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Title: Characterization of Coke on a Pt-Re/γ-Al2O3 Re-Forming Catalyst: Experimental and Theoretical Study

Authors:
ORCiD logo [1];  [2];  [3];  [3];  [4];  [5];  [5];  [2];  [3];  [2]
  1. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  2. Univ. of Washington, Seattle, WA (United States). Dept. of Physics
  3. Honeywell UOP, Des Plaines, IL (United States)
  4. Iowa State Univ., Ames, IA (United States). Dept. of Chemistry
  5. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Materials Measurement Lab.
Publication Date:
Research Org.:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1347923
Alternate Identifier(s):
OSTI ID: 1347926; OSTI ID: 1360785
Grant/Contract Number:  
FG02-03ER15476; AC02-76SF00515; AC02-98CH10886; AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 13C MAS NMR; carbon NEXAFS; catalyst deactivation; coke characterization; DFT calculations; Pt-Re/alumina; Raman; TPO

Citation Formats

Bare, Simon R., Vila, F. D., Charochak, Meghan E., Prabhakar, Sesh, Bradley, William J., Jaye, Cherno, Fischer, Daniel A., Hayashi, S. T., Bradley, Steven A., and Rehr, J. J. Characterization of Coke on a Pt-Re/γ-Al2O3 Re-Forming Catalyst: Experimental and Theoretical Study. United States: N. p., 2017. Web. doi:10.1021/acscatal.6b02785.
Bare, Simon R., Vila, F. D., Charochak, Meghan E., Prabhakar, Sesh, Bradley, William J., Jaye, Cherno, Fischer, Daniel A., Hayashi, S. T., Bradley, Steven A., & Rehr, J. J. Characterization of Coke on a Pt-Re/γ-Al2O3 Re-Forming Catalyst: Experimental and Theoretical Study. United States. https://doi.org/10.1021/acscatal.6b02785
Bare, Simon R., Vila, F. D., Charochak, Meghan E., Prabhakar, Sesh, Bradley, William J., Jaye, Cherno, Fischer, Daniel A., Hayashi, S. T., Bradley, Steven A., and Rehr, J. J. Mon . "Characterization of Coke on a Pt-Re/γ-Al2O3 Re-Forming Catalyst: Experimental and Theoretical Study". United States. https://doi.org/10.1021/acscatal.6b02785. https://www.osti.gov/servlets/purl/1347923.
@article{osti_1347923,
title = {Characterization of Coke on a Pt-Re/γ-Al2O3 Re-Forming Catalyst: Experimental and Theoretical Study},
author = {Bare, Simon R. and Vila, F. D. and Charochak, Meghan E. and Prabhakar, Sesh and Bradley, William J. and Jaye, Cherno and Fischer, Daniel A. and Hayashi, S. T. and Bradley, Steven A. and Rehr, J. J.},
abstractNote = {},
doi = {10.1021/acscatal.6b02785},
journal = {ACS Catalysis},
number = 2,
volume = 7,
place = {United States},
year = {Mon Jan 09 00:00:00 EST 2017},
month = {Mon Jan 09 00:00:00 EST 2017}
}

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Cited by: 25 works
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Works referenced in this record:

Mechanisms of catalyst deactivation
journal, April 2001


Characterization of aged hydrotreating catalysts. Part I: Coke depositions, study on the chemical nature and environment
journal, October 2009


Analysis of coke deposition profiles in commercial spent hydroprocessing catalysts using Raman spectroscopy
journal, May 2007


Ultraviolet Raman spectroscopy characterization of coke formation in zeolites
journal, January 1997


Catalytic action of platinum on coke burning
journal, February 1983


Structural characterization of coke deposits on industrial spent paraffin dehydrogenation catalysts
journal, May 2003


Coking of Reforming Catalysts
book, January 1987


Coke characterization for an industrial Pt–Sn/γ-Al2O3 reforming catalyst
journal, October 2005


Coke characterization by temperature programmed techniques
journal, August 1997


The role of Re and S in the Pt$z.sbnd;Re$z.sbnd;S/Al2O3 catalyst
journal, May 1986


Characterization of residual coke during burning
journal, April 1992

  • Pieck, Carlos L.; Jablonski, Estanislao L.; Parera, Jose M.
  • Industrial & Engineering Chemistry Research, Vol. 31, Issue 4
  • DOI: 10.1021/ie00004a006

Optimal Conditions for Coke Extraction of Spent Catalyst by Accelerated Solvent Extraction Compared to Soxhlet
journal, January 2006

  • Abdullah, Hanadi A.; Hauser, André; Ali, Fatima A.
  • Energy & Fuels, Vol. 20, Issue 1
  • DOI: 10.1021/ef050227l

The chemistry of coke deposits formed on a PtSn catalyst during dehydrogenation of n-alkanes to mono-olefins
journal, December 1994


Characterization of Coke on Zeolites
book, January 2007


Fluorescence Yield Near Edge Spectroscopy (FYNES) of benzene adsorbed in Na-Y zeolite
journal, January 1990

  • Fischer, D. A.; Gland, J. L.; Davis, S. M.
  • Catalysis Letters, Vol. 6, Issue 1
  • DOI: 10.1007/BF00764058

Carbon K-Edge X-Ray Absorption Spectroscopy of Gas Oil Derived Coke Deposits in LZ-210 Zeolite
journal, January 1993


Characterization of coke deposited on catalysts by carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy
journal, January 2000

  • Shimada, Hiromichi; Imamura, Motoyasu; Matsubayashi, Nobuyuki
  • Topics in Catalysis, Vol. 10, Issue 3/4, p. 265-271
  • DOI: 10.1023/A:1019188706587

O K-Edge XANES Study on Perovskite-Type La 1-x Sr x CoO 3-δ
journal, April 1997

  • Imamura, M.; Shimada, H.; Matsubayashi, N.
  • Le Journal de Physique IV, Vol. 7, Issue C2
  • DOI: 10.1051/jp4:1997280

NEXAFS Spectroscopy
book, January 1992


Carbon K-edge structure of chemisorbed molecules by means of fluorescence detection
journal, November 1986


Multiplexed Orientation and Structure Analysis by Imaging Near-Edge X-ray Absorption Fine Structure (MOSAIX) for Combinatorial Surface Science
journal, April 2013

  • Baio, Joe E.; Jaye, Cherno; Fischer, Daniel A.
  • Analytical Chemistry, Vol. 85, Issue 9
  • DOI: 10.1021/ac4003479

Quantitative aspects of solid state 13C n.m.r. of coals and related materials
journal, September 1983


Calculations of X-ray Emission Spectra of Molecules and Surface Adsorbates by Means of Density Functional Theory
journal, December 1998

  • Triguero, L.; Pettersson, L. G. M.; Ågren, H.
  • The Journal of Physical Chemistry A, Vol. 102, Issue 52
  • DOI: 10.1021/jp980824r

Accurate and simple density functional for the electronic exchange energy: Generalized gradient approximation
journal, June 1986


Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993

  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
  • DOI: 10.1063/1.464913

Advanced Applications of NEXAFS Spectroscopy for Functionalized Surfaces
book, January 2013


IFEFFIT  : interactive XAFS analysis and FEFF fitting
journal, March 2001


Raman Spectrum of Graphite
journal, August 1970

  • Tuinstra, F.; Koenig, J. L.
  • The Journal of Chemical Physics, Vol. 53, Issue 3
  • DOI: 10.1063/1.1674108

Model for Raman scattering from incompletely graphitized carbons
journal, January 1982


Coke deposition mechanism on the pores of a commercial Pt–Re/γ-Al2O3 naphtha reforming catalyst
journal, July 2010


Characterization of coke deposited on spent catalysts for long-chain-paraffin dehydrogenation
journal, October 2010


Obituary: Presidential address
journal, March 1994


Reaction of oxygen with graphite: x-ray absorption spectroscopy of carbonaceous materials
journal, May 1992

  • Atamny, F.; Bloecker, J.; Henschke, B.
  • The Journal of Physical Chemistry, Vol. 96, Issue 11
  • DOI: 10.1021/j100190a072

Chemical composition of the graphitic black carbon fraction in riverine and marine sediments at sub-micron scales using carbon X-ray spectromicroscopy
journal, March 2006

  • Haberstroh, Paul R.; Brandes, Jay A.; Gélinas, Yves
  • Geochimica et Cosmochimica Acta, Vol. 70, Issue 6
  • DOI: 10.1016/j.gca.2005.12.001

Works referencing / citing this record:

Mechanistic study of the selective hydrogenation of carboxylic acid derivatives over supported rhenium catalysts
journal, January 2019

  • Toyao, Takashi; Ting, Kah Wei; Siddiki, S. M. A. Hakim
  • Catalysis Science & Technology, Vol. 9, Issue 19
  • DOI: 10.1039/c9cy01404g

Preserved in a Shell: High‐Performance Graphene‐Confined Ruthenium Nanoparticles in Acetylene Hydrochlorination
journal, July 2019

  • Kaiser, Selina K.; Lin, Ronghe; Krumeich, Frank
  • Angewandte Chemie, Vol. 131, Issue 35
  • DOI: 10.1002/ange.201906916

Acidic effect of porous alumina as supports for Pt nanoparticle catalysts in n -hexane reforming
journal, January 2018

  • Yang, Euiseob; Jang, Eun Jeong; Lee, Jun Gyeong
  • Catalysis Science & Technology, Vol. 8, Issue 13
  • DOI: 10.1039/c8cy00776d

Preserved in a Shell: High‐Performance Graphene‐Confined Ruthenium Nanoparticles in Acetylene Hydrochlorination
journal, August 2019

  • Kaiser, Selina K.; Lin, Ronghe; Krumeich, Frank
  • Angewandte Chemie International Edition, Vol. 58, Issue 35
  • DOI: 10.1002/anie.201906916