Sample environment for in situ synchrotron corrosion studies of materials in extreme environments
Abstract
A new in situ sample environment has been designed and developed to study the interfacial interactions of nuclear cladding alloys with high temperature steam. The sample environment is particularly optimized for synchrotron X-ray diffraction (XRD) studies for in situ structural analysis. The sample environment is highly corrosion resistant and can be readily adapted for steam environments. The in situ sample environment design complies with G2 ASTM standards for studying corrosion in zirconium and its alloys and offers remote temperature and pressure monitoring during the in situ data collection. The use of the in situ sample environment is exemplified by monitoring the oxidation of metallic zirconium during exposure to steam at 350°C. Finally, the in situ sample environment provides a powerful tool for fundamental understanding of corrosion mechanisms by elucidating the substoichiometric oxide phases formed during early stages of corrosion, which can provide a better understanding the oxidation process.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Nuclear Science and Technology Dept.
- Pennsylvania State Univ., University Park, PA (United States). Dept of Mechanical and Nuclear Engineering
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Nuclear Physics (NP)
- OSTI Identifier:
- 1342628
- Alternate Identifier(s):
- OSTI ID: 1421104
- Report Number(s):
- BNL-113415-2017-JA
Journal ID: ISSN 0034-6748; TRN: US1701333
- Grant/Contract Number:
- SC0012704; AC02-CH10886; AC02-06CH11357; DMR-1332208; 13-027
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Review of Scientific Instruments
- Additional Journal Information:
- Journal Volume: 87; Journal Issue: 10; Journal ID: ISSN 0034-6748
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 73 NUCLEAR PHYSICS AND RADIATION PHYSICS; 36 MATERIALS SCIENCE
Citation Formats
Elbakhshwan, Mohamed S., Gill, Simerjeet K., Motta, Arthur T., Weidner, Randy, Anderson, Thomas, and Ecker, Lynne E. Sample environment for in situ synchrotron corrosion studies of materials in extreme environments. United States: N. p., 2016.
Web. doi:10.1063/1.4964101.
Elbakhshwan, Mohamed S., Gill, Simerjeet K., Motta, Arthur T., Weidner, Randy, Anderson, Thomas, & Ecker, Lynne E. Sample environment for in situ synchrotron corrosion studies of materials in extreme environments. United States. https://doi.org/10.1063/1.4964101
Elbakhshwan, Mohamed S., Gill, Simerjeet K., Motta, Arthur T., Weidner, Randy, Anderson, Thomas, and Ecker, Lynne E. Tue .
"Sample environment for in situ synchrotron corrosion studies of materials in extreme environments". United States. https://doi.org/10.1063/1.4964101. https://www.osti.gov/servlets/purl/1342628.
@article{osti_1342628,
title = {Sample environment for in situ synchrotron corrosion studies of materials in extreme environments},
author = {Elbakhshwan, Mohamed S. and Gill, Simerjeet K. and Motta, Arthur T. and Weidner, Randy and Anderson, Thomas and Ecker, Lynne E.},
abstractNote = {A new in situ sample environment has been designed and developed to study the interfacial interactions of nuclear cladding alloys with high temperature steam. The sample environment is particularly optimized for synchrotron X-ray diffraction (XRD) studies for in situ structural analysis. The sample environment is highly corrosion resistant and can be readily adapted for steam environments. The in situ sample environment design complies with G2 ASTM standards for studying corrosion in zirconium and its alloys and offers remote temperature and pressure monitoring during the in situ data collection. The use of the in situ sample environment is exemplified by monitoring the oxidation of metallic zirconium during exposure to steam at 350°C. Finally, the in situ sample environment provides a powerful tool for fundamental understanding of corrosion mechanisms by elucidating the substoichiometric oxide phases formed during early stages of corrosion, which can provide a better understanding the oxidation process.},
doi = {10.1063/1.4964101},
journal = {Review of Scientific Instruments},
number = 10,
volume = 87,
place = {United States},
year = {Tue Oct 25 00:00:00 EDT 2016},
month = {Tue Oct 25 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Hydrogen measurement during steam oxidation using coupled thermogravimetric analysis and quadrupole mass spectrometry
journal, March 2016
- Parkison, A. J.; Nelson, A. T.
- Measurement, Vol. 82
Nika : software for two-dimensional data reduction
journal, March 2012
- Ilavsky, Jan
- Journal of Applied Crystallography, Vol. 45, Issue 2
Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics
journal, August 2014
- Couet, Adrien; Motta, Arthur T.; Comstock, Robert J.
- Journal of Nuclear Materials, Vol. 451, Issue 1-3
High-temperature oxidation of zircaloy-2 and zircaloy-4 in steam
journal, August 1978
- Urbanic, V. F.; Heidrick, T. R.
- Journal of Nuclear Materials, Vol. 75, Issue 2
Some thoughts on the mechanisms of in-reactor corrosion of zirconium alloys
journal, February 2005
- Cox, B.
- Journal of Nuclear Materials, Vol. 336, Issue 2-3
Study of the Initial Stage and Anisotropic Growth of Oxide Layers Formed on Zircaloy-4
journal, January 2011
- Zhou, B. X.; Peng, J. C.; Yao, M. Y.
- Journal of ASTM International, Vol. 8, Issue 1
Corrosion of Zirconium Alloys Used for Nuclear Fuel Cladding
journal, July 2015
- Motta, Arthur T.; Couet, Adrien; Comstock, Robert J.
- Annual Review of Materials Research, Vol. 45, Issue 1
Depth profile of oxide volume fractions of Zircaloy-2 in high-temperature steam: An in-situ synchrotron radiation study
journal, November 2014
- Mohamed, Walid; Yun, Di; Mo, Kun
- Journal of Nuclear Materials, Vol. 454, Issue 1-3
Initial oxidation of zirconium and Zircaloy-2 with oxygen and water vapor at room temperature
journal, April 1996
- Yoshitaka Nishino, ; Krauss, Alan R.
- Journal of Nuclear Materials, Vol. 228, Issue 3
The coupled current charge compensation model for zirconium alloy fuel cladding oxidation: I. Parabolic oxidation of zirconium alloys
journal, November 2015
- Couet, Adrien; Motta, Arthur T.; Ambard, Antoine
- Corrosion Science, Vol. 100
The initial, thermal oxidation of zirconium at room temperature
journal, December 2004
- Lyapin, A.; Jeurgens, L. P. H.; Graat, P. C. J.
- Journal of Applied Physics, Vol. 96, Issue 12
Effect of temperature on the initial, thermal oxidation of zirconium
journal, June 2005
- Lyapin, A.; Jeurgens, L. P. H.; Mittemeijer, E. J.
- Acta Materialia, Vol. 53, Issue 10
Electro-deposition as a sample preparation technique for total-reflection X-ray fluorescence analysis
journal, November 2001
- Griesel, Simone; Reus, Ulrich; Prange, Andreas
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 56, Issue 11
Characterization of Zircaloy-4 corrosion films using microbeam synchrotron radiation
journal, September 2015
- Spengler, David J.; Motta, Arthur T.; Bajaj, Ram
- Journal of Nuclear Materials, Vol. 464
Thickness measurements of nanoscale brine films on silica surfaces under geologic CO 2 sequestration conditions using synchrotron X-ray fluorescence : MEASUREMENTS OF NANOSCALE BRINE FILMS ON SILICA SURFACES
journal, September 2012
- Kim, Tae Wook; Tokunaga, Tetsu K.; Shuman, Derek B.
- Water Resources Research, Vol. 48, Issue 9
Miniature diamond anvil pressure cell for single crystal x‐ray diffraction studies
journal, February 1974
- Merrill, Leo; Bassett, William A.
- Review of Scientific Instruments, Vol. 45, Issue 2
The initial oxidation of zirconium—oxide-film microstructure and growth mechanism
journal, January 2006
- Jeurgens, L. P. H.; Lyapin, A.; Mittemeijer, E. J.
- Surface and Interface Analysis, Vol. 38, Issue 4
The mechanism of low-temperature oxidation of zirconium
journal, October 2005
- Jeurgens, L. P. H.; Lyapin, A.; Mittemeijer, E. J.
- Acta Materialia, Vol. 53, Issue 18
Brine film thicknesses on mica surfaces under geologic CO 2 sequestration conditions and controlled capillary pressures : BRINE FILM THICKNESSES ON MICA SURFACES UNDER GCC
journal, August 2013
- Kim, Tae Wook; Tokunaga, Tetsu K.; Bargar, John R.
- Water Resources Research, Vol. 49, Issue 8
Residual stresses and tetragonal phase fraction characterisation of corrosion tested Zircaloy-4 using energy dispersive synchrotron X-ray diffraction
journal, January 2013
- Polatidis, E.; Frankel, P.; Wei, J.
- Journal of Nuclear Materials, Vol. 432, Issue 1-3
An STM study of the initial oxidation of single-crystalline zirconium surfaces
journal, May 2012
- Bakradze, Georgijs; Jeurgens, Lars P. H.; Mittemeijer, Eric J.
- Surface Science, Vol. 606, Issue 9-10
The different initial oxidation kinetics of Zr(0001) and Zr(101−0) surfaces
journal, July 2011
- Bakradze, Georgijs; Jeurgens, Lars P. H.; Mittemeijer, Eric J.
- Journal of Applied Physics, Vol. 110, Issue 2
Externally controlled pressure and temperature microreactor for in situ x-ray diffraction, visual and spectroscopic reaction investigations under supercritical and subcritical conditions
journal, January 2005
- Diefenbacher, Jason; McKelvy, Michael; Chizmeshya, Andrew V. G.
- Review of Scientific Instruments, Vol. 76, Issue 1
Microstructural study of oxide layers formed on Zircaloy-4 in autoclave and in reactor Part i: Impact of irradiation on the microstructure of the zirconia layer
journal, August 1995
- Iltis, X.; Lefebvre, F.; Lemaignan, C.
- Journal of Nuclear Materials, Vol. 224, Issue 2