Evolution of the magnetic and structural properties of Fe1-xCoxV2O4

Sinclair, R.; Ma, Jie; Cao, H. B.; Hong, Tao; Matsuda, Masaaki; Dun, Z. L.; Zhou, H. D.

doi:10.1103/PhysRevB.92.134410

Title: Evolution of the magnetic and structural properties of ${Fe}_{1 - x} {Co}_{x} V_{2} O_{4}$

Abstract

The magnetic and structural properties of single-crystal Fe_1-xCo_xV₂O₄ samples have been investigated by performing specific heat, susceptibility, neutron diffraction, and x-ray diffraction measurements. As the orbital-active Fe²⁺ ions with larger ionic size are gradually substituted by the orbital-inactive Co²⁺ ions with smaller ionic size, the system approaches the itinerant electron limit with decreasing V-V distance. Then, various factors such as the Jahn-Teller distortion and the spin-orbital coupling of the Fe²⁺ ions on the A sites and the orbital ordering and electronic itinerancy of the V³⁺ ions on the B sites compete with each other to produce a complex magnetic and structural phase diagram. Finally, this phase diagram is compared to those of Fe_1-xMn_xV₂O₄ and Mn_1-xCo_xV₂O₄ to emphasize several distinct features.

Authors:

Sinclair, R. ^[1]; Ma, Jie ^[1]; Cao, H. B. ^[2]; Hong, Tao ^[2]; Matsuda, Masaaki ^[2]; Dun, Z. L. ^[1]; Zhou, H. D. ^[1]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Mon Oct 12 00:00:00 EDT 2015

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1344988

Alternate Identifier(s):: OSTI ID: 1224641

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review. B, Condensed Matter and Materials Physics

Additional Journal Information:: Journal Volume: 92; Journal Issue: 13; Journal ID: ISSN 1098-0121

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Sinclair, R., Ma, Jie, Cao, H. B., Hong, Tao, Matsuda, Masaaki, Dun, Z. L., and Zhou, H. D. Evolution of the magnetic and structural properties of Fe1-xCoxV2O4.  United States: N. p., 2015. 
Web.  doi:10.1103/PhysRevB.92.134410.

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                    Sinclair, R., Ma, Jie, Cao, H. B., Hong, Tao, Matsuda, Masaaki, Dun, Z. L., & Zhou, H. D. Evolution of the magnetic and structural properties of Fe1-xCoxV2O4.  United States.  https://doi.org/10.1103/PhysRevB.92.134410

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                    Sinclair, R., Ma, Jie, Cao, H. B., Hong, Tao, Matsuda, Masaaki, Dun, Z. L., and Zhou, H. D. Mon .  
"Evolution of the magnetic and structural properties of Fe1-xCoxV2O4".  United States.  https://doi.org/10.1103/PhysRevB.92.134410.  https://www.osti.gov/servlets/purl/1344988.

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@article{osti_1344988,

  title        = {Evolution of the magnetic and structural properties of Fe1-xCoxV2O4},

  author       = {Sinclair, R. and Ma, Jie and Cao, H. B. and Hong, Tao and Matsuda, Masaaki and Dun, Z. L. and Zhou, H. D.},

  abstractNote = {The magnetic and structural properties of single-crystal Fe1-xCoxV2O4 samples have been investigated by performing specific heat, susceptibility, neutron diffraction, and x-ray diffraction measurements. As the orbital-active Fe2+ ions with larger ionic size are gradually substituted by the orbital-inactive Co2+ ions with smaller ionic size, the system approaches the itinerant electron limit with decreasing V-V distance. Then, various factors such as the Jahn-Teller distortion and the spin-orbital coupling of the Fe2+ ions on the A sites and the orbital ordering and electronic itinerancy of the V3+ ions on the B sites compete with each other to produce a complex magnetic and structural phase diagram. Finally, this phase diagram is compared to those of Fe1-xMnxV2O4 and Mn1-xCoxV2O4 to emphasize several distinct features.},

  doi          = {10.1103/PhysRevB.92.134410},

  journal      = {Physical Review. B, Condensed Matter and Materials Physics},

  number       = 13,

  volume       = 92,

  place        = {United States},

  year         = {Mon Oct 12 00:00:00 EDT 2015},

  month        = {Mon Oct 12 00:00:00 EDT 2015}

}

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Works referenced in this record:

Frustrated Magnetism and Cooperative Phase Transitions in Spinels
journal, January 2010

Lee, Seung-Hun; Takagi, Hidenori; Louca, Despina
Journal of the Physical Society of Japan, Vol. 79, Issue 1
DOI: 10.1143/JPSJ.79.011004

A distortion of pseudotetramers coupled with the Jahn Teller effect in the geometrically frustrated spinel system CdV ₂ O ₄
journal, January 2003

Onoda, Masashige; Hasegawa, Junichi
Journal of Physics: Condensed Matter, Vol. 15, Issue 3
DOI: 10.1088/0953-8984/15/3/101

Dielectric properties and magnetostriction of the collinear multiferroic spinel CdV $_{2}$ O $_{4}$
journal, February 2011

Giovannetti, G.; Stroppa, A.; Picozzi, S.
Physical Review B, Vol. 83, Issue 6
DOI: 10.1103/PhysRevB.83.060402

Specific heat and magnetic susceptibility of spinel compounds CdV2O4, ZnV2O4 and MgTi2O4
journal, May 2006

Vasiliev, A. N.; Markina, M. M.; Isobe, M.
Journal of Magnetism and Magnetic Materials, Vol. 300, Issue 1
DOI: 10.1016/j.jmmm.2005.10.132

Structural and magnetic studies on vanadium spinel MgV2O4
journal, April 1997

Mamiya, H.; Onoda, M.; Furubayashi, T.
Journal of Applied Physics, Vol. 81, Issue 8
DOI: 10.1063/1.364518

Spin and orbital order in the vanadium spinel ${MgV}_{2} O_{4}$
journal, October 2010

Wheeler, Elisa M.; Lake, Bella; Islam, A. T. M. Nazmul
Physical Review B, Vol. 82, Issue 14
DOI: 10.1103/PhysRevB.82.140406

Growth and magnetic properties of stoichiometric and site-disordered single crystalline MgV2O4
journal, January 2012

Islam, A. T. M. Nazmul; Wheeler, Elisa M.; Reehuis, Manfred
Physical Review B, Vol. 85, Issue 2
DOI: 10.1103/PhysRevB.85.024203

$A$ -Type Antiferro-Orbital Ordering with $I 4_{1} / a$ Symmetry and Geometrical Frustration in the Spinel Vanadate ${MgV}_{2} O_{4}$
journal, December 2013

Niitaka, S.; Ohsumi, H.; Sugimoto, K.
Physical Review Letters, Vol. 111, Issue 26
DOI: 10.1103/PhysRevLett.111.267201

Magnetic Field Induced Transition in Vanadium Spinels
journal, January 2014

Mun, E. D.; Chern, Gia-Wei; Pardo, V.
Physical Review Letters, Vol. 112, Issue 1
DOI: 10.1103/PhysRevLett.112.017207

Crystallographic and magnetic structure of ZnV $\mathsf{_2}$ O $\mathsf{_4}$
journal, October 2003

Reehuis, M.; Krimmel, A.; B�ttgen, N.
The European Physical Journal B - Condensed Matter, Vol. 35, Issue 3
DOI: 10.1140/epjb/e2003-00282-4

Orbital and Spin Chains in ${Z n V}_{2} O_{4}$
journal, October 2004

Lee, S. -H.; Louca, D.; Ueda, H.
Physical Review Letters, Vol. 93, Issue 15
DOI: 10.1103/PhysRevLett.93.156407

Magnetic-Field Switching of Crystal Structure in an Orbital-Spin-Coupled System: ${MnV}_{2} O_{4}$
journal, November 2005

Adachi, K.; Suzuki, T.; Kato, K.
Physical Review Letters, Vol. 95, Issue 19
DOI: 10.1103/PhysRevLett.95.197202

Two inequivalent sublattices and orbital ordering in ${MnV}_{2} O_{4}$ studied by ${}^{51}V$ NMR
journal, October 2009

Baek, S. -H.; Curro, N. J.; Choi, K. -Y.
Physical Review B, Vol. 80, Issue 14
DOI: 10.1103/PhysRevB.80.140406

Magnetic susceptibility and specific heat of a spinel MnV $_{2}$ O $_{4}$ single crystal
journal, January 2011

Myung-Whun, Kim; Kim, J. S.; Katsufuji, T.
Physical Review B, Vol. 83, Issue 2
DOI: 10.1103/PhysRevB.83.024403

Evolution of phonon Raman spectra with orbital ordering in spinel MnV $_{2}$ O $_{4}$
journal, September 2011

Takubo, K.; Kubota, R.; Suzuki, T.
Physical Review B, Vol. 84, Issue 9
DOI: 10.1103/PhysRevB.84.094406

Magnetic and Orbital Ordering in the Spinel ${MnV}_{2} O_{4}$
journal, February 2008

Garlea, V. O.; Jin, R.; Mandrus, D.
Physical Review Letters, Vol. 100, Issue 6
DOI: 10.1103/PhysRevLett.100.066404

Spin ordering and orbital ordering transitions in $Mn V_{2} O_{4}$
journal, November 2007

Zhou, H. D.; Lu, J.; Wiebe, C. R.
Physical Review B, Vol. 76, Issue 17
DOI: 10.1103/PhysRevB.76.174403

Magnon spectra and strong spin-lattice coupling in magnetically frustrated $Mn B_{2} O_{4}$ ( $B = Mn$ ,V): Inelastic light-scattering studies
journal, April 2014

Gleason, S. L.; Byrum, T.; Gim, Y.
Physical Review B, Vol. 89, Issue 13
DOI: 10.1103/PhysRevB.89.134402

$Co [V_{2}] O_{4}$ : A Spinel Approaching the Itinerant Electron Limit
journal, February 2011

Kismarahardja, A.; Brooks, J. S.; Kiswandhi, A.
Physical Review Letters, Vol. 106, Issue 5
DOI: 10.1103/PhysRevLett.106.056602

Magnetic, structural, and thermal properties of CoV ₂ O ₄
journal, January 2012

Huang, Yuanjie; Yang, Zhaorong; Zhang, Yuheng
Journal of Physics: Condensed Matter, Vol. 24, Issue 5
DOI: 10.1088/0953-8984/24/5/056003

The nature of itineracy in CoV ₂ O ₄ : a first-principles study
journal, January 2014

Kaur, Ramandeep; Maitra, Tulika; Nautiyal, Tashi
Journal of Physics: Condensed Matter, Vol. 26, Issue 4
DOI: 10.1088/0953-8984/26/4/045505

Homopolar Bond Formation in ${ZnV}_{2} O_{4}$ Close to a Metal-Insulator Transition
journal, December 2008

Pardo, V.; Blanco-Canosa, S.; Rivadulla, F.
Physical Review Letters, Vol. 101, Issue 25
DOI: 10.1103/PhysRevLett.101.256403

The preparation and properties of some vanadium spinels
journal, March 1963

Rogers, D. B.; Arnott, R. J.; Wold, A.
Journal of Physics and Chemistry of Solids, Vol. 24, Issue 3
DOI: 10.1016/0022-3697(63)90193-8

Electrical Conductivity in the Spinel System Co _{1— x} Li _x V ₂ O ₄
journal, March 1964

Rogers, D. B.; Goodenough, J. B.; Wold, A.
Journal of Applied Physics, Vol. 35, Issue 3
DOI: 10.1063/1.1713383

Enhanced Pressure Dependence of Magnetic Exchange in $A^{2 +} [V_{2}] O_{4}$ Spinels Approaching the Itinerant Electron Limit
journal, November 2007

Blanco-Canosa, S.; Rivadulla, F.; Pardo, V.
Physical Review Letters, Vol. 99, Issue 18
DOI: 10.1103/PhysRevLett.99.187201

Jahn-Teller Effects on Mössbauer Spectra of Fe ₅₇ in FeCr ₂ O ₄ and FeV ₂ O ₄
journal, February 1966

Tanaka, Midori; Tokoro, Tetsuzi; Aiyama, Yoshimichi
Journal of the Physical Society of Japan, Vol. 21, Issue 2
DOI: 10.1143/JPSJ.21.262

Structural and Magnetic Properties of Spinel FeV ₂ O ₄ with Two Ions Having Orbital Degrees of Freedom
journal, May 2008

Katsufuji, Takuro; Suzuki, Takehito; Takei, Haruki
Journal of the Physical Society of Japan, Vol. 77, Issue 5
DOI: 10.1143/JPSJ.77.053708

Ordering process and ferroelectricity in a spinel derived from FeV $_{2}$ O $_{4}$
journal, February 2012

Zhang, Q.; Singh, K.; Guillou, F.
Physical Review B, Vol. 85, Issue 5
DOI: 10.1103/PhysRevB.85.054405

Magnetic order and ice rules in the multiferroic spinel FeV $_{2}$ O $_{4}$
journal, August 2012

MacDougall, G. J.; Garlea, V. O.; Aczel, A. A.
Physical Review B, Vol. 86, Issue 6
DOI: 10.1103/PhysRevB.86.060414

Orbital structures in spinel vanadates $A$ V $_{2}$ O $_{4}$ ( $A$ $=$ Fe, Mn)
journal, September 2012

Nii, Y.; Sagayama, H.; Arima, T.
Physical Review B, Vol. 86, Issue 12
DOI: 10.1103/PhysRevB.86.125142

Comparative studies of the thermal conductivity of spinel oxides with orbital degrees of freedom
journal, December 2014

Ishitsuka, Y.; Ishikawa, T.; Koborinai, R.
Physical Review B, Vol. 90, Issue 22
DOI: 10.1103/PhysRevB.90.224411

Chemical pressure effects on structural, magnetic, and transport properties of Mn $_{1 - x}$ Co $_{x}$ V $_{2}$ O $_{4}$
journal, November 2011

Kiswandhi, A.; Brooks, J. S.; Lu, J.
Physical Review B, Vol. 84, Issue 20
DOI: 10.1103/PhysRevB.84.205138

Effects of inter-vanadium distance and $A$ -site magnetism in $A V_{2} O_{4}$ ( $A = Cd, Mg, Zn$ ) spinels near the itinerant electron limit
journal, October 2014

Kiswandhi, A.; Ma, J.; Brooks, J. S.
Physical Review B, Vol. 90, Issue 15
DOI: 10.1103/PhysRevB.90.155132

Strong competition between orbital ordering and itinerancy in a frustrated spinel vanadate
journal, January 2015

Ma, J.; Lee, J. H.; Hahn, S. E.
Physical Review B, Vol. 91, Issue 2
DOI: 10.1103/PhysRevB.91.020407

Evolution of magnetic and structural transitions and enhancement of magnetocaloric effect in ${Fe}_{1 - x} {Mn}_{x} V_{2} O_{4}$
journal, March 2014

Choudhury, D.; Suzuki, T.; Okuyama, D.
Physical Review B, Vol. 89, Issue 10
DOI: 10.1103/PhysRevB.89.104427

Ferro-to-antiferro orbital variation in vanadium spinel Fe _{1- x} Mn _x V ₂ O ₄
journal, August 2014

Kawaguchi, S.; Ishibashi, H.; Kim, J.
Journal of Physics: Condensed Matter, Vol. 26, Issue 34
DOI: 10.1088/0953-8984/26/34/346001

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Evolution of magnetic and structural transitions and enhancement of magnetocaloric effect in ${Fe}_{1 - x} {Mn}_{x} V_{2} O_{4}$
journal, March 2014

Ferro-to-antiferro orbital variation in vanadium spinel Fe _{1- x} Mn _x V ₂ O ₄
journal, August 2014