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Title: Arsenic, vanadium, iron, and manganese biogeochemistry in a deltaic wetland, southern Louisiana, USA

Abstract

Geochemical cycling of the redox-sensitive trace elements arsenic (As) and vanadium (V) was examined in shallow pore waters from a marsh in an interdistributary embayment of the lower Mississippi River Delta. In particular, we explore how redox changes with depth and distance from the Mississippi River affect As and V cycling in the marsh pore waters. Previous geophysical surveys and radon mass balance calculations suggested that Myrtle Grove Canal and bordering marsh receive fresh groundwater, derived in large part from seepage of the Mississippi River, which subsequently mixes with brackish waters of Barataria Bay. In addition, the redox geochemistry of pore waters in the wetlands is affected by Fe and S cycling in the shallow subsurface (0-20 cm). Sediments with high organic matter content undergo SO42- reduction, a process ubiquitous in the shallow subsurface but largely absent at greater depths (~3 m). Instead, at depth, in the absence of organic-rich sediments, Fe concentrations are elevated, suggesting that reduction of Fe(III) oxides/oxyhydroxides buffers redox conditions. Arsenic and V cycling in the shallow subsurface are decoupled from their behavior at depth, where both V and As appear to be removed from solution by either diffusion or adsorption onto, or co-precipitation with, authigenicmore » minerals within the deeper aquifer sediments. Pore water As concentrations are greatest in the shallow subsurface (e.g., up to 315 nmol kg-1 in the top ~20 cm of the sediment) but decrease with depth, reaching values <30 nmol kg-1 at depths between 3 and 4 m. Vanadium concentrations appear to be tightly coupled to Fe cycling in the shallow subsurface, but at depth, V may be adsorbed to clay or sedimentary organic matter (SOM). Diffusive fluxes are calculated to examine the export of trace elements from the shallow marsh pore waters to the overlying canal water that floods the marsh. The computed fluxes suggest that the shallow sediment serves as a source of Fe, Mn, and As to the surface waters, whereas the sediments act as a sink for V. Iron and Mn fluxes are substantial, ranging from 50 to 30,000 and 770 to 4,300 nmol cm-2 day-1, respectively, whereas As fluxes are much less, ranging from 2.1 to 17 nmol cm-2 day-1. Vanadium fluxes range from 3.0 nmol cm-2 day-1 directed into the sediment to 1.7 nmol cm-2 day-1 directed out of the sediment« less

Authors:
 [1];  [2];  [3];  [3];  [2];  [1];  [1]
+ Show Author Affiliations
  1. Tulane Univ., New Orleans, LA (United States)
  2. Tulane Univ., New Orleans, LA (United States); Louisiana Univ., Marine Consortium, Cocodrie, LA (United States)
  3. Univ. of North Carolina, Chapel Hill, NC (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
National Science Foundation (NSF); USDOE
OSTI Identifier:
1352446
Report Number(s):
LA-UR-16-25809
Journal ID: ISSN 0304-4203
Grant/Contract Number:  
AC52-06NA25396; EAR-1141692; EAR-1141685; EAR-1141716
Resource Type:
Accepted Manuscript
Journal Name:
Marine Chemistry
Additional Journal Information:
Journal Volume: 192; Journal Issue: C; Journal ID: ISSN 0304-4203
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; earth sciences; vanadium; arsenic; subterranean estuary; Myrtle Grove; wetland biogeochemistry; redox-sensitive trace elements; diffusive fluxes

Citation Formats

Telfeyan, Katherine, Breaux, Alexander, Kim, Jihyuk, Cable, Jaye E., Kolker, Alexander S., Grimm, Deborah A., and Johannesson, Karen H. Arsenic, vanadium, iron, and manganese biogeochemistry in a deltaic wetland, southern Louisiana, USA. United States: N. p., 2017. Web. doi:10.1016/j.marchem.2017.03.010.
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Telfeyan, Katherine, Breaux, Alexander, Kim, Jihyuk, Cable, Jaye E., Kolker, Alexander S., Grimm, Deborah A., & Johannesson, Karen H. Arsenic, vanadium, iron, and manganese biogeochemistry in a deltaic wetland, southern Louisiana, USA. United States. https://doi.org/10.1016/j.marchem.2017.03.010
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Telfeyan, Katherine, Breaux, Alexander, Kim, Jihyuk, Cable, Jaye E., Kolker, Alexander S., Grimm, Deborah A., and Johannesson, Karen H. Wed . "Arsenic, vanadium, iron, and manganese biogeochemistry in a deltaic wetland, southern Louisiana, USA". United States. https://doi.org/10.1016/j.marchem.2017.03.010. https://www.osti.gov/servlets/purl/1352446.
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@article{osti_1352446,
title = {Arsenic, vanadium, iron, and manganese biogeochemistry in a deltaic wetland, southern Louisiana, USA},
author = {Telfeyan, Katherine and Breaux, Alexander and Kim, Jihyuk and Cable, Jaye E. and Kolker, Alexander S. and Grimm, Deborah A. and Johannesson, Karen H.},
abstractNote = {Geochemical cycling of the redox-sensitive trace elements arsenic (As) and vanadium (V) was examined in shallow pore waters from a marsh in an interdistributary embayment of the lower Mississippi River Delta. In particular, we explore how redox changes with depth and distance from the Mississippi River affect As and V cycling in the marsh pore waters. Previous geophysical surveys and radon mass balance calculations suggested that Myrtle Grove Canal and bordering marsh receive fresh groundwater, derived in large part from seepage of the Mississippi River, which subsequently mixes with brackish waters of Barataria Bay. In addition, the redox geochemistry of pore waters in the wetlands is affected by Fe and S cycling in the shallow subsurface (0-20 cm). Sediments with high organic matter content undergo SO42- reduction, a process ubiquitous in the shallow subsurface but largely absent at greater depths (~3 m). Instead, at depth, in the absence of organic-rich sediments, Fe concentrations are elevated, suggesting that reduction of Fe(III) oxides/oxyhydroxides buffers redox conditions. Arsenic and V cycling in the shallow subsurface are decoupled from their behavior at depth, where both V and As appear to be removed from solution by either diffusion or adsorption onto, or co-precipitation with, authigenic minerals within the deeper aquifer sediments. Pore water As concentrations are greatest in the shallow subsurface (e.g., up to 315 nmol kg-1 in the top ~20 cm of the sediment) but decrease with depth, reaching values <30 nmol kg-1 at depths between 3 and 4 m. Vanadium concentrations appear to be tightly coupled to Fe cycling in the shallow subsurface, but at depth, V may be adsorbed to clay or sedimentary organic matter (SOM). Diffusive fluxes are calculated to examine the export of trace elements from the shallow marsh pore waters to the overlying canal water that floods the marsh. The computed fluxes suggest that the shallow sediment serves as a source of Fe, Mn, and As to the surface waters, whereas the sediments act as a sink for V. Iron and Mn fluxes are substantial, ranging from 50 to 30,000 and 770 to 4,300 nmol cm-2 day-1, respectively, whereas As fluxes are much less, ranging from 2.1 to 17 nmol cm-2 day-1. Vanadium fluxes range from 3.0 nmol cm-2 day-1 directed into the sediment to 1.7 nmol cm-2 day-1 directed out of the sediment},
doi = {10.1016/j.marchem.2017.03.010},
journal = {Marine Chemistry},
number = C,
volume = 192,
place = {United States},
year = {Wed Apr 05 00:00:00 EDT 2017},
month = {Wed Apr 05 00:00:00 EDT 2017}
}
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Works referenced in this record:

Determination of Dominant Biogeochemical Processes in a Contaminated Aquifer‐Wetland System Using Multivariate Statistical Analysis
journal, January 2008

  • Báez‐Cazull, Susan E.; McGuire, Jennifer T.; Cozzarelli, Isabelle M.
  • Journal of Environmental Quality, Vol. 37, Issue 1
  • DOI: 10.2134/jeq2007.0169

Cycling of trace metals (Mn, Fe, Mo, U, V, Cr) in deep pore waters of intertidal flat sediments
journal, June 2008

  • Beck, Melanie; Dellwig, Olaf; Schnetger, Bernhard
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 12
  • DOI: 10.1016/j.gca.2008.04.013

The distribution and speciation of dissolved trace metals in a shallow subterranean estuary
journal, August 2010

Sediment diffusive fluxes of Fe, Mn, and P in a eutrophic lake: Contribution from lateral vs bottom sediments
journal, January 1996

  • Belzile, Nelson; Pizarro, Jaime; Filella, Montserrat
  • Aquatic Sciences, Vol. 58, Issue 4
  • DOI: 10.1007/BF00877474

Arsenic and its speciation analysis using high-performance liquid chromatography and inductively coupled plasma mass spectrometry
journal, August 2004

Sources of Terrestrial Organic Carbon in the Mississippi Plume Region: Evidence for the Importance of Coastal Marsh Inputs
journal, September 2010

  • Bianchi, Thomas S.; Wysocki, Laura A.; Schreiner, Kathryn M.
  • Aquatic Geochemistry, Vol. 17, Issue 4-5
  • DOI: 10.1007/s10498-010-9110-3

Impacts of diverted freshwater on dissolved organic matter and microbial communities in Barataria Bay, Louisiana, U.S.A.
journal, December 2011

Heavy metal fluxes at the sediment–water interface of three coastal ecosystems from south-west of the Iberian Peninsula
journal, March 2000

Geochemical Cycling of Arsenic in a Coastal Aquifer
journal, May 2006

  • Bone, Sharon E.; Gonneea, Meagan Eagle; Charette, Matthew A.
  • Environmental Science & Technology, Vol. 40, Issue 10
  • DOI: 10.1021/es052352h

In situ analysis of thioarsenite complexes in neutral to alkaline arsenic sulphide solutions
journal, October 2005

The biogeochemistry of manganese and iron reduction in marine sediments
journal, October 1993

Sulfur biogeochemical cycling and novel Fe–S mineralization pathways in a tidally re-flooded wetland
journal, June 2011

  • Burton, Edward D.; Bush, Richard T.; Johnston, Scott G.
  • Geochimica et Cosmochimica Acta, Vol. 75, Issue 12
  • DOI: 10.1016/j.gca.2011.03.020

Coupling of arsenic mobility to sulfur transformations during microbial sulfate reduction in the presence and absence of humic acid
journal, April 2013

Application of 222 Rn and CH 4 for assessment of groundwater discharge to the coastal ocean
journal, September 1996

  • Cable, Jaye E.; Bugna, Glynnis C.; Burnett, William C.
  • Limnology and Oceanography, Vol. 41, Issue 6
  • DOI: 10.4319/lo.1996.41.6.1347

The geochemistry of dissolved inorganic carbon in a surficial groundwater aquifer in North Inlet, South Carolina, and the carbon fluxes to the coastal ocean
journal, February 2003

Reactive iron in marine sediments
journal, March 1989

The role of soluble Fe(III) in the cycling of iron and sulfur in coastal marine sediments
journal, July 2005

The behaviour of arsenic in muddy sediments of the Bay of Biscay (France)
journal, August 2003

Trace element cycling in a subterranean estuary: Part 2. Geochemistry of the pore water
journal, February 2006

  • Charette, Matthew A.; Sholkovitz, Edward R.
  • Geochimica et Cosmochimica Acta, Vol. 70, Issue 4
  • DOI: 10.1016/j.gca.2005.10.019

Radium isotopes as tracers of iron sources fueling a Southern Ocean phytoplankton bloom
journal, September 2007

  • Charette, Matthew A.; Gonneea, Meagan E.; Morris, Paul J.
  • Deep Sea Research Part II: Topical Studies in Oceanography, Vol. 54, Issue 18-20
  • DOI: 10.1016/j.dsr2.2007.06.003

Submarine groundwater discharge of rare earth elements to a tidally-mixed estuary in Southern Rhode Island
journal, March 2015

Rare earth element cycling in a sandy subterranean estuary in Florida, USA
journal, November 2015

Sorption of Arsenite, Arsenate, and Thioarsenates to Iron Oxides and Iron Sulfides: A Kinetic and Spectroscopic Investigation
journal, May 2013

  • Couture, R. -M.; Rose, J.; Kumar, N.
  • Environmental Science & Technology, Vol. 47, Issue 11
  • DOI: 10.1021/es3049724

Fine-scale vertical distributions of microbial biomass and activity in California Borderland sediments
journal, March 1986

  • Craven, D. B.; Jahnke, R. A.; Carlucci, A. F.
  • Deep Sea Research Part A. Oceanographic Research Papers, Vol. 33, Issue 3
  • DOI: 10.1016/0198-0149(86)90098-1

Arsenic speciation in the environment
journal, June 1989

  • Cullen, William R.; Reimer, Kenneth J.
  • Chemical Reviews, Vol. 89, Issue 4
  • DOI: 10.1021/cr00094a002

Antimony and arsenic biogeochemistry in the western Atlantic Ocean
journal, January 2001

  • Cutter, Gregory A.; Cutter, Lynda S.; Featherstone, Alison M.
  • Deep Sea Research Part II: Topical Studies in Oceanography, Vol. 48, Issue 13
  • DOI: 10.1016/S0967-0645(01)00023-6

Modeling estuarine-shelf exchanges in a deltaic estuary: Implications for coastal carbon budgets and hypoxia
journal, April 2010

Impacts of Mississippi River diversions on salinity gradients in a deltaic Louisiana estuary: Ecological and management implications
journal, October 2012

  • Das, Anindita; Justic, Dubravko; Inoue, Masamichi
  • Estuarine, Coastal and Shelf Science, Vol. 111
  • DOI: 10.1016/j.ecss.2012.06.005

Restoration of the Mississippi Delta: Lessons from Hurricanes Katrina and Rita
journal, March 2007

Sulfate reduction in Louisiana marsh soils of varying salinities
journal, January 2002

  • DeLaune, Ronald D.; Devai, Istvan; Crozier, Carl R.
  • Communications in Soil Science and Plant Analysis, Vol. 33, Issue 1-2
  • DOI: 10.1081/CSS-120002379

Impact of Mississippi River freshwater reintroduction on enhancing marsh accretionary processes in a Louisiana estuary
journal, November 2003

The behaviors and sources of dissolved arsenic and antimony in Bohai Bay
journal, August 2010

The solubility of amorphous As2S3 from 25 to 90°C
journal, June 1992

Arsenic speciation and diffusion flux in Danshuei Estuary sediments, Northern Taiwan
journal, December 2015

Spatial and Temporal Variations of Groundwater Arsenic in South and Southeast Asia
journal, May 2010

Cold-front-induced flushing of the Louisiana Bays
journal, September 2010

The presence of vanadium in groundwater of southeastern extreme the pampean region Argentina
journal, August 2007

  • Fiorentino, Carmen E.; Paoloni, Juan D.; Sequeira, Mario E.
  • Journal of Contaminant Hydrology, Vol. 93, Issue 1-4
  • DOI: 10.1016/j.jconhyd.2007.02.001

Early oxidation of organic matter in pelagic sediments of the eastern equatorial Atlantic: suboxic diagenesis
journal, July 1979

Trace element geochemistry of groundwater in a karst subterranean estuary (Yucatan Peninsula, Mexico)
journal, May 2014

  • Gonneea, Meagan Eagle; Charette, Matthew A.; Liu, Qian
  • Geochimica et Cosmochimica Acta, Vol. 132
  • DOI: 10.1016/j.gca.2014.01.037

Thermodynamics of hydrothermal systems at elevated temperatures and pressures
journal, September 1969

Greedy algae reduce arsenate
journal, November 2003

  • Hellweger, Ferdi L.; Farley, Kevin J.; Lall, Upmanu
  • Limnology and Oceanography, Vol. 48, Issue 6
  • DOI: 10.4319/lo.2003.48.6.2275

Activity of zero-valent sulfur in sulfidic natural waters
journal, August 2014

Thermodynamic model for arsenic speciation in sulfidic waters: A novel use of ab initio computations
journal, September 2008

Reactions of metal ions at surfaces of hydrous iron oxide
journal, April 1977

Arsenic speciation in Mono Lake, California: Response to seasonal stratification and anoxia
journal, April 2005

  • Hollibaugh, James T.; Carini, Steve; Gürleyük, Hakan
  • Geochimica et Cosmochimica Acta, Vol. 69, Issue 8
  • DOI: 10.1016/j.gca.2004.10.011

Characterisation of the hydrology of an estuarine wetland
journal, November 1998

A high-resolution integrated hydrology–hydrodynamic model of the Barataria Basin system
journal, September 2008

Arsenic-sulfides confound anion exchange resin speciation of aqueous arsenic
journal, March 2004

Vanadium behaviour in the global ocean and in the Mediterranean sea
journal, May 1987

Balancing the global oceanic neodymium budget: Evaluating the role of groundwater
journal, January 2007

  • Johannesson, Karen H.; Burdige, David J.
  • Earth and Planetary Science Letters, Vol. 253, Issue 1-2
  • DOI: 10.1016/j.epsl.2006.10.021

Rare earth element concentrations and speciation in organic-rich blackwaters of the Great Dismal Swamp, Virginia, USA
journal, September 2004

Submarine groundwater discharge is an important net source of light and middle REEs to coastal waters of the Indian River Lagoon, Florida, USA
journal, February 2011

  • Johannesson, Karen H.; Chevis, Darren A.; Burdige, David J.
  • Geochimica et Cosmochimica Acta, Vol. 75, Issue 3
  • DOI: 10.1016/j.gca.2010.11.005

Submarine groundwater discharge (SGD) into the Yellow Sea revealed by 228Ra and 226Ra isotopes: Implications for global silicate fluxes
journal, August 2005

  • Kim, Guebuem; Ryu, Jae-Woong; Yang, Han-Soeb
  • Earth and Planetary Science Letters, Vol. 237, Issue 1-2
  • DOI: 10.1016/j.epsl.2005.06.011

Experimental analysis of arsenic precipitation during microbial sulfate and iron reduction in model aquifer sediment reactors
journal, May 2010

  • Kirk, Matthew F.; Roden, Eric E.; Crossey, Laura J.
  • Geochimica et Cosmochimica Acta, Vol. 74, Issue 9
  • DOI: 10.1016/j.gca.2010.02.002

Composition and depth distribution of hydrocarbons in Barataria Bay marsh sediments after the Deepwater Horizon oil spill
journal, July 2016

An evaluation of subsidence rates and sea-level variability in the northern Gulf of Mexico: SUBSIDENCE AND SEA LEVEL VARIABILITY
journal, November 2011

  • Kolker, Alexander S.; Allison, Mead A.; Hameed, Sultan
  • Geophysical Research Letters, Vol. 38, Issue 21
  • DOI: 10.1029/2011GL049458

Pathways and processes associated with the transport of groundwater in deltaic systems
journal, August 2013

Seasonal cycling of Fe in saltmarsh sediments
journal, May 1995

  • Kostka, Joel E.; Luther, George W.
  • Biogeochemistry, Vol. 29, Issue 2
  • DOI: 10.1007/BF00000230

Distribution of organic and reduced sulfur forms in marsh soils of coastal Louisiana
journal, July 1992

Diffusion of ions in sea water and in deep-sea sediments
journal, May 1974

The geochemistry of salt marshes: Sedimentary ion diffusion, sulfate reduction, and pyritization
journal, August 1983

Dissolved organic Fe(III) and Fe(II) complexes in salt marsh porewaters
journal, March 1996

  • Luther, George W.; Shellenbarger, P. Ann; Brendel, Paul J.
  • Geochimica et Cosmochimica Acta, Vol. 60, Issue 6
  • DOI: 10.1016/0016-7037(95)00444-0

Groundwater-derived dissolved inorganic and organic carbon exports from a mangrove tidal creek: The missing mangrove carbon sink?
journal, February 2013

Importance of budgets for estimating the input of groundwater-derived nutrients to an eutrophic tidal river and estuary
journal, April 2014

  • Makings, Uriah; Santos, Isaac R.; Maher, Damien T.
  • Estuarine, Coastal and Shelf Science, Vol. 143
  • DOI: 10.1016/j.ecss.2014.02.003

Transition Metal Bonding in Humic Acid: an esr Study
journal, January 1978

Mobility and Reactions of VO2+ on Hydrated Smectite Surfaces1
journal, January 1979

Arsenic, antimony and vanadium in the North Atlantic Ocean
journal, December 1988

  • Mlddelburg, Jack J.; Hoede, Dirk; Van Der Sloot, Hans A.
  • Geochimica et Cosmochimica Acta, Vol. 52, Issue 12
  • DOI: 10.1016/0016-7037(88)90154-8

Sulfate reduction and porewater chemistry in a gulf coastJuncus roemerianus (Needlerush) marsh
journal, June 2004

Tungsten–molybdenum fractionation in estuarine environments
journal, March 2016

  • Mohajerin, T. Jade; Helz, George R.; Johannesson, Karen H.
  • Geochimica et Cosmochimica Acta, Vol. 177
  • DOI: 10.1016/j.gca.2015.12.030

The subterranean estuary: a reaction zone of ground water and sea water
journal, May 1999

Estimates of flushing times, submarine groundwater discharge, and nutrient fluxes to Okatee Estuary, South Carolina
journal, January 2006

  • Moore, Willard S.; Blanton, Jackson O.; Joye, Samantha B.
  • Journal of Geophysical Research, Vol. 111, Issue C9
  • DOI: 10.1029/2005JC003041

Diagenesis of oxyanions (V, U, Re, and Mo) in pore waters and sediments from a continental margin
journal, November 2005

  • Morford, Jennifer L.; Emerson, Steven R.; Breckel, Erin J.
  • Geochimica et Cosmochimica Acta, Vol. 69, Issue 21
  • DOI: 10.1016/j.gca.2005.05.015

The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters
journal, March 1987

Arsenic poisoning of Bangladesh groundwater
journal, September 1998

  • Nickson, Ross; McArthur, John; Burgess, William
  • Nature, Vol. 395, Issue 6700
  • DOI: 10.1038/26387

Thermodynamic Properties for Arsenic Minerals and Aqueous Species
journal, January 2014

  • Nordstrom, D. K.; Majzlan, J.; Konigsberger, E.
  • Reviews in Mineralogy and Geochemistry, Vol. 79, Issue 1
  • DOI: 10.2138/rmg.2014.79.4

Groundwater dynamics and surface water–groundwater interactions in a prograding delta island, Louisiana, USA
journal, May 2015

Geochemistry of redox-sensitive trace elements in a shallow subterranean estuary
journal, May 2015

The influence of sulfur and iron on dissolved arsenic concentrations in the shallow subsurface under changing redox conditions
journal, September 2004

  • O'Day, P. A.; Vlassopoulos, D.; Root, R.
  • Proceedings of the National Academy of Sciences, Vol. 101, Issue 38
  • DOI: 10.1073/pnas.0402775101

Fluxes of iron and manganese across the sediment–water interface under various redox conditions
journal, December 2007

Submarine groundwater discharge: An important source of new inorganic nitrogen to coral reef ecosystems
journal, January 2006

  • Paytan, Adina; Shellenbarger, Gregory G.; Street, Joseph H.
  • Limnology and Oceanography, Vol. 51, Issue 1
  • DOI: 10.4319/lo.2006.51.1.0343

Thioarsenates in Geothermal Waters of Yellowstone National Park:  Determination, Preservation, and Geochemical Importance
journal, August 2007

  • Planer-Friedrich, Britta; London, Jacqueline; McCleskey, R. Blaine
  • Environmental Science & Technology, Vol. 41, Issue 15
  • DOI: 10.1021/es070273v

Acute Toxicity of Thioarsenates to Vibrio Fischeri
journal, January 2008

  • Planer-Friedrich, Britta; Franke, Doreen; Merkel, Broder
  • Environmental Toxicology and Chemistry, Vol. 27, Issue 10
  • DOI: 10.1897/07-633.1

Assessment of vanadium distribution in shallow groundwaters
journal, February 2012

The response of coastal marshes to sea-level rise: Survival or submergence?
journal, February 1995

Behavior of dissolved inorganic arsenic in the Yellow Sea and East China Sea
journal, June 2010

  • Ren, J. L.; Zhang, J.; Li, D. D.
  • Deep Sea Research Part II: Topical Studies in Oceanography, Vol. 57, Issue 11-12
  • DOI: 10.1016/j.dsr2.2010.02.005

The solubility of FeS
journal, December 2006

Kinetics of Arsenate Reduction by Dissolved Sulfide
journal, November 2000

  • Rochette, Elizabeth A.; Bostick, Benjamin C.; Li, Guangchao
  • Environmental Science & Technology, Vol. 34, Issue 22
  • DOI: 10.1021/es000963y

Kinetics of iron complexation by dissolved natural organic matter in coastal waters
journal, December 2003

Dissolved iron exports from an estuary surrounded by coastal wetlands: Can small estuaries be a significant source of Fe to the ocean?
journal, November 2015

Elevated arsenic and manganese in groundwaters of Murshidabad, West Bengal, India
journal, August 2014

Uranium and barium cycling in a salt wedge subterranean estuary: The influence of tidal pumping
journal, August 2011

Porewater geochemistry in a Galician Ria (NW Iberian Peninsula): Implications for benthic fluxes of dissolved trace elements (Co, Cu, Ni, Pb, V, Zn)
journal, December 2009

Effect of tidal flooding on metal distribution in pore waters of marsh sediments and its transport to water column (Tagus estuary, Portugal)
journal, December 2010

Reactions forming pyrite and marcasite from solution: I. Nucleation of FeS2 below 100°C
journal, June 1991

Reactions forming pyrite and marcasite from solution: II. Via FeS precursors below 100°C
journal, June 1991

Early diagenesis in differing depositional environments: The response of transition metals in pore water
journal, May 1990

  • Shaw, Timothy J.; Gieskes, Joris M.; Jahnke, Richard A.
  • Geochimica et Cosmochimica Acta, Vol. 54, Issue 5
  • DOI: 10.1016/0016-7037(90)90149-F

Dissolved trace elements in the Mississippi River: Seasonal, interannual, and decadal variability
journal, October 1997

Dissolved vanadium on the Louisiana Shelf: effect of oxygen depletion
journal, June 1999

Dissolved vanadium in rivers: effects of silicate weathering
journal, April 2000

Nutrient inputs to the coastal ocean through submarine groundwater discharge: controls and potential impact
journal, August 2004

A review of the source, behaviour and distribution of arsenic in natural waters
journal, May 2002

Evaluating the source and seasonality of submarine groundwater discharge using a radon-222 pore water transport model
journal, September 2008

  • Smith, Christopher G.; Cable, Jaye E.; Martin, Jonathan B.
  • Earth and Planetary Science Letters, Vol. 273, Issue 3-4
  • DOI: 10.1016/j.epsl.2008.06.043

Thioarsenates in Sulfidic Waters
journal, August 2005

  • Stauder, S.; Raue, B.; Sacher, F.
  • Environmental Science & Technology, Vol. 39, Issue 16
  • DOI: 10.1021/es048034k

Hydrological dynamics of water sources in a Mediterranean lagoon
journal, January 2014

  • Stumpp, C.; Ekdal, A.; Gönenc, I. E.
  • Hydrology and Earth System Sciences, Vol. 18, Issue 12
  • DOI: 10.5194/hess-18-4825-2014

Diagenetic cycling of arsenic in Amazon shelf sediments
journal, May 1996

Redox Chemistry in the Root Zone of a Salt Marsh Sediment in the Tagus Estuary, Portugal
journal, September 2003

Uranium distribution in the coastal waters and pore waters of Tampa Bay, Florida
journal, February 2007

Vanadium geochemistry along groundwater flow paths in contrasting aquifers of the United States: Carrizo Sand (Texas) and Oasis Valley (Nevada) aquifers
journal, September 2015

Role of hydrothermal precipitates in the geochemical cycling of vanadium
journal, November 1989

  • Trefry, John H.; Metz, Simone
  • Nature, Vol. 342, Issue 6249
  • DOI: 10.1038/342531a0

Trace metals as paleoredox and paleoproductivity proxies: An update
journal, August 2006

Benthic fluxes of trace metals in the lagoon of Venice
journal, January 2005

Profiles of the redox-sensitive trace elements As, Sb, V, Mo and U in the Tyro and Bannock Basins (eastern Mediterranean)
journal, December 1990

  • Van der Weijden, Cornelis H.; Middelburg, Jack J.; De Lange, Gert J.
  • Marine Chemistry, Vol. 31, Issue 1-3
  • DOI: 10.1016/0304-4203(90)90037-D

Determination of (Oxy)thioarsenates in Sulfidic Waters
journal, May 2007

  • Wallschläger, Dirk; Stadey, Christopher J.
  • Analytical Chemistry, Vol. 79, Issue 10
  • DOI: 10.1021/ac070061g

Thermodynamics and kinetics of reactions involving vanadium in natural systems: Accumulation of vanadium in sedimentary rocks
journal, April 1992

Sediment-water exchange of Mn, Fe, Ni and Zn in Galveston Bay, Texas
journal, March 2001

The solubility of As2S3 and speciation of As in dilute and sulphide-bearing fluids at 25 and 90° C
journal, April 1990

Vanadyl in natural waters: Adsorption and hydrolysis promote oxygenation
journal, January 1989

Arsenic solid-phase partitioning in reducing sediments of a contaminated wetland
journal, April 2006

An equilibrium profile model for retreating marsh shorelines in southeast Louisiana
journal, December 2008

Submarine groundwater discharge: A large, previously unrecognized source of dissolved iron to the South Atlantic Ocean
journal, December 2006

Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite
journal, July 2005

  • Wolthers, Mariëtte; Charlet, Laurent; van Der Weijden, Cornelis H.
  • Geochimica et Cosmochimica Acta, Vol. 69, Issue 14
  • DOI: 10.1016/j.gca.2005.03.003

Influence of arsenic on iron sulfide transformations
journal, January 2007

Factors Controlling the Regional Distribution of Vanadium in Groundwater
journal, January 2010

Assessing the solubility controls on vanadium in groundwater, northeastern San Joaquin Valley, CA
journal, September 2014

Biogeochemistry of dissolved arsenic in the temperate to tropical North Atlantic Ocean
journal, June 2015

  • Wurl, Oliver; Shelley, Rachel U.; Landing, William M.
  • Deep Sea Research Part II: Topical Studies in Oceanography, Vol. 116
  • DOI: 10.1016/j.dsr2.2014.11.008

High arsenic (As) concentrations in the shallow groundwaters of southern Louisiana: Evidence of microbial controls on As mobilization from sediments
journal, March 2016

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    Works referencing / citing this record:

    Global biogeochemical cycle of vanadium
    journal, December 2017

    • Schlesinger, William H.; Klein, Emily M.; Vengosh, Avner
    • Proceedings of the National Academy of Sciences, Vol. 114, Issue 52
    • DOI: 10.1073/pnas.1715500114

    Distribution and Geochemistry of Arsenic in Sediments of the World’s Largest Choked Estuary: the Patos Lagoon, Brazil
    journal, July 2019

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