Orbital glass state of the nearly metallic spinel cobalt vanadate

Koborinai, R.; Dissanayake, Sachith E.; Reehuis, M.; Matsuda, Masaaki; Kajita, T.; Kuwahara, H.; Lee, Seung -Hun; Katsufuji, T.

doi:10.1103/PhysRevLett.116.037201

Title: Orbital glass state of the nearly metallic spinel cobalt vanadate

Abstract

Strain, magnetization, dielectric relaxation, and unpolarized and polarized neutron diffraction measurements were performed to study the magnetic and structural properties of spinel Co_1–xV_2+xO₄. The strain measurement indicates that, upon cooling, ΔL/L in the order of ~10^–4 starts increasing below T_C, becomes maximum at T_max, and then decreases and changes its sign at T*. Neutron measurements indicate that a collinear ferrimagnetic order develops below T_C and upon further cooling noncollinear ferrimagnetic ordering occurs below T_max. At low temperatures, the dielectric constant exhibits a frequency dependence, indicating slow dynamics. Lastly, these results indicate the existence of an orbital glassy state at low temperatures in this nearly metallic frustrated magnet.

Authors:

Koborinai, R. ^[1]; Dissanayake, Sachith E. ^[2]; Reehuis, M. ^[3]; Matsuda, Masaaki ^[4]; Kajita, T. ^[1]; Kuwahara, H. ^[5]; Lee, Seung -Hun ^[2]; Katsufuji, T. ^[1]

Waseda Univ., Tokyo (Japan)
Univ. of Virginia, Charlottesville, VA (United States)
Helmholtz-Zentrum fur Materialien und Energie, Berlin (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sophia Univ., Tokyo (Japan)

Publication Date:: Tue Jan 19 00:00:00 EST 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1265995

Alternate Identifier(s):: OSTI ID: 1235611

Grant/Contract Number:: AC05-00OR22725; FG02-07ER46384

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Letters

Additional Journal Information:: Journal Volume: 116; Journal Issue: 3; Journal ID: ISSN 0031-9007

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Koborinai, R., Dissanayake, Sachith E., Reehuis, M., Matsuda, Masaaki, Kajita, T., Kuwahara, H., Lee, Seung -Hun, and Katsufuji, T. Orbital glass state of the nearly metallic spinel cobalt vanadate.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevLett.116.037201.

Copy to clipboard


                    Koborinai, R., Dissanayake, Sachith E., Reehuis, M., Matsuda, Masaaki, Kajita, T., Kuwahara, H., Lee, Seung -Hun, & Katsufuji, T. Orbital glass state of the nearly metallic spinel cobalt vanadate.  United States.  https://doi.org/10.1103/PhysRevLett.116.037201

Copy to clipboard


                    Koborinai, R., Dissanayake, Sachith E., Reehuis, M., Matsuda, Masaaki, Kajita, T., Kuwahara, H., Lee, Seung -Hun, and Katsufuji, T. Tue .  
"Orbital glass state of the nearly metallic spinel cobalt vanadate".  United States.  https://doi.org/10.1103/PhysRevLett.116.037201.  https://www.osti.gov/servlets/purl/1265995.

Copy to clipboard


                    
@article{osti_1265995,

  title        = {Orbital glass state of the nearly metallic spinel cobalt vanadate},

  author       = {Koborinai, R. and Dissanayake, Sachith E. and Reehuis, M. and Matsuda, Masaaki and Kajita, T. and Kuwahara, H. and Lee, Seung -Hun and Katsufuji, T.},

  abstractNote = {Strain, magnetization, dielectric relaxation, and unpolarized and polarized neutron diffraction measurements were performed to study the magnetic and structural properties of spinel Co1–xV2+xO4. The strain measurement indicates that, upon cooling, ΔL/L in the order of ~10–4 starts increasing below TC, becomes maximum at Tmax, and then decreases and changes its sign at T*. Neutron measurements indicate that a collinear ferrimagnetic order develops below TC and upon further cooling noncollinear ferrimagnetic ordering occurs below Tmax. At low temperatures, the dielectric constant exhibits a frequency dependence, indicating slow dynamics. Lastly, these results indicate the existence of an orbital glassy state at low temperatures in this nearly metallic frustrated magnet.},

  doi          = {10.1103/PhysRevLett.116.037201},

  journal      = {Physical Review Letters},

  number       = 3,

  volume       = 116,

  place        = {United States},

  year         = {Tue Jan 19 00:00:00 EST 2016},

  month        = {Tue Jan 19 00:00:00 EST 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevLett.116.037201

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 24 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Magnetic and Structural Transitions in (Li _x Zn _{1 - x} )V ₂ O ₄ with the Spinel Structure
journal, March 1997

Ueda, Yutaka; Fujiwara, Naoki; Yasuoka, Hiroshi
Journal of the Physical Society of Japan, Vol. 66, Issue 3
DOI: 10.1143/JPSJ.66.778

Orbital and Spin Chains in ${Z n V}_{2} O_{4}$
journal, October 2004

Lee, S. -H.; Louca, D.; Ueda, H.
Physical Review Letters, Vol. 93, Issue 15
DOI: 10.1103/PhysRevLett.93.156407

Local order and frustration in the geometrically frustrated spinels ${Cd}_{1 - x} {Zn}_{x} V_{2} O_{4}$
journal, July 2006

Zhang, Z.; Louca, Despina; Visinoiu, A.
Physical Review B, Vol. 74, Issue 1
DOI: 10.1103/PhysRevB.74.014108

Orbital Ordering and Magnetic Field Effect in ${MnV}_{2} O_{4}$
journal, March 2007

Suzuki, T.; Katsumura, M.; Taniguchi, K.
Physical Review Letters, Vol. 98, Issue 12
DOI: 10.1103/PhysRevLett.98.127203

Spin ordering and orbital ordering transitions in $Mn V_{2} O_{4}$
journal, November 2007

Zhou, H. D.; Lu, J.; Wiebe, C. R.
Physical Review B, Vol. 76, Issue 17
DOI: 10.1103/PhysRevB.76.174403

Magnetic excitations and orbital physics in the ferrimagnetic spinels $Mn B_{2} O_{4}$ $(B = Mn, V)$
journal, February 2008

Chung, J. -H.; Kim, J. -H.; Lee, S. -H.
Physical Review B, Vol. 77, Issue 5
DOI: 10.1103/PhysRevB.77.054412

Magnetic and Orbital Ordering in the Spinel ${MnV}_{2} O_{4}$
journal, February 2008

Garlea, V. O.; Jin, R.; Mandrus, D.
Physical Review Letters, Vol. 100, Issue 6
DOI: 10.1103/PhysRevLett.100.066404

Phase diagram of the spinel oxide ${MnV}_{2} O_{4}$
journal, July 2008

Hardy, Vincent; Bréard, Yohann; Martin, Christine
Physical Review B, Vol. 78, Issue 2
DOI: 10.1103/PhysRevB.78.024406

Two inequivalent sublattices and orbital ordering in ${MnV}_{2} O_{4}$ studied by ${}^{51}V$ NMR
journal, October 2009

Baek, S. -H.; Curro, N. J.; Choi, K. -Y.
Physical Review B, Vol. 80, Issue 14
DOI: 10.1103/PhysRevB.80.140406

Proposed Orbital Ordering in ${MnV}_{2} O_{4}$ from First-Principles Calculations
journal, May 2009

Sarkar, S.; Maitra, T.; Valentí, Roser
Physical Review Letters, Vol. 102, Issue 21
DOI: 10.1103/PhysRevLett.102.216405

Quantum $120 °$ model on pyrochlore lattice: Orbital ordering in ${MnV}_{2} O_{4}$
journal, March 2010

Chern, Gia-Wei; Perkins, Natalia; Hao, Zhihao
Physical Review B, Vol. 81, Issue 12
DOI: 10.1103/PhysRevB.81.125127

Orbital-spin-coupled fluctuations in spinel vanadate MnV $_{2}$ O $_{4}$
journal, February 2013

Nii, Yoichi; Abe, Nobuyuki; Arima, Taka-hisa
Physical Review B, Vol. 87, Issue 8
DOI: 10.1103/PhysRevB.87.085111

Magnon spectra and strong spin-lattice coupling in magnetically frustrated $Mn B_{2} O_{4}$ ( $B = Mn$ ,V): Inelastic light-scattering studies
journal, April 2014

Gleason, S. L.; Byrum, T.; Gim, Y.
Physical Review B, Vol. 89, Issue 13
DOI: 10.1103/PhysRevB.89.134402

Structural and Magnetic Properties of Spinel FeV ₂ O ₄ with Two Ions Having Orbital Degrees of Freedom
journal, May 2008

Katsufuji, Takuro; Suzuki, Takehito; Takei, Haruki
Journal of the Physical Society of Japan, Vol. 77, Issue 5
DOI: 10.1143/JPSJ.77.053708

Orbital ordering in FeV $_{2}$ O $_{4}$ : Spinel with two orbitally active sites
journal, December 2011

Sarkar, Soumyajit; Saha-Dasgupta, T.
Physical Review B, Vol. 84, Issue 23
DOI: 10.1103/PhysRevB.84.235112

Magnetic order and ice rules in the multiferroic spinel FeV $_{2}$ O $_{4}$
journal, August 2012

MacDougall, G. J.; Garlea, V. O.; Aczel, A. A.
Physical Review B, Vol. 86, Issue 6
DOI: 10.1103/PhysRevB.86.060414

Ordering process and ferroelectricity in a spinel derived from FeV $_{2}$ O $_{4}$
journal, February 2012

Zhang, Q.; Singh, K.; Guillou, F.
Physical Review B, Vol. 85, Issue 5
DOI: 10.1103/PhysRevB.85.054405

Orbital structures in spinel vanadates $A$ V $_{2}$ O $_{4}$ ( $A$ $=$ Fe, Mn)
journal, September 2012

Nii, Y.; Sagayama, H.; Arima, T.
Physical Review B, Vol. 86, Issue 12
DOI: 10.1103/PhysRevB.86.125142

Valence states and spin structure of spinel FeV $_{2}$ O $_{4}$ with different orbital degrees of freedom
journal, April 2012

Kang, J. -S.; Hwang, Jihoon; Kim, D. H.
Physical Review B, Vol. 85, Issue 16
DOI: 10.1103/PhysRevB.85.165136

Anomalous magnetization behaviour in a single crystal of vanadium spinel FeV ₂ O ₄
journal, September 2013

Kawaguchi, S.; Ishibashi, H.; Nishihara, S.
Journal of Physics: Condensed Matter, Vol. 25, Issue 41
DOI: 10.1088/0953-8984/25/41/416005

Observation of the large magnetocaloric effect and suppression of orbital entropy change in Fe-doped MnV ₂ O ₄
journal, January 2014

Huang, Z. H.; Luo, X.; Hu, L.
Journal of Applied Physics, Vol. 115, Issue 3
DOI: 10.1063/1.4861630

Evolution of magnetic and structural transitions and enhancement of magnetocaloric effect in ${Fe}_{1 - x} {Mn}_{x} V_{2} O_{4}$
journal, March 2014

Choudhury, D.; Suzuki, T.; Okuyama, D.
Physical Review B, Vol. 89, Issue 10
DOI: 10.1103/PhysRevB.89.104427

$Co [V_{2}] O_{4}$ : A Spinel Approaching the Itinerant Electron Limit
journal, February 2011

Kismarahardja, A.; Brooks, J. S.; Kiswandhi, A.
Physical Review Letters, Vol. 106, Issue 5
DOI: 10.1103/PhysRevLett.106.056602

Chemical pressure effects on structural, magnetic, and transport properties of Mn $_{1 - x}$ Co $_{x}$ V $_{2}$ O $_{4}$
journal, November 2011

Kiswandhi, A.; Brooks, J. S.; Lu, J.
Physical Review B, Vol. 84, Issue 20
DOI: 10.1103/PhysRevB.84.205138

Magnetic, structural, and thermal properties of CoV ₂ O ₄
journal, January 2012

Huang, Yuanjie; Yang, Zhaorong; Zhang, Yuheng
Journal of Physics: Condensed Matter, Vol. 24, Issue 5
DOI: 10.1088/0953-8984/24/5/056003

The nature of itineracy in CoV ₂ O ₄ : a first-principles study
journal, January 2014

Kaur, Ramandeep; Maitra, Tulika; Nautiyal, Tashi
Journal of Physics: Condensed Matter, Vol. 26, Issue 4
DOI: 10.1088/0953-8984/26/4/045505

Dielectric properties of single crystal spinels in the series FeV $_{2}$ O $_{4}$ , MnV $_{2}$ O $_{4}$ , and CoV $_{2}$ O $_{4}$ in high magnetic fields
journal, February 2013

Kismarahardja, A.; Brooks, J. S.; Zhou, H. D.
Physical Review B, Vol. 87, Issue 5
DOI: 10.1103/PhysRevB.87.054432

Strong competition between orbital ordering and itinerancy in a frustrated spinel vanadate
journal, January 2015

Ma, J.; Lee, J. H.; Hahn, S. E.
Physical Review B, Vol. 91, Issue 2
DOI: 10.1103/PhysRevB.91.020407

Orbital Freezing and Orbital Glass State in $F e {C r}_{2} S_{4}$
journal, January 2005

Fichtl, R.; Tsurkan, V.; Lunkenheimer, P.
Physical Review Letters, Vol. 94, Issue 2
DOI: 10.1103/PhysRevLett.94.027601

Works referencing / citing this record:

Spin-Orbital Correlated Dynamics in the Spinel-Type Vanadium Oxide ${MnV}_{2} O_{4}$
journal, July 2017

Matsuura, Keisuke; Sagayama, Hajime; Uehara, Amane
Physical Review Letters, Vol. 119, Issue 1
DOI: 10.1103/physrevlett.119.017201

A variety of elastic anomalies in orbital-active nearly-itinerant cobalt vanadate spinel
text, January 2017

Watanabe, Tadataka; Yamada, Shogo; Koborinai, Rui
arXiv
DOI: 10.48550/arxiv.1704.07537

Similar Records in DOE PAGES and OSTI.GOV collections:

Polyhedral Distortions and Unusual Magnetic Order in Spinel FeMn₂O₄

Journal Article Zhang, Qiang ; Tian, Wei ; Nepal, Roshan ; ... - Chemistry of Materials

Spinel compounds AB₂X₄consist of both tetrahedral (AX₄) and octahedral (BX₆₎ environments with the former forming a diamond lattice and the latter a geometrically frustrated pyrochlore lattice. Exploring the fascinating physical properties and their correlations with structural features is critical in understanding these materials. FeMn₂O₄ has been reported to exhibit one structural transition and two successive magnetic transitions. In this work, we report the polyhedral distortions and their correlations to the structural and two magnetic transitions in FeMn₂O₄ by employing the high-resolution neutron powder diffraction. The cation distribution is found to be (more »« less
https://doi.org/10.1021/acs.chemmater.2c03182

Full Text Available
Spin canting and orbital order in spinel vanadate thin films

Journal Article Thompson, Christie ; Reig-i-Plessis, Dalmau ; Kish, Lasar ; ... - Physical Review Materials

Here, we report on the epitaxial film growth and characterization of CoV₂O₄, a near-itinerant spinel vanadate, grown on (001) SrTiO₃. The symmetry lowering of the unit cell from cubic in the bulk to orthorhombic in the films results in dramatic differences in the magnetic anisotropy compared to bulk, as determined from structural and magnetic characterization. Bulk cubic CoV₂O₄ has been found to defy predictions by showing orbital degeneracy seemingly lasting to very low temperatures, with only small anomalies in magnetization and neutron experiments signaling a possible spin/orbital glass transition at T = 90 K. In epitaxial thin films presented inmore »« less
Cited by 5
https://doi.org/10.1103/PhysRevMaterials.2.104411

Full Text Available
Spin reorientation in multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} with Mössbauer spectroscopy

Journal Article Myoung, Bo Ra ; Kim, Chul Sung, E-mail: cskim@kookmin.ac.kr - Journal of Applied Physics

We studied the magnetic properties of multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4}, especially focusing on the spin-ordering, spin-reorientation, and charge re-distribution effects. From the Rietveld refinement analysis, the crystal structure was identified to be a normal cubic spinel of Fd-3m. Based on the temperature-dependent measurements of the magnetization and magnetic hyperfine field (H{sub hf}), Curie temperature (T{sub C}) of Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} was determined to be around 86 K where H{sub hf} ≅ 0. From the change of slope in the M-T curve, the conical-spiral magnetic ordering temperature was determined to be 20 K, which coincides with H{sub hf} measurement. Also,more »« less
https://doi.org/10.1063/1.4918968
Magnetic and orbital ordering in the spinel MnV{sub 2}O{sub 4}.

Journal Article Garlea, V O ; Jin, R ; Mandrus, D ; ... - Phys. Rev. Lett.

Neutron inelastic scattering and diffraction techniques have been used to study the MnV{sub 2}O{sub 4} spinel system. Our measurements show the existence of two transitions to long-range ordered ferrimagnetic states, the first collinear and the second noncollinear. The lower temperature transition, characterized by development of antiferromagnetic components in the basal plane, is accompanied by a tetragonal distortion and the appearance of a gap in the magnetic excitation spectrum. The low-temperature noncollinear magnetic structure has been definitively resolved. Taken together, the crystal and magnetic structures indicate a staggered ordering of the V d orbitals. The anisotropy gap is a consequence ofmore » unquenched V orbital angular momentum.« less
https://doi.org/10.1103/PhysRevLett.100.066404
Magnetization reversal driven by electron localization-delocalization crossover in the inverse spinel Co 2 VO 4

Journal Article Kademane, Abhijit Bhat ; Bhandari, Churna ; Paudyal, Durga ; ... - Physical Review. B

Neutron diffraction, magnetization, and muon spin relaxation measurements, supplemented by density functional theory (DFT) calculations are employed to unravel temperature-driven magnetization reversal in inverse spinel Co₂VO₄. All measurements show a second-order magnetic phase transition at T_C = 168 K to a collinear ferrimagnetic phase. Neutron diffraction measurements reveal two antiparallel ferromagnetic (FM) sublattices, belonging to magnetic ions on two distinct crystal lattice sites, where the relative balance between the two sublattices determine the net FM moment in the unit cell. As the evolution of the ordered moment with temperature differs between the two sublattices, the net magnetic moment reaches amore »« less
https://doi.org/10.1103/physrevb.105.094408

Full Text Available

Similar Records

Title: Orbital glass state of the nearly metallic spinel cobalt vanadate

Abstract

Citation Formats

Magnetic and Structural Transitions in (Li x Zn 1 - x )V 2 O 4 with the Spinel Structure journal, March 1997

Orbital and Spin Chains in Z n V 2 O 4 journal, October 2004

Local order and frustration in the geometrically frustrated spinels Cd 1 − x Zn x V 2 O 4 journal, July 2006

Orbital Ordering and Magnetic Field Effect in MnV 2 O 4 journal, March 2007

Spin ordering and orbital ordering transitions in Mn V 2 O 4 journal, November 2007

Magnetic excitations and orbital physics in the ferrimagnetic spinels Mn B 2 O 4 ( B = Mn , V ) journal, February 2008

Magnetic and Orbital Ordering in the Spinel MnV 2 O 4 journal, February 2008

Phase diagram of the spinel oxide MnV 2 O 4 journal, July 2008

Two inequivalent sublattices and orbital ordering in MnV 2 O 4 studied by V 51 NMR journal, October 2009

Proposed Orbital Ordering in MnV 2 O 4 from First-Principles Calculations journal, May 2009

Quantum 120 ° model on pyrochlore lattice: Orbital ordering in MnV 2 O 4 journal, March 2010

Orbital-spin-coupled fluctuations in spinel vanadate MnV 2 O 4 journal, February 2013

Magnon spectra and strong spin-lattice coupling in magnetically frustrated Mn B 2 O 4 ( B = Mn ,V): Inelastic light-scattering studies journal, April 2014

Structural and Magnetic Properties of Spinel FeV 2 O 4 with Two Ions Having Orbital Degrees of Freedom journal, May 2008

Orbital ordering in FeV 2 O 4 : Spinel with two orbitally active sites journal, December 2011

Magnetic order and ice rules in the multiferroic spinel FeV 2 O 4 journal, August 2012

Ordering process and ferroelectricity in a spinel derived from FeV 2 O 4 journal, February 2012

Orbital structures in spinel vanadates A V 2 O 4 ( A = Fe, Mn) journal, September 2012

Valence states and spin structure of spinel FeV 2 O 4 with different orbital degrees of freedom journal, April 2012

Anomalous magnetization behaviour in a single crystal of vanadium spinel FeV 2 O 4 journal, September 2013

Observation of the large magnetocaloric effect and suppression of orbital entropy change in Fe-doped MnV 2 O 4 journal, January 2014

Evolution of magnetic and structural transitions and enhancement of magnetocaloric effect in Fe 1 − x Mn x V 2 O 4 journal, March 2014

Co [ V 2 ] O 4 : A Spinel Approaching the Itinerant Electron Limit journal, February 2011

Chemical pressure effects on structural, magnetic, and transport properties of Mn 1 − x Co x V 2 O 4 journal, November 2011

Magnetic, structural, and thermal properties of CoV 2 O 4 journal, January 2012

The nature of itineracy in CoV 2 O 4 : a first-principles study journal, January 2014

Dielectric properties of single crystal spinels in the series FeV 2 O 4 , MnV 2 O 4 , and CoV 2 O 4 in high magnetic fields journal, February 2013

Strong competition between orbital ordering and itinerancy in a frustrated spinel vanadate journal, January 2015

Orbital Freezing and Orbital Glass State in F e C r 2 S 4 journal, January 2005

Spin-Orbital Correlated Dynamics in the Spinel-Type Vanadium Oxide MnV 2 O 4 journal, July 2017

A variety of elastic anomalies in orbital-active nearly-itinerant cobalt vanadate spinel text, January 2017

Magnetic and Structural Transitions in (Li _x Zn _{1 - x} )V ₂ O ₄ with the Spinel Structure
journal, March 1997

Orbital and Spin Chains in ${Z n V}_{2} O_{4}$
journal, October 2004

Local order and frustration in the geometrically frustrated spinels ${Cd}_{1 - x} {Zn}_{x} V_{2} O_{4}$
journal, July 2006

Orbital Ordering and Magnetic Field Effect in ${MnV}_{2} O_{4}$
journal, March 2007

Spin ordering and orbital ordering transitions in $Mn V_{2} O_{4}$
journal, November 2007

Magnetic excitations and orbital physics in the ferrimagnetic spinels $Mn B_{2} O_{4}$ $(B = Mn, V)$
journal, February 2008

Magnetic and Orbital Ordering in the Spinel ${MnV}_{2} O_{4}$
journal, February 2008

Phase diagram of the spinel oxide ${MnV}_{2} O_{4}$
journal, July 2008

Two inequivalent sublattices and orbital ordering in ${MnV}_{2} O_{4}$ studied by ${}^{51}V$ NMR
journal, October 2009

Proposed Orbital Ordering in ${MnV}_{2} O_{4}$ from First-Principles Calculations
journal, May 2009

Quantum $120 °$ model on pyrochlore lattice: Orbital ordering in ${MnV}_{2} O_{4}$
journal, March 2010

Orbital-spin-coupled fluctuations in spinel vanadate MnV $_{2}$ O $_{4}$
journal, February 2013

Magnon spectra and strong spin-lattice coupling in magnetically frustrated $Mn B_{2} O_{4}$ ( $B = Mn$ ,V): Inelastic light-scattering studies
journal, April 2014

Structural and Magnetic Properties of Spinel FeV ₂ O ₄ with Two Ions Having Orbital Degrees of Freedom
journal, May 2008

Orbital ordering in FeV $_{2}$ O $_{4}$ : Spinel with two orbitally active sites
journal, December 2011

Magnetic order and ice rules in the multiferroic spinel FeV $_{2}$ O $_{4}$
journal, August 2012

Ordering process and ferroelectricity in a spinel derived from FeV $_{2}$ O $_{4}$
journal, February 2012

Orbital structures in spinel vanadates $A$ V $_{2}$ O $_{4}$ ( $A$ $=$ Fe, Mn)
journal, September 2012

Valence states and spin structure of spinel FeV $_{2}$ O $_{4}$ with different orbital degrees of freedom
journal, April 2012

Anomalous magnetization behaviour in a single crystal of vanadium spinel FeV ₂ O ₄
journal, September 2013

Observation of the large magnetocaloric effect and suppression of orbital entropy change in Fe-doped MnV ₂ O ₄
journal, January 2014

Evolution of magnetic and structural transitions and enhancement of magnetocaloric effect in ${Fe}_{1 - x} {Mn}_{x} V_{2} O_{4}$
journal, March 2014

$Co [V_{2}] O_{4}$ : A Spinel Approaching the Itinerant Electron Limit
journal, February 2011

Chemical pressure effects on structural, magnetic, and transport properties of Mn $_{1 - x}$ Co $_{x}$ V $_{2}$ O $_{4}$
journal, November 2011

Magnetic, structural, and thermal properties of CoV ₂ O ₄
journal, January 2012

The nature of itineracy in CoV ₂ O ₄ : a first-principles study
journal, January 2014

Dielectric properties of single crystal spinels in the series FeV $_{2}$ O $_{4}$ , MnV $_{2}$ O $_{4}$ , and CoV $_{2}$ O $_{4}$ in high magnetic fields
journal, February 2013

Strong competition between orbital ordering and itinerancy in a frustrated spinel vanadate
journal, January 2015

Orbital Freezing and Orbital Glass State in $F e {C r}_{2} S_{4}$
journal, January 2005

Spin-Orbital Correlated Dynamics in the Spinel-Type Vanadium Oxide ${MnV}_{2} O_{4}$
journal, July 2017

A variety of elastic anomalies in orbital-active nearly-itinerant cobalt vanadate spinel
text, January 2017