Synthesis and structure of synthetically pure and deuterated amorphous (basic) calcium carbonates
Abstract
It is generally believed that H2O and OH- are the key species stabilizing and controlling amorphous calcium carbonate “polyamorph” forms, and may in turn control the ultimate crystallization products during synthesis and in natural systems. Yet, the locations and hydrogen-bonding network of these species in ACC have never been measured directly using neutron diffraction. In this paper, we report a synthesis route that overcomes the existing challenges with respect to yield quantities and deuteration, both of which are critically necessary for high quality neutron studies.
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1347339
- Grant/Contract Number:
- AC05-00OR22725; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 20; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Wang, Hsiu-Wen, Daemen, Luke L., Cheshire, Michael C., Kidder, Michelle K., Stack, Andrew G., Allard, Lawrence F., Neuefeind, Jörg, Olds, Daniel, Liu, Jue, and Page, Katharine. Synthesis and structure of synthetically pure and deuterated amorphous (basic) calcium carbonates. United States: N. p., 2017.
Web. doi:10.1039/C6CC08848A.
Wang, Hsiu-Wen, Daemen, Luke L., Cheshire, Michael C., Kidder, Michelle K., Stack, Andrew G., Allard, Lawrence F., Neuefeind, Jörg, Olds, Daniel, Liu, Jue, & Page, Katharine. Synthesis and structure of synthetically pure and deuterated amorphous (basic) calcium carbonates. United States. https://doi.org/10.1039/C6CC08848A
Wang, Hsiu-Wen, Daemen, Luke L., Cheshire, Michael C., Kidder, Michelle K., Stack, Andrew G., Allard, Lawrence F., Neuefeind, Jörg, Olds, Daniel, Liu, Jue, and Page, Katharine. Fri .
"Synthesis and structure of synthetically pure and deuterated amorphous (basic) calcium carbonates". United States. https://doi.org/10.1039/C6CC08848A. https://www.osti.gov/servlets/purl/1347339.
@article{osti_1347339,
title = {Synthesis and structure of synthetically pure and deuterated amorphous (basic) calcium carbonates},
author = {Wang, Hsiu-Wen and Daemen, Luke L. and Cheshire, Michael C. and Kidder, Michelle K. and Stack, Andrew G. and Allard, Lawrence F. and Neuefeind, Jörg and Olds, Daniel and Liu, Jue and Page, Katharine},
abstractNote = {It is generally believed that H2O and OH- are the key species stabilizing and controlling amorphous calcium carbonate “polyamorph” forms, and may in turn control the ultimate crystallization products during synthesis and in natural systems. Yet, the locations and hydrogen-bonding network of these species in ACC have never been measured directly using neutron diffraction. In this paper, we report a synthesis route that overcomes the existing challenges with respect to yield quantities and deuteration, both of which are critically necessary for high quality neutron studies.},
doi = {10.1039/C6CC08848A},
journal = {ChemComm},
number = 20,
volume = 53,
place = {United States},
year = {Fri Feb 17 00:00:00 EST 2017},
month = {Fri Feb 17 00:00:00 EST 2017}
}
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Works referenced in this record:
Transformation and crystallization energetics of synthetic and biogenic amorphous calcium carbonate
journal, September 2010
- Radha, A. V.; Forbes, T. Z.; Killian, C. E.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 38
Characterization of Structure in Biogenic Amorphous Calcium Carbonate: Pair Distribution Function and Nuclear Magnetic Resonance Studies of Lobster Gastrolith
journal, April 2013
- Reeder, Richard J.; Tang, Yuanzhi; Schmidt, Millicent P.
- Crystal Growth & Design, Vol. 13, Issue 5
Amorphous Calcium Carbonate: Synthesis and Potential Intermediate in Biomineralization
journal, June 2004
- Faatz, M.; Gröhn, F.; Wegner, G.
- Advanced Materials, Vol. 16, Issue 12
Stability and Structure of Hydrated Amorphous Calcium Carbonate
journal, October 2015
- Bushuev, Yuriy G.; Finney, Aaron R.; Rodger, P. Mark
- Crystal Growth & Design, Vol. 15, Issue 11
Taking Advantage of Disorder: Amorphous Calcium Carbonate and Its Roles in Biomineralization
journal, June 2003
- Addadi, L.; Raz, S.; Weiner, S.
- Advanced Materials, Vol. 15, Issue 12
Anisotropic thermal expansion and hydrogen bonding behavior of portlandite: A high-temperature neutron diffraction study
journal, April 2007
- Xu, H.; Zhao, Y.; Vogel, S. C.
- Journal of Solid State Chemistry, Vol. 180, Issue 4
Binding of Ethanol on Calcite: The Role of the OH Bond and Its Relevance to Biomineralization
journal, October 2010
- Sand, K. K.; Yang, M.; Makovicky, E.
- Langmuir, Vol. 26, Issue 19
Ethanol assisted synthesis of pure and stable amorphous calcium carbonate nanoparticles
journal, January 2013
- Chen, Shao-Feng; Cölfen, Helmut; Antonietti, Markus
- Chemical Communications, Vol. 49, Issue 83
Energetic and structural studies of amorphous Ca1−xMgxCO3·nH2O (0⩽x⩽1)
journal, August 2012
- Radha, A. V.; Fernandez-Martinez, Alejandro; Hu, Yandi
- Geochimica et Cosmochimica Acta, Vol. 90
Freeze-drying yields stable and pure amorphous calcium carbonate (ACC)
journal, January 2013
- Ihli, Johannes; Kulak, Alexander N.; Meldrum, Fiona C.
- Chemical Communications, Vol. 49, Issue 30
The Multiple Structures of Vaterite
journal, April 2013
- Demichelis, Raffaella; Raiteri, Paolo; Gale, Julian D.
- Crystal Growth & Design, Vol. 13, Issue 6
Pressure-Induced Polyamorphism and Formation of ‘Aragonitic’ Amorphous Calcium Carbonate
journal, July 2013
- Fernandez-Martinez, Alejandro; Kalkan, Bora; Clark, Simon M.
- Angewandte Chemie International Edition, Vol. 52, Issue 32
Stable Prenucleation Calcium Carbonate Clusters
journal, December 2008
- Gebauer, Denis; Völkel, Antje; Cölfen, Helmut
- Science, Vol. 322, Issue 5909
Microscopic Evidence for Liquid-Liquid Separation in Supersaturated CaCO3 Solutions
journal, August 2013
- Wallace, A. F.; Hedges, L. O.; Fernandez-Martinez, A.
- Science, Vol. 341, Issue 6148
Viscosity of deuterium oxide and water in the range 5 to 125 C
journal, June 1949
- Hardy, Robert C.; Cottington, Robert L.
- Journal of Research of the National Bureau of Standards, Vol. 42, Issue 6
In vitro Synthesis and Structural Characterization of Amorphous Calcium Carbonate
journal, October 2005
- Günther, C.; Becker, A.; Wolf, G.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 631, Issue 13-14
Synthesis of Amorphous Calcium Carbonate and Its Crystallization
journal, January 1993
- Kojima, Yoshiyuki; Kawanobe, Akio; Yasue, Tamotsu
- Journal of the Ceramic Society of Japan, Vol. 101, Issue 1178
How to make ‘stable’ ACC: protocol and preliminary structural characterization
journal, February 2008
- Rodriguez-Blanco, J. D.; Shaw, S.; Benning, L. G.
- Mineralogical Magazine, Vol. 72, Issue 1
Monohydrocalcite in Comparison with Hydrated Amorphous Calcium Carbonate: Precipitation Condition and Thermal Behavior
journal, September 2011
- Kimura, Tomoyasu; Koga, Nobuyoshi
- Crystal Growth & Design, Vol. 11, Issue 9
On the Structure of Amorphous Calcium CarbonateA Detailed Study by Solid-State NMR Spectroscopy
journal, September 2008
- Nebel, Holger; Neumann, Markus; Mayer, Christian
- Inorganic Chemistry, Vol. 47, Issue 17
Structural Changes upon Dehydration of Amorphous Calcium Carbonate
journal, January 2014
- Schmidt, Millicent P.; Ilott, Andrew J.; Phillips, Brian L.
- Crystal Growth & Design, Vol. 14, Issue 3
Nanoporous Structure and Medium-Range Order in Synthetic Amorphous Calcium Carbonate
journal, May 2010
- Goodwin, Andrew L.; Michel, F. Marc; Phillips, Brian L.
- Chemistry of Materials, Vol. 22, Issue 10
The roles of water and polyelectrolytes in the phase transformation of amorphous calcium carbonate
journal, August 2008
- Xu, Xu-Rong; Cai, An-Hua; Liu, Rui
- Journal of Crystal Growth, Vol. 310, Issue 16
Proto-Calcite and Proto-Vaterite in Amorphous Calcium Carbonates
journal, October 2010
- Gebauer, Denis; Gunawidjaja, Philips N.; Ko, J. Y. Peter
- Angewandte Chemie International Edition, Vol. 49, Issue 47
Dehydration-Induced Amorphous Phases of Calcium Carbonate
journal, March 2013
- Saharay, Moumita; Yazaydin, A. Ozgur; Kirkpatrick, R. James
- The Journal of Physical Chemistry B, Vol. 117, Issue 12
Synthesis of Vaterite by Carbonation Process in Aqueous System
journal, January 1996
- Matsushita, Isao; Hamada, Yukitoshi; Moriga, Toshihiro
- Journal of the Ceramic Society of Japan, Vol. 104, Issue 1215
Effect of pH on Amorphous Calcium Carbonate Structure and Transformation
journal, July 2016
- Tobler, Dominique J.; Rodriguez Blanco, Juan Diego; Sørensen, Henning O.
- Crystal Growth & Design, Vol. 16, Issue 8
THE ORTHORHOMBIC STRUCTURE OF CaCO3, SrCO3, PbCO3 AND BaCO3: LINEAR STRUCTURAL TRENDS
journal, October 2009
- Antao, S. M.; Hassan, I.
- The Canadian Mineralogist, Vol. 47, Issue 5
Stable prenucleation mineral clusters are liquid-like ionic polymers
journal, September 2011
- Demichelis, Raffaella; Raiteri, Paolo; Gale, Julian D.
- Nature Communications, Vol. 2, Issue 1
Neutron and X-ray diffraction and empirical potential structure refinement modelling of magnesium stabilised amorphous calcium carbonate
journal, October 2014
- Cobourne, G.; Mountjoy, G.; Rodriguez-Blanco, J. D.
- Journal of Non-Crystalline Solids, Vol. 401
Structure and Transformation of Amorphous Calcium Carbonate: A Solid-State 43 Ca NMR and Computational Molecular Dynamics Investigation
journal, May 2012
- Singer, Jared Wesley; Yazaydin, A. Özgür; Kirkpatrick, R. James
- Chemistry of Materials, Vol. 24, Issue 10
Microtwinning hypothesis for a more ordered vaterite model
journal, March 2011
- Le Bail, A.; Ouhenia, S.; Chateigner, D.
- Powder Diffraction, Vol. 26, Issue 1
Biomimetic Model Systems for Investigating the Amorphous Precursor Pathway and Its Role in Biomineralization
journal, November 2008
- Gower, Laurie B.
- Chemical Reviews, Vol. 108, Issue 11
Disordered amorphous calcium carbonate from direct precipitation
journal, January 2015
- Farhadi Khouzani, Masoud; Chevrier, Daniel M.; Güttlein, Patricia
- CrystEngComm, Vol. 17, Issue 26
The role of pH and Mg on the stability and crystallization of amorphous calcium carbonate
journal, September 2012
- Rodriguez-Blanco, J. D.; Shaw, S.; Bots, P.
- Journal of Alloys and Compounds, Vol. 536
Water Is the Key to Nonclassical Nucleation of Amorphous Calcium Carbonate
journal, December 2010
- Raiteri, Paolo; Gale, Julian D.
- Journal of the American Chemical Society, Vol. 132, Issue 49
Crystallization of amorphous calcium carbonate
journal, September 1998
- Koga, Nobuyoshi; Nakagoe, Yuzou; Tanaka, Haruhiko
- Thermochimica Acta, Vol. 318, Issue 1-2
Mechanistic Insights into the Crystallization of Amorphous Calcium Carbonate (ACC)
journal, May 2012
- Bots, Pieter; Benning, Liane G.; Rodriguez-Blanco, Juan-Diego
- Crystal Growth & Design, Vol. 12, Issue 7
Structural Characteristics of Synthetic Amorphous Calcium Carbonate
journal, July 2008
- Michel, F. Marc; MacDonald, Jason; Feng, Jian
- Chemistry of Materials, Vol. 20, Issue 14
Calcium Carbonate Polyamorphism and Its Role in Biomineralization: How Many Amorphous Calcium Carbonates Are There?
journal, November 2012
- Cartwright, Julyan H. E.; Checa, Antonio G.; Gale, Julian D.
- Angewandte Chemie International Edition, Vol. 51, Issue 48
Synthesis-dependant structural variations in amorphous calcium carbonate
journal, January 2007
- Lam, Raymond S. K.; Charnock, John M.; Lennie, Alistair
- CrystEngComm, Vol. 9, Issue 12
Works referencing / citing this record:
A high temperature gas flow environment for neutron total scattering studies of complex materials
journal, September 2018
- Olds, Daniel; Mills, Rebecca A.; McDonnell, Marshall T.
- Review of Scientific Instruments, Vol. 89, Issue 9
A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
journal, September 2018
- Calder, S.; An, K.; Boehler, R.
- Review of Scientific Instruments, Vol. 89, Issue 9
Advances in utilizing event based data structures for neutron scattering experiments
journal, September 2018
- Peterson, Peter F.; Olds, Daniel; Savici, Andrei T.
- Review of Scientific Instruments, Vol. 89, Issue 9
Selective Separation of MA(III) from Ln(III) by Highly Stable Silica-Polymer-based N-Donor Iso Bu-BTP/SiO 2 - P Adsorbent
journal, February 2019
- Ning, Shunyan; Zhang, Wei; Yu, Shuqi
- Solvent Extraction and Ion Exchange, Vol. 37, Issue 2