Catalysts, Vol. 8, Issue 10
Restructuring effects of the chemical environment in metal nanocatalysis and single-atom catalysis
journal, April 2020
- Piccolo, Laurent
- Catalysis Today