Small nickel nanoparticle arrays from long chain imidazolium ionic liquids
Abstract
A series of six long chain alkyl mono- and bi-cationic imidazolium based salts with bis(trifluoromethylsulfonyl)imide (NTf2–) as the anion were synthesized and characterized. Single crystal structure of 1-methyl-3-octadecylimidazolium bis(trifluoromethylsulfonyl)imide could be obtained by X-ray analysis. All these long chain alkyl imidazolium based ILs were applied in the synthesis of nickel nanoparticles via chemical decomposition of an organometallic precursor of nickel. In these media, spontaneous decomposition of Ni(COD)2 (COD = 1,5-cyclooctadiene) in the absence of H2 occurred giving small NPs (≤4 nm) with narrow size distributions. Interestingly, formation of regularly interspaced NP arrays was also observed in long chain ILs. Lastly, such array formation could be interesting for potential applications such as carbon nanotube growth.
- Authors:
-
- Ruhr-Univ. Bochum, Bochum (Germany)
- Univ. de Lyon, Villeurbanne (France)
- Ruhr-Univ. Bochum, Bochum (Germany); Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1240909
- Report Number(s):
- IS-J-8295
Journal ID: ISSN 2040-3364; NANOHL
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Yang, Mei, Campbell, Paul S., Santini, Catherine C., and Mudring, Anja -Verena. Small nickel nanoparticle arrays from long chain imidazolium ionic liquids. United States: N. p., 2013.
Web. doi:10.1039/c3nr05048c.
Yang, Mei, Campbell, Paul S., Santini, Catherine C., & Mudring, Anja -Verena. Small nickel nanoparticle arrays from long chain imidazolium ionic liquids. United States. https://doi.org/10.1039/c3nr05048c
Yang, Mei, Campbell, Paul S., Santini, Catherine C., and Mudring, Anja -Verena. Fri .
"Small nickel nanoparticle arrays from long chain imidazolium ionic liquids". United States. https://doi.org/10.1039/c3nr05048c. https://www.osti.gov/servlets/purl/1240909.
@article{osti_1240909,
title = {Small nickel nanoparticle arrays from long chain imidazolium ionic liquids},
author = {Yang, Mei and Campbell, Paul S. and Santini, Catherine C. and Mudring, Anja -Verena},
abstractNote = {A series of six long chain alkyl mono- and bi-cationic imidazolium based salts with bis(trifluoromethylsulfonyl)imide (NTf2–) as the anion were synthesized and characterized. Single crystal structure of 1-methyl-3-octadecylimidazolium bis(trifluoromethylsulfonyl)imide could be obtained by X-ray analysis. All these long chain alkyl imidazolium based ILs were applied in the synthesis of nickel nanoparticles via chemical decomposition of an organometallic precursor of nickel. In these media, spontaneous decomposition of Ni(COD)2 (COD = 1,5-cyclooctadiene) in the absence of H2 occurred giving small NPs (≤4 nm) with narrow size distributions. Interestingly, formation of regularly interspaced NP arrays was also observed in long chain ILs. Lastly, such array formation could be interesting for potential applications such as carbon nanotube growth.},
doi = {10.1039/c3nr05048c},
journal = {Nanoscale},
number = 6,
volume = 6,
place = {United States},
year = {Fri Nov 08 00:00:00 EST 2013},
month = {Fri Nov 08 00:00:00 EST 2013}
}
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Works referencing / citing this record:
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