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Title: Cycling behavior of NCM523/graphite lithium-ion cells in the 3–4.4 V range: Diagnostic studies of full cells and harvested electrodes

Abstract

Energy density of full cells containing layered-oxide positive electrodes can be increased by raising the upper cutoff voltage above the current 4.2 V limit. In this article we examine aging behavior of cells, containing LiNi0.5Co0.2Mn0.3O2 (NCM523)-based positive and graphite-based negative electrodes, which underwent up to ~400 cycles in the 3-4.4 V range. Electrochemistry results from electrodes harvested from the cycled cells were obtained to identify causes of cell performance loss; these results were complemented with data from X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) measurements. Our experiments indicate that the full cell capacity fade increases linearly with cycle number and results from irreversible lithium loss in the negative electrode solid electrolyte interphase (SEI) layer. The accompanying electrode potential shift reduces utilization of active material in both electrodes and causes the positive electrode to cycle at higher states-of-charge. Here, full cell impedance rise on aging arises primarily at the positive electrode and results mainly from changes at the electrode-electrolyte interface; the small growth in negative electrode impedance reflects changes in the SEI layer. Our results indicate that cell performance loss could be mitigated by modifying the electrode-electrolyte interfaces through use of appropriate electrode coatings and/or electrolyte additives.

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1337947
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 164; Journal Issue: 1; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
30 DIRECT ENERGY CONVERSION

Citation Formats

Gilbert, James A., Bareño, Javier, Spila, Timothy, Trask, Stephen E., Miller, Dean J., Polzin, Bryant J., Jansen, Andrew N., and Abraham, Daniel P. Cycling behavior of NCM523/graphite lithium-ion cells in the 3–4.4 V range: Diagnostic studies of full cells and harvested electrodes. United States: N. p., 2016. Web. doi:10.1149/2.0081701jes.
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Gilbert, James A., Bareño, Javier, Spila, Timothy, Trask, Stephen E., Miller, Dean J., Polzin, Bryant J., Jansen, Andrew N., & Abraham, Daniel P. Cycling behavior of NCM523/graphite lithium-ion cells in the 3–4.4 V range: Diagnostic studies of full cells and harvested electrodes. United States. https://doi.org/10.1149/2.0081701jes
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Gilbert, James A., Bareño, Javier, Spila, Timothy, Trask, Stephen E., Miller, Dean J., Polzin, Bryant J., Jansen, Andrew N., and Abraham, Daniel P. Thu . "Cycling behavior of NCM523/graphite lithium-ion cells in the 3–4.4 V range: Diagnostic studies of full cells and harvested electrodes". United States. https://doi.org/10.1149/2.0081701jes. https://www.osti.gov/servlets/purl/1337947.
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@article{osti_1337947,
title = {Cycling behavior of NCM523/graphite lithium-ion cells in the 3–4.4 V range: Diagnostic studies of full cells and harvested electrodes},
author = {Gilbert, James A. and Bareño, Javier and Spila, Timothy and Trask, Stephen E. and Miller, Dean J. and Polzin, Bryant J. and Jansen, Andrew N. and Abraham, Daniel P},
abstractNote = {Energy density of full cells containing layered-oxide positive electrodes can be increased by raising the upper cutoff voltage above the current 4.2 V limit. In this article we examine aging behavior of cells, containing LiNi0.5Co0.2Mn0.3O2 (NCM523)-based positive and graphite-based negative electrodes, which underwent up to ~400 cycles in the 3-4.4 V range. Electrochemistry results from electrodes harvested from the cycled cells were obtained to identify causes of cell performance loss; these results were complemented with data from X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectroscopy (SIMS) measurements. Our experiments indicate that the full cell capacity fade increases linearly with cycle number and results from irreversible lithium loss in the negative electrode solid electrolyte interphase (SEI) layer. The accompanying electrode potential shift reduces utilization of active material in both electrodes and causes the positive electrode to cycle at higher states-of-charge. Here, full cell impedance rise on aging arises primarily at the positive electrode and results mainly from changes at the electrode-electrolyte interface; the small growth in negative electrode impedance reflects changes in the SEI layer. Our results indicate that cell performance loss could be mitigated by modifying the electrode-electrolyte interfaces through use of appropriate electrode coatings and/or electrolyte additives.},
doi = {10.1149/2.0081701jes},
journal = {Journal of the Electrochemical Society},
number = 1,
volume = 164,
place = {United States},
year = {Thu Sep 22 00:00:00 EDT 2016},
month = {Thu Sep 22 00:00:00 EDT 2016}
}
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Works referenced in this record:

Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012

  • Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21892e

Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007

  • Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
  • Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
  • DOI: 10.1039/b702425h

Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries
journal, July 2016

  • Qiu, Bao; Zhang, Minghao; Wu, Lijun
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12108

Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina
journal, July 2013

Understanding Long-Term Cycling Performance of Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 –Graphite Lithium-Ion Cells
journal, January 2013

  • Li, Y.; Bettge, M.; Polzin, B.
  • Journal of The Electrochemical Society, Vol. 160, Issue 5
  • DOI: 10.1149/2.002305jes

High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries: toward rechargeable capacity more than 300 mA h g−1
journal, January 2011

  • Ohzuku, Tsutomu; Nagayama, Masatoshi; Tsuji, Kyoji
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c0jm04325g

Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries
journal, January 2016

  • Hy, Sunny; Liu, Haodong; Zhang, Minghao
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03573B

Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process
journal, July 2013

  • Zheng, Jianming; Gu, Meng; Xiao, Jie
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl401849t

Review—Lithium-Excess Layered Cathodes for Lithium Rechargeable Batteries
journal, January 2015

  • Hong, Jihyun; Gwon, Hyeokjo; Jung, Sung-Kyun
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0071514jes

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013

  • Bettge, Martin; Li, Yan; Gallagher, Kevin
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.034311jes

Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013

  • Gallagher, Kevin G.; Croy, Jason R.; Balasubramanian, Mahalingam
  • Electrochemistry Communications, Vol. 33
  • DOI: 10.1016/j.elecom.2013.04.022

Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes
journal, October 2015

  • Croy, Jason R.; Balasubramanian, Mahalingam; Gallagher, Kevin G.
  • Accounts of Chemical Research, Vol. 48, Issue 11
  • DOI: 10.1021/acs.accounts.5b00277

Neutron Diffraction and Magnetic Susceptibility Studies on a High-Voltage Li 1.2 Mn 0.55 Ni 0.15 Co 0.10 O 2 Lithium Ion Battery Cathode: Insight into the Crystal Structure
journal, September 2013

  • Mohanty, Debasish; Huq, Ashfia; Payzant, E. Andrew
  • Chemistry of Materials, Vol. 25, Issue 20
  • DOI: 10.1021/cm402278q

Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study
journal, January 2013

  • Mohanty, Debasish; Sefat, Athena S.; Li, Jianlin
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 44
  • DOI: 10.1039/c3cp53658k

Evolutions of Li 1.2 Mn 0.61 Ni 0.18 Mg 0.01 O 2 during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy
journal, September 2012

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Chemistry of Materials, Vol. 24, Issue 18
  • DOI: 10.1021/cm301140g

Exploring Electrochemistry and Interface Characteristics of Lithium-Ion Cells with Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 Positive and Li 4 Ti 5 O 12 Negative Electrodes
journal, January 2015

  • Li, Yan; Bettge, Martin; Bareño, Javier
  • Journal of The Electrochemical Society, Vol. 162, Issue 13
  • DOI: 10.1149/2.0071513jes

Unexpected Voltage Fade in LMR-NMC Oxides Cycled below the “Activation” Plateau
journal, November 2014

  • Li, Yan; Bareño, Javier; Bettge, Martin
  • Journal of The Electrochemical Society, Vol. 162, Issue 1
  • DOI: 10.1149/2.0741501jes

Origin of voltage decay in high-capacity layered oxide electrodes
journal, December 2014

  • Sathiya, M.; Abakumov, A. M.; Foix, D.
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4137

Role of Negative Electrode Porosity in Long-Term Aging of NMC//Graphite Li-Ion Batteries
journal, January 2015

  • Bernard, Pierre; Martinez, Hervé; Tessier, Cécile
  • Journal of The Electrochemical Society, Vol. 162, Issue 13
  • DOI: 10.1149/2.0151513jes

Aging Analysis of Graphite/LiNi 1/3 Mn 1/3 Co 1/3 O 2 Cells Using XRD, PGAA, and AC Impedance
journal, January 2015

  • Buchberger, Irmgard; Seidlmayer, Stefan; Pokharel, Aneil
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0721514jes

An effective approach to improve the electrochemical performance of LiNi 0.6 Co 0.2 Mn 0.2 O 2 cathode by an MOF-derived coating
journal, January 2016

  • Li, Siwu; Fu, Xiaotao; Zhou, Junwen
  • Journal of Materials Chemistry A, Vol. 4, Issue 16
  • DOI: 10.1039/C5TA10773C

The Limited Effect of VC in Graphite/NMC Cells
journal, December 2014

  • Deshpande, Rutooj D.; Ridgway, Paul; Fu, Yanbao
  • Journal of The Electrochemical Society, Vol. 162, Issue 3
  • DOI: 10.1149/2.0221503jes

Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014

  • Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 24
  • DOI: 10.1021/am506712c

Thermodynamic and kinetic studies of LiNi 0.5 Co 0.2 Mn 0.3 O 2 as a positive electrode material for Li-ion batteries using first principles
journal, January 2016

  • Dixit, Mudit; Kosa, Monica; Lavi, Onit Srur
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 9
  • DOI: 10.1039/C5CP07128C

Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013

  • Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
  • Advanced Energy Materials, Vol. 4, Issue 1
  • DOI: 10.1002/aenm.201300787

Studies of Aluminum-Doped LiNi 0.5 Co 0.2 Mn 0.3 O 2 : Electrochemical Behavior, Aging, Structural Transformations, and Thermal Characteristics
journal, January 2015

  • Aurbach, Doron; Srur-Lavi, Onit; Ghanty, Chandan
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.0681506jes

Interfacial Origin of Performance Improvement and Fade for 4.6 V LiNi 0.5 Co 0.2 Mn 0.3 O 2 Battery Cathodes
journal, May 2014

  • Lee, Yu-Mi; Nam, Kyoung-Mo; Hwang, Eui-Hyung
  • The Journal of Physical Chemistry C, Vol. 118, Issue 20
  • DOI: 10.1021/jp501670g

Performance degradation of high-power lithium-ion cells—Electrochemistry of harvested electrodes
journal, July 2007

Evidence of Transition-Metal Accumulation on Aged Graphite Anodes by SIMS
journal, January 2008

  • Abraham, D. P.; Spila, T.; Furczon, M. M.
  • Electrochemical and Solid-State Letters, Vol. 11, Issue 12
  • DOI: 10.1149/1.2987680

Differential voltage analyses of high-power, lithium-ion cells
journal, January 2005

Differential voltage analyses of high-power lithium-ion cells
journal, June 2006

A High Precision Coulometry Study of the SEI Growth in Li/Graphite Cells
journal, January 2011

  • Smith, A. J.; Burns, J. C.; Zhao, Xuemei
  • Journal of The Electrochemical Society, Vol. 158, Issue 5
  • DOI: 10.1149/1.3557892

Performance of high-power lithium-ion cells under pulse discharge and charge conditions
journal, December 2009

  • Abraham, D. P.; Dees, D. W.; Christophersen, J.
  • International Journal of Energy Research, Vol. 34, Issue 2
  • DOI: 10.1002/er.1665

Application of a lithium–tin reference electrode to determine electrode contributions to impedance rise in high-power lithium-ion cells
journal, October 2004

Electrochemical Modeling of Lithium-Ion Positive Electrodes during Hybrid Pulse Power Characterization Tests
journal, January 2008

  • Dees, Dennis; Gunen, Evren; Abraham, Daniel
  • Journal of The Electrochemical Society, Vol. 155, Issue 8
  • DOI: 10.1149/1.2939211

Alternating Current Impedance Electrochemical Modeling of Lithium-Ion Positive Electrodes
journal, January 2005

  • Dees, Dennis; Gunen, Evren; Abraham, Daniel
  • Journal of The Electrochemical Society, Vol. 152, Issue 7
  • DOI: 10.1149/1.1928169

Investigating the Low-Temperature Impedance Increase of Lithium-Ion Cells
journal, January 2008

  • Abraham, D. P.; Heaton, J. R.; Kang, S. -H.
  • Journal of The Electrochemical Society, Vol. 155, Issue 1
  • DOI: 10.1149/1.2801366

Modeling the impedance versus voltage characteristics of LiNi0.8Co0.15Al0.05O2
journal, January 2008

Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode
journal, January 2015

  • Dees, Dennis W.; Abraham, Daniel P.; Lu, Wenquan
  • Journal of The Electrochemical Society, Vol. 162, Issue 4
  • DOI: 10.1149/2.0231504jes

Diagnostic Studies of Polyolefin Separators in High-Power Li-Ion Cells
journal, January 2004

  • Kostecki, Robert; Norin, Laura; Song, Xiangyun
  • Journal of The Electrochemical Society, Vol. 151, Issue 4
  • DOI: 10.1149/1.1649233

Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells
journal, January 2012

  • Zhu, Ye; Li, Yan; Bettge, Martin
  • Journal of The Electrochemical Society, Vol. 159, Issue 12
  • DOI: 10.1149/2.083212jes

Manganese in Graphite Anode and Capacity Fade in Li Ion Batteries
journal, October 2014

  • Shkrob, Ilya A.; Kropf, A. Jeremy; Marin, Timothy W.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 42
  • DOI: 10.1021/jp507833u

Examining the Solid Electrolyte Interphase on Binder-Free Graphite Electrodes
journal, January 2009

  • Xiao, Ang; Yang, Li; Lucht, Brett L.
  • Journal of The Electrochemical Society, Vol. 156, Issue 4
  • DOI: 10.1149/1.3078020

X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade
journal, November 2004

Surface Characterization of Electrodes from High Power Lithium-Ion Batteries
journal, January 2002

  • Andersson, A. M.; Abraham, D. P.; Haasch, R.
  • Journal of The Electrochemical Society, Vol. 149, Issue 10
  • DOI: 10.1149/1.1505636

Aging mechanism in Li ion cells and calendar life predictions
journal, July 2001

Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells
journal, January 2004

  • Ploehn, Harry J.; Ramadass, Premanand; White, Ralph E.
  • Journal of The Electrochemical Society, Vol. 151, Issue 3
  • DOI: 10.1149/1.1644601

Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction
journal, December 2012

  • Pinson, Matthew B.; Bazant, Martin Z.
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.044302jes

Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries
journal, July 2013

  • Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng
  • The Journal of Physical Chemistry C, Vol. 117, Issue 31
  • DOI: 10.1021/jp405158m

The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface
journal, March 2015

  • Jarry, Angélique; Gottis, Sébastien; Yu, Young-Sang
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/ja5116698

Capacity Fading of Graphite Electrodes Due to the Deposition of Manganese Ions on Them in Li-Ion Batteries
journal, January 2002

  • Tsunekawa, Hajime; Tanimoto,a, Satoshi; Marubayashi, Ryoji
  • Journal of The Electrochemical Society, Vol. 149, Issue 10
  • DOI: 10.1149/1.1502686

Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 2. Radiolytically Induced Polymerization of Ethylene Carbonate
journal, September 2013

  • Shkrob, Ilya A.; Zhu, Ye; Marin, Timothy W.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 38, p. 19270-19279
  • DOI: 10.1021/jp406273p

Molecular Dynamics Simulations and Experimental Study of Lithium Ion Transport in Dilithium Ethylene Dicarbonate
journal, April 2013

  • Borodin, Oleg; Zhuang, Guorong V.; Ross, Philip N.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 15
  • DOI: 10.1021/jp4000494

Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase
journal, September 2012

  • Shi, Siqi; Lu, Peng; Liu, Zhongyi
  • Journal of the American Chemical Society, Vol. 134, Issue 37
  • DOI: 10.1021/ja305366r

Observation of anisotropic microstructural changes during cycling in LiNi0.5Co0.2Mn0.3O2 cathode material
journal, February 2015

Surface changes on LiNi0.8Co0.2O2 particles during testing of high-power lithium-ion cells
journal, August 2002

Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells
journal, January 2003

  • Abraham, D. P.; Twesten, R. D.; Balasubramanian, M.
  • Journal of The Electrochemical Society, Vol. 150, Issue 11
  • DOI: 10.1149/1.1613291

Observation of Microstructural Evolution in Li Battery Cathode Oxide Particles by In Situ Electron Microscopy
journal, May 2013

  • Miller, Dean J.; Proff, Christian; Wen, J. G.
  • Advanced Energy Materials, Vol. 3, Issue 8
  • DOI: 10.1002/aenm.201300015

Design criteria for electrochemical shock resistant battery electrodes
journal, January 2012

  • Woodford, William H.; Carter, W. Craig; Chiang, Yet-Ming
  • Energy & Environmental Science, Vol. 5, Issue 7, p. 8014-8024
  • DOI: 10.1039/c2ee21874g

The Limited Effect of VC in Graphite / NMC Cells
journal, April 2015

  • Deshpande, Rutooj; Ridgeway, Paul; Fu, Yanbao
  • ECS Meeting Abstracts, Vol. MA2015-01, Issue 2, p. 231-231
  • DOI: 10.1149/ma2015-01/2/231

Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode
journal, April 2015

  • Dees, Dennis W.; Abraham, Daniel P.; Lu, Wenquan
  • ECS Meeting Abstracts, Vol. MA2015-01, Issue 2
  • DOI: 10.1149/ma2015-01/2/606
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    • Advanced Materials Interfaces, Vol. 5, Issue 9
    • DOI: 10.1002/admi.201701447

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    journal, February 2018

    • Li, Wangda; Liu, Xiaoming; Celio, Hugo
    • Advanced Energy Materials, Vol. 8, Issue 15
    • DOI: 10.1002/aenm.201703154

    Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries
    journal, June 2017

    Degradation Mechanisms and Mitigation Strategies of Nickel-Rich NMC-Based Lithium-Ion Batteries
    journal, October 2019

    Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability
    journal, August 2019

    Using nanoconfinement to inhibit the degradation pathways of conversion-metal oxide anodes for highly stable fast-charging Li-ion batteries
    journal, January 2020

    • Ng, Benjamin; Peng, Xiong; Faegh, Ehsan
    • Journal of Materials Chemistry A, Vol. 8, Issue 5
    • DOI: 10.1039/c9ta11708c

    Active formation of Li-ion batteries and its effect on cycle life
    journal, August 2019

    • Pathan, Tanveerkhan S.; Rashid, Muhammad; Walker, Marc
    • Journal of Physics: Energy, Vol. 1, Issue 4
    • DOI: 10.1088/2515-7655/ab2e92

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    journal, August 2019

    • Harris, Oliver C.; Lin, Yuxiao; Qi, Yue
    • Journal of The Electrochemical Society, Vol. 167, Issue 1
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    • DOI: 10.1149/2.0131709jes

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    journal, January 2019

    • Weber, Rochelle; Louli, A. J.; Plucknett, K. P.
    • Journal of The Electrochemical Society, Vol. 166, Issue 10
    • DOI: 10.1149/2.0361910jes

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    journal, January 2019

    • Rodrigues, Marco-Tulio F.; Kalaga, Kaushik; Trask, Stephen E.
    • Journal of The Electrochemical Society, Vol. 166, Issue 6
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    • DOI: 10.1149/2.0571910jes

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    • Journal of The Electrochemical Society, Vol. 164, Issue 7
    • DOI: 10.1149/2.0861707jes

    In Situ Carbon-Coated NCM622 through CF x for Lithium-Ion Batteries with High Cycling Stability
    journal, January 2019

    • Cao, Ran; Fan, Wei; Li, Congju
    • Journal of The Electrochemical Society, Vol. 166, Issue 14
    • DOI: 10.1149/2.0871914jes

    Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
    journal, December 2016

    • Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
    • Journal of The Electrochemical Society, Vol. 164, Issue 2
    • DOI: 10.1149/2.1111702jes

    Nickel, Manganese, and Cobalt Dissolution from Ni-Rich NMC and Their Effects on NMC622-Graphite Cells
    journal, January 2019

    • Jung, Roland; Linsenmann, Fabian; Thomas, Rowena
    • Journal of The Electrochemical Society, Vol. 166, Issue 2
    • DOI: 10.1149/2.1151902jes

    Temperature Dependence of Oxygen Release from LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) Cathode Materials for Li-Ion Batteries
    journal, January 2018

    • Jung, Roland; Strobl, Philipp; Maglia, Filippo
    • Journal of The Electrochemical Society, Vol. 165, Issue 11
    • DOI: 10.1149/2.1261811jes

    Enhanced Electrochemical Performance of LiNi 0.8 Co 0.1 Mn 0.1 O 2 Cathode with an Ionic Liquid-Based Electrolyte
    journal, January 2019

    • Ma, Chenchong; Wang, Dong; Yang, Yun
    • Journal of The Electrochemical Society, Vol. 166, Issue 14
    • DOI: 10.1149/2.1271914jes

    Advancing Lithium- and Manganese-Rich Cathodes through a Combined Electrolyte Additive/Surface Treatment Strategy
    journal, January 2019

    • Gutierrez, Arturo; He, Meinan; Yonemoto, Bryan T.
    • Journal of The Electrochemical Society, Vol. 166, Issue 16
    • DOI: 10.1149/2.1281915jes

    Impact of the Temperature in the Evaluation of Battery Performances During Long-Term Cycling—Characterisation and Modelling
    journal, August 2018

    • Capron, Odile; Jaguemont, Joris; Gopalakrishnan, Rahul
    • Applied Sciences, Vol. 8, Issue 8
    • DOI: 10.3390/app8081364

    Capacity Decay Mechanism of the LCO + NMC532/Graphite Cells Combined with Post-Mortem Technique
    journal, August 2017

    • Zhang, Linjing; Jiang, Jiuchun; Zhang, Weige
    • Energies, Vol. 10, Issue 8
    • DOI: 10.3390/en10081147

    Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability
    journal, August 2019

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