Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Multilayer graphane synthesized under high hydrogen pressure

Abstract

A new hydrocarbon – hydrographite – with the composition close to CH is shown to form from graphite and gaseous hydrogen at pressures above 2 GPa and temperatures from 450 to 700 °C. Hydrographite is a black solid thermally stable under ambient conditions. When heated in vacuum, it decomposes into graphite and molecular hydrogen at temperatures from 500 to 650 °C. Powder X-ray diffraction characterizes hydrographite as a multilayer “graphane II” phase predicted by ab initio calculations [Wen X-D et al. PNAS 2011; 108:6833] and consisting of graphane sheets in the chair conformation stacked along the hexagonal c axis in the -ABAB- sequence. The crystal structure of the synthesized phase belongs to the P63mc space group. Moreover, the unit cell parameters are a = 2.53(1) Å and c = 9.54(1) Å and therefore exceed the corresponding parameters of graphite by 2.4(2)% and 42.0(3)%. Stretching vibrations of C–H groups on the surface of the hydrographite particles are examined by infrared spectroscopy.

Authors:
 [1];  [1];  [1];  [2];  [1];  [1];  [3];  [1];  [4];  [1];  [1];  [5]
+ Show Author Affiliations
  1. Inst. of Solid State Physics, Moscow District (Russia)
  2. Moscow State Univ., Moscow (Russian Federation)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Inst. of Problems of Chemical Physics RAS, Moscow District (Russia)
  5. National Univ. of Science and Technology, Moscow (Russia)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1265908
Alternate Identifier(s):
OSTI ID: 1266404
Grant/Contract Number:  
AC05-00OR22725; 11-02-00401
Resource Type:
Accepted Manuscript
Journal Name:
Carbon
Additional Journal Information:
Journal Volume: 100; Journal Issue: C; Journal ID: ISSN 0008-6223
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Antonov, V. E., Bashkin, I. O., Bazhenov, A. V., Bulychev, B. M., Fedotov, V. K., Fursova, T. N., Kolesnikov, A. I., Kulakov, V. I., Lukashev, R. V., Matveev, D. V., Sakharov, M. K., and Shulga, Y. M. Multilayer graphane synthesized under high hydrogen pressure. United States: N. p., 2015. Web. doi:10.1016/j.carbon.2015.12.051.
Copy to clipboard
Antonov, V. E., Bashkin, I. O., Bazhenov, A. V., Bulychev, B. M., Fedotov, V. K., Fursova, T. N., Kolesnikov, A. I., Kulakov, V. I., Lukashev, R. V., Matveev, D. V., Sakharov, M. K., & Shulga, Y. M. Multilayer graphane synthesized under high hydrogen pressure. United States. https://doi.org/10.1016/j.carbon.2015.12.051
Copy to clipboard
Antonov, V. E., Bashkin, I. O., Bazhenov, A. V., Bulychev, B. M., Fedotov, V. K., Fursova, T. N., Kolesnikov, A. I., Kulakov, V. I., Lukashev, R. V., Matveev, D. V., Sakharov, M. K., and Shulga, Y. M. Sat . "Multilayer graphane synthesized under high hydrogen pressure". United States. https://doi.org/10.1016/j.carbon.2015.12.051. https://www.osti.gov/servlets/purl/1265908.
Copy to clipboard
@article{osti_1265908,
title = {Multilayer graphane synthesized under high hydrogen pressure},
author = {Antonov, V. E. and Bashkin, I. O. and Bazhenov, A. V. and Bulychev, B. M. and Fedotov, V. K. and Fursova, T. N. and Kolesnikov, A. I. and Kulakov, V. I. and Lukashev, R. V. and Matveev, D. V. and Sakharov, M. K. and Shulga, Y. M.},
abstractNote = {A new hydrocarbon – hydrographite – with the composition close to CH is shown to form from graphite and gaseous hydrogen at pressures above 2 GPa and temperatures from 450 to 700 °C. Hydrographite is a black solid thermally stable under ambient conditions. When heated in vacuum, it decomposes into graphite and molecular hydrogen at temperatures from 500 to 650 °C. Powder X-ray diffraction characterizes hydrographite as a multilayer “graphane II” phase predicted by ab initio calculations [Wen X-D et al. PNAS 2011; 108:6833] and consisting of graphane sheets in the chair conformation stacked along the hexagonal c axis in the -ABAB- sequence. The crystal structure of the synthesized phase belongs to the P63mc space group. Moreover, the unit cell parameters are a = 2.53(1) Å and c = 9.54(1) Å and therefore exceed the corresponding parameters of graphite by 2.4(2)% and 42.0(3)%. Stretching vibrations of C–H groups on the surface of the hydrographite particles are examined by infrared spectroscopy.},
doi = {10.1016/j.carbon.2015.12.051},
journal = {Carbon},
number = C,
volume = 100,
place = {United States},
year = {Sat Dec 19 00:00:00 EST 2015},
month = {Sat Dec 19 00:00:00 EST 2015}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.carbon.2015.12.051
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 19 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Generation of methane in the Earth's mantle: In situ high pressure-temperature measurements of carbonate reduction
journal, September 2004

  • Scott, H. P.; Hemley, R. J.; Mao, H. -k.
  • Proceedings of the National Academy of Sciences, Vol. 101, Issue 39
  • DOI: 10.1073/pnas.0405930101

Synthesis of complex hydrocarbon systems at temperatures and pressures corresponding to the Earth’s upper mantle conditions
journal, July 2010

  • Kutcherov, V. G.; Kolesnikov, A. Yu.; Dyuzheva, T. I.
  • Doklady Physical Chemistry, Vol. 433, Issue 1
  • DOI: 10.1134/S0012501610070079

Thermally stable hydrogen compounds obtained under high pressure on the basis of carbon nanotubes and nanofibers
journal, March 2004

  • Bashkin, I. O.; Antonov, V. E.; Bazhenov, A. V.
  • Journal of Experimental and Theoretical Physics Letters, Vol. 79, Issue 5
  • DOI: 10.1134/1.1753421

Hydrogen storage using carbon adsorbents: past, present and future
journal, February 2001

  • Dillon, A. C.; Heben, M. J.
  • Applied Physics A Materials Science & Processing, Vol. 72, Issue 2
  • DOI: 10.1007/s003390100788

Hydrogen in the mechanically prepared nanostructured graphite
journal, November 1999

  • Orimo, S.; Majer, G.; Fukunaga, T.
  • Applied Physics Letters, Vol. 75, Issue 20
  • DOI: 10.1063/1.125241

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004

The rise of graphene
journal, March 2007

  • Geim, A. K.; Novoselov, K. S.
  • Nature Materials, Vol. 6, Issue 3, p. 183-191
  • DOI: 10.1038/nmat1849

Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane
journal, January 2009

Structure and Layer Interaction in Carbon Monofluoride and Graphane: A Comparative Computational Study
journal, April 2010

  • Artyukhov, Vasilii I.; Chernozatonskii, Leonid A.
  • The Journal of Physical Chemistry A, Vol. 114, Issue 16
  • DOI: 10.1021/jp1003566

Structure and energetics of hydrogen chemisorbed on a single graphene layer to produce graphane
journal, August 2011

Chair and Twist-Boat Membranes in Hydrogenated Graphene
journal, November 2009

  • Samarakoon, Duminda K.; Wang, Xiao-Qian
  • ACS Nano, Vol. 3, Issue 12
  • DOI: 10.1021/nn901317d

Graphane sheets and crystals under pressure
journal, April 2011

  • Wen, X. -D.; Hand, L.; Labet, V.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 17
  • DOI: 10.1073/pnas.1103145108

Magnetic ordering in hydrofullerite C60H24
journal, January 2002

Toroid type high-pressure device: history and prospects
journal, September 2004

Neutron spectroscopy of H impurities in PdD: Covibrations of the H and D atoms
journal, October 2009

Neutron spectroscopy study of single-walled carbon nanotubes hydrogenated under high pressure
journal, October 2007

Hydrogen desorption property of mechanically prepared nanostructured graphite
journal, August 2001

  • Orimo, S.; Matsushima, T.; Fujii, H.
  • Journal of Applied Physics, Vol. 90, Issue 3
  • DOI: 10.1063/1.1385362

Structural change of graphite subjected to mechanical milling
journal, July 1998

Nanoporous carbon produced by ball milling
journal, May 1999

  • Chen, Ying; Fitz Gerald, John; Chadderton, Lewis T.
  • Applied Physics Letters, Vol. 74, Issue 19
  • DOI: 10.1063/1.124012

Infrared spectra of ground graphite
journal, April 1971

  • Friedel, Robert A.; Carlson, Gerald L.
  • The Journal of Physical Chemistry, Vol. 75, Issue 8
  • DOI: 10.1021/j100678a021

Bonding in hydrogenated hard carbon studied by optical spectroscopy
journal, October 1983

Vibrational spectra in the CH stretching region and the structure of the polymethylene chain
journal, January 1978

  • Snyder, R. G.; Hsu, S. L.; Krimm, S.
  • Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 34, Issue 4
  • DOI: 10.1016/0584-8539(78)80167-6
    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Pressure-Induced Diels-Alder Reactions in C 6 H 6 -C 6 F 6 Cocrystal towards Graphane Structure
    journal, January 2019

    Pressure-Induced Diels-Alder Reactions in C 6 H 6 -C 6 F 6 Cocrystal towards Graphane Structure
    journal, January 2019

    • Wang, Yajie; Dong, Xiao; Tang, Xingyu
    • Angewandte Chemie International Edition, Vol. 58, Issue 5
    • DOI: 10.1002/anie.201813120

    Emerging chemical strategies for imprinting magnetism in graphene and related 2D materials for spintronic and biomedical applications
    journal, January 2018

    • Tuček, Jiří; Błoński, Piotr; Ugolotti, Juri
    • Chemical Society Reviews, Vol. 47, Issue 11
    • DOI: 10.1039/c7cs00288b

    Bulk graphanes synthesized from benzene and pyridine
    journal, January 2017

    • Kondrin, M. V.; Nikolaev, N. A.; Boldyrev, K. N.
    • CrystEngComm, Vol. 19, Issue 6
    • DOI: 10.1039/c6ce02327d
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: