Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure

zhang, Bangmin; Chen, Jingsheng; Venkatesan, T.; Sun, Cheng -Jun; Heald, Steve M.; Chow, Gan Moog; Yang, Ping; Chi, Xiao; Lin, Weinan

doi:10.1038/srep19886

Title: Effects of strain relaxation in Pr_0.67Sr_0.33MnO₃ films probed by polarization dependent X-ray absorption near edge structure

Abstract

In this study, the Mn K edge X-ray absorption near edge structure (XANES) of Pr_0.67Sr_0.33MnO₃ films with different thicknesses on (001) LaAlO₃ substrate were measured, and the effects of strain relaxation on film properties were investigated. The films experienced in-plane compressive strain and out-of-plane tensile strain. Strain relaxation evolved with the film thickness. In the polarization dependent XANES measurements, the in-plane (parallel) and out-of-plane (perpendicular) XANES spectrocopies were anisotropic with different absorption energy E_r. The resonance energy Er along two directions shifted towards each other with increasing film thickness. Based on the X-ray diffraction results, it was suggested that the strain relaxation weakened the difference of the local environment and probability of electronic charge transfer (between Mn 3d and O 2p orbitals) along the in-plane and out-of-plane directions, which was responsible for the change of E_r. XANES is a useful tool to probe the electronic structures, of which the effects on magnetic properties with the strain relaxation was also been studied.

Authors:

zhang, Bangmin ^[1]; Chen, Jingsheng ^[1]; Venkatesan, T. ^[1]; Sun, Cheng -Jun ^[2]; Heald, Steve M. ^[2]; Chow, Gan Moog ^[1]; Yang, Ping ^[1]; Chi, Xiao ^[1]; Lin, Weinan ^[1]

National Univ. of Singapore (Singapore)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Thu Jan 28 00:00:00 EST 2016

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1248885

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 6; Journal Issue: 2; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    zhang, Bangmin, Chen, Jingsheng, Venkatesan, T., Sun, Cheng -Jun, Heald, Steve M., Chow, Gan Moog, Yang, Ping, Chi, Xiao, and Lin, Weinan. Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure.  United States: N. p., 2016. 
Web.  doi:10.1038/srep19886.

Copy to clipboard


                    zhang, Bangmin, Chen, Jingsheng, Venkatesan, T., Sun, Cheng -Jun, Heald, Steve M., Chow, Gan Moog, Yang, Ping, Chi, Xiao, & Lin, Weinan. Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure.  United States.  https://doi.org/10.1038/srep19886

Copy to clipboard


                    zhang, Bangmin, Chen, Jingsheng, Venkatesan, T., Sun, Cheng -Jun, Heald, Steve M., Chow, Gan Moog, Yang, Ping, Chi, Xiao, and Lin, Weinan. Thu .  
"Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure".  United States.  https://doi.org/10.1038/srep19886.  https://www.osti.gov/servlets/purl/1248885.

Copy to clipboard


                    
@article{osti_1248885,

  title        = {Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure},

  author       = {zhang, Bangmin and Chen, Jingsheng and Venkatesan, T. and Sun, Cheng -Jun and Heald, Steve M. and Chow, Gan Moog and Yang, Ping and Chi, Xiao and Lin, Weinan},

  abstractNote = {In this study, the Mn K edge X-ray absorption near edge structure (XANES) of Pr0.67Sr0.33MnO3 films with different thicknesses on (001) LaAlO3 substrate were measured, and the effects of strain relaxation on film properties were investigated. The films experienced in-plane compressive strain and out-of-plane tensile strain. Strain relaxation evolved with the film thickness. In the polarization dependent XANES measurements, the in-plane (parallel) and out-of-plane (perpendicular) XANES spectrocopies were anisotropic with different absorption energy Er. The resonance energy Er along two directions shifted towards each other with increasing film thickness. Based on the X-ray diffraction results, it was suggested that the strain relaxation weakened the difference of the local environment and probability of electronic charge transfer (between Mn 3d and O 2p orbitals) along the in-plane and out-of-plane directions, which was responsible for the change of Er. XANES is a useful tool to probe the electronic structures, of which the effects on magnetic properties with the strain relaxation was also been studied.},

  doi          = {10.1038/srep19886},

  journal      = {Scientific Reports},

  number       = 2,

  volume       = 6,

  place        = {United States},

  year         = {Thu Jan 28 00:00:00 EST 2016},

  month        = {Thu Jan 28 00:00:00 EST 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1038/srep19886

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 12 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Local atomic and electronic structures of epitaxial strained LaCoO $_{3}$ thin films
journal, January 2012

Sterbinsky, G. E.; Ryan, P. J.; Kim, J. -W.
Physical Review B, Vol. 85, Issue 2
DOI: 10.1103/PhysRevB.85.020403

Low-temperature resistivity of La 0.7 Sr 0.3 Mn O 3 ultra thin films: Role of quantum interference effects
journal, March 2006

Maritato, L.; Adamo, C.; Barone, C.
Physical Review B, Vol. 73, Issue 9
DOI: 10.1103/PhysRevB.73.094456

Cooperative Jahn-Teller effect and electron-phonon coupling in ${La}_{1 - x}$ $A_{x}$ ${MnO}_{3}$
journal, April 1996

Millis, A. J.
Physical Review B, Vol. 53, Issue 13
DOI: 10.1103/PhysRevB.53.8434

Pressure-dependent electronic structures and orbital hybridization of Mn $3 d$ states in multiferroic BiMnO $_{3}$ : A combined x-ray absorption, x-ray emission, and resonant x-ray emission study
journal, July 2012

Chen, J. M.; Haw, S. C.; Lee, J. M.
Physical Review B, Vol. 86, Issue 4
DOI: 10.1103/PhysRevB.86.045103

Octahedral Tilting in Perovskites. II. Structure Stabilizing Forces
journal, February 1997

Woodward, P. M.
Acta Crystallographica Section B Structural Science, Vol. 53, Issue 1
DOI: 10.1107/S0108768196012050

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
journal, May 2013

Qiao, Ruimin; Chin, Timothy; Harris, Stephen J.
Current Applied Physics, Vol. 13, Issue 3
DOI: 10.1016/j.cap.2012.09.017

Role of Interface Structure and Chemistry in Resistive Switching of NiO Nanocrystals on SrTiO3
journal, August 2015

Cheng, Xuan; Sullaphen, Jivika; Weyland, Matthew
Microscopy and Microanalysis, Vol. 21, Issue S3
DOI: 10.1017/s1431927615004705

Role of strain in magnetotransport properties of Pr0.67Sr0.33MnO3 thin films
journal, May 2000

Wang, H. S.; Wertz, E.; Hu, Y. F.
Journal of Applied Physics, Vol. 87, Issue 10
DOI: 10.1063/1.373002

Strain-induced crystal structure change in ultrathin films of Pr0.7Sr0.3MnO3
journal, February 2002

MacLaren, Ian; Wang, Zhong Lin; Wang, H. S.
Applied Physics Letters, Vol. 80, Issue 8
DOI: 10.1063/1.1453482

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
text, January 2014

Magnuson, Martin; Strocov, Thorsten Schmitt Vladimir N.; Schlappa, Justina
arXiv
DOI: 10.48550/arxiv.1411.3301

Surface Nanostructures in Manganite Films
journal, June 2014

Gambardella, A.; Graziosi, P.; Bergenti, I.
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep05353

Unipolar resistive switching behavior of amorphous gallium oxide thin films for nonvolatile memory applications
journal, January 2015

Guo, D. Y.; Wu, Z. P.; An, Y. H.
Applied Physics Letters, Vol. 106, Issue 4
DOI: 10.1063/1.4907174

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films
journal, January 2012

Pesquera, D.; Herranz, G.; Barla, A.
Nature Communications, Vol. 3, Issue 1
DOI: 10.1038/ncomms2189

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
journal, November 2014

Magnuson, M.; Schmitt, T.; Strocov, V. N.
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep07017

Octahedral Tilting in Perovskites. I. Geometrical Considerations
journal, February 1997

Woodward, P. M.
Acta Crystallographica Section B Structural Science, Vol. 53, Issue 1
DOI: 10.1107/S0108768196010713

CMR manganites: physics, thin films and devices
journal, April 2003

Haghiri-Gosnet, A-M; Renard, J-P
Journal of Physics D: Applied Physics, Vol. 36, Issue 8
DOI: 10.1088/0022-3727/36/8/201

A Minimal tight-binding model for ferromagnetic canted bilayer manganites
text, January 2014

Baublitz, M.; Lane, C.; Lin, Hsin
arXiv
DOI: 10.48550/arxiv.1412.4728

Enhanced tunnelling electroresistance effect due to a ferroelectrically induced phase transition at a magnetic complex oxide interface
journal, February 2013

Yin, Y. W.; Burton, J. D.; Kim, Y-M.
Nature Materials, Vol. 12, Issue 5
DOI: 10.1038/nmat3564

Dynamic Jahn-Teller Effect and Colossal Magnetoresistance in ${La}_{1 - x} {Sr}_{x} {MnO}_{3}$
journal, July 1996

Millis, A. J.; Shraiman, Boris I.; Mueller, R.
Physical Review Letters, Vol. 77, Issue 1
DOI: 10.1103/PhysRevLett.77.175

Unit-cell determination of epitaxial thin films based on reciprocal-space vectors by high-resolution X-ray diffractometry
journal, January 2014

Yang, Ping; Liu, Huajun; Chen, Zuhuang
Journal of Applied Crystallography, Vol. 47, Issue 1
DOI: 10.1107/S1600576713031191

Strain modulated anisotropic electronic charge transfer in perovskite $\Pr_{0.67}$ ${Sr}_{0.33}$ ${MnO}_{3}$ thin films
journal, May 2014

Zhang, Bangmin; Sun, Cheng-Jun; Yang, Ping
Physical Review B, Vol. 89, Issue 19
DOI: 10.1103/PhysRevB.89.195140

The PNC/XOR X-ray microprobe station at APS sector 20
journal, November 2007

Heald, S. M.; Cross, J. O.; Brewe, D. L.
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 582, Issue 1
DOI: 10.1016/j.nima.2007.08.109

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
text, January 2014

Magnuson, Martin; Strocov, Thorsten Schmitt Vladimir N.; Schlappa, Justina
arXiv
DOI: 10.48550/arxiv.1411.3301

One-Center Charge Transfer Transitions in Manganites
text, January 2001

Moskvin, A. S.
arXiv
DOI: 10.48550/arxiv.cond-mat/0111198

Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange
journal, April 2015

Liu, M. F.; Du, Z. Z.; Xie, Y. L.
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep09922

Low-temperature resistivity minima in colossal magnetoresistive La 0.7 Ca 0.3 MnO 3 thin films
journal, February 2002

Kumar, D.; Sankar, J.; Narayan, J.
Physical Review B, Vol. 65, Issue 9
DOI: 10.1103/PhysRevB.65.094407

Double Exchange Alone Does Not Explain the Resistivity of ${La}_{1}_{- x} {Sr}_{x} {MnO}_{3}$
journal, June 1995

Millis, A. J.; Littlewood, P. B.; Shraiman, B. I.
Physical Review Letters, Vol. 74, Issue 25
DOI: 10.1103/PhysRevLett.74.5144

Magnetoelectric transport and quantum interference effect in ultrathin manganite films
journal, April 2014

Wang, Cong; Jin, Kui-juan; Gu, Lin
Applied Physics Letters, Vol. 104, Issue 16
DOI: 10.1063/1.4873337

Quantifying strain dependence in “colossal” magnetoresistance manganites
journal, February 1998

Millis, A. J.; Darling, T.; Migliori, A.
Journal of Applied Physics, Vol. 83, Issue 3
DOI: 10.1063/1.367310

Anisotropy of the core-hole relaxation in x-ray-absorption spectroscopy as probed in square planar cuprates
journal, April 1992

Tolentino, H.; Medarde, M.; Fontaine, A.
Physical Review B, Vol. 45, Issue 14
DOI: 10.1103/physrevb.45.8091

Magnetic phase diagrams of $L_{1 - x} A_{x} {MnO}_{3}$ manganites $(L = P r, S m;$ $A = C a, S r)$
journal, November 1999

Martin, C.; Maignan, A.; Hervieu, M.
Physical Review B, Vol. 60, Issue 17
DOI: 10.1103/PhysRevB.60.12191

Colossal magnetoresistant materials: the key role of phase separation
journal, April 2001

Dagotto, Elbio; Hotta, Takashi; Moreo, Adriana
Physics Reports, Vol. 344, Issue 1-3
DOI: 10.1016/S0370-1573(00)00121-6

Considerations on Double Exchange
journal, October 1955

Anderson, P. W.; Hasegawa, H.
Physical Review, Vol. 100, Issue 2
DOI: 10.1103/PhysRev.100.675

Surface Magnetic Phase Diagram of Tetragonal Manganites
journal, November 2001

Fang, Zhong; Terakura, Kiyoyuki
Journal of the Physical Society of Japan, Vol. 70, Issue 11
DOI: 10.1143/JPSJ.70.3356

Metal-insulator transitions
journal, June 1991

Paesler, Michael
Journal of Non-Crystalline Solids, Vol. 130, Issue 1
DOI: 10.1016/0022-3093(91)90162-y

Coaction of electric field induced strain and polarization effects in ${La}_{0.7} {Ca}_{0.3} {MnO}_{3} / PMN-PT$ structures
journal, May 2009

Sheng, Z. G.; Gao, J.; Sun, Y. P.
Physical Review B, Vol. 79, Issue 17
DOI: 10.1103/PhysRevB.79.174437

Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange
journal, April 2015

Liu, M. F.; Du, Z. Z.; Xie, Y. L.
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep09922

Effects of electrode material and configuration on the characteristics of planar resistive switching devices
journal, November 2013

Peng, H. Y.; Pu, L.; Wu, J. C.
APL Materials, Vol. 1, Issue 5
DOI: 10.1063/1.4827597

Metal-insulator transitions
journal, October 1998

Imada, Masatoshi; Fujimori, Atsushi; Tokura, Yoshinori
Reviews of Modern Physics, Vol. 70, Issue 4, p. 1039-1263
DOI: 10.1103/RevModPhys.70.1039

Effects of electrode material and configuration on the characteristics of planar resistive switching devices
journal, November 2013

Peng, H. Y.; Pu, L.; Wu, J. C.
APL Materials, Vol. 1, Issue 5
DOI: 10.1063/1.4827597

Orbital-State-Mediated Phase-Control of Manganites
journal, December 1999

Konishi, Yoshinori; Fang, Zhong; Izumi, Makoto
Journal of the Physical Society of Japan, Vol. 68, Issue 12
DOI: 10.1143/JPSJ.68.3790

A Minimal tight-binding model for ferromagnetic canted bilayer manganites
journal, December 2014

Baublitz, M.; Lane, C.; Lin, Hsin
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep07512

Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
journal, May 2015

Jin, Kyoungsuk; Chu, Arim; Park, Jimin
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep10279

Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998

Ankudinov, A. L.; Ravel, B.; Rehr, J. J.
Physical Review B, Vol. 58, Issue 12
DOI: 10.1103/PhysRevB.58.7565

Nature of the Well Screened State in Hard X-Ray Mn $2 p$ Core-Level Photoemission Measurements of ${L a}_{1 - x} {S r}_{x} {M n O}_{3}$ Films
journal, November 2004

Horiba, K.; Taguchi, M.; Chainani, A.
Physical Review Letters, Vol. 93, Issue 23
DOI: 10.1103/PhysRevLett.93.236401

Strain Effects in Narrow-Bandwidth Manganites: The Case of Epitaxial ${Eu}_{0.7} {Sr}_{0.3} {MnO}_{3}$ Thin Films
journal, June 2014

Moon, Eun Ju; Keavney, David J.; May, Steven J.
Physical Review Applied, Vol. 1, Issue 5
DOI: 10.1103/PhysRevApplied.1.054006

One-Center Charge Transfer Transitions in Manganites
text, January 2001

Moskvin, A. S.
arXiv
DOI: 10.48550/arxiv.cond-mat/0111198

A Minimal tight-binding model for ferromagnetic canted bilayer manganites
text, January 2014

Baublitz, M.; Lane, C.; Lin, Hsin
arXiv
DOI: 10.48550/arxiv.1412.4728

The classification of tilted octahedra in perovskites
journal, November 1972

Glazer, A. M.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11
DOI: 10.1107/S0567740872007976

Local structural distortions in manganites probed by comparative x-ray-emission and x-ray-absorption near-edge measurements
journal, June 2001

Qian, Q.; Tyson, T. A.; Kao, C. -C.
Physical Review B, Vol. 64, Issue 2
DOI: 10.1103/PhysRevB.64.024430

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO ₃
journal, March 2014

Cheng, Xuan; Sullaphen, Jivika; Weyland, Matthew
APL Materials, Vol. 2, Issue 3
DOI: 10.1063/1.4869457

Interfacial Strain: The Driving Force for Selective Orbital Occupancy in Manganite Thin Films
journal, December 2007

Abad, L.; Laukhin, V.; Valencia, S.
Advanced Functional Materials, Vol. 17, Issue 18
DOI: 10.1002/adfm.200700137

Competition between lattice distortion and charge dynamics for the charge carriers of double-layered manganites
journal, November 1998

Park, J. -H.; Kimura, T.; Tokura, Y.
Physical Review B, Vol. 58, Issue 20
DOI: 10.1103/PhysRevB.58.R13330

Quantifying strain dependence in “colossal” magnetoresistance manganites
journal, February 1998

Millis, A. J.; Darling, T.; Migliori, A.
Journal of Applied Physics, Vol. 83, Issue 3
DOI: 10.1063/1.367310

Phase Diagram of Tetragonal Manganites
journal, April 2000

Fang, Z.; Solovyev, I. V.; Terakura, K.
Physical Review Letters, Vol. 84, Issue 14
DOI: 10.1103/PhysRevLett.84.3169

Directional short range order in $L 1_{0}$ FeMnPt magnetic thin films
journal, October 2011

Sun, Cheng-Jun; Xu, Dongbin; Heald, Steve M.
Physical Review B, Vol. 84, Issue 14
DOI: 10.1103/PhysRevB.84.140408

One-center charge transfer transitions in manganites
journal, May 2002

Moskvin, A. S.
Physical Review B, Vol. 65, Issue 20
DOI: 10.1103/PhysRevB.65.205113

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films
journal, January 2012

Pesquera, D.; Herranz, G.; Barla, A.
Nature Communications, Vol. 3, Issue 1
DOI: 10.1038/ncomms2189

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO ₃
journal, March 2014

Cheng, Xuan; Sullaphen, Jivika; Weyland, Matthew
APL Materials, Vol. 2, Issue 3
DOI: 10.1063/1.4869457

Glass-like recovery of antiferromagnetic spin ordering in a photo-excited manganite Pr0.7Ca0.3MnO3
journal, February 2014

Zhou, S. Y.; Langner, M. C.; Zhu, Y.
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep04050

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
text, January 2012

Qiao, Ruimin; Chin, Timothy; Harris, Stephen J.
arXiv
DOI: 10.48550/arxiv.1208.6319

Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
journal, May 2015

Jin, Kyoungsuk; Chu, Arim; Park, Jimin
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep10279

Simple ways of determining perovskite structures
journal, November 1975

Glazer, A. M.
Acta Crystallographica Section A, Vol. 31, Issue 6
DOI: 10.1107/S0567739475001635

Works referencing / citing this record:

The particle size effect of Yb0.8R0.2MnO3 (R is Sm, Nd, and Eu) on some physical properties
journal, February 2020

Abdel-Latif, I. A.
Journal of Nanoparticle Research, Vol. 22, Issue 2
DOI: 10.1007/s11051-020-4759-z

Atomic-scale investigation of MgO growth on fused quartz using angle-dependent NEXAFS measurements
journal, January 2018

Singh, Jitendra Pal; Kim, So Hee; Won, Sung Ok
RSC Advances, Vol. 8, Issue 55
DOI: 10.1039/c8ra02873g

Similar Records in DOE PAGES and OSTI.GOV collections:

Temperature dependent electronic structure of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film probed by X-ray absorption near edge structure

Journal Article Zhang, Bangmin ; Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 ; NUSNNI-Nanocore, National University of Singapore, Singapore 117411 ; ... - Journal of Applied Physics

The Mn K edge X-ray absorption near edge structures (XANES) of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film (100 nm) on (001) LaAlO{sub 3} substrate was measured at different temperatures to probe the MnO{sub 6} octahedron distortion and corresponding electronic structure. The absorption of high temperature paramagnetic-insulator phase differed from that of the low temperature ferromagnetic-metal phase. The temperature-dependent absorption intensity of Mn K edge XANES was correlated with the relaxation of distorted MnO{sub 6} octahedron, which changed the crystal field acting on the Mn site and the related electronic structure and properties. At low temperature, the splitting of Mn majority e{submore »« less
https://doi.org/10.1063/1.4862092
Evolution of strain-dependent transport properties in ultrathin La{sub 0.67}Sr{sub 0.33}MnO{sub 3} films

Journal Article Ju, H L ; Krishnan, K M ; Lederman, D - Journal of Applied Physics

We report on a systematic investigation of strain-induced lattice distortion effects on the crystal structure and transport properties of as-grown and postannealed ultrathin La{sub 0.67}Sr{sub 0.33}MnO{sub 3} epitaxial films grown on LaAlO{sub 3} (001) substrates by pulsed laser deposition. The resistivity of the as-grown films is critically dependent on the thickness, i.e., 100 {Angstrom} thick films show insulating behavior, 300 {Angstrom} thick films show metal-insulator transitions, and 500 {Angstrom} thick films show metallic behavior. However, all the annealed films show identical metallic behavior. Conventional {theta}{endash}2{theta} x-ray scans with momentum transfer (q) along the [001] direction, and {theta}{endash}2{theta} scans of themore »« less
https://doi.org/10.1063/1.367864
Depth analysis of the in-plane lattice constants in compressively strained La{sub 0.67}Ca{sub 0.33}MnO{sub 3} thin films

Journal Article Petit, M ; Rajeswari, M ; Biswas, A ; ... - Journal of Applied Physics

We have performed depth profile analyses of the lattice parameters in epitaxial thin films of La{sub 0.67}Ca{sub 0.33}MnO{sub 3} to understand the evolution of strain relaxation processes in these materials. The analyses were done using grazing incidence x-ray scattering on films of different thicknesses on (100)-oriented LaAlO{sub 3} with a lattice mismatch of -2%. We find that such films exhibit two and sometimes up to three in-plane strained lattice constants, corresponding to a slight orthorhombic distortion of the crystal, as well as near-surface lattice relaxation. As a function of film thickness, we find that the strain is in the samemore »« less
https://doi.org/10.1063/1.1884761
Electric-field-induced strain effects on the magnetization of a Pr_0.67Sr_0.33MnO₃ film

Journal Article Zhang, B. ; Sun, C. -J. ; Lu, W. ; ... - Physical Review. B, Condensed Matter and Materials Physics

The electric-field control of magnetic properties of Pr_0.67Sr_0.33MnO₃ (PSMO) film on piezoelectric Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ (PMNT) substrate was investigated. The piezoelectric response of the PMNT substrate to the electric field produced strain that was coupled to the PSMO film. The in-plane compressive (tensile) strain increased (decreased) the magnetization. The change of magnetic moment was associated with the Mn ions. First principle simulations showed that the strain-induced electronic redistribution of the two e_g orbitals (3d_z² and 3d_x²_-y²) of Mn ions was responsible for the change of magnetic moment. This work demonstrates that the magnetoelectric effect in manganite/piezoelectric hetero-structures originates from the change inmore »« less
Cited by 6
https://doi.org/10.1103/PhysRevB.91.174431

Full Text Available
Strain- and thickness-dependent magnetic properties of epitaxial La_0.67Sr_0.33CoO₃/La_0.67Sr_0.33MnO₃ bilayers

Journal Article Feng, Mingzhen ; Ahlm, Nolan J. ; Kane, Alexander M. ; ... - Journal of Applied Physics

Magnetic properties and interfacial phenomena of epitaxial perovskite oxides depend sensitively on parameters such as film thickness and strain state. In this work, epitaxial La0_.67Sr_0.33CoO₃(LSCO)/La_0.67Sr_0.33MnO₃ (LSMO) bilayers were grown on NdGaO₃ (NGO) and LaAlO₃ (LAO) substrates with a fixed LSMO thickness of 6 nm, and LSCO thickness (t_LSCO) varying from 2 to 10 nm. Soft x-ray magnetic spectroscopy revealed that magnetically active Co²⁺ions that strongly coupled to the LSMO layer were observed below a critical t_LSCO for bilayers grown on both substrates. On LAO substrates, this critical thickness was 2 nm, above which the formation of Co²⁺ ions was quicklymore »« less
https://doi.org/10.1063/5.0122009

Full Text Available

Similar Records

Title: Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure

Abstract

Citation Formats

Local atomic and electronic structures of epitaxial strained LaCoO 3 thin films journal, January 2012

Low-temperature resistivity of La 0.7 Sr 0.3 Mn O 3 ultra thin films: Role of quantum interference effects journal, March 2006

Cooperative Jahn-Teller effect and electron-phonon coupling in La 1 − x A x MnO 3 journal, April 1996

Pressure-dependent electronic structures and orbital hybridization of Mn 3 d states in multiferroic BiMnO 3 : A combined x-ray absorption, x-ray emission, and resonant x-ray emission study journal, July 2012

Octahedral Tilting in Perovskites. II. Structure Stabilizing Forces journal, February 1997

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides journal, May 2013

Role of Interface Structure and Chemistry in Resistive Switching of NiO Nanocrystals on SrTiO3 journal, August 2015

Role of strain in magnetotransport properties of Pr0.67Sr0.33MnO3 thin films journal, May 2000

Strain-induced crystal structure change in ultrathin films of Pr0.7Sr0.3MnO3 journal, February 2002

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9 text, January 2014

Surface Nanostructures in Manganite Films journal, June 2014

Unipolar resistive switching behavior of amorphous gallium oxide thin films for nonvolatile memory applications journal, January 2015

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films journal, January 2012

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9 journal, November 2014

Octahedral Tilting in Perovskites. I. Geometrical Considerations journal, February 1997

CMR manganites: physics, thin films and devices journal, April 2003

A Minimal tight-binding model for ferromagnetic canted bilayer manganites text, January 2014

Enhanced tunnelling electroresistance effect due to a ferroelectrically induced phase transition at a magnetic complex oxide interface journal, February 2013

Dynamic Jahn-Teller Effect and Colossal Magnetoresistance in La 1 − x Sr x MnO 3 journal, July 1996

Unit-cell determination of epitaxial thin films based on reciprocal-space vectors by high-resolution X-ray diffractometry journal, January 2014

Strain modulated anisotropic electronic charge transfer in perovskite Pr 0.67 Sr 0.33 MnO 3 thin films journal, May 2014

The PNC/XOR X-ray microprobe station at APS sector 20 journal, November 2007

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9 text, January 2014

One-Center Charge Transfer Transitions in Manganites text, January 2001

Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange journal, April 2015

Low-temperature resistivity minima in colossal magnetoresistive La 0.7 Ca 0.3 MnO 3 thin films journal, February 2002

Double Exchange Alone Does Not Explain the Resistivity of La 1 − x Sr x MnO 3 journal, June 1995

Magnetoelectric transport and quantum interference effect in ultrathin manganite films journal, April 2014

Quantifying strain dependence in “colossal” magnetoresistance manganites journal, February 1998

Anisotropy of the core-hole relaxation in x-ray-absorption spectroscopy as probed in square planar cuprates journal, April 1992

Magnetic phase diagrams of L 1 − x A x MnO 3 manganites ( L = P r , S m ; A = C a , S r ) journal, November 1999

Colossal magnetoresistant materials: the key role of phase separation journal, April 2001

Considerations on Double Exchange journal, October 1955

Surface Magnetic Phase Diagram of Tetragonal Manganites journal, November 2001

Metal-insulator transitions journal, June 1991

Coaction of electric field induced strain and polarization effects in La 0.7 Ca 0.3 MnO 3 / PMN-PT structures journal, May 2009

Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange journal, April 2015

Effects of electrode material and configuration on the characteristics of planar resistive switching devices journal, November 2013

Metal-insulator transitions journal, October 1998

Effects of electrode material and configuration on the characteristics of planar resistive switching devices journal, November 2013

Orbital-State-Mediated Phase-Control of Manganites journal, December 1999

A Minimal tight-binding model for ferromagnetic canted bilayer manganites journal, December 2014

Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis journal, May 2015

Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure journal, September 1998

Nature of the Well Screened State in Hard X-Ray Mn 2 p Core-Level Photoemission Measurements of L a 1 − x S r x M n O 3 Films journal, November 2004

Strain Effects in Narrow-Bandwidth Manganites: The Case of Epitaxial Eu 0.7 Sr 0.3 MnO 3 Thin Films journal, June 2014

One-Center Charge Transfer Transitions in Manganites text, January 2001

A Minimal tight-binding model for ferromagnetic canted bilayer manganites text, January 2014

The classification of tilted octahedra in perovskites journal, November 1972

Local structural distortions in manganites probed by comparative x-ray-emission and x-ray-absorption near-edge measurements journal, June 2001

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO 3 journal, March 2014

Interfacial Strain: The Driving Force for Selective Orbital Occupancy in Manganite Thin Films journal, December 2007

Competition between lattice distortion and charge dynamics for the charge carriers of double-layered manganites journal, November 1998

Quantifying strain dependence in “colossal” magnetoresistance manganites journal, February 1998

Phase Diagram of Tetragonal Manganites journal, April 2000

Directional short range order in L 1 0 FeMnPt magnetic thin films journal, October 2011

One-center charge transfer transitions in manganites journal, May 2002

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films journal, January 2012

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO 3 journal, March 2014

Glass-like recovery of antiferromagnetic spin ordering in a photo-excited manganite Pr0.7Ca0.3MnO3 journal, February 2014

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides text, January 2012

Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis journal, May 2015

Simple ways of determining perovskite structures journal, November 1975

The particle size effect of Yb0.8R0.2MnO3 (R is Sm, Nd, and Eu) on some physical properties journal, February 2020

Atomic-scale investigation of MgO growth on fused quartz using angle-dependent NEXAFS measurements journal, January 2018

Title: Effects of strain relaxation in Pr_0.67Sr_0.33MnO₃ films probed by polarization dependent X-ray absorption near edge structure

Local atomic and electronic structures of epitaxial strained LaCoO $_{3}$ thin films
journal, January 2012

Low-temperature resistivity of La 0.7 Sr 0.3 Mn O 3 ultra thin films: Role of quantum interference effects
journal, March 2006

Cooperative Jahn-Teller effect and electron-phonon coupling in ${La}_{1 - x}$ $A_{x}$ ${MnO}_{3}$
journal, April 1996

Pressure-dependent electronic structures and orbital hybridization of Mn $3 d$ states in multiferroic BiMnO $_{3}$ : A combined x-ray absorption, x-ray emission, and resonant x-ray emission study
journal, July 2012

Octahedral Tilting in Perovskites. II. Structure Stabilizing Forces
journal, February 1997

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
journal, May 2013

Role of Interface Structure and Chemistry in Resistive Switching of NiO Nanocrystals on SrTiO3
journal, August 2015

Role of strain in magnetotransport properties of Pr0.67Sr0.33MnO3 thin films
journal, May 2000

Strain-induced crystal structure change in ultrathin films of Pr0.7Sr0.3MnO3
journal, February 2002

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
text, January 2014

Surface Nanostructures in Manganite Films
journal, June 2014

Unipolar resistive switching behavior of amorphous gallium oxide thin films for nonvolatile memory applications
journal, January 2015

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films
journal, January 2012

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
journal, November 2014

Octahedral Tilting in Perovskites. I. Geometrical Considerations
journal, February 1997

CMR manganites: physics, thin films and devices
journal, April 2003

A Minimal tight-binding model for ferromagnetic canted bilayer manganites
text, January 2014

Enhanced tunnelling electroresistance effect due to a ferroelectrically induced phase transition at a magnetic complex oxide interface
journal, February 2013

Dynamic Jahn-Teller Effect and Colossal Magnetoresistance in ${La}_{1 - x} {Sr}_{x} {MnO}_{3}$
journal, July 1996

Unit-cell determination of epitaxial thin films based on reciprocal-space vectors by high-resolution X-ray diffractometry
journal, January 2014

Strain modulated anisotropic electronic charge transfer in perovskite $\Pr_{0.67}$ ${Sr}_{0.33}$ ${MnO}_{3}$ thin films
journal, May 2014

The PNC/XOR X-ray microprobe station at APS sector 20
journal, November 2007

Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
text, January 2014

One-Center Charge Transfer Transitions in Manganites
text, January 2001

Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange
journal, April 2015

Low-temperature resistivity minima in colossal magnetoresistive La 0.7 Ca 0.3 MnO 3 thin films
journal, February 2002

Double Exchange Alone Does Not Explain the Resistivity of ${La}_{1}_{- x} {Sr}_{x} {MnO}_{3}$
journal, June 1995

Magnetoelectric transport and quantum interference effect in ultrathin manganite films
journal, April 2014

Quantifying strain dependence in “colossal” magnetoresistance manganites
journal, February 1998

Anisotropy of the core-hole relaxation in x-ray-absorption spectroscopy as probed in square planar cuprates
journal, April 1992

Magnetic phase diagrams of $L_{1 - x} A_{x} {MnO}_{3}$ manganites $(L = P r, S m;$ $A = C a, S r)$
journal, November 1999

Colossal magnetoresistant materials: the key role of phase separation
journal, April 2001

Considerations on Double Exchange
journal, October 1955

Surface Magnetic Phase Diagram of Tetragonal Manganites
journal, November 2001

Metal-insulator transitions
journal, June 1991

Coaction of electric field induced strain and polarization effects in ${La}_{0.7} {Ca}_{0.3} {MnO}_{3} / PMN-PT$ structures
journal, May 2009

Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange
journal, April 2015

Effects of electrode material and configuration on the characteristics of planar resistive switching devices
journal, November 2013

Metal-insulator transitions
journal, October 1998

Effects of electrode material and configuration on the characteristics of planar resistive switching devices
journal, November 2013

Orbital-State-Mediated Phase-Control of Manganites
journal, December 1999

A Minimal tight-binding model for ferromagnetic canted bilayer manganites
journal, December 2014

Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
journal, May 2015

Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998

Nature of the Well Screened State in Hard X-Ray Mn $2 p$ Core-Level Photoemission Measurements of ${L a}_{1 - x} {S r}_{x} {M n O}_{3}$ Films
journal, November 2004

Strain Effects in Narrow-Bandwidth Manganites: The Case of Epitaxial ${Eu}_{0.7} {Sr}_{0.3} {MnO}_{3}$ Thin Films
journal, June 2014

One-Center Charge Transfer Transitions in Manganites
text, January 2001

A Minimal tight-binding model for ferromagnetic canted bilayer manganites
text, January 2014

The classification of tilted octahedra in perovskites
journal, November 1972

Local structural distortions in manganites probed by comparative x-ray-emission and x-ray-absorption near-edge measurements
journal, June 2001

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO ₃
journal, March 2014

Interfacial Strain: The Driving Force for Selective Orbital Occupancy in Manganite Thin Films
journal, December 2007

Competition between lattice distortion and charge dynamics for the charge carriers of double-layered manganites
journal, November 1998

Quantifying strain dependence in “colossal” magnetoresistance manganites
journal, February 1998

Phase Diagram of Tetragonal Manganites
journal, April 2000

Directional short range order in $L 1_{0}$ FeMnPt magnetic thin films
journal, October 2011

One-center charge transfer transitions in manganites
journal, May 2002

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films
journal, January 2012

Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO ₃
journal, March 2014

Glass-like recovery of antiferromagnetic spin ordering in a photo-excited manganite Pr0.7Ca0.3MnO3
journal, February 2014

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
text, January 2012

Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
journal, May 2015

Simple ways of determining perovskite structures
journal, November 1975

The particle size effect of Yb0.8R0.2MnO3 (R is Sm, Nd, and Eu) on some physical properties
journal, February 2020

Atomic-scale investigation of MgO growth on fused quartz using angle-dependent NEXAFS measurements
journal, January 2018