Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation

Zhou, Lan; Yan, Qimin; Yu, Jie; Jones, Ryan J.  R.; Becerra-Stasiewicz, Natalie; Suram, Santosh K.; Shinde, Aniketa; Guevarra, Dan; Neaton, Jeffrey B.; Persson, Kristin A.; Gregoire, John M.

doi:10.1039/C6CP00473C

Title: Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation

Abstract

Self-passivation under operational conditions is observed for several copper vanadate photoanodes, demonstrating their viability for durable solar fuels devices.

Authors:

Zhou, Lan ^[1]; Yan, Qimin ^[2]; Yu, Jie ^[3]; Jones, Ryan J. R. ^[1]; Becerra-Stasiewicz, Natalie ^[1]; Suram, Santosh K. ^[1]; Shinde, Aniketa ^[1]; Guevarra, Dan ^[1]; Neaton, Jeffrey B. ^[4]; Persson, Kristin A. ^[5]; Gregoire, John M. ^[1]

California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
Brookhaven National Lab. (BNL), Upton, NY (United States). Molecular Foundry; Univ. of California, Berkeley, CA (United States). Dept. of Physics
Brookhaven National Lab. (BNL), Upton, NY (United States). Molecular Foundry; California Inst. of Technology (CalTech), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis (JCAP); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division
Brookhaven National Lab. (BNL), Upton, NY (United States). Molecular Foundry; Univ. of California, Berkeley, CA (United States). Dept. of Physics; Kavli Energy Nanosciences Inst., Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division

Publication Date:: Mon Mar 14 00:00:00 EDT 2016

Research Org.:: California Institute of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1334192

Alternate Identifier(s):: OSTI ID: 1454462

Grant/Contract Number:: SC0004993; AC02-76SF00515; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Physical Chemistry Chemical Physics. PCCP

Additional Journal Information:: Journal Volume: 18; Journal Issue: 14; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 14 SOLAR ENERGY

Citation Formats


                    Zhou, Lan, Yan, Qimin, Yu, Jie, Jones, Ryan J.  R., Becerra-Stasiewicz, Natalie, Suram, Santosh K., Shinde, Aniketa, Guevarra, Dan, Neaton, Jeffrey B., Persson, Kristin A., and Gregoire, John M. Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation.  United States: N. p., 2016. 
Web.  doi:10.1039/C6CP00473C.

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                    Zhou, Lan, Yan, Qimin, Yu, Jie, Jones, Ryan J.  R., Becerra-Stasiewicz, Natalie, Suram, Santosh K., Shinde, Aniketa, Guevarra, Dan, Neaton, Jeffrey B., Persson, Kristin A., & Gregoire, John M. Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation.  United States.  https://doi.org/10.1039/C6CP00473C

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                    Zhou, Lan, Yan, Qimin, Yu, Jie, Jones, Ryan J.  R., Becerra-Stasiewicz, Natalie, Suram, Santosh K., Shinde, Aniketa, Guevarra, Dan, Neaton, Jeffrey B., Persson, Kristin A., and Gregoire, John M. Mon .  
"Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation".  United States.  https://doi.org/10.1039/C6CP00473C.  https://www.osti.gov/servlets/purl/1334192.

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@article{osti_1334192,

  title        = {Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation},

  author       = {Zhou, Lan and Yan, Qimin and Yu, Jie and Jones, Ryan J.  R. and Becerra-Stasiewicz, Natalie and Suram, Santosh K. and Shinde, Aniketa and Guevarra, Dan and Neaton, Jeffrey B. and Persson, Kristin A. and Gregoire, John M.},

  abstractNote = {Self-passivation under operational conditions is observed for several copper vanadate photoanodes, demonstrating their viability for durable solar fuels devices.},

  doi          = {10.1039/C6CP00473C},

  journal      = {Physical Chemistry Chemical Physics. PCCP},

  number       = 14,

  volume       = 18,

  place        = {United States},

  year         = {Mon Mar 14 00:00:00 EDT 2016},

  month        = {Mon Mar 14 00:00:00 EDT 2016}

}

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Title: Stability and self-passivation of copper vanadate photoanodes under chemical, electrochemical, and photoelectrochemical operation

Abstract

Citation Formats

Photoelectron spectroscopy study of oxygen vacancy on vanadium oxides surface journal, September 2004

Prediction of solid-aqueous equilibria: Scheme to combine first-principles calculations of solids with experimental aqueous states journal, June 2012

High Throughput Discovery of Solar Fuels Photoanodes in the CuO-V 2 O 5 System journal, August 2015

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Progress in bismuth vanadate photoanodes for use in solar water oxidation journal, January 2013

Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators journal, October 2015

Inorganic Materials as Catalysts for Photochemical Splitting of Water journal, January 2008

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation journal, July 2013

Oxygen Vacancy: The Invisible Agent on Oxide Surfaces journal, October 2003

Conductivity and Microstructure of Combinatorially Sputter-Deposited Ta–Ti–Al Nitride Thin Films journal, June 2015

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Prediction of solid-aqueous equilibria: Scheme to combine first-principles calculations of solids with experimental aqueous states
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High Throughput Discovery of Solar Fuels Photoanodes in the CuO-V ₂ O ₅ System
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Reduction mechanisms of the CuO(111) surface through surface oxygen vacancy formation and hydrogen adsorption
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