Structural and magnetic properties of the 5d2 double perovskites Sr2BReO6 (B = Y, In)
Abstract
With this study, we have performed magnetic susceptibility, heat capacity, neutron powder diffraction, and muon spin relaxation experiments to investigate the magnetic ground states of the 5$d^2$ double perovskites Sr$$_2$$YReO$$_6$$ and Sr$$_2$$InReO$$_6$$. We find that Sr$$_2$$YReO$$_6$$ is a spin glass, while Sr$$_2$$InReO$$_6$$ hosts a non-magnetic singlet state. By making detailed comparisons with other 5$d^2$ double perovskites, we argue that a delicate interplay between spin-orbit coupling, non-cubic crystal fields, and exchange interactions plays a key role in the great variation of magnetic ground states observed for this family of materials.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- STFC Rutherford Appleton Lab., Oxfordshire (United Kingdom); Univ. of Johannesburg, Auckland Park (South Africa)
- STFC Rutherford Appleton Lab., Oxfordshire (United Kingdom)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1256821
- Alternate Identifier(s):
- OSTI ID: 1256116
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 93; Journal Issue: 21; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; magnetism; double perovskites; rhenates
Citation Formats
Aczel, A. A., Zhao, Z., Calder, S., Adroja, D. T., Baker, P. J., and Yan, J. -Q. Structural and magnetic properties of the 5d2 double perovskites Sr2BReO6 (B = Y, In). United States: N. p., 2016.
Web. doi:10.1103/PhysRevB.93.214407.
Aczel, A. A., Zhao, Z., Calder, S., Adroja, D. T., Baker, P. J., & Yan, J. -Q. Structural and magnetic properties of the 5d2 double perovskites Sr2BReO6 (B = Y, In). United States. https://doi.org/10.1103/PhysRevB.93.214407
Aczel, A. A., Zhao, Z., Calder, S., Adroja, D. T., Baker, P. J., and Yan, J. -Q. Wed .
"Structural and magnetic properties of the 5d2 double perovskites Sr2BReO6 (B = Y, In)". United States. https://doi.org/10.1103/PhysRevB.93.214407. https://www.osti.gov/servlets/purl/1256821.
@article{osti_1256821,
title = {Structural and magnetic properties of the 5d2 double perovskites Sr2BReO6 (B = Y, In)},
author = {Aczel, A. A. and Zhao, Z. and Calder, S. and Adroja, D. T. and Baker, P. J. and Yan, J. -Q.},
abstractNote = {With this study, we have performed magnetic susceptibility, heat capacity, neutron powder diffraction, and muon spin relaxation experiments to investigate the magnetic ground states of the 5$d^2$ double perovskites Sr$_2$YReO$_6$ and Sr$_2$InReO$_6$. We find that Sr$_2$YReO$_6$ is a spin glass, while Sr$_2$InReO$_6$ hosts a non-magnetic singlet state. By making detailed comparisons with other 5$d^2$ double perovskites, we argue that a delicate interplay between spin-orbit coupling, non-cubic crystal fields, and exchange interactions plays a key role in the great variation of magnetic ground states observed for this family of materials.},
doi = {10.1103/PhysRevB.93.214407},
journal = {Physical Review B},
number = 21,
volume = 93,
place = {United States},
year = {Wed Jun 01 00:00:00 EDT 2016},
month = {Wed Jun 01 00:00:00 EDT 2016}
}
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Works referencing / citing this record:
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