Element-resolved magnetism across the temperature- and pressure-induced spin reorientation in MnBi
Abstract
Rare-earth free permanent magnet MnBi (NiAs-type crystal structure) displays strong uniaxial magnetic anisotropy above its similar to 90 K spin reorientation transition (SRT). X-ray magnetic circular dichroism (XMCD) measurements at the Mn K and Bi L-2,(3) edges show induced magnetism in Bi, which is strongly coupled to the magnetism of Mn. Temperature- and pressure-dependent XMCD results reveal that hydrostatic pressure mimics the effect of temperature, driving a transition from uniaxial to in-plane anisotropy. The pressure and temperature transitions are shown to be connected to an anisotropic lattice contraction in NiAs-type structures. Temperature and pressure, hence, induce coupled structural and magnetic responses, highlighting the importance of both anisotropic lattice change and Mn-Bi hybridization in leading to the magnetic anisotropy change across the SRT. The dependence of magnetic anisotropy on the anisotropic lattice change is confirmed by density functional theory.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Geology
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Ames Lab., Ames, IA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Carnegie Inst. of Washington, Argonne, IL (United States). Geophysical Lab.
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States. Materials Science and Engineering Dept/
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1342924
- Alternate Identifier(s):
- OSTI ID: 1333604; OSTI ID: 1333993; OSTI ID: 1357208
- Report Number(s):
- IS-J-9161; PNNL-SA-118447
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1701202
- Grant/Contract Number:
- FG02-99ER45775; AC02-06CH11357; NA0001974; AC02-07CH1358; AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 94; Journal Issue: 18; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; MnBi; spin reorientation; xmcd
Citation Formats
Choi, Yongseong, Jiang, Xiujuan, Bi, Wenli, Lapa, Pavel, Chouhan, Rajiv K., Paudyal, D., Varga, Tamas, Popov, Dmitry, Cui, Jun, Haskel, Daniel, and Jiang, J. S. Element-resolved magnetism across the temperature- and pressure-induced spin reorientation in MnBi. United States: N. p., 2016.
Web. doi:10.1103/PhysRevB.94.184433.
Choi, Yongseong, Jiang, Xiujuan, Bi, Wenli, Lapa, Pavel, Chouhan, Rajiv K., Paudyal, D., Varga, Tamas, Popov, Dmitry, Cui, Jun, Haskel, Daniel, & Jiang, J. S. Element-resolved magnetism across the temperature- and pressure-induced spin reorientation in MnBi. United States. https://doi.org/10.1103/PhysRevB.94.184433
Choi, Yongseong, Jiang, Xiujuan, Bi, Wenli, Lapa, Pavel, Chouhan, Rajiv K., Paudyal, D., Varga, Tamas, Popov, Dmitry, Cui, Jun, Haskel, Daniel, and Jiang, J. S. Mon .
"Element-resolved magnetism across the temperature- and pressure-induced spin reorientation in MnBi". United States. https://doi.org/10.1103/PhysRevB.94.184433. https://www.osti.gov/servlets/purl/1342924.
@article{osti_1342924,
title = {Element-resolved magnetism across the temperature- and pressure-induced spin reorientation in MnBi},
author = {Choi, Yongseong and Jiang, Xiujuan and Bi, Wenli and Lapa, Pavel and Chouhan, Rajiv K. and Paudyal, D. and Varga, Tamas and Popov, Dmitry and Cui, Jun and Haskel, Daniel and Jiang, J. S.},
abstractNote = {Rare-earth free permanent magnet MnBi (NiAs-type crystal structure) displays strong uniaxial magnetic anisotropy above its similar to 90 K spin reorientation transition (SRT). X-ray magnetic circular dichroism (XMCD) measurements at the Mn K and Bi L-2,(3) edges show induced magnetism in Bi, which is strongly coupled to the magnetism of Mn. Temperature- and pressure-dependent XMCD results reveal that hydrostatic pressure mimics the effect of temperature, driving a transition from uniaxial to in-plane anisotropy. The pressure and temperature transitions are shown to be connected to an anisotropic lattice contraction in NiAs-type structures. Temperature and pressure, hence, induce coupled structural and magnetic responses, highlighting the importance of both anisotropic lattice change and Mn-Bi hybridization in leading to the magnetic anisotropy change across the SRT. The dependence of magnetic anisotropy on the anisotropic lattice change is confirmed by density functional theory.},
doi = {10.1103/PhysRevB.94.184433},
journal = {Physical Review B},
number = 18,
volume = 94,
place = {United States},
year = {Mon Nov 28 00:00:00 EST 2016},
month = {Mon Nov 28 00:00:00 EST 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 6 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Magnetic, optical, and magneto-optical properties of Mn X ( X =As, Sb, or Bi) from full-potential calculations
journal, June 1999
- Ravindran, P.; Delin, A.; James, P.
- Physical Review B, Vol. 59, Issue 24
Anomalous magneto-structural behavior of MnBi explained: A path towards an improved permanent magnet
journal, March 2014
- Zarkevich, N. A.; Wang, L. -L.; Johnson, D. D.
- APL Materials, Vol. 2, Issue 3
Contribution to the equilibrium phase diagram of the Mn–Bi system near MnBi
journal, May 1974
- Chen, Tu
- Journal of Applied Physics, Vol. 45, Issue 5
Electronic structure of MnSb
journal, February 1985
- Coehoorn, R.; Haas, C.; de Groot, R. A.
- Physical Review B, Vol. 31, Issue 4
The electronic structure of MnBi
journal, October 1985
- Coehoorn, R.; Groot, R. A. de
- Journal of Physics F: Metal Physics, Vol. 15, Issue 10
Electronic structure and magneto‐optical properties of MnBi and MnBiAl
journal, May 1994
- Jaswal, S. S.; Shen, J. X.; Kirby, R. D.
- Journal of Applied Physics, Vol. 75, Issue 10
The ruby pressure standard to 150GPa
journal, December 2005
- Chijioke, Akobuije D.; Nellis, W. J.; Soldatov, A.
- Journal of Applied Physics, Vol. 98, Issue 11
Influence of chemical doping and hydrostatic pressure on the magnetic properties of magnetocaloric compounds
journal, February 2016
- Rocco, D. L.; de Campos, A.; Carvalho, A. Magnus G.
- Physical Review B, Vol. 93, Issue 5
Can near-edge structure of the Bi L 3 edge determine the formal valence states of Bi?
journal, August 2006
- Jiang, Nan; Spence, John C. H.
- Journal of Physics: Condensed Matter, Vol. 18, Issue 34
Crystal structure, magnetic properties and electronic structure of the MnBi intermetallic compound
journal, June 2002
- Yang, J. B.; Yelon, W. B.; James, W. J.
- Journal of Physics: Condensed Matter, Vol. 14, Issue 25
Depth profile of spin and orbital magnetic moments in a subnanometer Pt film on Co
journal, August 2005
- Suzuki, Motohiro; Muraoka, Hiroaki; Inaba, Yuuki
- Physical Review B, Vol. 72, Issue 5
Development of MnBi permanent magnet: Neutron diffraction of MnBi powder
journal, May 2014
- Cui, J.; Choi, J. P.; Li, G.
- Journal of Applied Physics, Vol. 115, Issue 17
Au and Fe magnetic moments in disordered Au-Fe alloys
journal, June 2008
- Wilhelm, F.; Poulopoulos, P.; Kapaklis, V.
- Physical Review B, Vol. 77, Issue 22
X-ray circular dichroism and local magnetic fields
journal, February 1993
- Carra, Paolo; Thole, B. T.; Altarelli, Massimo
- Physical Review Letters, Vol. 70, Issue 5
First-Principles Study of Electronic Structures of Mn X ( X =As, Sb, or Bi): Fully Relativistic Full-Potential Calculations
journal, June 2007
- Li, Ming-Fang; Ariizumi, Toshihiro; Koyanagi, Kazumi
- Japanese Journal of Applied Physics, Vol. 46, Issue 6A
The phase transformation and physical properties of the MnBi and Mn<inf>1.08</inf>Bi compounds
journal, September 1974
- Tu Chen, ; Stutius, W.
- IEEE Transactions on Magnetics, Vol. 10, Issue 3
Magnetic circular dichroism at the K edge of nickel and iron
journal, December 1994
- Igarashi, Jun-ichi; Hirai, Kunitomo
- Physical Review B, Vol. 50, Issue 24
Magnetic anisotropic effects and electronic correlations in MnBi ferromagnet
journal, August 2014
- Antropov, V. P.; Antonov, V. N.; Bekenov, L. V.
- Physical Review B, Vol. 90, Issue 5
Element-resolved orbital polarization in (III,Mn)As ferromagnetic semiconductors from -edge x-ray magnetic circular dichroism
journal, June 2010
- Wadley, P.; Freeman, A. A.; Edmonds, K. W.
- Physical Review B, Vol. 81, Issue 23
Anisotropic nanocrystalline MnBi with high coercivity at high temperature
journal, August 2011
- Yang, J. B.; Yang, Y. B.; Chen, X. G.
- Applied Physics Letters, Vol. 99, Issue 8
Theoretical study on the role of dynamics on the unusual magnetic properties in MnBi
journal, November 2014
- Shanavas, K. V.; Parker, David; Singh, David J.
- Scientific Reports, Vol. 4, Issue 1
Spin reorientation in MnBi
journal, April 2001
- Yoshida, H.; Shima, T.; Takahashi, T.
- Journal of Alloys and Compounds, Vol. 317-318
Magnetic spectroscopy at high pressures using X-ray magnetic circular dichroism
journal, September 2008
- Haskel, Daniel; Tseng, Y. C.; Souza-Neto, N. M.
- High Pressure Research, Vol. 28, Issue 3
Magnetic properties of the MnBi intermetallic compound
journal, September 2001
- Yang, J. B.; Kamaraju, K.; Yelon, W. B.
- Applied Physics Letters, Vol. 79, Issue 12
Ab initio and experimental pre-edge investigations of the Mn -edge XANES in oxide-type materials
journal, April 2005
- Farges, François
- Physical Review B, Vol. 71, Issue 15
X-ray circular dichroism as a probe of orbital magnetization
journal, March 1992
- Thole, B. T.; Carra, P.; Sette, F.
- Physical Review Letters, Vol. 68, Issue 12
Neutron Diffraction Study of the Structures and Magnetic Properties of Manganese Bismuthide
journal, November 1956
- Roberts, B. W.
- Physical Review, Vol. 104, Issue 3
The pressure dependence of the lattice parameters of MnSb and MnTe
journal, February 1969
- Nagasaki, Hiroshi; Wakabayashi, Ippei; Minomura, Shigeru
- Journal of Physics and Chemistry of Solids, Vol. 30, Issue 2
Coordination and chemical effects on the structural, electronic, and magnetic properties in Mn pnictides
journal, August 2001
- Continenza, A.; Picozzi, S.; Geng, W. T.
- Physical Review B, Vol. 64, Issue 8
Valence band orbital polarization in III-V ferromagnetic semiconductors
journal, February 2008
- Freeman, A. A.; Edmonds, K. W.; van der Laan, G.
- Physical Review B, Vol. 77, Issue 7
Symmetry-lowering lattice distortion at the spin reorientation in MnBi single crystals
journal, November 2014
- McGuire, Michael A.; Cao, Huibo; Chakoumakos, Bryan C.
- Physical Review B, Vol. 90, Issue 17
Origin of Magnetic Anisotropy in Cobalt-Substituted Magnetite
journal, June 1958
- Slonczewski, J. C.
- Physical Review, Vol. 110, Issue 6
Works referencing / citing this record:
Giant magnetostriction effect near onset of spin reorientation in MnBi
journal, May 2018
- Choi, Y.; Ryan, P. J.; McGuire, M. A.
- Applied Physics Letters, Vol. 112, Issue 19