Influence of annealing on the photodeposition of silver on periodically poled lithium niobate
Abstract
Here, the preferential deposition of metal nanoparticles onto periodically poled lithium niobate surfaces, whereby photogenerated electrons accumulate in accordance with local electric fields and reduce metal ions from solution, is known to depend on the intensity and wavelength of the illumination and the concentration of the solution used. Here, it is shown that for identical deposition conditions (wavelength, intensity, concentration), post-poling annealing for 10 h at 200 °C modifies the surface reactivity through the reorientation of internal defect fields. Whereas silver nanoparticles deposit preferentially on the +z domains on unannealed crystals, the deposition occurs preferentially along 180 degrees domain walls for annealed crystals. In neither case is the deposition selective; limited deposition occurs also on the unannealed -z domain surface and on both annealed domain surfaces. The observed behavior is attributed to a relaxation of the poling-induced defect frustration mediated by Li+ ion mobility during annealing, which affects the accumulation of electrons, thereby changing the surface reactivity. The evolution of the defect field with temperature is corroborated using Raman spectroscopy.
- Authors:
-
- Univ. College Dublin, Dublin (Ireland)
- KTH - Royal Institute of Technology, Stockholm (Sweden)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1337841
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 119; Journal Issue: 5; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; ferroelectric; lithium niobate; nanofabrication; lithography; directed assembly; domain patterning; photochemistry; atomic force microscopy; depolarization field; detect field
Citation Formats
Carville, N. Craig, Neumayer, Sabine M., Manzo, Michele, Baghban, Mohammad-Amin, Ivanov, Ilia N., Gallo, Katia, and Rodriguez, Brian J. Influence of annealing on the photodeposition of silver on periodically poled lithium niobate. United States: N. p., 2016.
Web. doi:10.1063/1.4940968.
Carville, N. Craig, Neumayer, Sabine M., Manzo, Michele, Baghban, Mohammad-Amin, Ivanov, Ilia N., Gallo, Katia, & Rodriguez, Brian J. Influence of annealing on the photodeposition of silver on periodically poled lithium niobate. United States. https://doi.org/10.1063/1.4940968
Carville, N. Craig, Neumayer, Sabine M., Manzo, Michele, Baghban, Mohammad-Amin, Ivanov, Ilia N., Gallo, Katia, and Rodriguez, Brian J. Wed .
"Influence of annealing on the photodeposition of silver on periodically poled lithium niobate". United States. https://doi.org/10.1063/1.4940968. https://www.osti.gov/servlets/purl/1337841.
@article{osti_1337841,
title = {Influence of annealing on the photodeposition of silver on periodically poled lithium niobate},
author = {Carville, N. Craig and Neumayer, Sabine M. and Manzo, Michele and Baghban, Mohammad-Amin and Ivanov, Ilia N. and Gallo, Katia and Rodriguez, Brian J.},
abstractNote = {Here, the preferential deposition of metal nanoparticles onto periodically poled lithium niobate surfaces, whereby photogenerated electrons accumulate in accordance with local electric fields and reduce metal ions from solution, is known to depend on the intensity and wavelength of the illumination and the concentration of the solution used. Here, it is shown that for identical deposition conditions (wavelength, intensity, concentration), post-poling annealing for 10 h at 200 °C modifies the surface reactivity through the reorientation of internal defect fields. Whereas silver nanoparticles deposit preferentially on the +z domains on unannealed crystals, the deposition occurs preferentially along 180 degrees domain walls for annealed crystals. In neither case is the deposition selective; limited deposition occurs also on the unannealed -z domain surface and on both annealed domain surfaces. The observed behavior is attributed to a relaxation of the poling-induced defect frustration mediated by Li+ ion mobility during annealing, which affects the accumulation of electrons, thereby changing the surface reactivity. The evolution of the defect field with temperature is corroborated using Raman spectroscopy.},
doi = {10.1063/1.4940968},
journal = {Journal of Applied Physics},
number = 5,
volume = 119,
place = {United States},
year = {Wed Feb 03 00:00:00 EST 2016},
month = {Wed Feb 03 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Tunable and highly reproducible surface-enhanced Raman scattering substrates made from large-scale nanoparticle arrays based on periodically poled LiNbO 3 templates
journal, March 2013
- Liu, Xiaoyan; Kitamura, Kenji; Yu, Qiuming
- Science and Technology of Advanced Materials, Vol. 14, Issue 5
Plasmon Enhanced Raman from Ag Nanopatterns Made Using Periodically Poled Lithium Niobate and Periodically Proton Exchanged Template Methods
journal, December 2012
- Damm, Signe; Carville, N. Craig; Rodriguez, Brian J.
- The Journal of Physical Chemistry C, Vol. 116, Issue 50
Atomic Polarization and Local Reactivity on Ferroelectric Surfaces: A New Route toward Complex Nanostructures
journal, June 2002
- Kalinin, S. V.; Bonnell, D. A.; Alvarez, T.
- Nano Letters, Vol. 2, Issue 6
Multifunctional Protein-Enabled Patterning on Arrayed Ferroelectric Materials
journal, April 2012
- Hnilova, M.; Liu, X.; Yuca, E.
- ACS Applied Materials & Interfaces, Vol. 4, Issue 4
Polarization-dependent electron affinity of LiNbO3 surfaces
journal, September 2004
- Yang, W. -C.; Rodriguez, B. J.; Gruverman, A.
- Applied Physics Letters, Vol. 85, Issue 12
Photochemistry on a polarisable semi-conductor: what do we understand today?
journal, October 2009
- Tiwari, Divya; Dunn, Steve
- Journal of Materials Science, Vol. 44, Issue 19
Spatially Selective Photochemical Reduction of Silver on the Surface of Ferroelectric Barium Titanate
journal, February 2001
- Giocondi, Jennifer L.; Rohrer, Gregory S.
- Chemistry of Materials, Vol. 13, Issue 2
Spatial Separation of Photochemical Oxidation and Reduction Reactions on the Surface of Ferroelectric BaTiO 3
journal, September 2001
- Giocondi, Jennifer L.; Rohrer, Gregory S.
- The Journal of Physical Chemistry B, Vol. 105, Issue 35
Photo-reduction of silver salts on highly heterogeneous lead zirconate titanate
journal, April 2007
- Jones, P. M.; Dunn, S.
- Nanotechnology, Vol. 18, Issue 18
Photochemical Investigation of a Polarizable Semiconductor, Lead-Zirconate-Titanate
journal, September 2008
- Jones, P. M.; Gallardo, D. E.; Dunn, S.
- Chemistry of Materials, Vol. 20, Issue 18
Interaction of Stern layer and domain structure on photochemistry of lead-zirconate-titanate
journal, February 2009
- Jones, P. M.; Dunn, S.
- Journal of Physics D: Applied Physics, Vol. 42, Issue 6
The photochemical growth of silver nanoparticles on semiconductor surfaces—initial nucleation stage
journal, February 2009
- Dunn, S.; Sharp, S.; Burgess, S.
- Nanotechnology, Vol. 20, Issue 11
Photochemical Growth of Silver Nanoparticles on c - and c + Domains on Lead Zirconate Titanate Thin Films
journal, July 2007
- Dunn, Steve; Jones, Paul M.; Gallardo, Diego E.
- Journal of the American Chemical Society, Vol. 129, Issue 28
Fabrication of metallic nanowires on a ferroelectric template via photochemical reaction
journal, September 2006
- Hanson, J. N.; Rodriguez, B. J.; Nemanich, R. J.
- Nanotechnology, Vol. 17, Issue 19
Ferroelectric Lithography: Bottom-up Assembly and Electrical Performance of a Single Metallic Nanowire
journal, February 2009
- Haussmann, Alexander; Milde, Peter; Erler, Christiane
- Nano Letters, Vol. 9, Issue 2
Anomalous Photodeposition of Ag on Ferroelectric Surfaces with Below-Bandgap Excitation
journal, January 2014
- Seal, Katyayani; Rodriguez, Brian J.; Ivanov, Ilia N.
- Advanced Optical Materials, Vol. 2, Issue 3
Photoreduction of SERS-Active Metallic Nanostructures on Chemically Patterned Ferroelectric Crystals
journal, July 2012
- Carville, N. Craig; Manzo, Michele; Damm, Signe
- ACS Nano, Vol. 6, Issue 8
Growth mechanism of photoreduced silver nanostructures on periodically proton exchanged lithium niobate: Time and concentration dependence
journal, May 2013
- Craig Carville, N.; Manzo, Michele; Denning, Denise
- Journal of Applied Physics, Vol. 113, Issue 18
Surface enhanced luminescence and Raman scattering from ferroelectrically defined Ag nanopatterned arrays
journal, August 2013
- Damm, Signe; Craig Carville, N.; Manzo, Michele
- Applied Physics Letters, Vol. 103, Issue 8
Direct shape control of photoreduced nanostructures on proton exchanged ferroelectric templates
journal, January 2013
- Balobaid, Laila; Craig Carville, N.; Manzo, Michele
- Applied Physics Letters, Vol. 102, Issue 4
Photoreduction of metal nanostructures on periodically proton exchanged MgO-doped lithium niobate crystals
journal, October 2013
- Balobaid, Laila; Craig Carville, N.; Manzo, Michele
- Applied Physics Letters, Vol. 103, Issue 18
PATTERNING OF SURFACE ELECTRONIC PROPERTIES AND SELECTIVE SILVER DEPOSITION ON LiNbO 3 TEMPLATE
journal, December 2008
- Liu, Xiaoyan; Ohuchi, Fumio; Kitamura, Kenji
- Functional Materials Letters, Vol. 01, Issue 03
Photocatalytic nanoparticle deposition on LiNbO3 nanodomain patterns via photovoltaic effect
journal, July 2007
- Liu, Xiaoyan; Kitamura, Kenji; Terabe, Kazuya
- Applied Physics Letters, Vol. 91, Issue 4
Influence of ferroelectricity on the photoelectric effect of LiNbO3
journal, September 2008
- Dunn, S.; Tiwari, D.
- Applied Physics Letters, Vol. 93, Issue 9
Photo-induced Ag deposition on periodically poled lithium niobate: Concentration and intensity dependence
journal, October 2011
- Sun, Yang; Eller, Brianna S.; Nemanich, Robert J.
- Journal of Applied Physics, Vol. 110, Issue 8
Photoinduced Ag deposition on periodically poled lithium niobate: Wavelength and polarization screening dependence
journal, May 2011
- Sun, Yang; Nemanich, Robert J.
- Journal of Applied Physics, Vol. 109, Issue 10
First‐order quasi‐phase matched LiNbO 3 waveguide periodically poled by applying an external field for efficient blue second‐harmonic generation
journal, February 1993
- Yamada, M.; Nada, N.; Saitoh, M.
- Applied Physics Letters, Vol. 62, Issue 5
High-resolution X-ray characterization of periodically domain-inverted nonlinear optical crystals
journal, April 1995
- Hu, Z. W.; Thomas, P. A.; Webjorn, J.
- Journal of Physics D: Applied Physics, Vol. 28, Issue 4A
Nanoscale piezoelectric response across a single antiparallel ferroelectric domain wall
journal, July 2005
- Scrymgeour, David A.; Gopalan, Venkatraman
- Physical Review B, Vol. 72, Issue 2
Domain reversal and nonstoichiometry in lithium tantalate
journal, September 2001
- Kim, Sungwon; Gopalan, Venkatraman; Kitamura, K.
- Journal of Applied Physics, Vol. 90, Issue 6
Defect–Domain Wall Interactions in Trigonal Ferroelectrics
journal, August 2007
- Gopalan, Venkatraman; Dierolf, Volkmar; Scrymgeour, David A.
- Annual Review of Materials Research, Vol. 37, Issue 1
Origin and characteristics of internal fields in LiNbO 3 crystals
journal, June 1997
- Gopalan, Venkatraman; Gupta, Mool C.
- Ferroelectrics, Vol. 198, Issue 1
Evaluation of the internal field in lithium niobate ferroelectric domains by an interferometric method
journal, October 2004
- de Angelis, M.; De Nicola, S.; Finizio, A.
- Applied Physics Letters, Vol. 85, Issue 14
Enhancement of crystalline, piezoelectric and optical quality of LiNbO3 single crystals by post-growth annealing and poling
journal, September 2005
- Bhagavannarayana, G.; Budakoti, G. C.; Maurya, K. K.
- Journal of Crystal Growth, Vol. 282, Issue 3-4
Observation of internal field in LiTaO 3 single crystals: Its origin and time‐temperature dependence
journal, February 1996
- Gopalan, Venkatraman; Gupta, Mool C.
- Applied Physics Letters, Vol. 68, Issue 7
The role of nonstoichiometry in 180° domain switching of LiNbO3 crystals
journal, April 1998
- Gopalan, Venkatraman; Mitchell, Terence E.; Furukawa, Y.
- Applied Physics Letters, Vol. 72, Issue 16, p. 1981-1983
Two-dimensional domain engineering in LiNbO_3 via a hybrid patterning technique
journal, January 2011
- Manzo, Michele; Laurell, Fredrik; Pasiskevicius, Valdas
- Optical Materials Express, Vol. 1, Issue 3
Domain growth kinetics in lithium niobate single crystals studied by piezoresponse force microscopy
journal, January 2005
- Rodriguez, B. J.; Nemanich, R. J.; Kingon, A.
- Applied Physics Letters, Vol. 86, Issue 1
Micro- and nanoscale domain engineering in lithium niobate and lithium tantalate
conference, June 2000
- Shur, Vladimir Y.; Rumyantsev, Evgenii L.; Nikolaeva, Ekaterina
- SPIE's 7th Annual International Symposium on Smart Structures and Materials, SPIE Proceedings
A Raman study of single-crystal congruent lithium niobate following electric-field repoling
journal, August 2004
- Scott, J. G.; Mailis, S.; Sones, C. L.
- Applied Physics A, Vol. 79, Issue 3
Depth profiling of proton exchanged LiNbO 3 waveguides by micro‐Raman spectroscopy
journal, June 1993
- Paz‐Pujalt, Gustavo R.; Tuschel, David D.
- Applied Physics Letters, Vol. 62, Issue 26
A micro-Raman spectroscopic investigation of He^+-irradiation damage in LiNbO_3
journal, January 2013
- Huang, Hsu-Cheng; Dadap, Jerry I.; Gaathon, Ophir
- Optical Materials Express, Vol. 3, Issue 2
Ilmenite-like stacking defect in nonstoichiometric lithium niobate crystals investigated by Raman scattering spectra
journal, May 2000
- Kong, Yongfa; Xu, Jingjun; Chen, Xiaojun
- Journal of Applied Physics, Vol. 87, Issue 9
Photocatalysts with internal electric fields
journal, January 2014
- Li, Li; Salvador, Paul A.; Rohrer, Gregory S.
- Nanoscale, Vol. 6, Issue 1
Ferroelectric Lithography of Multicomponent Nanostructures
journal, May 2004
- Kalinin, S. V.; Bonnell, D. A.; Alvarez, T.
- Advanced Materials, Vol. 16, Issue 910
Influence of the Ferroelectric Nature of Lithium Niobate to Drive Photocatalytic Dye Decolorization under Artificial Solar Light
journal, September 2012
- Stock, Matt; Dunn, Steve
- The Journal of Physical Chemistry C, Vol. 116, Issue 39
In situ deposition/positioning of magnetic nanoparticles with ferroelectric nanolithography
journal, March 2005
- Lei, Xiaojun; Li, Dongbo; Shao, Rui
- Journal of Materials Research, Vol. 20, Issue 3
Photo electron emission microscopy of polarity-patterned materials
journal, April 2005
- Yang, W-C; Rodriguez, B. J.; Gruverman, A.
- Journal of Physics: Condensed Matter, Vol. 17, Issue 16
Works referencing / citing this record:
Hybrid Plasmonic–Ferroelectric Architectures for Lasing and SHG Processes at the Nanoscale
journal, June 2019
- O. Ramírez, Mariola; Molina, Pablo; Gómez‐Tornero, Alejandro
- Advanced Materials, Vol. 31, Issue 35
Formation mechanism and elimination methods for anti-site defects in LiNbO 3 /LiTaO 3 crystals
journal, January 2016
- Kang, Xueliang; Liang, Longyue; Song, Wei
- CrystEngComm, Vol. 18, Issue 42