Single crystal magnetic structure and susceptibility of CoSe2O5

Rodriguez, Efrain E.; Cao, Huibo; Haiges, Ralf; Melot, Brent C.

doi:10.1016/j.jssc.2015.09.006

Title: Single crystal magnetic structure and susceptibility of CoSe₂O₅

Abstract

The structure of CoSe₂O₅ consists of one-dimensional ribbons of edge-sharing CoO₆ octahedra bound together by polyanionic subunits of Se₂O₅. Previous work on polycrystalline samples reported a canted antiferromagnetic arrangement of the magnetic moments below the ordering temperature of 8.5 K. Here, we report a single crystal investigation using variable temperature and field magnetic susceptibility and low-temperature neutron diffraction to more precisely characterize the nature of the magnetic ground state of CoSe₂O₅. Contrary to previous reports, we find that the single crystal magnetic structure shows no canting of the antiferromagnetic ground state, and in the process have identified several field-induced changes to the magnetization. Lastly, we discuss these results in the context of the revised magnetic structure and highlight the importance of crystal growth for the accurate characterization of these properties.

Authors:

Rodriguez, Efrain E. ^[1]; Cao, Huibo ^[2]; Haiges, Ralf ^[3]; Melot, Brent C. ^[3]

Univ. of Maryland, College Park, MD (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Southern California, Los Angeles, CA (United States)

Publication Date:: Tue Sep 08 00:00:00 EDT 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1335307

Alternate Identifier(s):: OSTI ID: 1252059

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Solid State Chemistry

Additional Journal Information:: Journal Volume: 236; Journal Issue: C; Journal ID: ISSN 0022-4596

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; metamagnetism; single crystal; magnetic structure

Citation Formats


                    Rodriguez, Efrain E., Cao, Huibo, Haiges, Ralf, and Melot, Brent C. Single crystal magnetic structure and susceptibility of CoSe2O5.  United States: N. p., 2015. 
Web.  doi:10.1016/j.jssc.2015.09.006.

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                    Rodriguez, Efrain E., Cao, Huibo, Haiges, Ralf, & Melot, Brent C. Single crystal magnetic structure and susceptibility of CoSe2O5.  United States.  https://doi.org/10.1016/j.jssc.2015.09.006

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                    Rodriguez, Efrain E., Cao, Huibo, Haiges, Ralf, and Melot, Brent C. Tue .  
"Single crystal magnetic structure and susceptibility of CoSe2O5".  United States.  https://doi.org/10.1016/j.jssc.2015.09.006.  https://www.osti.gov/servlets/purl/1335307.

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@article{osti_1335307,

  title        = {Single crystal magnetic structure and susceptibility of CoSe2O5},

  author       = {Rodriguez, Efrain E. and Cao, Huibo and Haiges, Ralf and Melot, Brent C.},

  abstractNote = {The structure of CoSe2O5 consists of one-dimensional ribbons of edge-sharing CoO6 octahedra bound together by polyanionic subunits of Se2O5. Previous work on polycrystalline samples reported a canted antiferromagnetic arrangement of the magnetic moments below the ordering temperature of 8.5 K. Here, we report a single crystal investigation using variable temperature and field magnetic susceptibility and low-temperature neutron diffraction to more precisely characterize the nature of the magnetic ground state of CoSe2O5. Contrary to previous reports, we find that the single crystal magnetic structure shows no canting of the antiferromagnetic ground state, and in the process have identified several field-induced changes to the magnetization. Lastly, we discuss these results in the context of the revised magnetic structure and highlight the importance of crystal growth for the accurate characterization of these properties.},

  doi          = {10.1016/j.jssc.2015.09.006},

  journal      = {Journal of Solid State Chemistry},

  number       = C,

  volume       = 236,

  place        = {United States},

  year         = {Tue Sep 08 00:00:00 EDT 2015},

  month        = {Tue Sep 08 00:00:00 EDT 2015}

}

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High-throughput prediction of the ground-state collinear magnetic order of inorganic materials using Density Functional Theory
journal, June 2019

Horton, Matthew Kristofer; Montoya, Joseph Harold; Liu, Miao
npj Computational Materials, Vol. 5, Issue 1
DOI: 10.1038/s41524-019-0199-7

Hydrothermal Synthesis and Crystal Structures of Na ₂ Be ₃ (SeO ₃ ) ₄ ·H ₂ O and Cs ₂ [Mg(H ₂ O) ₆ ] ₃ (SeO ₃ ) ₄ : Hydrothermal Synthesis and Crystal Structures of Na
journal, July 2017

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Title: Single crystal magnetic structure and susceptibility of CoSe2O5

Abstract

Citation Formats

Peierls instability in Heisenberg chains journal, December 1974

Ferroelectricity in an S = 1 / 2 Chain Cuprate journal, January 2007

Experimental and Computational Investigation of the Polar Ferrimagnet VOSe 2 O 5 journal, September 2010

Magnetic anisotropy obtained from demagnetization curves: Influence of particle orientation and interactions journal, June 1999

Magnetization Curves for Polycrystalline Ferromagnetics journal, August 1950

Magnetic structure and susceptibility of CoSe 2 O 5 : An antiferromagnetic chain compound journal, July 2010

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Symmetry-Based Computational Tools for Magnetic Crystallography journal, July 2015

Magnetic Structure Analysis and Group Theory journal, February 1971

Neutron Diffraction Study of the Magnetic Properties of the Series of Perovskite-Type Compounds [ ( 1 − x ) La , x Ca ] Mn O 3 journal, October 1955

Strongly Geometrically Frustrated Magnets journal, August 1994

Geometrically frustrated magnetic materials journal, January 2001

Structure and Magnetic Ordering of M II [N(CN) 2 ] 2 (M = Co, Ni) † journal, September 1998

Electron-Phonon and Magnetoelastic Interactions in Ferromagnetic Co [ N ( CN ) 2 ] 2 journal, July 2013

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Title: Single crystal magnetic structure and susceptibility of CoSe₂O₅

Peierls instability in Heisenberg chains
journal, December 1974

Ferroelectricity in an $S = 1 / 2$ Chain Cuprate
journal, January 2007

Experimental and Computational Investigation of the Polar Ferrimagnet VOSe ₂ O ₅
journal, September 2010

Magnetic anisotropy obtained from demagnetization curves: Influence of particle orientation and interactions
journal, June 1999

Magnetization Curves for Polycrystalline Ferromagnetics
journal, August 1950

Magnetic structure and susceptibility of ${CoSe}_{2} O_{5}$ : An antiferromagnetic chain compound
journal, July 2010

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Symmetry-Based Computational Tools for Magnetic Crystallography
journal, July 2015

Magnetic Structure Analysis and Group Theory
journal, February 1971

Neutron Diffraction Study of the Magnetic Properties of the Series of Perovskite-Type Compounds $[(1 - x) La, x Ca] Mn O_{3}$
journal, October 1955

Strongly Geometrically Frustrated Magnets
journal, August 1994

Geometrically frustrated magnetic materials
journal, January 2001

Structure and Magnetic Ordering of M ^II [N(CN) ₂ ] ₂ (M = Co, Ni) ^†
journal, September 1998

Electron-Phonon and Magnetoelastic Interactions in Ferromagnetic $Co [N (CN)_{2}]_{2}$
journal, July 2013

High-throughput prediction of the ground-state collinear magnetic order of inorganic materials using Density Functional Theory
journal, June 2019

Hydrothermal Synthesis and Crystal Structures of Na ₂ Be ₃ (SeO ₃ ) ₄ ·H ₂ O and Cs ₂ [Mg(H ₂ O) ₆ ] ₃ (SeO ₃ ) ₄ : Hydrothermal Synthesis and Crystal Structures of Na
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