Studies on the magnetic ground state of a spin Mobius strip
Abstract
Abstract Here we report the synthesis, structure and detailed characterisation of three n ‐membered oxovanadium rings, Na n [(V=O) n Na n (H 2 O) n (α, β, or γ‐CD) 2 ]⋅ m H 2 O ( n =6, 7, or 8), prepared by the reactions of (V=O)SO 4 ⋅ x H 2 O with α, β, or γ‐cyclodextrins (CDs) and NaOH in water. Their alternating heterometallic vanadium/sodium cyclic core structures were sandwiched between two CD moieties such that O‐Na‐O groups separated the neighbouring vanadyl ions. Antiferromagnetic interactions between the S =1/2 vanadyl ions led to S =0 ground states for the even‐membered rings, but to two quasi‐degenerate S =1/2 states for the spin‐frustrated heptanuclear cluster.
- Authors:
-
- Univ. of Tsukuba, Tsukuba (Japan); Univ. of Nottingham, Nottingham (United Kingdom)
- Univ. of Tsukuba, Tsukuba (Japan)
- Osaka Univ., Osaka (Japan)
- Tohoku Univ., Sendai (Japan)
- CNRS, Institut NEEL, Univ. Grenoble Alpes, Grenoble (France)
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1337681
- Alternate Identifier(s):
- OSTI ID: 1401473
- Report Number(s):
- IS-J-9141
Journal ID: ISSN 0947-6539
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 22; Journal Issue: 40; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Newton, Graham N., Hoshino, Norihisa, Matsumoto, Takuto, Shiga, Takuya, Nakano, Motohiro, Nojiri, Hiroyuki, Wernsdorfer, Wolfgang, Furukawa, Yuji, and Oshio, Hiroki. Studies on the magnetic ground state of a spin Mobius strip. United States: N. p., 2016.
Web. doi:10.1002/chem.201602439.
Newton, Graham N., Hoshino, Norihisa, Matsumoto, Takuto, Shiga, Takuya, Nakano, Motohiro, Nojiri, Hiroyuki, Wernsdorfer, Wolfgang, Furukawa, Yuji, & Oshio, Hiroki. Studies on the magnetic ground state of a spin Mobius strip. United States. https://doi.org/10.1002/chem.201602439
Newton, Graham N., Hoshino, Norihisa, Matsumoto, Takuto, Shiga, Takuya, Nakano, Motohiro, Nojiri, Hiroyuki, Wernsdorfer, Wolfgang, Furukawa, Yuji, and Oshio, Hiroki. Mon .
"Studies on the magnetic ground state of a spin Mobius strip". United States. https://doi.org/10.1002/chem.201602439. https://www.osti.gov/servlets/purl/1337681.
@article{osti_1337681,
title = {Studies on the magnetic ground state of a spin Mobius strip},
author = {Newton, Graham N. and Hoshino, Norihisa and Matsumoto, Takuto and Shiga, Takuya and Nakano, Motohiro and Nojiri, Hiroyuki and Wernsdorfer, Wolfgang and Furukawa, Yuji and Oshio, Hiroki},
abstractNote = {Abstract Here we report the synthesis, structure and detailed characterisation of three n ‐membered oxovanadium rings, Na n [(V=O) n Na n (H 2 O) n (α, β, or γ‐CD) 2 ]⋅ m H 2 O ( n =6, 7, or 8), prepared by the reactions of (V=O)SO 4 ⋅ x H 2 O with α, β, or γ‐cyclodextrins (CDs) and NaOH in water. Their alternating heterometallic vanadium/sodium cyclic core structures were sandwiched between two CD moieties such that O‐Na‐O groups separated the neighbouring vanadyl ions. Antiferromagnetic interactions between the S =1/2 vanadyl ions led to S =0 ground states for the even‐membered rings, but to two quasi‐degenerate S =1/2 states for the spin‐frustrated heptanuclear cluster.},
doi = {10.1002/chem.201602439},
journal = {Chemistry - A European Journal},
number = 40,
volume = 22,
place = {United States},
year = {Mon Aug 22 00:00:00 EDT 2016},
month = {Mon Aug 22 00:00:00 EDT 2016}
}
Web of Science
Figures / Tables:
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