Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4

Poudel, N.; Lorenz, B.; Lv, B.; Wang, Y. Q.; Ye, F.; Wang, Jinchen; Fernandez-baca, J. A.; Chu, C. W.

doi:10.1080/10584587.2015.1102565

Title: Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO ₄

Abstract

There are various orders in multiferroic materials with a frustrated spiral spin modulation inducing a ferroelectric state are extremely sensitive to small perturbations such as magnetic and electric fields, external pressure, or chemical substitutions. A classical multiferroic, the mineral Hubnerite with chemical formula MnWO₄, shows three different magnetic phases at low temperature. The intermediate phase between 7.5K < T < 12.7K is multiferroic and ferroelectricity is induced by an inversion symmetry breaking spiral Mn-spin order and strong spin-lattice interactions. Furthermore, the substitution of Ni²⁺ (spin 1) for Mn²⁺ (spin 5/2) in MnWO₄ and its effects on the magnetic and multiferroic phases are studied. The ferroelectric phase is stabilized for low Ni content (up to 10%). Upon further Ni doping, the polarization in the ferroelectric phase is quickly suppressed while a collinear and commensurate magnetic phase, characteristic of the magnetic structure in NiWO₄, appears first at higher temperature, gradually extends to lower temperature, and becomes the ground state above 30% doping. Between 10% and 30%, the multiferroic phase coexists with the collinear commensurate phase. In this concentration region, the spin spiral plane is close to the a-b plane which explains the drop of the ferroelectric polarization. Finally, the phase diagram ofmore »« less

Authors:

Poudel, N. ^[1]; Lorenz, B. ^[1]; Lv, B. ^[1]; Wang, Y. Q. ^[1]; Ye, F. ^[2]; Wang, Jinchen ^[3]; Fernandez-baca, J. A. ^[4]; Chu, C. W. ^[5]

Univ. of Houston, TX (United States). Texas Center for Superconductivity and Dept. of Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Kentucky, Lexington, KY (United States). Center for Advanced Materials
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Kentucky, Lexington, KY (United States). Center for Advanced Materials; Renmin Univ. of China, Beijing (China). Dept. of Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
Univ. of Houston, TX (United States). Texas Center for Superconductivity and Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Tue Dec 15 00:00:00 EST 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1324156

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Integrated Ferroelectrics

Additional Journal Information:: Journal Volume: 166; Journal Issue: 1; Journal ID: ISSN 1058-4587

Publisher:: Taylor & Francis

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Poudel, N., Lorenz, B., Lv, B., Wang, Y. Q., Ye, F., Wang, Jinchen, Fernandez-baca, J. A., and Chu, C. W. Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4.  United States: N. p., 2015. 
Web.  doi:10.1080/10584587.2015.1102565.

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                    Poudel, N., Lorenz, B., Lv, B., Wang, Y. Q., Ye, F., Wang, Jinchen, Fernandez-baca, J. A., & Chu, C. W. Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4.  United States.  https://doi.org/10.1080/10584587.2015.1102565

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                    Poudel, N., Lorenz, B., Lv, B., Wang, Y. Q., Ye, F., Wang, Jinchen, Fernandez-baca, J. A., and Chu, C. W. Tue .  
"Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4".  United States.  https://doi.org/10.1080/10584587.2015.1102565.  https://www.osti.gov/servlets/purl/1324156.

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@article{osti_1324156,

  title        = {Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4},

  author       = {Poudel, N. and Lorenz, B. and Lv, B. and Wang, Y. Q. and Ye, F. and Wang, Jinchen and Fernandez-baca, J. A. and Chu, C. W.},

  abstractNote = {There are various orders in multiferroic materials with a frustrated spiral spin modulation inducing a ferroelectric state are extremely sensitive to small perturbations such as magnetic and electric fields, external pressure, or chemical substitutions. A classical multiferroic, the mineral Hubnerite with chemical formula MnWO4, shows three different magnetic phases at low temperature. The intermediate phase between 7.5K < T < 12.7K is multiferroic and ferroelectricity is induced by an inversion symmetry breaking spiral Mn-spin order and strong spin-lattice interactions. Furthermore, the substitution of Ni2+ (spin 1) for Mn2+ (spin 5/2) in MnWO4 and its effects on the magnetic and multiferroic phases are studied. The ferroelectric phase is stabilized for low Ni content (up to 10%). Upon further Ni doping, the polarization in the ferroelectric phase is quickly suppressed while a collinear and commensurate magnetic phase, characteristic of the magnetic structure in NiWO4, appears first at higher temperature, gradually extends to lower temperature, and becomes the ground state above 30% doping. Between 10% and 30%, the multiferroic phase coexists with the collinear commensurate phase. In this concentration region, the spin spiral plane is close to the a-b plane which explains the drop of the ferroelectric polarization. Finally, the phase diagram of Mn1-xNixWO4 is derived by a combination of magnetic susceptibility, specific heat, electric polarization, and neutron scattering measurements.},

  doi          = {10.1080/10584587.2015.1102565},

  journal      = {Integrated Ferroelectrics},

  number       = 1,

  volume       = 166,

  place        = {United States},

  year         = {Tue Dec 15 00:00:00 EST 2015},

  month        = {Tue Dec 15 00:00:00 EST 2015}

}

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https://doi.org/10.1080/10584587.2015.1102565

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Works referencing / citing this record:

The Ir ⁴⁺ substitution dependence of electric polarization as a probe of magnetic phase stability in multiferroic MnWO ₄
journal, August 2019

Wang, H. W.; Zheng, S. H.; Zhou, G. Z.
Journal of Applied Physics, Vol. 126, Issue 6
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Title: Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO 4

Abstract

Citation Formats

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Ferroelectricity in the cycloidal spiral magnetic phase of Mn W O 4 journal, November 2006

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Magnetic phase transitions of MnWO 4 studied by the use of neutron diffraction journal, September 1993

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Ising model in a transverse field. I. Basic theory journal, August 1973

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Title: Effects of Nickel Doping on the Multiferroic and Magnetic Phases of MnWO ₄

Revival of the magnetoelectric effect
journal, April 2005

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005

Multiferroics—toward strong coupling between magnetization and polarization in a solid
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Giant magnetoelectric effect in multiferroic ${HoMnO}_{3}$ with a high ferroelectric transition temperature
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Magnetic phase control by an electric field
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Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites
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Ferroelectricity in Spiral Magnets
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Magnetic structure and ferroelectric polarization of ${MnWO}_{4}$ investigated by density functional calculations and classical spin analysis
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Suppression and recovery of the ferroelectric phase in multiferroic $Mn W O_{4}$
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Stabilization of the elliptical spiral phase and the spin-flop transition in multiferroic ${Mn}_{1 - x} {Co}_{x} {WO}_{4}$
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Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
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journal, August 1973

Magnetic properties of a number of divalent transition metal tungstates, molybdates and titanates
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Verfeinerung der momentrichtungen in den magnetischen strukturen von NiWO4 und CoWO4
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Magnetic-field-induced spontaneous polarization reversal in multiferroic ${Mn}_{0.85}$ ${Co}_{0.15}$ ${WO}_{4}$
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