Thermal stability of poly(ethylene-co-vinyl acetate) based materials
Abstract
The thermal stability properties of poly (ethylene-co-vinyl acetate) composites have been studied in support of our core programmes in materials qualification and life assessment. The material is used as a binder phase for boron particles in highly filled (70 wt %) composites. Our studies show that the uncured resin readily accumulates acetic acid through hydrolysis of the pendent acetate groups which alters the acidity (pH) of the material. Thermal desorption studies in combination with gas-chromatography-mass spectrometry show that the resin readily evolves acetic acid when thermally aged to temperatures up to 75°C. Gel Permeation Chromatography (GPC) suggests that thermal ageing induces a gradual reduction in resin molecular weight and confirms the susceptibility of the material to chain scission. Heating at elevated temperatures in excess of 300oC is required to induce significant changes in the carbon skeleton through deacetylation and dehydration processes and the production of unsaturated main chain double bonds. Overall, the mechanical response of these filled composites are found to be relatively complex with the extent of polymer-filler interactions possibly playing an important role in determining key engineering properties. Mechanical property studies confirm a small but significant decrease in modulus presumably linked to thermally induced chain scission of themore »
- Authors:
-
- Atomic Weapons Establishment (AWE), Reading (United Kingdom)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1240064
- Report Number(s):
- LLNL-JRNL-607753
Journal ID: ISSN 0142-9418
- Grant/Contract Number:
- AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polymer Testing
- Additional Journal Information:
- Journal Volume: 32; Journal Issue: 4; Journal ID: ISSN 0142-9418
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Characterisation; thermal stability; Poly (ethylene-co-vinyl acetate)
Citation Formats
Patel, Mogon, Pitts, Simon, Beavis, Peter, Robinson, Mathew, Morrell, Paul, Khan, Niaz, Khan, Imran, Pockett, Nicola, Letant, Sonia, Von White, Gregory, and Labouriau, Andrea. Thermal stability of poly(ethylene-co-vinyl acetate) based materials. United States: N. p., 2013.
Web. doi:10.1016/j.polymertesting.2013.03.014.
Patel, Mogon, Pitts, Simon, Beavis, Peter, Robinson, Mathew, Morrell, Paul, Khan, Niaz, Khan, Imran, Pockett, Nicola, Letant, Sonia, Von White, Gregory, & Labouriau, Andrea. Thermal stability of poly(ethylene-co-vinyl acetate) based materials. United States. https://doi.org/10.1016/j.polymertesting.2013.03.014
Patel, Mogon, Pitts, Simon, Beavis, Peter, Robinson, Mathew, Morrell, Paul, Khan, Niaz, Khan, Imran, Pockett, Nicola, Letant, Sonia, Von White, Gregory, and Labouriau, Andrea. Tue .
"Thermal stability of poly(ethylene-co-vinyl acetate) based materials". United States. https://doi.org/10.1016/j.polymertesting.2013.03.014. https://www.osti.gov/servlets/purl/1240064.
@article{osti_1240064,
title = {Thermal stability of poly(ethylene-co-vinyl acetate) based materials},
author = {Patel, Mogon and Pitts, Simon and Beavis, Peter and Robinson, Mathew and Morrell, Paul and Khan, Niaz and Khan, Imran and Pockett, Nicola and Letant, Sonia and Von White, Gregory and Labouriau, Andrea},
abstractNote = {The thermal stability properties of poly (ethylene-co-vinyl acetate) composites have been studied in support of our core programmes in materials qualification and life assessment. The material is used as a binder phase for boron particles in highly filled (70 wt %) composites. Our studies show that the uncured resin readily accumulates acetic acid through hydrolysis of the pendent acetate groups which alters the acidity (pH) of the material. Thermal desorption studies in combination with gas-chromatography-mass spectrometry show that the resin readily evolves acetic acid when thermally aged to temperatures up to 75°C. Gel Permeation Chromatography (GPC) suggests that thermal ageing induces a gradual reduction in resin molecular weight and confirms the susceptibility of the material to chain scission. Heating at elevated temperatures in excess of 300oC is required to induce significant changes in the carbon skeleton through deacetylation and dehydration processes and the production of unsaturated main chain double bonds. Overall, the mechanical response of these filled composites are found to be relatively complex with the extent of polymer-filler interactions possibly playing an important role in determining key engineering properties. Mechanical property studies confirm a small but significant decrease in modulus presumably linked to thermally induced chain scission of the EVA binder.},
doi = {10.1016/j.polymertesting.2013.03.014},
journal = {Polymer Testing},
number = 4,
volume = 32,
place = {United States},
year = {Tue Mar 26 00:00:00 EDT 2013},
month = {Tue Mar 26 00:00:00 EDT 2013}
}
Web of Science
Works referenced in this record:
Synthesis and thermal behaviour of layered silicate–EVA nanocomposites
journal, February 2001
- Zanetti, M.
- Polymer, Vol. 42, Issue 10
Aspects of the thermal oxidation, yellowing and stabilisation of ethylene vinyl acetate copolymer
journal, January 2000
- S. Allen, Norman; Edge, Michele; Rodriguez, Miguel
- Polymer Degradation and Stability, Vol. 71, Issue 1
Aspects of the thermal oxidation of ethylene vinyl acetate copolymer
journal, May 2000
- Allen, Norman S.; Edge, Michele; Rodriguez, Miguel
- Polymer Degradation and Stability, Vol. 68, Issue 3
The thermal degradation of poly(vinyl acetate) and poly(ethylene-co-vinyl acetate), Part I: Experimental study of the degradation mechanism
journal, April 2008
- Rimez, B.; Rahier, H.; Van Assche, G.
- Polymer Degradation and Stability, Vol. 93, Issue 4
Surface modifications on eva treated with sulphuric acid
journal, June 2003
- Martínez-García, Asunción; Sánchez-Reche, Ana; Martín-Martínez, José Miguel
- The Journal of Adhesion, Vol. 79, Issue 6
The thermal degradation of polyvinyl acetate. I. Products and reaction mechanism at low temperatures
journal, January 1952
- Grassie, N.
- Transactions of the Faraday Society, Vol. 48
Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy
journal, April 2013
- Patel, Mogon; Bowditch, Martin; Jones, Ben
- Polymer Testing, Vol. 32, Issue 2
Application of density functional theory to the investigation of polymer degradation: Example of cross-linked ethylene–vinyl acetate–vinyl alcohol (EVA-OH) terpolymer de-acetylation
journal, November 2011
- Létant, Sonia E.; Plant, David F.; Wilson, Thomas S.
- Polymer Degradation and Stability, Vol. 96, Issue 11
UV aging behaviour of ethylene-vinyl acetate copolymers (EVA) with different vinyl acetate contents
journal, May 2010
- Jin, Jing; Chen, Shuangjun; Zhang, Jun
- Polymer Degradation and Stability, Vol. 95, Issue 5
Mechanism of thermal degradation of poly(vinyl acetate)
journal, August 1975
- Bataille, P.; Van, B. T.
- Journal of Thermal Analysis, Vol. 8, Issue 1
A thermal degradation mechanism of polyvinyl alcohol/silica nanocomposites
journal, June 2007
- Peng, Zheng; Kong, Ling Xue
- Polymer Degradation and Stability, Vol. 92, Issue 6
Works referencing / citing this record:
Multi angle laser light scattering evaluation of field exposed thermoplastic photovoltaic encapsulant materials
journal, January 2016
- Kempe, Michael D.; Miller, David C.; Wohlgemuth, John H.
- Energy Science & Engineering, Vol. 4, Issue 1
Characterization of Thermo-Physical Properties of EVA/ATH: Application to Gasification Experiments and Pyrolysis Modeling
journal, November 2015
- Girardin, Bertrand; Fontaine, Gaëlle; Duquesne, Sophie
- Materials, Vol. 8, Issue 11