Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance

Yin, Jiefu; Pelliccione, Christopher J.; Lee, Shu Han; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Marschilok, Amy C.

doi:10.1149/2.0781609jes

Title: Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg _x V ₂ O ₅ · nH ₂ O: The Role of Structural Mg ²⁺ on Battery Performance

Abstract

Magnesium intercalated vanadium oxide xerogels, Mg_0.1V₂O₅ · 2.35H₂O and Mg_0.2V₂O₅ · 2.46H₂O were synthesized using an ion removal sol gel strategy. X-ray diffraction indicated lamellar ordering with turbostratic character. X-ray absorption spectroscopy indicated greater distortion of the vanadium-oxygen coordination environment in Mg_0.2V₂O₅ · 2.46H₂O. Elemental analysis after cycling in Li⁺ or Mg²⁺ based electrolytes revealed that the magnesium content was unchanged, indicating structural Mg²⁺ are retained. Furthermore, the Mg_0.1V₂O₅ · 2.35H₂O material displayed high voltage, energy density, and discharge/charge efficiency, indicating promise as a cathode material for future magnesium based batteries.

Authors:

Yin, Jiefu ^[1]; Pelliccione, Christopher J. ^[2]; Lee, Shu Han ^[3]; Takeuchi, Esther S. ^[4]; Takeuchi, Kenneth J. ^[1]; Marschilok, Amy C. ^[1]

Stony Brook Univ., NY (United States). Chemistry and Materials Science and Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
State Univ. of New York (SUNY), Buffalo, NY (United States). Chemical and Biological Engineering
Stony Brook Univ., NY (United States). Chemistry and Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate

Publication Date:: Tue Jul 12 00:00:00 EDT 2016

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1342654

Report Number(s):: BNL-113490-2017-JA
Journal ID: ISSN 0013-4651

Grant/Contract Number:: SC0012704; AC02-98CH10886; SC0012673

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 163; Journal Issue: 9; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; battery; magnesium; spectroscopy; energy

Citation Formats


                    Yin, Jiefu, Pelliccione, Christopher J., Lee, Shu Han, Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C. Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance.  United States: N. p., 2016. 
Web.  doi:10.1149/2.0781609jes.

Copy to clipboard


                    Yin, Jiefu, Pelliccione, Christopher J., Lee, Shu Han, Takeuchi, Esther S., Takeuchi, Kenneth J., & Marschilok, Amy C. Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance.  United States.  https://doi.org/10.1149/2.0781609jes

Copy to clipboard


                    Yin, Jiefu, Pelliccione, Christopher J., Lee, Shu Han, Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C. Tue .  
"Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance".  United States.  https://doi.org/10.1149/2.0781609jes.  https://www.osti.gov/servlets/purl/1342654.

Copy to clipboard


                    
@article{osti_1342654,

  title        = {Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance},

  author       = {Yin, Jiefu and Pelliccione, Christopher J. and Lee, Shu Han and Takeuchi, Esther S. and Takeuchi, Kenneth J. and Marschilok, Amy C.},

  abstractNote = {Magnesium intercalated vanadium oxide xerogels, Mg0.1V2O5 · 2.35H2O and Mg0.2V2O5 · 2.46H2O were synthesized using an ion removal sol gel strategy. X-ray diffraction indicated lamellar ordering with turbostratic character. X-ray absorption spectroscopy indicated greater distortion of the vanadium-oxygen coordination environment in Mg0.2V2O5 · 2.46H2O. Elemental analysis after cycling in Li+ or Mg2+ based electrolytes revealed that the magnesium content was unchanged, indicating structural Mg2+ are retained. Furthermore, the Mg0.1V2O5 · 2.35H2O material displayed high voltage, energy density, and discharge/charge efficiency, indicating promise as a cathode material for future magnesium based batteries.},

  doi          = {10.1149/2.0781609jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 9,

  volume       = 163,

  place        = {United States},

  year         = {Tue Jul 12 00:00:00 EDT 2016},

  month        = {Tue Jul 12 00:00:00 EDT 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1149/2.0781609jes

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 22 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referencing / citing this record:

Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed
journal, August 2017

Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas
Angewandte Chemie International Edition, Vol. 56, Issue 40
DOI: 10.1002/anie.201700673

Similar Records in DOE PAGES and OSTI.GOV collections:

Free-standing bilayered vanadium oxide films synthesized by liquid exfoliation of chemically preintercalated δ-Li _x V ₂ O ₅ · n H ₂ O

Journal Article Houseman, Luke ; Mukherjee, Santanu ; Andris, Ryan ; ... - Materials Advances

A free-standing film composed of bilayered vanadium oxide nanoflakes is for the first time synthesized using a new low-energy process. The precursor powder, δ-Li_xV₂O₅·nH₂O, was prepared using a simple sol–gel based chemical preintercalation synthesis procedure. δ-Li_xV₂O₅·nH₂O was dispersed and probe sonicated in N-methyl pyrrolidone to exfoliate the bilayers followed by vacuum filtration resulting in the formation of a free-standing film with obsidian color. X-ray diffraction showed lamellar ordering of a single-phase material with a decreased interlayer distance compared to that of the precursor powder. Scanning electron microscopy images demonstrated stacking of the individual nanoflakes. This morphology was further confirmed withmore »« less
https://doi.org/10.1039/D1MA00085C
Quasi-one-dimensional nanostructured cobalt (Co) intercalated vanadium oxide (V{sub 2}O{sub 5}): Peroxovanadate sol gel synthesis and structural study

Journal Article Langie da Silva, Douglas, E-mail: douglas.langie@ufpel.edu.br ; Moreira, Eduardo Ceretta ; Dias, Fábio Teixeira ; ... - Journal of Solid State Chemistry

Nanostructured cobalt vanadium oxide (V{sub 2}O{sub 5}) xerogels spread onto crystalline Si substrates were synthesized via peroxovanadate sol gel route. The resulting products were characterized by distinct experimental techniques. The surface morphology and the nanostructure of xerogels correlate with Co concentration. The decrease of the structural coherence length is followed by the formation of a loose network of nanopores when the concentration of intercalated species was greater than 4 at% of Co. The efficiency of the synthesis route also drops with the increase of Co concentration. The interaction between the Co(OH{sub 2}){sub 6}{sup 2+} cations and the (H{sub 2}V{sub 10}O{submore »« less
https://doi.org/10.1016/J.JSSC.2014.09.019
V{sub 2}O{sub 5} xerogel-poly(ethylene oxide) hybrid material: Synthesis, characterization, and electrochemical properties

Journal Article Guerra, Elidia M ; Ciuffi, Katia J ; Oliveira, Herenilton P - Journal of Solid State Chemistry

In this work, we report the synthesis, characterization, and electrochemical properties of vanadium pentoxide xerogel-poly(ethylene oxide) (PEO) hybrid materials obtained by varying the average molecular weight of the organic component as well as the components' ratios. The materials were characterized by X-ray diffraction, ultraviolet/visible and infrared spectroscopies, thermogravimetric analysis, scanning electron microscopy, electron paramagnetic resonance, and cyclic voltammetry. Despite the presence of broad and low intensity peaks, the X-ray diffractograms indicate that the lamellar structure of the vanadium pentoxide xerogel is preserved, with increase in the interplanar spacing, giving evidence of a low-crystalline structure. We found that the electrochemical behaviourmore »« less
https://doi.org/10.1016/j.jssc.2006.08.018
Vanadium Oxide Pillared by Interlayer Mg²⁺ Ions and Water as Ultralong-Life Cathodes for Magnesium-Ion Batteries

Journal Article Xu, Yanan ; Deng, Xuanwei ; Li, Qidong ; ... - Chem

Magnesium-ion batteries (MIBs) show great potential for large-scale energy storage because of the advantages of low cost and safety, but their application is severely hindered by the difficulty in finding desirable electrode materials. In this work, we develop a bilayer-structured vanadium oxide (Mg_0.3V₂O₅·1.1H₂O) with synergistic effect of Mg²⁺ ions and lattice water as the cathode material for MIBs. The pre-intercalated Mg²⁺ ions provide high electronic conductivity and excellent structural stability. The lattice water enables fast Mg²⁺ ions mobility because of its charge shielding effect. As a result, the Mg_0.3V₂O₅·1.1H₂O exhibits excellent rate performance and an unprecedented cycling life with capacitymore »« less
Cited by 128
https://doi.org/10.1016/j.chempr.2019.02.014

Full Text Available
Giant voids in the hydrothermally synthesized microporous square pyramidal-tetrahedral framework vanadium phosphates [HN(CH{sub 2}CH{sub 2}){sub 3}NH]K{sub 1.35}[V{sub 5}O{sub 9}(PO{sub 4}){sub 2}]{sm_bullet}xH{sub 2}O and Cs{sub 3}[V{sub 5}O{sub 9}(PO{sub 4}){sub 2}]{sm_bullet}xH{sub 2}O

Journal Article Khan, M I ; Zubieta, J ; Meyer, L M - Chemistry of Materials

The author presents a procedure for the low-temperature hydrothermal synthesis of a novel three-dimensional square pyramidal-tetrahedral framework vanadium phosphates [HN(CH{sub 2}CH{sub 2}){sub 3-}NH]K{sub 1.35}[V{sub 5}O{sub 9}(PO{sub 4}){sub 2}]{sm_bullet}xH{sub 2}O. These materials have extremely low framework densities and among the largest cavities observed in open-framework solid-state materials. The X-ray crystallography of these compounds is discussed. The large cavities are interconnected to one another in a diamond-like topology. Ion exchange and sorption properties of the phosphate hydrates are presented. 21 refs., 10 figs., 6 tabs.
https://doi.org/10.1021/cm950249t

Similar Records

Title: Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg x V 2 O 5 · nH 2 O: The Role of Structural Mg 2+ on Battery Performance

Abstract

Citation Formats

Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed journal, August 2017

Title: Communication—Sol-Gel Synthesized Magnesium Vanadium Oxide, Mg _x V ₂ O ₅ · nH ₂ O: The Role of Structural Mg ²⁺ on Battery Performance

Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed
journal, August 2017