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Title: Simple, benign, aqueous-based amination of polycarbonate surfaces

Abstract

Here we report a simple, safe, environmentally-friendly aqueous method that uses diamines to functionalize a polycarbonate surface with amino groups. We demonstrate the ability of this facile method to serve as a foundation upon which other functionalities may be attached, including anti-fouling coatings and oriented membrane proteins. The use of water as the solvent for the functionalization ensures that solvent induced swelling does not affect the optical or mechanical properties of the polycarbonate.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1]
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  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1235260
Report Number(s):
SAND-2014-17759J
Journal ID: ISSN 1944-8244; 537562
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Volume: 7; Journal Issue: 10; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

VanDelinder, Virginia, Wheeler, David R., Small, Leo J., Brumbach, Michael T., Spoerke, Erik D., Henderson, Ian, and Bachand, George D. Simple, benign, aqueous-based amination of polycarbonate surfaces. United States: N. p., 2015. Web. doi:10.1021/am508797h.
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VanDelinder, Virginia, Wheeler, David R., Small, Leo J., Brumbach, Michael T., Spoerke, Erik D., Henderson, Ian, & Bachand, George D. Simple, benign, aqueous-based amination of polycarbonate surfaces. United States. https://doi.org/10.1021/am508797h
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VanDelinder, Virginia, Wheeler, David R., Small, Leo J., Brumbach, Michael T., Spoerke, Erik D., Henderson, Ian, and Bachand, George D. Wed . "Simple, benign, aqueous-based amination of polycarbonate surfaces". United States. https://doi.org/10.1021/am508797h. https://www.osti.gov/servlets/purl/1235260.
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@article{osti_1235260,
title = {Simple, benign, aqueous-based amination of polycarbonate surfaces},
author = {VanDelinder, Virginia and Wheeler, David R. and Small, Leo J. and Brumbach, Michael T. and Spoerke, Erik D. and Henderson, Ian and Bachand, George D.},
abstractNote = {Here we report a simple, safe, environmentally-friendly aqueous method that uses diamines to functionalize a polycarbonate surface with amino groups. We demonstrate the ability of this facile method to serve as a foundation upon which other functionalities may be attached, including anti-fouling coatings and oriented membrane proteins. The use of water as the solvent for the functionalization ensures that solvent induced swelling does not affect the optical or mechanical properties of the polycarbonate.},
doi = {10.1021/am508797h},
journal = {ACS Applied Materials and Interfaces},
number = 10,
volume = 7,
place = {United States},
year = {Wed Mar 18 00:00:00 EDT 2015},
month = {Wed Mar 18 00:00:00 EDT 2015}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1021/am508797h
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Works referenced in this record:

DNA Detection on Plastic:  Surface Activation Protocol To Convert Polycarbonate Substrates to Biochip Platforms
journal, January 2007

  • Li, Yunchao; Wang, Zhen; Ou, Lily M. L.
  • Analytical Chemistry, Vol. 79, Issue 2
  • DOI: 10.1021/ac061134j

Amination of Polycarbonate Surface and Its Application for Cell Attachment
journal, January 1999

  • Chang, Shwu Jen; Kuo, Shyh Ming; Lan, Jenq Wen
  • Artificial Cells, Blood Substitutes, and Biotechnology, Vol. 27, Issue 3
  • DOI: 10.3109/10731199909117696

Molecular screening on a compact disc
journal, January 2003

  • La Clair, James J.; Burkart, Michael D.
  • Organic & Biomolecular Chemistry, Vol. 1, Issue 18
  • DOI: 10.1039/b306391g

Heat-mediated enzyme-linked immunosorbent assay procedure on a photoactivated surface
journal, October 2004

  • Bora, Utpal; Kannan, Krishnamoorthy; Nahar, Pradip
  • Journal of Immunological Methods, Vol. 293, Issue 1-2
  • DOI: 10.1016/j.jim.2004.06.023

Photochemical activation of a polycarbonate surface for covalent immobilization of a protein ligand
journal, October 2006

Light-Induced Activation of an Inert Surface for Covalent Immobilization of a Protein Ligand
journal, July 2001

  • Nahar, Pradip; Wali, Nalini Moza; Gandhi, R. P.
  • Analytical Biochemistry, Vol. 294, Issue 2
  • DOI: 10.1006/abio.2001.5168

Functionalization of polycarbonate with proteins; open-tubular enzymatic microreactors
journal, January 2012

  • Ogończyk, D.; Jankowski, P.; Garstecki, P.
  • Lab on a Chip, Vol. 12, Issue 15
  • DOI: 10.1039/c2lc40204a

Chemical Derivatization of Compact Disc Polycarbonate Surfaces for SNPs detection
journal, February 2008

  • Bañuls, María-José; García-Piñón, Francisco; Puchades, Rosa
  • Bioconjugate Chemistry, Vol. 19, Issue 3
  • DOI: 10.1021/bc7003457

Development of Hapten-Linked Microimmunoassays on Polycarbonate Discs
journal, February 2010

  • Tamarit-López, Jesús; Morais, Sergi; Bañuls, María-José
  • Analytical Chemistry, Vol. 82, Issue 5
  • DOI: 10.1021/ac902706t

Highly sensitive detection of Salmonella typhi using surface aminated polycarbonate membrane enhanced-ELISA
journal, January 2012

  • Jain, Swati; Chattopadhyay, Sruti; Jackeray, Richa
  • Biosensors and Bioelectronics, Vol. 31, Issue 1
  • DOI: 10.1016/j.bios.2011.09.031

Surface Modification and Characterization of Polycarbonate Microdevices for Capture of Circulating Biomarkers, Both in Vitro and in Vivo
journal, October 2013

  • Yeow, Bernard; Coffey, Jacob W.; Muller, David A.
  • Analytical Chemistry, Vol. 85, Issue 21, p. 10196-10204
  • DOI: 10.1021/ac402942x

Calculations of electron inelastic mean free paths. V. Data for 14 organic compounds over the 50-2000 eV range
journal, March 1994

  • Tanuma, S.; Powell, C. J.; Penn, D. R.
  • Surface and Interface Analysis, Vol. 21, Issue 3
  • DOI: 10.1002/sia.740210302

Polycarbonate Spin Cast Films by XPS
journal, January 1999

  • Burrell, Michael C.; Chera, John J.
  • Surface Science Spectra, Vol. 6, Issue 1
  • DOI: 10.1116/1.1247900

Analysis of Polycarbonate (PC) by XPS
journal, April 1999

  • Lannon, John M.; Meng, Qingru
  • Surface Science Spectra, Vol. 6, Issue 2
  • DOI: 10.1116/1.1247901

Reactions of Surface Amines with Heterobifunctional Cross-Linkers Bearing Both Succinimidyl Ester and Maleimide for Grafting Biomolecules
journal, October 2004

  • Xiao, Shou-Jun; Brunner, Samuel; Wieland, Marco
  • The Journal of Physical Chemistry B, Vol. 108, Issue 42
  • DOI: 10.1021/jp047726s

XPS and NEXAFS studies of aliphatic and aromatic amine species on functionalized surfaces
journal, September 2009

Surface modification of polycarbonate and polyethylene naphtalate foils by UV-ozone treatment and μPlasma printing
journal, January 2014

Combined XPS and TPD study of oxygen-functionalized carbon nanofibers grown on sintered metal fibers
journal, May 2010

A Reinvestigation of the Binding Energy Versus Atomic Charge Relation for Oxygen From X-Ray Photoelectron Spectroscopy
journal, January 1987

Structure of tert -Butyl Carbamate-Terminated Thiol Chemisorbed to Gold
journal, August 2005

  • Petoral, Rodrigo M.; Uvdal, Kajsa
  • The Journal of Physical Chemistry B, Vol. 109, Issue 33
  • DOI: 10.1021/jp0526445

Activation of carbon dioxide leading to a chemisorbed carbamate species at a Cu(100) surface
journal, January 1989

  • Carley, A. F.; Davies, P. R.; Roberts, M. W.
  • Journal of the Chemical Society, Chemical Communications, Issue 11
  • DOI: 10.1039/c39890000677

On the adsorption of proteins on solid surfaces, a common but very complicated phenomenon
journal, January 2001

  • Nakanishi, Kazuhiro; Sakiyama, Takaharu; Imamura, Koreyoshi
  • Journal of Bioscience and Bioengineering, Vol. 91, Issue 3
  • DOI: 10.1016/S1389-1723(01)80127-4

Homologous gene knockout in the archaeon Halobacterium salinarum with ura3 as a counterselectable marker: ura3-based gene knockout in H. salinarum
journal, February 2000

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    Works referencing / citing this record:

    Atmospheric pressure air plasma treatment to improve the 3D printing of polyoxymethylene
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    Polyelectrolyte layer-by-layer deposition on nanoporous supports for ion selective membranes
    journal, January 2018

    • Percival, Stephen J.; Small, Leo J.; Spoerke, Erik D.
    • RSC Advances, Vol. 8, Issue 57
    • DOI: 10.1039/c8ra05580g

    Well-Adhering, Easily Producible Photonic Reflective Coatings for Plastic Substrates
    journal, August 2018

    • Heeswijk, Ellen P. A. van; Kloos, Joey J. H.; Heer, Jos de
    • ACS Applied Materials & Interfaces, Vol. 10, Issue 35
    • DOI: 10.1021/acsami.8b11583
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