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Title: The adsorption of rare earth ions using carbonized polydopamine nano shells

Abstract

Herein we reported the structure effects of carbon nano-shells prepared by the carbonization of polydopamine for the adsorption of rare earth elements (REEs) for the first time. Solid carbon spheres, 60 nm carbon shells and 500 nm carbon shells were prepared and evaluated for adsorption and desorption of REEs. The adsorption performance of carbon nano-shells for REEs was far superior to the solid carbon spheres. In addition, the effect of acidity on the adsorption and desorption properties was discussed. The good adsorption performance of the carbon nano-shells could be attributed to their pore structure, specific surface area, and the presence of both amine and carbonyl groups from the grafted dopamine.

Authors:
 [1];  [2];  [2];  [3];  [2];  [2];  [3]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Chinese Academy of Sciences (CAS), Xiamen (China)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1240515
Alternate Identifier(s):
OSTI ID: 1335332
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Rare Earths
Additional Journal Information:
Journal Volume: 34; Journal Issue: 1; Journal ID: ISSN 1002-0721
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
Carbon shell; Rare earth elements; and adsorption; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; carbon shells; rare earths; adsorption; separation; HIERARCHICALLY IMPRINTED SORBENTS; METAL-IONS; MESOPOROUS SILICA; LIQUID-EXTRACTION; AQUEOUS-SOLUTIONS; RESIN; CHROMATOGRAPHY; COMPOSITE; DOPAMINE

Citation Formats

Sun, Xiaoqi, Luo, Huimin, Mahurin, Shannon Mark, Dai, Sheng, Liu, Rui, Hou, Xisen, and Dai, Sheng. The adsorption of rare earth ions using carbonized polydopamine nano shells. United States: N. p., 2016. Web. doi:10.1016/S1002-0721(14)60582-2.
Sun, Xiaoqi, Luo, Huimin, Mahurin, Shannon Mark, Dai, Sheng, Liu, Rui, Hou, Xisen, & Dai, Sheng. The adsorption of rare earth ions using carbonized polydopamine nano shells. United States. https://doi.org/10.1016/S1002-0721(14)60582-2
Sun, Xiaoqi, Luo, Huimin, Mahurin, Shannon Mark, Dai, Sheng, Liu, Rui, Hou, Xisen, and Dai, Sheng. Thu . "The adsorption of rare earth ions using carbonized polydopamine nano shells". United States. https://doi.org/10.1016/S1002-0721(14)60582-2. https://www.osti.gov/servlets/purl/1240515.
@article{osti_1240515,
title = {The adsorption of rare earth ions using carbonized polydopamine nano shells},
author = {Sun, Xiaoqi and Luo, Huimin and Mahurin, Shannon Mark and Dai, Sheng and Liu, Rui and Hou, Xisen and Dai, Sheng},
abstractNote = {Herein we reported the structure effects of carbon nano-shells prepared by the carbonization of polydopamine for the adsorption of rare earth elements (REEs) for the first time. Solid carbon spheres, 60 nm carbon shells and 500 nm carbon shells were prepared and evaluated for adsorption and desorption of REEs. The adsorption performance of carbon nano-shells for REEs was far superior to the solid carbon spheres. In addition, the effect of acidity on the adsorption and desorption properties was discussed. The good adsorption performance of the carbon nano-shells could be attributed to their pore structure, specific surface area, and the presence of both amine and carbonyl groups from the grafted dopamine.},
doi = {10.1016/S1002-0721(14)60582-2},
journal = {Journal of Rare Earths},
number = 1,
volume = 34,
place = {United States},
year = {Thu Jan 07 00:00:00 EST 2016},
month = {Thu Jan 07 00:00:00 EST 2016}
}

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