Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry
Abstract
We demonstrated the synthesis and characterization of Mg-birnessite (MgxMnO2) with different crystallite sizes, prepared though low temperature precipitation and ion exchange. The influence of crystallite size on electrochemical performance of Mg-birnessite was studied for the first time, where material with smaller crystallite size was demonstrated to have enhanced capacity and rate capability in Li ion, Na ion, and Mg ion based electrolytes. Cation diffusion using GITT type testing demonstrated the ion diffusion coefficient of Mg2+ was ~10× lower compared with Li+ and Na+. This work illustrates that tuning of inorganic materials properties can lead to significant enhancement of electrochemical performance in lithium, sodium as well as magnesium based batteries for materials such as Mg-birnessite and provides a deliberate approach to improve electrochemical performance.
- Authors:
-
- Stony Brook Univ., NY (United States). Dept. of Chemistry
- Stony Brook Univ., NY (United States). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States)
- Stony Brook Univ., NY (United States). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Materials Science and Engineering;
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1341696
- Alternate Identifier(s):
- OSTI ID: 1396668
- Report Number(s):
- BNL-113442-2017-JA
Journal ID: ISSN 0020-1693
- Grant/Contract Number:
- SC0012704; SC0012673; 1275961
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganica Chimica Acta
- Additional Journal Information:
- Journal Volume: 453; Journal Issue: C; Journal ID: ISSN 0020-1693
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; manganese; birnessite; crystallite; Li; Na; Mg; Electrochemistry; manganese oxide; lithium ion battery; sodium ion battery; magnesium ion battery
Citation Formats
Yin, Jiefu, Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C. Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry. United States: N. p., 2016.
Web. doi:10.1016/j.ica.2016.08.026.
Yin, Jiefu, Takeuchi, Esther S., Takeuchi, Kenneth J., & Marschilok, Amy C. Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry. United States. https://doi.org/10.1016/j.ica.2016.08.026
Yin, Jiefu, Takeuchi, Esther S., Takeuchi, Kenneth J., and Marschilok, Amy C. Fri .
"Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry". United States. https://doi.org/10.1016/j.ica.2016.08.026. https://www.osti.gov/servlets/purl/1341696.
@article{osti_1341696,
title = {Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry},
author = {Yin, Jiefu and Takeuchi, Esther S. and Takeuchi, Kenneth J. and Marschilok, Amy C.},
abstractNote = {We demonstrated the synthesis and characterization of Mg-birnessite (MgxMnO2) with different crystallite sizes, prepared though low temperature precipitation and ion exchange. The influence of crystallite size on electrochemical performance of Mg-birnessite was studied for the first time, where material with smaller crystallite size was demonstrated to have enhanced capacity and rate capability in Li ion, Na ion, and Mg ion based electrolytes. Cation diffusion using GITT type testing demonstrated the ion diffusion coefficient of Mg2+ was ~10× lower compared with Li+ and Na+. This work illustrates that tuning of inorganic materials properties can lead to significant enhancement of electrochemical performance in lithium, sodium as well as magnesium based batteries for materials such as Mg-birnessite and provides a deliberate approach to improve electrochemical performance.},
doi = {10.1016/j.ica.2016.08.026},
journal = {Inorganica Chimica Acta},
number = C,
volume = 453,
place = {United States},
year = {Fri Aug 12 00:00:00 EDT 2016},
month = {Fri Aug 12 00:00:00 EDT 2016}
}
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Works referencing / citing this record:
Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries
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