Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresis
Abstract
Ni scaffolded mesostructured 3D Fe2O3 electrodes were fabricated by colloidal templating and pulsed electrodeposition. The scaffold provided short pathways for both lithium ions and electrons in the active phase, enabling fast kinetics and thus a high power density. The scaffold also resulted in a reduced voltage hysteresis. The electrode showed a reversible capacity of ~1000 mA h g-1 at 0.2 A g-1 (~0.2 C) for about 20 cycles, and at a current density of 20 A g-1 (~20 C) the deliverable capacity was about 450 mA h g-1. The room temperature voltage hysteresis at 0.1 A g-1 (~0.1 C) was 0.62 V, which is significantly smaller than that normally reported in the literature. And it could be further reduced to 0.42 V when cycling at 45 ºC. Potentiostatic electrochemical impedance spectroscopy (PEIS) studies indicated the small voltage hysteresis may be due to a reduction in the Li2O/Fe interfacial area in the electrode during cycling relative to convention-al conversion systems.
- Authors:
-
- Univ. of Illinois, Urbana-Champaign, IL (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1265755
- Alternate Identifier(s):
- OSTI ID: 1876447
- Grant/Contract Number:
- AC05-00OR22725; FG02-07ER46471
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Volume: 27; Journal Issue: 8; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Electrodes; Hysteresis; Lithium; Materials; Nanoparticles
Citation Formats
Wang, Junjie, Braun, Paul V., Zhou, Hui, and Nanda, Jagjit. Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresis. United States: N. p., 2015.
Web. doi:10.1021/cm504365s.
Wang, Junjie, Braun, Paul V., Zhou, Hui, & Nanda, Jagjit. Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresis. United States. https://doi.org/10.1021/cm504365s
Wang, Junjie, Braun, Paul V., Zhou, Hui, and Nanda, Jagjit. Thu .
"Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresis". United States. https://doi.org/10.1021/cm504365s. https://www.osti.gov/servlets/purl/1265755.
@article{osti_1265755,
title = {Three-Dimensionally Mesostructured Fe2O3 Electrodes with Good Rate Performance and Reduced Voltage Hysteresis},
author = {Wang, Junjie and Braun, Paul V. and Zhou, Hui and Nanda, Jagjit},
abstractNote = {Ni scaffolded mesostructured 3D Fe2O3 electrodes were fabricated by colloidal templating and pulsed electrodeposition. The scaffold provided short pathways for both lithium ions and electrons in the active phase, enabling fast kinetics and thus a high power density. The scaffold also resulted in a reduced voltage hysteresis. The electrode showed a reversible capacity of ~1000 mA h g-1 at 0.2 A g-1 (~0.2 C) for about 20 cycles, and at a current density of 20 A g-1 (~20 C) the deliverable capacity was about 450 mA h g-1. The room temperature voltage hysteresis at 0.1 A g-1 (~0.1 C) was 0.62 V, which is significantly smaller than that normally reported in the literature. And it could be further reduced to 0.42 V when cycling at 45 ºC. Potentiostatic electrochemical impedance spectroscopy (PEIS) studies indicated the small voltage hysteresis may be due to a reduction in the Li2O/Fe interfacial area in the electrode during cycling relative to convention-al conversion systems.},
doi = {10.1021/cm504365s},
journal = {Chemistry of Materials},
number = 8,
volume = 27,
place = {United States},
year = {Thu Mar 26 00:00:00 EDT 2015},
month = {Thu Mar 26 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications
journal, June 2006
- Taberna, P. L.; Mitra, S.; Poizot, P.
- Nature Materials, Vol. 5, Issue 7, p. 567-573
Revisiting LiClO[sub 4] as an Electrolyte for Rechargeable Lithium-Ion Batteries
journal, January 2010
- Marom, Rotem; Haik, Ortal; Aurbach, Doron
- Journal of The Electrochemical Society, Vol. 157, Issue 8
Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013
- Reddy, M. V.; Subba Rao, G. V.; Chowdari, B. V. R.
- Chemical Reviews, Vol. 113, Issue 7
Assembling carbon-coated α-Fe 2 O 3 hollow nanohorns on the CNT backbone for superior lithium storage capability
journal, January 2012
- Wang, Zhiyu; Luan, Deyan; Madhavi, Srinivasan
- Energy Environ. Sci., Vol. 5, Issue 1
A Transmission Electron Microscopy Study of the Reactivity Mechanism of Tailor-Made CuO Particles toward Lithium
journal, January 2001
- Débart, A.; Dupont, L.; Poizot, P.
- Journal of The Electrochemical Society, Vol. 148, Issue 11
High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes
journal, April 2013
- Pikul, James H.; Gang Zhang, Hui; Cho, Jiung
- Nature Communications, Vol. 4, Article No. 1732
α-Fe 2 O 3 Nanostructures: Inorganic Salt-Controlled Synthesis and Their Electrochemical Performance toward Lithium Storage
journal, October 2008
- Wu, Xing-Long; Guo, Yu-Guo; Wan, Li-Jun
- The Journal of Physical Chemistry C, Vol. 112, Issue 43
Electrode architectures for high capacity multivalent conversion compounds: iron (ii and iii) fluoride
journal, January 2014
- Martha, Surendra K.; Nanda, Jagjit; Zhou, Hui
- RSC Advances, Vol. 4, Issue 13
Fabrication of Nano/Micro Hierarchical Fe[sub 2]O[sub 3]∕Ni Micrometer-Wire Structure and Characteristics for High Rate Li Rechargeable Battery
journal, January 2006
- Hosono, Eiji; Fujihara, Shinobu; Honma, Itaru
- Journal of The Electrochemical Society, Vol. 153, Issue 7
First-Principles Investigation of the Li−Fe−F Phase Diagram and Equilibrium and Nonequilibrium Conversion Reactions of Iron Fluorides with Lithium
journal, August 2008
- Doe, Robert E.; Persson, Kristin A.; Meng, Y. Shirley
- Chemistry of Materials, Vol. 20, Issue 16
Multifunctional 3D nanoarchitectures for energy storage and conversion
journal, January 2009
- Rolison, Debra R.; Long, Jeffrey W.; Lytle, Justin C.
- Chemical Society Reviews, Vol. 38, Issue 1, p. 226-252
Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008
- Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
- Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
Hierarchical battery electrodes based on inverted opal structures
journal, August 2002
- Sakamoto, Jeffrey S.; Dunn, Bruce
- Journal of Materials Chemistry, Vol. 12, Issue 10
Synthesis of mixed-conducting carbon coated porous γ-Fe2O3 microparticles and their properties for reversible lithium ion storage
journal, January 2011
- Ma, Yue; Ji, Ge; Lee, Jim Yang
- Journal of Materials Chemistry, Vol. 21, Issue 34
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002
- Laruelle, S.; Grugeon, S.; Poizot, P.
- Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634
The Iron Oxides Strike Back: From Biomedical Applications to Energy Storage Devices and Photoelectrochemical Water Splitting
journal, July 2011
- Tartaj, Pedro; Morales, Maria P.; Gonzalez-Carreño, Teresita
- Advanced Materials, Vol. 23, Issue 44
Graphene-Based Electrodes
journal, August 2012
- Huang, Xiao; Zeng, Zhiyuan; Fan, Zhanxi
- Advanced Materials, Vol. 24, Issue 45
Controlled Formation of Mixed Nanoscale Domains of High Capacity Fe 2 O 3 –FeF 3 Conversion Compounds by Direct Fluorination
journal, February 2015
- Zhou, Hui; Ruther, Rose E.; Adcock, Jamie
- ACS Nano, Vol. 9, Issue 3
Effect of capping and particle size on Raman laser-induced degradation of γ-Fe2O3 nanoparticles
journal, November 2004
- Varadwaj, K. S. K.; Panigrahi, M. K.; Ghose, J.
- Journal of Solid State Chemistry, Vol. 177, Issue 11
?-Fe2O3 Nanotubes in Gas Sensor and Lithium-Ion Battery Applications
journal, March 2005
- Chen, J.; Xu, L.; Li, W.
- Advanced Materials, Vol. 17, Issue 5
Iron-Oxide-Based Advanced Anode Materials for Lithium-Ion Batteries
journal, November 2013
- Zhang, Lei; Wu, Hao Bin; Lou, Xiong Wen David
- Advanced Energy Materials, Vol. 4, Issue 4
Ultrahigh Rate Capabilities of Lithium-Ion Batteries from 3D Ordered Hierarchically Porous Electrodes with Entrapped Active Nanoparticles Configuration
journal, January 2014
- Huang, Xin; Yu, Hong; Chen, Jing
- Advanced Materials, Vol. 26, Issue 8
α-Fe2O3 Nanoflakes as an Anode Material for Li-Ion Batteries
journal, October 2007
- Reddy, M. V.; Yu, T.; Sow, C. H.
- Advanced Functional Materials, Vol. 17, Issue 15
Electrochemical lithiation of tin and tin-based intermetallics and composites
journal, September 1999
- Winter, Martin; Besenhard, Jürgen O.
- Electrochimica Acta, Vol. 45, Issue 1-2, p. 31-50
Effect of Particle Size on Lithium Intercalation into α-Fe[sub 2]O[sub 3]
journal, January 2003
- Larcher, D.; Masquelier, C.; Bonnin, D.
- Journal of The Electrochemical Society, Vol. 150, Issue 1
Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries
journal, April 2011
- Zhu, Xianjun; Zhu, Yanwu; Murali, Shanthi
- ACS Nano, Vol. 5, Issue 4, p. 3333-3338
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
- Poizot, P.; Laruelle, S.; Grugeon, S.
- Nature, Vol. 407, Issue 6803, p. 496-499
Self-Assembled Fe 2 O 3 /Graphene Aerogel with High Lithium Storage Performance
journal, March 2013
- Xiao, Li; Wu, Dongqing; Han, Sheng
- ACS Applied Materials & Interfaces, Vol. 5, Issue 9
Quasiemulsion-Templated Formation of α-Fe 2 O 3 Hollow Spheres with Enhanced Lithium Storage Properties
journal, November 2011
- Wang, Bao; Chen, Jun Song; Wu, Hao Bin
- Journal of the American Chemical Society, Vol. 133, Issue 43
Raman microspectroscopy of some iron oxides and oxyhydroxides
journal, November 1997
- de Faria, D. L. A.; Venâncio Silva, S.; de Oliveira, M. T.
- Journal of Raman Spectroscopy, Vol. 28, Issue 11
Hollow Iron Oxide Nanoparticles for Application in Lithium Ion Batteries
journal, April 2012
- Koo, Bonil; Xiong, Hui; Slater, Michael D.
- Nano Letters, Vol. 12, Issue 5, p. 2429-2435
An Electrochemical Deposition Route for Obtaining α-Fe[sub 2]O[sub 3] Thin Films
journal, January 2006
- Schrebler, Ricardo; Bello, Karen; Vera, Francisca
- Electrochemical and Solid-State Letters, Vol. 9, Issue 7
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010
- Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
- Advanced Materials, Vol. 22, Issue 35
Three-Dimensional Battery Architectures
journal, October 2004
- Long, Jeffrey W.; Dunn, Bruce; Rolison, Debra R.
- Chemical Reviews, Vol. 104, Issue 10, p. 4463-4492
Engineering Empty Space between Si Nanoparticles for Lithium-Ion Battery Anodes
journal, January 2012
- Wu, Hui; Zheng, Guangyuan; Liu, Nian
- Nano Letters, Vol. 12, Issue 2
Combined Surface and Electrochemical Study of the Lithiation/Delithiation Mechanism of the Iron Oxide Thin-Film Anode for Lithium-Ion Batteries
journal, October 2013
- Tian, Bingbing; Światowska, Jolanta; Maurice, Vincent
- The Journal of Physical Chemistry C, Vol. 117, Issue 42
Origin of the Voltage Hysteresis in the CoP Conversion Material for Li-Ion Batteries
journal, January 2013
- Khatib, R.; Dalverny, A. -L.; Saubanère, M.
- The Journal of Physical Chemistry C, Vol. 117, Issue 2
Thermodynamics and Kinetics of the Li/FeF 3 Reaction by Electrochemical Analysis
journal, February 2012
- Liu, Ping; Vajo, John J.; Wang, John S.
- The Journal of Physical Chemistry C, Vol. 116, Issue 10
Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents
journal, January 2009
- Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie
- Journal of The Electrochemical Society, Vol. 156, Issue 12
Nano-sized γ-Fe2O3 as lithium battery cathode
journal, August 2005
- Kanzaki, Sho; Inada, Taro; Matsumura, Tadaaki
- Journal of Power Sources, Vol. 146, Issue 1-2
Photonic Crystal Structures as a Basis for a Three-Dimensionally Interpenetrating Electrochemical-Cell System
journal, July 2006
- Ergang, N. S.; Lytle, J. C.; Lee, K. T.
- Advanced Materials, Vol. 18, Issue 13
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes
journal, March 2011
- Zhang, Huigang; Yu, Xindi; Braun, Paul V.
- Nature Nanotechnology, Vol. 6, Issue 5, p. 277-281
Li[sub x]Cu[sub 6]Sn[sub 5] (0<x<13): An Intermetallic Insertion Electrode for Rechargeable Lithium Batteries
journal, January 1999
- Kepler, Keith D.
- Electrochemical and Solid-State Letters, Vol. 2, Issue 7
Carbon Nanocapsules as Nanoreactors for Controllable Synthesis of Encapsulated Iron and Iron Oxides: Magnetic Properties and Reversible Lithium Storage
journal, February 2011
- Wu, Ping; Du, Ning; Zhang, Hui
- The Journal of Physical Chemistry C, Vol. 115, Issue 9
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Factors Influencing the Rate of Fe[sub 2]O[sub 3] Conversion Reaction
journal, January 2007
- Jiao, Feng; Bao, Jianli; Bruce, Peter G.
- Electrochemical and Solid-State Letters, Vol. 10, Issue 12
Intercalation of lithium into graphite and other carbons
journal, August 1975
- Guerard, D.; Herold, A.
- Carbon, Vol. 13, Issue 4
Carbon Nanomaterials for Advanced Energy Conversion and Storage
journal, March 2012
- Dai, Liming; Chang, Dong Wook; Baek, Jong-Beom
- Small, Vol. 8, Issue 8
Controllable Synthesis and Magnetism of Iron Oxides Nanorings
journal, April 2010
- Lv, Baoliang; Xu, Yao; Gao, Qiang
- Journal of Nanoscience and Nanotechnology, Vol. 10, Issue 4
Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe2O3 with Various Particle Sizes
journal, January 2003
- Larcher, D.; Bonnin, D.; Cortes, R.
- Journal of The Electrochemical Society, Vol. 150, Issue 12, p. A1643-A1650
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980
- Mizushima, K.; Jones, P. C.; Wiseman, P. J.
- Materials Research Bulletin, Vol. 15, Issue 6
In Situ Transmission Electron Microscopy Observation of the Conversion Mechanism of Fe 2 O 3 /Graphene Anode during Lithiation–Delithiation Processes
journal, September 2013
- Su, Qingmei; Xie, Dong; Zhang, Jun
- ACS Nano, Vol. 7, Issue 10
Works referencing / citing this record:
High Volumetric and Gravimetric Capacity Electrodeposited Mesostructured Sb 2 O 3 Sodium Ion Battery Anodes
journal, April 2019
- Kim, Sanghyeon; Qu, Subing; Zhang, Runyu
- Small
Three-dimensional ordered porous electrode materials for electrochemical energy storage
journal, March 2019
- Liu, Zaichun; Yuan, Xinhai; Zhang, Shuaishuai
- NPG Asia Materials, Vol. 11, Issue 1
Polynuclear Iron-Oxo/Hydroxy Complexes of Ketoacidoximate Ligands: Synthesis, Structures and Conversion to Ferric Oxide
journal, June 2017
- Davaasuren, Bambar; Khanderi, Jayaprakash; Rothenberger, Alexander
- ChemistrySelect, Vol. 2, Issue 17
A review on porous polymer composite materials for multifunctional electronic applications
journal, November 2018
- Sadasivuni, Kishor Kumar; Cabibihan, John-John; Deshmukh, Kalim
- Polymer-Plastics Technology and Materials, Vol. 58, Issue 12
A critical review-promises and barriers of conversion electrodes for Li-ion batteries
journal, April 2017
- Kraytsberg, Alexander; Ein-Eli, Yair
- Journal of Solid State Electrochemistry, Vol. 21, Issue 7
Electrodeposition Technologies for Li‐Based Batteries: New Frontiers of Energy Storage
journal, September 2019
- Pu, Jun; Shen, Zihan; Zhong, Chenglin
- Advanced Materials
Improved Performance in FeF 2 Conversion Cathodes through Use of a Conductive 3D Scaffold and Al 2 O 3 ALD Coating
journal, July 2017
- Kim, Sanghyeon; Liu, Jinyun; Sun, Ke
- Advanced Functional Materials, Vol. 27, Issue 35
Electrodeposited high strength, thermally stable spectrally selective rhenium nickel inverse opals
journal, January 2017
- Zhang, Runyu; Cohen, Joseph; Fan, Shanhui
- Nanoscale, Vol. 9, Issue 31
Free-standing transition metal oxide electrode architectures for electrochemical energy storage
journal, July 2019
- Spencer, Michael A.; Augustyn, Veronica
- Journal of Materials Science, Vol. 54, Issue 20
Exploiting High-Performance Anode through Tuning the Character of Chemical Bonds for Li-Ion Batteries and Capacitors
journal, September 2016
- Liu, Chaofeng; Zhang, Changkun; Fu, Haoyu
- Advanced Energy Materials, Vol. 7, Issue 1