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Title: Growth of metal phthalocyanine on deactivated semiconducting surfaces steered by selective orbital coupling

Abstract

Using scanning tunneling microscopy and density functional theory, we show that the molecular ordering and orientation of metal phthalocyanine molecules on the deactivated Si surface display a strong dependency on the central transition-metal ion, driven by the degree of orbital hybridization at the heterointerface via selective p – d orbital coupling. As a result, this Letter identifies a selective mechanism for modifying the molecule-substrate interaction which impacts the growth behavior of transition-metal-incorporated organic molecules on a technologically relevant substrate for silicon-based devices.

Authors:
 [1];  [1];  [2];  [1];  [2];  [2]
+ Show Author Affiliations
  1. Michigan State Univ., East Lansing, MI (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1263862
Alternate Identifier(s):
OSTI ID: 1213101
Grant/Contract Number:  
AC05-00OR22725; AC02-05CH11231; SC0006400
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Letters
Additional Journal Information:
Journal Volume: 115; Journal Issue: 9; Journal ID: ISSN 0031-9007
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Wagner, Sean R., Feng, Jiagui, Yoon, Mina, Zhang, Pengpeng, Huang, Bing, and Park, Changwon. Growth of metal phthalocyanine on deactivated semiconducting surfaces steered by selective orbital coupling. United States: N. p., 2015. Web. doi:10.1103/PhysRevLett.115.096101.
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Wagner, Sean R., Feng, Jiagui, Yoon, Mina, Zhang, Pengpeng, Huang, Bing, & Park, Changwon. Growth of metal phthalocyanine on deactivated semiconducting surfaces steered by selective orbital coupling. United States. https://doi.org/10.1103/PhysRevLett.115.096101
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Wagner, Sean R., Feng, Jiagui, Yoon, Mina, Zhang, Pengpeng, Huang, Bing, and Park, Changwon. Tue . "Growth of metal phthalocyanine on deactivated semiconducting surfaces steered by selective orbital coupling". United States. https://doi.org/10.1103/PhysRevLett.115.096101. https://www.osti.gov/servlets/purl/1263862.
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@article{osti_1263862,
title = {Growth of metal phthalocyanine on deactivated semiconducting surfaces steered by selective orbital coupling},
author = {Wagner, Sean R. and Feng, Jiagui and Yoon, Mina and Zhang, Pengpeng and Huang, Bing and Park, Changwon},
abstractNote = {Using scanning tunneling microscopy and density functional theory, we show that the molecular ordering and orientation of metal phthalocyanine molecules on the deactivated Si surface display a strong dependency on the central transition-metal ion, driven by the degree of orbital hybridization at the heterointerface via selective p – d orbital coupling. As a result, this Letter identifies a selective mechanism for modifying the molecule-substrate interaction which impacts the growth behavior of transition-metal-incorporated organic molecules on a technologically relevant substrate for silicon-based devices.},
doi = {10.1103/PhysRevLett.115.096101},
journal = {Physical Review Letters},
number = 9,
volume = 115,
place = {United States},
year = {Tue Aug 25 00:00:00 EDT 2015},
month = {Tue Aug 25 00:00:00 EDT 2015}
}
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https://doi.org/10.1103/PhysRevLett.115.096101
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    Works referencing / citing this record:

    Tailoring the growth and electronic structures of organic molecular thin films
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    • Olszowski, Piotr; Zajac, Lukasz; Godlewski, Szymon
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