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Title: A review of molecular beam epitaxy of ferroelectric BaTiO3 films on Si, Ge and GaAs substrates and their applications

Abstract

SrTiO3 epitaxial growth by molecular beam epitaxy (MBE) on silicon has opened up the route to the monolithic integration of various complex oxides on the complementary metal-oxide-semiconductor silicon platform. Among functional oxides, ferroelectric perovskite oxides offer promising perspectives to improve or add functionalities on-chip. We review the growth by MBE of the ferroelectric compound BaTiO3 on silicon (Si), germanium (Ge) and gallium arsenide (GaAs) and we discuss the film properties in terms of crystalline structure, microstructure and ferroelectricity. Lastly, we review the last developments in two areas of interest for the applications of BaTiO3 films on silicon, namely integrated photonics, which benefits from the large Pockels effect of BaTiO3, and low power logic devices, which may benefit from the negative capacitance of the ferroelectric.

Authors:
 [1];  [2];  [2];  [3];  [1]
  1. Univ. de Lyon, Ecully (France)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Univ. de Toulouse, Toulouse (France)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE
OSTI Identifier:
1337832
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Science and Technology of Advanced Materials
Additional Journal Information:
Journal Volume: 16; Journal Issue: 3; Journal ID: ISSN 1468-6996
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; molecular beam epitaxy; ferroelectric; semiconductor

Citation Formats

Mazet, Lucie, Yang, Sang Mo, Kalinin, Sergei V., Schamm-Chardon, Sylvie, and Dubourdieu, Catherine. A review of molecular beam epitaxy of ferroelectric BaTiO3 films on Si, Ge and GaAs substrates and their applications. United States: N. p., 2015. Web. doi:10.1088/1468-6996/16/3/036005.
Mazet, Lucie, Yang, Sang Mo, Kalinin, Sergei V., Schamm-Chardon, Sylvie, & Dubourdieu, Catherine. A review of molecular beam epitaxy of ferroelectric BaTiO3 films on Si, Ge and GaAs substrates and their applications. United States. https://doi.org/10.1088/1468-6996/16/3/036005
Mazet, Lucie, Yang, Sang Mo, Kalinin, Sergei V., Schamm-Chardon, Sylvie, and Dubourdieu, Catherine. Tue . "A review of molecular beam epitaxy of ferroelectric BaTiO3 films on Si, Ge and GaAs substrates and their applications". United States. https://doi.org/10.1088/1468-6996/16/3/036005. https://www.osti.gov/servlets/purl/1337832.
@article{osti_1337832,
title = {A review of molecular beam epitaxy of ferroelectric BaTiO3 films on Si, Ge and GaAs substrates and their applications},
author = {Mazet, Lucie and Yang, Sang Mo and Kalinin, Sergei V. and Schamm-Chardon, Sylvie and Dubourdieu, Catherine},
abstractNote = {SrTiO3 epitaxial growth by molecular beam epitaxy (MBE) on silicon has opened up the route to the monolithic integration of various complex oxides on the complementary metal-oxide-semiconductor silicon platform. Among functional oxides, ferroelectric perovskite oxides offer promising perspectives to improve or add functionalities on-chip. We review the growth by MBE of the ferroelectric compound BaTiO3 on silicon (Si), germanium (Ge) and gallium arsenide (GaAs) and we discuss the film properties in terms of crystalline structure, microstructure and ferroelectricity. Lastly, we review the last developments in two areas of interest for the applications of BaTiO3 films on silicon, namely integrated photonics, which benefits from the large Pockels effect of BaTiO3, and low power logic devices, which may benefit from the negative capacitance of the ferroelectric.},
doi = {10.1088/1468-6996/16/3/036005},
journal = {Science and Technology of Advanced Materials},
number = 3,
volume = 16,
place = {United States},
year = {Tue Jun 30 00:00:00 EDT 2015},
month = {Tue Jun 30 00:00:00 EDT 2015}
}

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Mechanism of cleaning Si(100) surface using Sr or SrO for the growth of crystalline SrTiO[sub 3] films
journal, January 2002

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  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 20, Issue 4
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Combined in-situ photoemission spectroscopy and density functional theory of the Sr Zintl template for oxide heteroepitaxy on Si(001)
journal, July 2013

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  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 31, Issue 4
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Tunable electrical properties of TaN x thin films grown by ionized physical vapor deposition
journal, September 2014

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  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 32, Issue 5
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Characterization of a radio frequency plasma source for molecular beam epitaxial growth of high‐ T c superconductor films
journal, September 1992

  • Locquet, Jean‐Pierre; Mächler, Erich
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 10, Issue 5
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Augmented methods for growth and development of novel multi-cation oxides
conference, March 2014

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  • SPIE OPTO, SPIE Proceedings
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A Ferroelectric Oxide Made Directly on Silicon
journal, April 2009


Giant Piezoelectricity on Si for Hyperactive MEMS
journal, November 2011


High-Temperature Superconducting Multilayers and Heterostructures Grown by Atomic Layer-By-Layer Molecular Beam Epitaxy
journal, August 1995


125 pm/V hybrid silicon and lithium niobate optical microring resonator with integrated electrodes
journal, January 2013

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Towards precise defect control in layered oxide structures by using oxide molecular beam epitaxy
journal, January 2014

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  • Beilstein Journal of Nanotechnology, Vol. 5
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Experimental Evidence of Ferroelectric Negative Capacitance in Nanoscale Heterostructures
text, January 2011


Ionically-mediated electromechanical hysteresis in transition metal oxides
preprint, January 2011


Converse flexoelectricity around ferroelastic domain walls
preprint, January 2019


Physics of thin-film ferroelectric oxides
text, January 2005


Ferroelectricity in ultra-thin perovskite films
text, January 2005


Works referencing / citing this record:

Epitaxial Oxides on Semiconductors: From Fundamentals to New Devices
journal, July 2019


Mixed electrochemical–ferroelectric states in nanoscale ferroelectrics
journal, May 2017

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  • Nature Physics, Vol. 13, Issue 8
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Ferroelectric negative capacitance
journal, March 2019

  • Íñiguez, Jorge; Zubko, Pavlo; Luk’yanchuk, Igor
  • Nature Reviews Materials, Vol. 4, Issue 4
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Interfacial structure of SrZr x Ti 1− x O 3 films on Ge
journal, November 2018

  • Chen, Tongjie; Ahmadi-Majlan, Kamyar; Lim, Zheng Hui
  • Applied Physics Letters, Vol. 113, Issue 20
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Atomic layer deposition of epitaxial ferroelectric barium titanate on Si(001) for electronic and photonic applications
journal, August 2019

  • Lin, Edward L.; Posadas, Agham B.; Zheng, Lu
  • Journal of Applied Physics, Vol. 126, Issue 6
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Traps induced Greens function based mathematical modeling for BaTiO 3 –SrTiO 3 gate stack dual metal GAA MOSFET
journal, October 2019

  • Gauba, Tushar; Pratap, Yogesh; Rewari, Sonam
  • Semiconductor Science and Technology, Vol. 34, Issue 11
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Epitaxial growth of (111) BaTiO3 thin films on (0002) GaN substrates with SrTiO3/TiN buffer layers
journal, April 2019

  • Jia, Shasha; Li, Xiaomin; Li, Guanjie
  • Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 10
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van der Waals epitaxy of highly (111)-oriented BaTiO 3 on MXene
journal, January 2019

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  • Nanoscale, Vol. 11, Issue 2
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Strain-dependence of χ(2) in thin film barium strontium titanate
journal, February 2019

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Bragg coherent diffractive imaging of strain at the nanoscale
journal, March 2019

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Enhanced in-plane ferroelectricity in BaTiO 3 thin films fabricated by aqueous chemical solution deposition
journal, October 2018

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Interfacial Structure of SrZr$_{x}$Ti$_{1-x}$O$_3$ films on Ge
text, January 2018