Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb1-xGdxFe2 system

Adil, Murtaza; Yang, Sen; Mi, Meng; Zhou, Chao; Wang, Jieqiong; Zhang, Rui; Liao, Xiaoqi; Wang, Yu; Ren, Xiaobing; Song, Xiaoping; Ren, Yang

doi:10.1063/1.4916652

Title: Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb_1-xGd_xFe₂ system

Abstract

Morphotropic phase boundary (MPB), separating two ferroic phases of different crystal symmetries, has been studied extensively for its extraordinary enhancement of piezoelectricity in ferroelectrics. Based on the same mechanism, we have designed a magnetic MPB in the pseudobinary ferromagnetic system of Tb_1-xGd_xFe₂ and the corresponding crystal structure, magnetic properties, and magnetostriction are explored. With the synchrotron x-ray diffractometry, the structure symmetry of TbFe₂-rich compositions is detected to be rhombohedral (R) and that of GdFe₂-rich compositions is tetragonal (T) below T_c. With the change of concentration, the value of magnetostriction of the samples changes monotonously, while the MPB composition Tb_0.1Gd_0.9Fe₂, which corresponds to the coexistence of R and T phases, exhibits the maximum magnetization among all available compositions and superposition of magnetostriction behaviour of R and T phases. Furthermore, our result of MPB phenomena in ferromagnets may provide an effective route to design functional magnetic materials with exotic properties.

Authors:

Adil, Murtaza ^[1]; Yang, Sen ^[1]; Mi, Meng ^[1]; Zhou, Chao ^[1]; Wang, Jieqiong ^[1]; Zhang, Rui ^[1]; Liao, Xiaoqi ^[1]; Wang, Yu ^[1]; Ren, Xiaobing ^[1]; Song, Xiaoping ^[1]; Ren, Yang ^[2]

Xi'an Jiaotong Univ., Xi'an (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Tue Mar 31 00:00:00 EDT 2015

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: National Basic Research Program of China; National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1248372

Alternate Identifier(s):: OSTI ID: 1226730

Grant/Contract Number:: AC02-06CH11357; 2012CB619401; 51222104; 51371134; 51471125; 51431007

Resource Type:: Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Volume: 106; Journal Issue: 13; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Adil, Murtaza, Yang, Sen, Mi, Meng, Zhou, Chao, Wang, Jieqiong, Zhang, Rui, Liao, Xiaoqi, Wang, Yu, Ren, Xiaobing, Song, Xiaoping, and Ren, Yang. Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb1-xGdxFe2 system.  United States: N. p., 2015. 
Web.  doi:10.1063/1.4916652.

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                    Adil, Murtaza, Yang, Sen, Mi, Meng, Zhou, Chao, Wang, Jieqiong, Zhang, Rui, Liao, Xiaoqi, Wang, Yu, Ren, Xiaobing, Song, Xiaoping, & Ren, Yang. Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb1-xGdxFe2 system.  United States.  https://doi.org/10.1063/1.4916652

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                    Adil, Murtaza, Yang, Sen, Mi, Meng, Zhou, Chao, Wang, Jieqiong, Zhang, Rui, Liao, Xiaoqi, Wang, Yu, Ren, Xiaobing, Song, Xiaoping, and Ren, Yang. Tue .  
"Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb1-xGdxFe2 system".  United States.  https://doi.org/10.1063/1.4916652.  https://www.osti.gov/servlets/purl/1248372.

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@article{osti_1248372,

  title        = {Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb1-xGdxFe2 system},

  author       = {Adil, Murtaza and Yang, Sen and Mi, Meng and Zhou, Chao and Wang, Jieqiong and Zhang, Rui and Liao, Xiaoqi and Wang, Yu and Ren, Xiaobing and Song, Xiaoping and Ren, Yang},

  abstractNote = {Morphotropic phase boundary (MPB), separating two ferroic phases of different crystal symmetries, has been studied extensively for its extraordinary enhancement of piezoelectricity in ferroelectrics. Based on the same mechanism, we have designed a magnetic MPB in the pseudobinary ferromagnetic system of Tb1-xGdxFe2 and the corresponding crystal structure, magnetic properties, and magnetostriction are explored. With the synchrotron x-ray diffractometry, the structure symmetry of TbFe2-rich compositions is detected to be rhombohedral (R) and that of GdFe2-rich compositions is tetragonal (T) below Tc. With the change of concentration, the value of magnetostriction of the samples changes monotonously, while the MPB composition Tb0.1Gd0.9Fe2, which corresponds to the coexistence of R and T phases, exhibits the maximum magnetization among all available compositions and superposition of magnetostriction behaviour of R and T phases. Furthermore, our result of MPB phenomena in ferromagnets may provide an effective route to design functional magnetic materials with exotic properties.},

  doi          = {10.1063/1.4916652},

  journal      = {Applied Physics Letters},

  number       = 13,

  volume       = 106,

  place        = {United States},

  year         = {Tue Mar 31 00:00:00 EDT 2015},

  month        = {Tue Mar 31 00:00:00 EDT 2015}

}

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Title: Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb1-xGdxFe2 system

Abstract

Citation Formats

Origin of morphotropic phase boundaries in ferroelectrics journal, January 2008

Ferroelectric solid solutions with morphotropic boundaries: Vanishing polarization anisotropy, adaptive, polar glass, and two-phase states journal, June 2008

Piezoelectric Properties of Lead Zirconate‐Lead Titanate Solid‐Solution Ceramics journal, June 1954

Historical Introduction book, January 1971

High-resolution x-ray diffraction study of single crystals of lead zirconate titanate journal, July 2011

Nonmajor cubic symmetry axes of easy magnetization in rare-earth-iron Laves compounds journal, May 1976

Noncubic crystallographic symmetry of a cubic ferromagnet: Simultaneous structural change at the ferromagnetic transition journal, January 2008

Inverse effect of morphotropic phase boundary on the magnetostriction of ferromagnetic Tb 1 − x Gd x Co 2 journal, March 2014

Modern magnetostrictive materials: classical and nonclassical alloys conference, July 2002

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution journal, April 1999

59 Co NMR Study of Spin Orientation in Pseudobinary Tb 1- x Dy x Co 2 journal, April 1982

Nanodomain structure of Pb [ Zr 1 − x Ti x ] O 3 at its morphotropic phase boundary: Investigations from local to average structure journal, May 2007

Large Piezoelectric Effect in Pb-Free Ceramics journal, December 2009

Magnetostrictive Rare Earth-Fe2 Compounds book, January 1988

Magnetic properties and spontaneous distortion in TbCo 2 journal, May 1979

Phase Transformations in Smart Materials journal, November 1998

Large piezoelectric effect in Pb-free Ba(Ti,Sn)O 3 -x(Ba,Ca)TiO 3 ceramics journal, September 2011

Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of PbZr 0.52 Ti 0.48 O 3 journal, April 2000

Morphotropic phase boundary in Pb (Mg13Nb23) O3-PbTiO3 system journal, July 1989

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Ground state of (Pb 0.94 Sr 0.06 )(Zr 0.530 Ti 0.470 )O 3 in the morphotropic phase boundary region: Evidence for a monoclinic C c space group journal, October 2011

Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries journal, November 2003

Spin-orientation diagram of the pseudobinary Tb 1 − x Dy x Fe 2 Laves compounds journal, April 1977

Magnetic anisotropy and hyperfine interactions in Ce Fe 2 , Gd Fe 2 , and Lu Fe 2 journal, September 1974

Structural Heterogeneity and Diffuse Scattering in Morphotropic Lead Zirconate-Titanate Single Crystals journal, August 2012

Triple-point-type morphotropic phase boundary based large piezoelectric Pb-free material—Ba(Ti 0.8 Hf 0.2 )O 3 -(Ba 0.7 Ca 0.3 )TiO 3 journal, May 2012

Effects of tricritical points and morphotropic phase boundaries on the piezoelectric properties of ferroelectrics journal, May 2011

A morphotropic phase boundary system based on polarization rotation and polarization extension journal, August 2010

Title: Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb_1-xGd_xFe₂ system

Origin of morphotropic phase boundaries in ferroelectrics
journal, January 2008

Ferroelectric solid solutions with morphotropic boundaries: Vanishing polarization anisotropy, adaptive, polar glass, and two-phase states
journal, June 2008

Piezoelectric Properties of Lead Zirconate‐Lead Titanate Solid‐Solution Ceramics
journal, June 1954

Historical Introduction
book, January 1971

High-resolution x-ray diffraction study of single crystals of lead zirconate titanate
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Nonmajor cubic symmetry axes of easy magnetization in rare-earth-iron Laves compounds
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Noncubic crystallographic symmetry of a cubic ferromagnet: Simultaneous structural change at the ferromagnetic transition
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Inverse effect of morphotropic phase boundary on the magnetostriction of ferromagnetic Tb $_{1 - x}$ Gd $_{x}$ Co $_{2}$
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Modern magnetostrictive materials: classical and nonclassical alloys
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A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
journal, April 1999

⁵⁹ Co NMR Study of Spin Orientation in Pseudobinary Tb _{1- x} Dy _x Co ₂
journal, April 1982

Nanodomain structure of $Pb [{Zr}_{1 - x} {Ti}_{x}] O_{3}$ at its morphotropic phase boundary: Investigations from local to average structure
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Large Piezoelectric Effect in Pb-Free Ceramics
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Magnetostrictive Rare Earth-Fe2 Compounds
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Magnetic properties and spontaneous distortion in TbCo ₂
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Phase Transformations in Smart Materials
journal, November 1998

Large piezoelectric effect in Pb-free Ba(Ti,Sn)O ₃ -x(Ba,Ca)TiO ₃ ceramics
journal, September 2011

Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of ${PbZr}_{0.52} {Ti}_{0.48} O_{3}$
journal, April 2000

Morphotropic phase boundary in Pb (Mg13Nb23) O3-PbTiO3 system
journal, July 1989

Phase coexistence and ferroelastic texture in high strain (1−x)Ba(Zr _0.2 Ti _0.8 )O ₃ –x(Ba _0.7 Ca _0.3 )TiO ₃ piezoceramics
journal, June 2012

Ground state of (Pb $_{0.94}$ Sr $_{0.06}$ )(Zr $_{0.530}$ Ti $_{0.470}$ )O $_{3}$ in the morphotropic phase boundary region: Evidence for a monoclinic $C c$ space group
journal, October 2011

Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries
journal, November 2003

Spin-orientation diagram of the pseudobinary ${Tb}_{1 - x} {Dy}_{x} {Fe}_{2}$ Laves compounds
journal, April 1977

Magnetic anisotropy and hyperfine interactions in Ce ${Fe}_{2}$ , Gd ${Fe}_{2}$ , and Lu ${Fe}_{2}$
journal, September 1974

Structural Heterogeneity and Diffuse Scattering in Morphotropic Lead Zirconate-Titanate Single Crystals
journal, August 2012

Triple-point-type morphotropic phase boundary based large piezoelectric Pb-free material—Ba(Ti _0.8 Hf _0.2 )O ₃ -(Ba _0.7 Ca _0.3 )TiO ₃
journal, May 2012

Effects of tricritical points and morphotropic phase boundaries on the piezoelectric properties of ferroelectrics
journal, May 2011

A morphotropic phase boundary system based on polarization rotation and polarization extension
journal, August 2010