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Title: The effects of physical and chemical preprocessing on the flowability of corn stover

Abstract

Continuous and reliable feeding of biomass is essential for successful biofuel production. However, the challenges associated with biomass solids handling are commonly overlooked. In this study, we examine the effects of preprocessing (particle size reduction, moisture content, chemical additives, etc.) on the flow properties of corn stover. Compressibility, flow properties (interparticle friction, cohesion, unconfined yield stress, etc.), and wall friction were examined for five corn stover samples: ground, milled (dry and wet), acid impregnated, and deacetylated. The ground corn stover was found to be the least compressible and most flowable material. The water and acid impregnated stovers had similar compressibilities. Yet, the wet corn stover was less flowable than the acid impregnated sample, which displayed a flow index equivalent to the dry, milled corn stover. The deacetylated stover, on the other hand, was the most compressible and least flowable examined material. However, all of the tested stover samples had internal friction angles >30°, which could present additional feeding and handling challenges. All of the ''wetted'' materials (water, acid, and deacetylated) displayed reduced flowabilities (excluding the acid impregnated sample), and enhanced compressibilities and wall friction angles, indicating the potential for added handling issues; which was corroborated via theoretical hopper design calculations.more » All of the ''wetted'' corn stovers require larger theoretical hopper outlet diameters and steeper hopper walls than the examined ''dry'' stovers.« less

Authors:
 [1];  [1];  [1];  [1]
  1. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)
OSTI Identifier:
1236159
Alternate Identifier(s):
OSTI ID: 1398004
Report Number(s):
NREL/JA-5100-64986
Journal ID: ISSN 0961-9534
Grant/Contract Number:  
AC36-08GO28308; AC36-08-GO28308
Resource Type:
Accepted Manuscript
Journal Name:
Biomass and Bioenergy
Additional Journal Information:
Journal Volume: 85; Journal Issue: C; Journal ID: ISSN 0961-9534
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; biomass; feedstock; flowability; shear; powder rheometer; compressibility; yield stress; friction; hopper design

Citation Formats

Crawford, Nathan C., Nagle, Nick, Sievers, David A., and Stickel, Jonathan J. The effects of physical and chemical preprocessing on the flowability of corn stover. United States: N. p., 2015. Web. doi:10.1016/j.biombioe.2015.12.015.
Crawford, Nathan C., Nagle, Nick, Sievers, David A., & Stickel, Jonathan J. The effects of physical and chemical preprocessing on the flowability of corn stover. United States. https://doi.org/10.1016/j.biombioe.2015.12.015
Crawford, Nathan C., Nagle, Nick, Sievers, David A., and Stickel, Jonathan J. Sun . "The effects of physical and chemical preprocessing on the flowability of corn stover". United States. https://doi.org/10.1016/j.biombioe.2015.12.015. https://www.osti.gov/servlets/purl/1236159.
@article{osti_1236159,
title = {The effects of physical and chemical preprocessing on the flowability of corn stover},
author = {Crawford, Nathan C. and Nagle, Nick and Sievers, David A. and Stickel, Jonathan J.},
abstractNote = {Continuous and reliable feeding of biomass is essential for successful biofuel production. However, the challenges associated with biomass solids handling are commonly overlooked. In this study, we examine the effects of preprocessing (particle size reduction, moisture content, chemical additives, etc.) on the flow properties of corn stover. Compressibility, flow properties (interparticle friction, cohesion, unconfined yield stress, etc.), and wall friction were examined for five corn stover samples: ground, milled (dry and wet), acid impregnated, and deacetylated. The ground corn stover was found to be the least compressible and most flowable material. The water and acid impregnated stovers had similar compressibilities. Yet, the wet corn stover was less flowable than the acid impregnated sample, which displayed a flow index equivalent to the dry, milled corn stover. The deacetylated stover, on the other hand, was the most compressible and least flowable examined material. However, all of the tested stover samples had internal friction angles >30°, which could present additional feeding and handling challenges. All of the ''wetted'' materials (water, acid, and deacetylated) displayed reduced flowabilities (excluding the acid impregnated sample), and enhanced compressibilities and wall friction angles, indicating the potential for added handling issues; which was corroborated via theoretical hopper design calculations. All of the ''wetted'' corn stovers require larger theoretical hopper outlet diameters and steeper hopper walls than the examined ''dry'' stovers.},
doi = {10.1016/j.biombioe.2015.12.015},
journal = {Biomass and Bioenergy},
number = C,
volume = 85,
place = {United States},
year = {Sun Dec 20 00:00:00 EST 2015},
month = {Sun Dec 20 00:00:00 EST 2015}
}

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Cited by: 32 works
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Works referenced in this record:

IEA biomass thermal gasification project
journal, January 1992


Ancillary equipment for biomass gasification
journal, August 2002


Biomass feeding for thermochemical reactors
journal, October 2012

  • Dai, Jianjun; Cui, Heping; Grace, John R.
  • Progress in Energy and Combustion Science, Vol. 38, Issue 5
  • DOI: 10.1016/j.pecs.2012.04.002

Flow and Physical Properties of Switchgrass, Peanut Hull, and Poultry Litter
journal, January 2006

  • Fasina, O. O.
  • Transactions of the ASABE, Vol. 49, Issue 3, p. 721-728
  • DOI: 10.13031/2013.20470

Flowability parameters for chopped switchgrass, wheat straw and corn stover
journal, July 2009


The angle of repose of bulk corn stover particles
journal, October 2008


Rheological modification of corn stover biomass at high solids concentrations
journal, May 2012

  • Samaniuk, Joseph R.; Scott, C. Tim; Root, Thatcher W.
  • Journal of Rheology, Vol. 56, Issue 3
  • DOI: 10.1122/1.3702101

Handling behavior of two milled biomass: SRF poplar and corn stover
journal, August 2013


Flow properties and arching behavior of biomass particulate solids
journal, February 2013


Evaluating the pelletization of “pure” and blended lignocellulosic biomass feedstocks
journal, December 2015


Dilute-Sulfuric Acid Pretreatment of Corn Stover in Pilot-Scale Reactor: Investigation of Yields, Kinetics, and Enzymatic Digestibilities of Solids
journal, January 2003

  • Schell, Daniel J.; Farmer, Jody; Newman, Millie
  • Applied Biochemistry and Biotechnology, Vol. 105, Issue 1-3, p. 69-86
  • DOI: 10.1385/ABAB:105:1-3:69

Effects of Temperature and Moisture on Dilute-Acid Steam Explosion Pretreatment of Corn Stover and Cellulase Enzyme Digestibility
journal, January 2003

  • Tucker, Melvin P.; Kim, Kyoung H.; Newman, Mildred M.
  • Applied Biochemistry and Biotechnology, Vol. 105, Issue 1-3
  • DOI: 10.1385/ABAB:105:1-3:165

Measuring shear properties and normal stresses generated within a rotational shear cell for consolidated and non-consolidated powders
journal, March 2009


Development of an international standard for shear testing
journal, September 2006


Improved Xylan Hydrolysis of Corn Stover by Deacetylation with High Solids Dilute Acid Pretreatment
journal, December 2011

  • Chen, Xiaowen; Shekiro, Joseph; Elander, Rick
  • Industrial & Engineering Chemistry Research, Vol. 51, Issue 1
  • DOI: 10.1021/ie201493g

Flow properties of three fuel powders
journal, August 2012


Evaluation of dilute acid and alkaline pretreatments, enzymatic hydrolysis and fermentation of napiergrass for fuel ethanol production
journal, March 2015


Biomass pretreatment: Fundamentals toward application
journal, November 2011


Progress in bioethanol processing
journal, October 2008

  • Balat, Mustafa; Balat, Havva; Öz, Cahide
  • Progress in Energy and Combustion Science, Vol. 34, Issue 5
  • DOI: 10.1016/j.pecs.2007.11.001

Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production
journal, April 2009

  • Kumar, Parveen; Barrett, Diane M.; Delwiche, Michael J.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 8, p. 3713-3729
  • DOI: 10.1021/ie801542g

Grinding performance and physical properties of wheat and barley straws, corn stover and switchgrass
journal, October 2004


Flowability and handling characteristics of bulk solids and powders – a review with implications for DDGS
journal, December 2008


Flow property measurement of food powders and sensitivity of Jenike’s hopper design methodology to the measured values
journal, February 2004


Works referencing / citing this record:

Microscopy Applied In Biomass Characterization
book, January 2016

  • Valdez-Vazquez, Idania; Quiroz-Figueroa, Francisco R.; Carrillo-Reyes, Julián
  • Analytical Techniques and Methods for Biomass
  • DOI: 10.1007/978-3-319-41414-0_7