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Title: Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene

Abstract

The instability of hybrid perovskite materials due to water and moisture arises as one major challenge to be addressed before any practical application of the demonstrated high efficiency perovskite solar cells. Here we report a facile strategy that can simultaneously enhance the stability and efficiency of p-i-n planar heterojunction-structure perovskite devices. Crosslinkable silane molecules with hydrophobic functional groups are bonded onto fullerene to make the fullerene layer highly water-resistant. Methylammonium iodide is introduced in the fullerene layer for n-doping via anion-induced electron transfer, resulting in dramatically increased conductivity over 100-fold. With crosslinkable silane-functionalized and doped fullerene electron transport layer, the perovskite devices deliver an efficiency of 19.5% with a high fill factor of 80.6%. Furthermore, a crosslinked silane-modified fullerene layer also enhances the water and moisture stability of the non-sealed perovskite devices by retaining nearly 90% of their original efficiencies after 30 days’ exposure in an ambient environment.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
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  1. Univ. of Nebraska-Lincoln, Lincoln, NE (United States)
Publication Date:
Research Org.:
Univ. of Nebraska, Lincoln, NE (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
OSTI Identifier:
1342744
Grant/Contract Number:  
EE0006709
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY; electronic devices; solar cells

Citation Formats

Bai, Yang, Dong, Qingfeng, Shao, Yuchuan, Deng, Yehao, Wang, Qi, Shen, Liang, Wang, Dong, Wei, Wei, and Huang, Jinsong. Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene. United States: N. p., 2016. Web. doi:10.1038/ncomms12806.
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Bai, Yang, Dong, Qingfeng, Shao, Yuchuan, Deng, Yehao, Wang, Qi, Shen, Liang, Wang, Dong, Wei, Wei, & Huang, Jinsong. Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene. United States. https://doi.org/10.1038/ncomms12806
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Bai, Yang, Dong, Qingfeng, Shao, Yuchuan, Deng, Yehao, Wang, Qi, Shen, Liang, Wang, Dong, Wei, Wei, and Huang, Jinsong. Wed . "Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene". United States. https://doi.org/10.1038/ncomms12806. https://www.osti.gov/servlets/purl/1342744.
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@article{osti_1342744,
title = {Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene},
author = {Bai, Yang and Dong, Qingfeng and Shao, Yuchuan and Deng, Yehao and Wang, Qi and Shen, Liang and Wang, Dong and Wei, Wei and Huang, Jinsong},
abstractNote = {The instability of hybrid perovskite materials due to water and moisture arises as one major challenge to be addressed before any practical application of the demonstrated high efficiency perovskite solar cells. Here we report a facile strategy that can simultaneously enhance the stability and efficiency of p-i-n planar heterojunction-structure perovskite devices. Crosslinkable silane molecules with hydrophobic functional groups are bonded onto fullerene to make the fullerene layer highly water-resistant. Methylammonium iodide is introduced in the fullerene layer for n-doping via anion-induced electron transfer, resulting in dramatically increased conductivity over 100-fold. With crosslinkable silane-functionalized and doped fullerene electron transport layer, the perovskite devices deliver an efficiency of 19.5% with a high fill factor of 80.6%. Furthermore, a crosslinked silane-modified fullerene layer also enhances the water and moisture stability of the non-sealed perovskite devices by retaining nearly 90% of their original efficiencies after 30 days’ exposure in an ambient environment.},
doi = {10.1038/ncomms12806},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {Wed Oct 05 00:00:00 EDT 2016},
month = {Wed Oct 05 00:00:00 EDT 2016}
}
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https://doi.org/10.1038/ncomms12806
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Works referenced in this record:

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012

  • Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00591

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014

  • Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
  • Nature Materials, Vol. 13, Issue 9, p. 897-903
  • DOI: 10.1038/nmat4014

Interface engineering of highly efficient perovskite solar cells
journal, July 2014

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015

The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013

  • Snaith, Henry J.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630
  • DOI: 10.1021/jz4020162

Solvent Annealing of Perovskite-Induced Crystal Growth for Photovoltaic-Device Efficiency Enhancement
journal, August 2014

Hall mobility in tin iodide perovskite CH3NH3SnI3: Evidence for a doped semiconductor
journal, September 2013

  • Takahashi, Yukari; Hasegawa, Hiroyuki; Takahashi, Yukihiro
  • Journal of Solid State Chemistry, Vol. 205
  • DOI: 10.1016/j.jssc.2013.07.008

High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites
journal, December 2013

  • Wehrenfennig, Christian; Eperon, Giles E.; Johnston, Michael B.
  • Advanced Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adma.201305172

Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013

Unusual defect physics in CH 3 NH 3 PbI 3 perovskite solar cell absorber
journal, February 2014

  • Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa
  • Applied Physics Letters, Vol. 104, Issue 6
  • DOI: 10.1063/1.4864778

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells
journal, January 2016

Hysteresis-less inverted CH 3 NH 3 PbI 3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency
journal, January 2015

  • Heo, Jin Hyuck; Han, Hye Ji; Kim, Dasom
  • Energy & Environmental Science, Vol. 8, Issue 5
  • DOI: 10.1039/C5EE00120J

Organometal halide perovskite solar cells: degradation and stability
journal, January 2016

  • Berhe, Taame Abraha; Su, Wei-Nien; Chen, Ching-Hsiang
  • Energy & Environmental Science, Vol. 9, Issue 2
  • DOI: 10.1039/C5EE02733K

Stability of Metal Halide Perovskite Solar Cells
journal, September 2015

  • Leijtens, Tomas; Eperon, Giles E.; Noel, Nakita K.
  • Advanced Energy Materials, Vol. 5, Issue 20
  • DOI: 10.1002/aenm.201500963

Beyond Efficiency: the Challenge of Stability in Mesoscopic Perovskite Solar Cells
journal, September 2015

  • Rong, Yaoguang; Liu, Linfeng; Mei, Anyi
  • Advanced Energy Materials, Vol. 5, Issue 20
  • DOI: 10.1002/aenm.201501066

A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014

  • Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
  • Angewandte Chemie International Edition, Vol. 53, Issue 42
  • DOI: 10.1002/anie.201406466

Improved performance and stability of perovskite solar cells by crystal crosslinking with alkylphosphonic acid ω-ammonium chlorides
journal, August 2015

  • Li, Xiong; Ibrahim Dar, M.; Yi, Chenyi
  • Nature Chemistry, Vol. 7, Issue 9
  • DOI: 10.1038/nchem.2324

Functionalization of perovskite thin films with moisture-tolerant molecules
journal, January 2016

A polymer scaffold for self-healing perovskite solar cells
journal, January 2016

  • Zhao, Yicheng; Wei, Jing; Li, Heng
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10228

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
journal, December 2014

  • Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6784

Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells
journal, July 2015

  • Bi, Cheng; Wang, Qi; Shao, Yuchuan
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8747

Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers
journal, October 2015

Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers
journal, October 2015

Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers
journal, January 2014

  • Xiao, Zhengguo; Bi, Cheng; Shao, Yuchuan
  • Energy Environ. Sci., Vol. 7, Issue 8
  • DOI: 10.1039/C4EE01138D

Infrared spectra-structure correlations for organosilicon compounds
journal, January 1960

Fully Printable Mesoscopic Perovskite Solar Cells with Organic Silane Self-Assembled Monolayer
journal, January 2015

  • Liu, Linfeng; Mei, Anyi; Liu, Tongfa
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja5125594

Surface Functionality of Amorphous Silica by Infrared Spectroscopy
journal, October 1958

  • McDonald, Robert S.
  • The Journal of Physical Chemistry, Vol. 62, Issue 10
  • DOI: 10.1021/j150568a004

Steric Effects on Hydrogen Bonding 1
journal, May 1966

  • Singh, Surjit; Rao, C. N. R.
  • Journal of the American Chemical Society, Vol. 88, Issue 10
  • DOI: 10.1021/ja00962a011

Effect of steric hindrance on hydrogen-bonding interaction between polyesters and natural polyphenol catechin
journal, January 2004

  • Zhu, Bo; Li, Jianchun; He, Yong
  • Journal of Applied Polymer Science, Vol. 91, Issue 6
  • DOI: 10.1002/app.13581

Synthesis of Thin, Rectangular C60 Nanorods Usingm-Xylene as a Shape Controller
journal, July 2006

Creation of 1D [60]fullerene superstructures and its polymerization by γ-ray irradiation
journal, January 2007

  • Malik, Sudip; Fujita, Norifumi; Mukhopadhyay, Pritam
  • J. Mater. Chem., Vol. 17, Issue 23
  • DOI: 10.1039/B701583F

Determining the C60 molecular arrangement in thin films by means of X-ray diffraction
journal, September 2011

  • Elschner, Chris; Levin, Alexandr A.; Wilde, Lutz
  • Journal of Applied Crystallography, Vol. 44, Issue 5
  • DOI: 10.1107/S002188981103531X

Organic Thin Film Transistors for Large Area Electronics
journal, January 2002

Doping of Fullerenes via Anion-Induced Electron Transfer and Its Implication for Surfactant Facilitated High Performance Polymer Solar Cells
journal, June 2013

  • Li, Chang-Zhi; Chueh, Chu-Chen; Ding, Feizhi
  • Advanced Materials, Vol. 25, Issue 32
  • DOI: 10.1002/adma.201300580

A solution-processed n-doped fullerene cathode interfacial layer for efficient and stable large-area perovskite solar cells
journal, January 2016

  • Chang, Chih-Yu; Huang, Wen-Kuan; Chang, Yu-Chia
  • Journal of Materials Chemistry A, Vol. 4, Issue 2
  • DOI: 10.1039/C5TA09080F

Solution-Processible Highly Conducting Fullerenes
journal, March 2013

  • Li, Chang-Zhi; Chueh, Chu-Chen; Yip, Hin-Lap
  • Advanced Materials, Vol. 25, Issue 17, p. 2457-2461
  • DOI: 10.1002/adma.201204543

Conductance mechanisms in crystals containing hydrogen bonds
journal, January 1956

  • Pollock, J. McC.; Ubbelohde, A. R.
  • Transactions of the Faraday Society, Vol. 52
  • DOI: 10.1039/tf9565201112

Effect of Hydrogen Bonding on the Electrical Conductivity of Organic Solids
journal, January 1967

  • Gravatt, C. C.; Gross, Paul M.
  • The Journal of Chemical Physics, Vol. 46, Issue 2
  • DOI: 10.1063/1.1840681

Chitosan/NiO nanocomposites: a potential new dielectric material
journal, January 2011

  • Bhatt, Aarti Sripathi; Bhat, Denthaje Krishna; Santosh, Mysore Sridhar
  • Journal of Materials Chemistry, Vol. 21, Issue 35
  • DOI: 10.1039/c1jm12011e

Unraveling the hidden function of a stabilizer in a precursor in improving hybrid perovskite film morphology for high efficiency solar cells
journal, January 2016

  • Xiao, Zhengguo; Wang, Dong; Dong, Qingfeng
  • Energy & Environmental Science, Vol. 9, Issue 3
  • DOI: 10.1039/C6EE00183A

Bulk heterojunction perovskite–PCBM solar cells with high fill factor
journal, February 2016

Electrochemical Impedance Spectroscopic Analysis of Dye-Sensitized Solar Cells
journal, August 2005

  • Wang, Qing; Moser, Jacques-E.; Grätzel, Michael
  • The Journal of Physical Chemistry B, Vol. 109, Issue 31
  • DOI: 10.1021/jp052768h

Electron Lifetime in Dye-Sensitized Solar Cells: Theory and Interpretation of Measurements
journal, August 2009

  • Bisquert, Juan; Fabregat-Santiago, Francisco; Mora-Seró, Iván
  • The Journal of Physical Chemistry C, Vol. 113, Issue 40
  • DOI: 10.1021/jp9037649

Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy
journal, January 2011

  • Fabregat-Santiago, Francisco; Garcia-Belmonte, Germà; Mora-Seró, Iván
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 20
  • DOI: 10.1039/c0cp02249g

Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells
journal, December 2013

  • Dualeh, Amalie; Moehl, Thomas; Tétreault, Nicolas
  • ACS Nano, Vol. 8, Issue 1, p. 362-373
  • DOI: 10.1021/nn404323g

Mechanism of carrier accumulation in perovskite thin-absorber solar cells
journal, July 2013

  • Kim, Hui-Seon; Mora-Sero, Ivan; Gonzalez-Pedro, Victoria
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3242

Low-temperature solution-processed wavelength-tunable perovskites for lasing
journal, March 2014

  • Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3911

Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells
journal, January 2016

  • Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/C6EE00409A

A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014

  • Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
  • Angewandte Chemie, Vol. 126, Issue 42
  • DOI: 10.1002/ange.201406466

Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells
text, January 2016

  • Jinsong, Huang,; Yongbo, Yuan,; Yuchuan, Shao,
  • The University of North Carolina at Chapel Hill University Libraries
  • DOI: 10.17615/gcrf-5b77

Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells
text, January 2015

  • Yongbo, Yuan,; Yuchuan, Shao,; Zhengguo, Xiao,
  • The University of North Carolina at Chapel Hill University Libraries
  • DOI: 10.17615/h36r-a084

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
text, January 2014

  • Zhengguo, Xio,; Yuchuan, Shao,; Jinsong, Huang,
  • The University of North Carolina at Chapel Hill University Libraries
  • DOI: 10.17615/kpp6-9914

Solution-Processible Highly Conducting Fullerenes
journal, March 2013

  • Li, Chang-Zhi; Chueh, Chu-Chen; Yip, Hin-Lap
  • Advanced Materials, Vol. 25, Issue 17, p. 2457-2461
  • DOI: 10.1002/adma.201204543

Doping of Fullerenes via Anion-Induced Electron Transfer and Its Implication for Surfactant Facilitated High Performance Polymer Solar Cells
journal, June 2013

  • Li, Chang-Zhi; Chueh, Chu-Chen; Ding, Feizhi
  • Advanced Materials, Vol. 25, Issue 32
  • DOI: 10.1002/adma.201300580

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Electrochemical Impedance Spectroscopic Analysis of Dye-Sensitized Solar Cells
journal, August 2005

  • Wang, Qing; Moser, Jacques-E.; Grätzel, Michael
  • The Journal of Physical Chemistry B, Vol. 109, Issue 31
  • DOI: 10.1021/jp052768h

Electron Lifetime in Dye-Sensitized Solar Cells: Theory and Interpretation of Measurements
journal, August 2009

  • Bisquert, Juan; Fabregat-Santiago, Francisco; Mora-Seró, Iván
  • The Journal of Physical Chemistry C, Vol. 113, Issue 40
  • DOI: 10.1021/jp9037649

Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells
journal, December 2013

  • Dualeh, Amalie; Moehl, Thomas; Tétreault, Nicolas
  • ACS Nano, Vol. 8, Issue 1, p. 362-373
  • DOI: 10.1021/nn404323g

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

A polymer scaffold for self-healing perovskite solar cells
journal, January 2016

  • Zhao, Yicheng; Wei, Jing; Li, Heng
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10228

Mechanism of carrier accumulation in perovskite thin-absorber solar cells
journal, July 2013

  • Kim, Hui-Seon; Mora-Sero, Ivan; Gonzalez-Pedro, Victoria
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3242

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
journal, December 2014

  • Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6784

Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers
journal, October 2015

Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012

  • Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00591
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    • DOI: 10.1002/adfm.201804128

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    • DOI: 10.1002/adma.201800455

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    • DOI: 10.1002/admi.201901469

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    journal, November 2019

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    • Deng, Lin-Long; Xie, Su-Yuan; Gao, Feng
    • Advanced Electronic Materials, Vol. 4, Issue 10
    • DOI: 10.1002/aelm.201700435

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    journal, September 2017

    • Deng, Wentao; Liang, Xinxing; Kubiak, Peter S.
    • Advanced Energy Materials, Vol. 8, Issue 1
    • DOI: 10.1002/aenm.201701544

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    • Advanced Energy Materials, Vol. 8, Issue 12
    • DOI: 10.1002/aenm.201702287

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    journal, February 2018

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    • Angewandte Chemie International Edition, Vol. 57, Issue 10
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    • Völker, Sebastian F.; Vallés-Pelarda, Marta; Pascual, Jorge
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    • DOI: 10.1002/chem.201801069

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    journal, February 2017

    • Rong, Yaoguang; Hou, Xiaomeng; Hu, Yue
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms14555

    Perovskite solar cells: Stability lies at interfaces
    journal, July 2017

    Relationship between ion migration and interfacial degradation of CH3NH3PbI3 perovskite solar cells under thermal conditions
    journal, April 2017

    Surface engineering of perovskite films for efficient solar cells
    journal, November 2017

    Amplified Spontaneous Emission Threshold Reduction and Operational Stability Improvement in CsPbBr3 Nanocrystals Films by Hydrophobic Functionalization of the Substrate
    journal, November 2019

    • De Giorgi, Maria Luisa; Krieg, Franziska; Kovalenko, Maksym V.
    • Scientific Reports, Vol. 9, Issue 1
    • DOI: 10.1038/s41598-019-54412-7

    A chemical sensor for CBr 4 based on quasi-2D and 3D hybrid organic–inorganic perovskites immobilized on TiO 2 films
    journal, January 2018

    • Nikolaou, Pavlos; Vassilakopoulou, Anastasia; Papadatos, Dionysios
    • Materials Chemistry Frontiers, Vol. 2, Issue 4
    • DOI: 10.1039/c7qm00550d

    A Ga-doped SnO 2 mesoporous contact for UV stable highly efficient perovskite solar cells
    journal, January 2018

    • Roose, Bart; Johansen, Christian M.; Dupraz, Kevin
    • Journal of Materials Chemistry A, Vol. 6, Issue 4
    • DOI: 10.1039/c7ta07663k

    Efficient and UV-stable perovskite solar cells enabled by side chain-engineered polymeric hole-transporting layers
    journal, January 2018

    • Tsai, Chang-Hung; Li, Nan; Lee, Chia-Chen
    • Journal of Materials Chemistry A, Vol. 6, Issue 27
    • DOI: 10.1039/c8ta03608j

    Interfacial engineering enables high efficiency with a high open-circuit voltage above 1.23 V in 2D perovskite solar cells
    journal, January 2018

    • Chen, Jiehuan; Lian, Xiaomei; Zhang, Yingzhu
    • Journal of Materials Chemistry A, Vol. 6, Issue 37
    • DOI: 10.1039/c8ta06925e

    Unravelling fullerene–perovskite interactions introduces advanced blend films for performance-improved solar cells
    journal, January 2019

    • Pascual, Jorge; Collavini, Silvia; Völker, Sebastian F.
    • Sustainable Energy & Fuels, Vol. 3, Issue 10
    • DOI: 10.1039/c9se00438f

    Solution-processed electron transport layer of n-doped fullerene for efficient and stable all carbon based perovskite solar cells
    journal, January 2019

    • Zhou, Junshuai; Hou, Jie; Tao, Xia
    • Journal of Materials Chemistry A, Vol. 7, Issue 13
    • DOI: 10.1039/c9ta00118b

    Guanidinium induced phase separated perovskite layer for efficient and highly stable solar cells
    journal, January 2019

    • Zhang, Weihai; Xiong, Juan; Li, Jinhua
    • Journal of Materials Chemistry A, Vol. 7, Issue 16
    • DOI: 10.1039/c9ta01893j

    Pathways toward high-performance inorganic perovskite solar cells: challenges and strategies
    journal, January 2019

    • Li, Bo; Fu, Lin; Li, Shuang
    • Journal of Materials Chemistry A, Vol. 7, Issue 36
    • DOI: 10.1039/c9ta04114a

    Introducing pyridyl into electron transport materials plays a key role in improving electron mobility and interface properties for inverted perovskite solar cells
    journal, January 2019

    • Zhu, Rui; Li, Quan-Song; Li, Ze-Sheng
    • Journal of Materials Chemistry A, Vol. 7, Issue 27
    • DOI: 10.1039/c9ta04856a

    Steering the electron transport properties of pyridine-functionalized fullerene derivatives in inverted perovskite solar cells: the nitrogen site matters
    journal, January 2020

    • Li, Bairu; Zhen, Jieming; Wan, Yangyang
    • Journal of Materials Chemistry A, Vol. 8, Issue 7
    • DOI: 10.1039/c9ta12188a

    Functional graded fullerene derivatives for improving the fill factor and device stability of inverted-type perovskite solar cells
    journal, May 2018

    Highly efficient and stable 2D–3D perovskite solar cells fabricated by interfacial modification
    journal, April 2019

    Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells
    journal, August 2017

    Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells
    journal, March 2019

    Self-assembly monolayers boosting organic–inorganic halide perovskite solar cell performance
    journal, January 2018

    Analysing the Prospects of Perovskite Solar Cells within the Purview of Recent Scientific Advancements
    journal, June 2018

    • Bhat, Aakash; Dhamaniya, Bhanu; Chhillar, Priyanka
    • Crystals, Vol. 8, Issue 6
    • DOI: 10.3390/cryst8060242

    Targeted Therapy for Interfacial Engineering Toward Stable and Efficient Perovskite Solar Cells
    journal, August 2019

    • Wang, Shuhui; Chen, Haiyang; Zhang, Jiandong
    • Advanced Materials, Vol. 31, Issue 41
    • DOI: 10.1002/adma.201903691

    Triarylphosphine Oxide as Cathode Interfacial Material for Inverted Perovskite Solar Cells
    journal, April 2019

    • Wang, Kai; Neophytou, Marios; Aydin, Erkan
    • Advanced Materials Interfaces, Vol. 6, Issue 12
    • DOI: 10.1002/admi.201900434

    Efficient n-Dopants and Their Roles in Organic Electronics
    journal, July 2018

    • Bin, Zhengyang; Liu, Ziyang; Qiu, Yong
    • Advanced Optical Materials, Vol. 6, Issue 18
    • DOI: 10.1002/adom.201800536

    Diammonium and Monoammonium Mixed-Organic-Cation Perovskites for High Performance Solar Cells with Improved Stability
    journal, May 2017

    • Lu, Jianfeng; Jiang, Liangcong; Li, Wei
    • Advanced Energy Materials, Vol. 7, Issue 18
    • DOI: 10.1002/aenm.201700444

    Interface Engineering for Highly Efficient and Stable Planar p-i-n Perovskite Solar Cells
    journal, November 2017

    • Bai, Yang; Meng, Xiangyue; Yang, Shihe
    • Advanced Energy Materials, Vol. 8, Issue 5
    • DOI: 10.1002/aenm.201701883

    Low‐Dimensional Dion–Jacobson‐Phase Lead‐Free Perovskites for High‐Performance Photovoltaics with Improved Stability
    journal, April 2020

    • Li, Pengwei; Liu, Xiaolong; Zhang, Yiqiang
    • Angewandte Chemie, Vol. 132, Issue 17
    • DOI: 10.1002/ange.202000460

    Understanding Hydrogen Bonding Interactions in Crosslinked Methylammonium Lead Iodide Crystals: Towards Reducing Moisture and Light Degradation Pathways
    journal, September 2019

    • Nimens, Wendy J.; Lefave, Sarah J.; Flannery, Laura
    • Angewandte Chemie International Edition, Vol. 58, Issue 39
    • DOI: 10.1002/anie.201906017

    From Exceptional Properties to Stability Challenges of Perovskite Solar Cells
    journal, August 2018

    General Nondestructive Passivation by 4‐Fluoroaniline for Perovskite Solar Cells with Improved Performance and Stability
    journal, October 2018

    Surface Chlorination of ZnO for Perovskite Solar Cells with Enhanced Efficiency and Stability
    journal, May 2019

    A Short Review on Interface Engineering of Perovskite Solar Cells: A Self‐Assembled Monolayer and Its Roles
    journal, August 2019

    Fluorinated fused nonacyclic interfacial materials for efficient and stable perovskite solar cells
    journal, January 2017

    • Liu, Kuan; Dai, Shuixing; Meng, Fanqi
    • J. Mater. Chem. A, Vol. 5, Issue 40
    • DOI: 10.1039/c7ta06923e

    Nitrogen substitution improves the mobility and stability of electron transport materials for inverted perovskite solar cells
    journal, January 2018

    • Zhu, Rui; Li, Quan-Song; Li, Ze-Sheng
    • Nanoscale, Vol. 10, Issue 37
    • DOI: 10.1039/c8nr05588b

    The multiple effects of polyaniline additive to improve the efficiency and stability of perovskite solar cells
    journal, January 2019

    • Zheng, Haiying; Xu, Xiaoxiao; Xu, Shendong
    • Journal of Materials Chemistry C, Vol. 7, Issue 15
    • DOI: 10.1039/c8tc05975f

    Challenges for commercializing perovskite solar cells
    journal, September 2018

    Matching Charge Extraction Contact for Wide-Bandgap Perovskite Solar Cells
    text, January 2017

    • B., Chen,; Y., Shao,; J., Huang,
    • The University of North Carolina at Chapel Hill University Libraries
    • DOI: 10.17615/50rf-ma51

    Argon Plasma Treatment to Tune Perovskite Surface Composition for High Efficiency Solar Cells and Fast Photodetectors
    text, January 2018

    • Y., Fang,; X., Xiao,; Y., Gao,
    • The University of North Carolina at Chapel Hill University Libraries
    • DOI: 10.17615/8gyw-8442

    Electrical Stress Influences the Efficiency of CH 3 NH 3 PbI 3 Perovskite Light Emitting Devices
    journal, April 2017

    Interfacial Engineering of Metal Oxides for Highly Stable Halide Perovskite Solar Cells
    journal, August 2018

    • Mingorance, Alba; Xie, Haibing; Kim, Hui‐Seon
    • Advanced Materials Interfaces, Vol. 5, Issue 22
    • DOI: 10.1002/admi.201800367

    Improved Moisture Stability of Perovskite Solar Cells with a Surface-Treated PCBM Layer
    journal, December 2018

    Interface and Defect Engineering for Metal Halide Perovskite Optoelectronic Devices
    journal, September 2018

    Synergistic Hematite-Fullerene Electron-Extracting Layers for Improved Efficiency and Stability in Perovskite Solar Cells
    journal, February 2018

    Electron-Transport Materials in Perovskite Solar Cells
    journal, July 2018

    Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells
    text, January 2019

    • J., Huang,; X., Xiao,; J., Zhao,
    • The University of North Carolina at Chapel Hill University Libraries
    • DOI: 10.17615/r232-5f04

    Understanding Hydrogen Bonding Interactions in Crosslinked Methylammonium Lead Iodide Crystals: Towards Reducing Moisture and Light Degradation Pathways
    journal, July 2019

    • Nimens, Wendy J.; Lefave, Sarah J.; Flannery, Laura
    • Angewandte Chemie, Vol. 131, Issue 39
    • DOI: 10.1002/ange.201906017

    Aqueous-Containing Precursor Solutions for Efficient Perovskite Solar Cells
    journal, November 2017

    • Liu, Dianyi; Traverse, Christopher J.; Chen, Pei
    • Advanced Science, Vol. 5, Issue 1
    • DOI: 10.1002/advs.201700484

    Recent Advance in Solution-Processed Organic Interlayers for High-Performance Planar Perovskite Solar Cells
    journal, May 2018

    • Zhang, Wenxiao; Wang, Ying-Chiao; Li, Xiaodong
    • Advanced Science, Vol. 5, Issue 7
    • DOI: 10.1002/advs.201800159

    Effect of Cs-Incorporated NiOx on the Performance of Perovskite Solar Cells
    journal, December 2017

    Synergy of ammonium chloride and moisture on perovskite crystallization for efficient printable mesoscopic solar cells
    journal, February 2017

    • Rong, Yaoguang; Hou, Xiaomeng; Hu, Yue
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms14555

    Relationship between ion migration and interfacial degradation of CH3NH3PbI3 perovskite solar cells under thermal conditions
    journal, April 2017

    Surface engineering of perovskite films for efficient solar cells
    journal, November 2017

    Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells
    journal, August 2017

    Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells
    journal, March 2019

    Excess charge-carrier induced instability of hybrid perovskites
    text, January 2018

    • Y., Fang,; B., Chen,; Y., Lin,
    • The University of North Carolina at Chapel Hill University Libraries
    • DOI: 10.17615/qj2r-3306
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