Guest-induced emergent properties in Metal–Organic Frameworks
Abstract
Metal–Organic frameworks (MOFs) are crystalline nanoporous materials comprised of organic electron donors linked to metal ions by strong coordination bonds. Applications such as gas storage and separations are currently receiving considerable attention, but if the unique properties of MOFs could be extended to electronics, magnetics, and photonics, the impact on material science would greatly increase. Recently, we obtained “emergent properties,” such as electronic conductivity and energy transfer, by infiltrating MOF pores with “guest” molecules that interact with the framework electronic structure. In this Perspective, we define a path to emergent properties based on the Guest@MOF concept, using zinc-carboxylate and copper-paddlewheel MOFs for illustration. Energy transfer and light harvesting are discussed for zinc carboxylate frameworks infiltrated with triplet-scavenging organometallic compounds and thiophene- and fullerene-infiltrated MOF-177. In addition, we discuss the mechanism of charge transport in TCNQ-infiltrated HKUST-1, the first MOF with electrical conductivity approaching conducting organic polymers. Lastly, these examples show that guest molecules in MOF pores should be considered not merely as impurities or analytes to be sensed but also as an important aspect of rational design.
- Authors:
-
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Stanford Univ., Stanford, CA (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1235927
- Report Number(s):
- SAND-2015-20820J
Journal ID: ISSN 1948-7185; 558248
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry Letters
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 7; Journal ID: ISSN 1948-7185
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Allendorf, Mark D., Foster, Michael E., Léonard, François, Stavila, Vitalie, Feng, Patrick L., Doty, F. Patrick, Leong, Kirsty, Ma, Eric Yue, Johnston, Scott R., Talin, A. Alec, and Shen, Zhi -Xun. Guest-induced emergent properties in Metal–Organic Frameworks. United States: N. p., 2015.
Web. doi:10.1021/jz5026883.
Allendorf, Mark D., Foster, Michael E., Léonard, François, Stavila, Vitalie, Feng, Patrick L., Doty, F. Patrick, Leong, Kirsty, Ma, Eric Yue, Johnston, Scott R., Talin, A. Alec, & Shen, Zhi -Xun. Guest-induced emergent properties in Metal–Organic Frameworks. United States. https://doi.org/10.1021/jz5026883
Allendorf, Mark D., Foster, Michael E., Léonard, François, Stavila, Vitalie, Feng, Patrick L., Doty, F. Patrick, Leong, Kirsty, Ma, Eric Yue, Johnston, Scott R., Talin, A. Alec, and Shen, Zhi -Xun. Thu .
"Guest-induced emergent properties in Metal–Organic Frameworks". United States. https://doi.org/10.1021/jz5026883. https://www.osti.gov/servlets/purl/1235927.
@article{osti_1235927,
title = {Guest-induced emergent properties in Metal–Organic Frameworks},
author = {Allendorf, Mark D. and Foster, Michael E. and Léonard, François and Stavila, Vitalie and Feng, Patrick L. and Doty, F. Patrick and Leong, Kirsty and Ma, Eric Yue and Johnston, Scott R. and Talin, A. Alec and Shen, Zhi -Xun},
abstractNote = {Metal–Organic frameworks (MOFs) are crystalline nanoporous materials comprised of organic electron donors linked to metal ions by strong coordination bonds. Applications such as gas storage and separations are currently receiving considerable attention, but if the unique properties of MOFs could be extended to electronics, magnetics, and photonics, the impact on material science would greatly increase. Recently, we obtained “emergent properties,” such as electronic conductivity and energy transfer, by infiltrating MOF pores with “guest” molecules that interact with the framework electronic structure. In this Perspective, we define a path to emergent properties based on the Guest@MOF concept, using zinc-carboxylate and copper-paddlewheel MOFs for illustration. Energy transfer and light harvesting are discussed for zinc carboxylate frameworks infiltrated with triplet-scavenging organometallic compounds and thiophene- and fullerene-infiltrated MOF-177. In addition, we discuss the mechanism of charge transport in TCNQ-infiltrated HKUST-1, the first MOF with electrical conductivity approaching conducting organic polymers. Lastly, these examples show that guest molecules in MOF pores should be considered not merely as impurities or analytes to be sensed but also as an important aspect of rational design.},
doi = {10.1021/jz5026883},
journal = {Journal of Physical Chemistry Letters},
number = 7,
volume = 6,
place = {United States},
year = {Thu Mar 19 00:00:00 EDT 2015},
month = {Thu Mar 19 00:00:00 EDT 2015}
}
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