Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Hydrogenation of CO2 to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO2

Abstract

In this study, the high thermochemical stability of CO2 makes it very difficult to achieve the catalytic conversion of the molecule into alcohols or other hydrocarbon compounds, which can be used as fuels or the starting point for the generation of fine chemicals. Pure metals and bimetallic systems used for the CO2 → CH3OH conversion usually bind CO2 too weakly and, thus, show low catalytic activity. Here, we discuss a series of recent studies that illustrate the advantages of metal–oxide and metal–carbide interfaces when aiming at the conversion of CO2 into methanol. CeOx/Cu(111), Cu/CeOx/TiO2(110), and Au/CeOx/TiO2(110) exhibit an activity for the CO2 → CH3OH conversion that is 2–3 orders of magnitude higher than that of a benchmark Cu(111) catalyst. In the Cu–ceria and Au–ceria interfaces, the multifunctional combination of metal and oxide centers leads to complementary chemical properties that open active reaction pathways for methanol synthesis. Efficient catalysts are also generated after depositing Cu and Au on TiC(001). In these cases, strong metal–support interactions modify the electronic properties of the admetals and make them active for the binding of CO2 and its subsequent transformation into CH3OH at the metal–carbide interfaces.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
+ Show Author Affiliations
  1. Brookhaven National Laboratory (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1225435
Report Number(s):
BNL-108509-2015-JA
Journal ID: ISSN 2155-5435; R&D Project: CO027; KC0302010
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 5; Journal Issue: 11; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; National Synchrotron Light Source; CO2 activation; CO2 hydrogenation; methanol synthesis; reverse water-gas shift reaction; metal oxides; metal carbides; copper; gold

Citation Formats

Rodriguez, José A., Liu, Ping, Stacchiola, Dario J., Senanayake, Sanjaya D., White, Michael G., and Chen, Jingguang G. Hydrogenation of CO2 to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO2. United States: N. p., 2015. Web. doi:10.1021/acscatal.5b01755.
Copy to clipboard
Rodriguez, José A., Liu, Ping, Stacchiola, Dario J., Senanayake, Sanjaya D., White, Michael G., & Chen, Jingguang G. Hydrogenation of CO2 to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO2. United States. https://doi.org/10.1021/acscatal.5b01755
Copy to clipboard
Rodriguez, José A., Liu, Ping, Stacchiola, Dario J., Senanayake, Sanjaya D., White, Michael G., and Chen, Jingguang G. Wed . "Hydrogenation of CO2 to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO2". United States. https://doi.org/10.1021/acscatal.5b01755. https://www.osti.gov/servlets/purl/1225435.
Copy to clipboard
@article{osti_1225435,
title = {Hydrogenation of CO2 to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO2},
author = {Rodriguez, José A. and Liu, Ping and Stacchiola, Dario J. and Senanayake, Sanjaya D. and White, Michael G. and Chen, Jingguang G.},
abstractNote = {In this study, the high thermochemical stability of CO2 makes it very difficult to achieve the catalytic conversion of the molecule into alcohols or other hydrocarbon compounds, which can be used as fuels or the starting point for the generation of fine chemicals. Pure metals and bimetallic systems used for the CO2 → CH3OH conversion usually bind CO2 too weakly and, thus, show low catalytic activity. Here, we discuss a series of recent studies that illustrate the advantages of metal–oxide and metal–carbide interfaces when aiming at the conversion of CO2 into methanol. CeOx/Cu(111), Cu/CeOx/TiO2(110), and Au/CeOx/TiO2(110) exhibit an activity for the CO2 → CH3OH conversion that is 2–3 orders of magnitude higher than that of a benchmark Cu(111) catalyst. In the Cu–ceria and Au–ceria interfaces, the multifunctional combination of metal and oxide centers leads to complementary chemical properties that open active reaction pathways for methanol synthesis. Efficient catalysts are also generated after depositing Cu and Au on TiC(001). In these cases, strong metal–support interactions modify the electronic properties of the admetals and make them active for the binding of CO2 and its subsequent transformation into CH3OH at the metal–carbide interfaces.},
doi = {10.1021/acscatal.5b01755},
journal = {ACS Catalysis},
number = 11,
volume = 5,
place = {United States},
year = {Wed Sep 30 00:00:00 EDT 2015},
month = {Wed Sep 30 00:00:00 EDT 2015}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acscatal.5b01755
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 340 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Activity and Selectivity Trends in Synthesis Gas Conversion to Higher Alcohols
journal, October 2013

  • Medford, Andrew J.; Lausche, Adam C.; Abild-Pedersen, Frank
  • Topics in Catalysis, Vol. 57, Issue 1-4
  • DOI: 10.1007/s11244-013-0169-0

A quantum theory of molecular structure and its applications
journal, July 1991

High catalytic activity of Au/CeOx/TiO2(110) controlled by the nature of the mixed-metal oxide at the nanometer level
journal, March 2009

  • Park, J. B.; Graciani, J.; Evans, J.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 13
  • DOI: 10.1073/pnas.0812604106

Energy of Supported Metal Catalysts: From Single Atoms to Large Metal Nanoparticles
journal, September 2015

  • James, Trevor E.; Hemmingson, Stephanie L.; Campbell, Charles T.
  • ACS Catalysis, Vol. 5, Issue 10
  • DOI: 10.1021/acscatal.5b01372

In situ gas-phase catalytic properties of TiC-supported size-selected gold nanoparticles synthesized by diblock copolymer encapsulation
journal, December 2006

Gold, Copper, and Platinum Nanoparticles Dispersed on CeO x /TiO 2 (110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level
journal, January 2010

  • Park, Joon B.; Graciani, Jesus; Evans, Jaime
  • Journal of the American Chemical Society, Vol. 132, Issue 1
  • DOI: 10.1021/ja9087677

High Activity Carbide Supported Catalysts for Water Gas Shift
journal, March 2011

  • Schweitzer, Neil M.; Schaidle, Joshua A.; Ezekoye, Obiefune K.
  • Journal of the American Chemical Society, Vol. 133, Issue 8
  • DOI: 10.1021/ja110705a

CO2 activation and promotional effect in the oxidation of cyclic olefins over mesoporous carbon nitrides
journal, January 2011

  • Ansari, Mohd Bismillah; Min, Byung-Hoon; Mo, Yong-Hwan
  • Green Chemistry, Vol. 13, Issue 6
  • DOI: 10.1039/c0gc00951b

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes
journal, January 2013

  • Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas
  • Energy & Environmental Science, Vol. 6, Issue 11
  • DOI: 10.1039/c3ee41272e

Heterogeneous Catalysis of CO 2 Conversion to Methanol on Copper Surfaces
journal, October 2014

Adsorption of gold on TiC(001): Au–C interactions and charge polarization
journal, December 2007

  • Rodriguez, J. A.; Viñes, F.; Illas, F.
  • The Journal of Chemical Physics, Vol. 127, Issue 21
  • DOI: 10.1063/1.2814246

Interaction of carbon dioxide with clean and oxygenated Cu(110) surfaces
journal, January 1992

  • Schneider, T.; Hirschwald, W.
  • Catalysis Letters, Vol. 14, Issue 2
  • DOI: 10.1007/BF00765233

Fundamental Studies of Well-Defined Surfaces of Mixed-Metal Oxides: Special Properties of MO x /TiO 2 (110) {M = V, Ru, Ce, or W}
journal, December 2012

  • Stacchiola, Darío J.; Senanayake, Sanjaya D.; Liu, Ping
  • Chemical Reviews, Vol. 113, Issue 6
  • DOI: 10.1021/cr300316v

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons
journal, January 2009

  • Olah, George A.; Goeppert, Alain; Prakash, G. K. Surya
  • The Journal of Organic Chemistry, Vol. 74, Issue 2, p. 487-498
  • DOI: 10.1021/jo801260f

Theoretical Study of Methanol Synthesis from CO 2 Hydrogenation on Metal-Doped Cu(111) Surfaces
journal, December 2011

  • Yang, Yixiong; White, Michael G.; Liu, Ping
  • The Journal of Physical Chemistry C, Vol. 116, Issue 1
  • DOI: 10.1021/jp208448c

Electron Transfer at Oxide Surfaces. The MgO Paradigm: from Defects to Ultrathin Films
journal, November 2012

  • Pacchioni, Gianfranco; Freund, Hajo
  • Chemical Reviews, Vol. 113, Issue 6
  • DOI: 10.1021/cr3002017

Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst
journal, August 2011

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015

  • Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201411581

Structure–Property Relationship and Chemical Aspects of Oxide–Metal Hybrid Nanostructures
journal, December 2012

  • Surnev, Svetlozar; Fortunelli, Alessandro; Netzer, Falko P.
  • Chemical Reviews, Vol. 113, Issue 6
  • DOI: 10.1021/cr300307n

Adsorption and Reaction of CO 2 on Mo 2 C Catalyst
journal, September 2002

  • Solymosi, F.; Oszkó, A.; Bánsági, T.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 37
  • DOI: 10.1021/jp0203696

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014

Higher Alcohols through CO Hydrogenation over CoCu Catalysts: Influence of Precursor Activation
journal, July 2014

  • Xiang, Yizhi; Barbosa, Roland; Kruse, Norbert
  • ACS Catalysis, Vol. 4, Issue 8
  • DOI: 10.1021/cs500696z

Structure and function of Cu-based composite catalysts for highly effective synthesis of methanol by hydrogenation of CO2 and CO
journal, April 1997

Development of an active Ga2O3 supported palladium catalyst for the synthesis of methanol from carbon dioxide and hydrogen
journal, May 1995

Surface Chemistry of Transition Metal Carbides
journal, January 2005

  • Hwu, Henry H.; Chen, Jingguang G.
  • Chemical Reviews, Vol. 105, Issue 1
  • DOI: 10.1021/cr0204606

A theoretical insight into the catalytic effect of a mixed-metal oxide at the nanometer level: The case of the highly active metal/CeOx/TiO2(110) catalysts
journal, March 2010

  • Graciani, Jesús; Plata, José J.; Sanz, Javier Fdez.
  • The Journal of Chemical Physics, Vol. 132, Issue 10
  • DOI: 10.1063/1.3337918

Rationalization of Interactions in Precious Metal/Ceria Catalysts Using the d-Band Center Model
journal, June 2013

  • Acerbi, N.; Tsang, S. C. Edman; Jones, G.
  • Angewandte Chemie International Edition, Vol. 52, Issue 30
  • DOI: 10.1002/anie.201300130

Adsorption, Dissociation, and Hydrogenation of CO 2 on WC(0001) and WC-Co Alloy Surfaces Investigated with Theoretical Calculations
journal, June 2012

  • Wu, Shiuan-Yau; Ho, Jia-Jen
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24
  • DOI: 10.1021/jp302901r

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013

  • Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
  • Angewandte Chemie International Edition, Vol. 52, Issue 19
  • DOI: 10.1002/anie.201210077

CO2 Hydrogenation over Carbide Catalysts.
journal, January 1992

  • Dubois, Jean-Luc; Sayama, Kazuhiro; Arakawa, Hironori
  • Chemistry Letters, Issue 1
  • DOI: 10.1246/cl.1992.5

Synthesis of methanol from a mixture of H2 and CO2 on Cu(100)
journal, October 1994

Direct CO2 hydrogenation to methane or methanol from post-combustion exhaust streams – A thermodynamic study
journal, January 2015

  • Miguel, Carlos V.; Soria, Miguel A.; Mendes, Adélio
  • Journal of Natural Gas Science and Engineering, Vol. 22
  • DOI: 10.1016/j.jngse.2014.11.010

Mechanism of Methanol Synthesis on Cu through CO 2 and CO Hydrogenation
journal, February 2011

  • Grabow, L. C.; Mavrikakis, M.
  • ACS Catalysis, Vol. 1, Issue 4
  • DOI: 10.1021/cs200055d

Carbon Dioxide as Chemical Feedstock
book, January 2010

Cerium oxide layers on the Cu(111) surface: Substrate-mediated redox properties
journal, January 2008

Low Pressure CO 2 Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeO x /TiO 2 Interface
journal, August 2015

  • Yang, Xiaofang; Kattel, Shyam; Senanayake, Sanjaya D.
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b06150

The stability of Cu/ZnO-based catalysts in methanol synthesis from a CO2-rich feed and from a CO-rich feed
journal, September 2001

Identifying trends and descriptors for selective CO 2 conversion to CO over transition metal carbides
journal, January 2015

  • Porosoff, Marc D.; Kattel, Shyam; Li, Wenhui
  • Chemical Communications, Vol. 51, Issue 32
  • DOI: 10.1039/C5CC01545F

Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO 2 to CO
journal, May 2014

  • Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal
  • Angewandte Chemie International Edition, Vol. 53, Issue 26
  • DOI: 10.1002/anie.201404109

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol
journal, March 2014

  • Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1873

STM Study of Copper Growth on ZnO(0001)−Zn and ZnO(0001̄)−O Surfaces
journal, September 2003

  • Koplitz, Lynn Vogel; Dulub, Olga; Diebold, Ulrike
  • The Journal of Physical Chemistry B, Vol. 107, Issue 38
  • DOI: 10.1021/jp0352175

Methanol synthesis from CO2/H2 using Ga2O3–Pd/silica catalysts: Kinetic modeling
journal, July 2009

  • Chiavassa, Dante L.; Collins, Sebastián E.; Bonivardi, Adrian L.
  • Chemical Engineering Journal, Vol. 150, Issue 1
  • DOI: 10.1016/j.cej.2009.02.013

Synthesis of α-MoC1-x and β-MoCy Catalysts for CO2 Hydrogenation by Thermal Carburization of Mo-oxide in Hydrocarbon and Hydrogen Mixtures
journal, June 2014

Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies
journal, November 2014

  • Jadhav, Suhas G.; Vaidya, Prakash D.; Bhanage, Bhalchandra M.
  • Chemical Engineering Research and Design, Vol. 92, Issue 11
  • DOI: 10.1016/j.cherd.2014.03.005

Recent Advances on TiO 2 ‐ZrO 2 Mixed Oxides as Catalysts and Catalyst Supports
journal, April 2005

CeO 2 ↔ CuO x Interactions and the Controlled Assembly of CeO 2 (111) and CeO 2 (100) Nanoparticles on an Oxidized Cu(111) Substrate
journal, October 2011

  • Yang, Fan; Choi, YongMan; Agnoli, Stefano
  • The Journal of Physical Chemistry C, Vol. 115, Issue 46
  • DOI: 10.1021/jp2082837

Anthropogenic Chemical Carbon Cycle for a Sustainable Future
journal, August 2011

  • Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain
  • Journal of the American Chemical Society, Vol. 133, Issue 33
  • DOI: 10.1021/ja202642y

Does CO 2 dissociatively adsorb on Cu surfaces?
journal, October 1989

  • Nakamura, J.; Rodriguez, J. A.; Campbell, C. T.
  • Journal of Physics: Condensed Matter, Vol. 1, Issue SB
  • DOI: 10.1088/0953-8984/1/SB/026

Methanol synthesis on Cu(100) from a binary gas mixture of CO2 and H2
journal, January 1994

  • Rasmussen, P. B.; Holmblad, P. M.; Askgaard, T.
  • Catalysis Letters, Vol. 26, Issue 3-4
  • DOI: 10.1007/BF00810611

Adsorption of carbon monoxide carbon dioxide on clean and cesium-covered copper(110)
journal, June 1989

  • Rodriguez, Jose A.; Clendening, William D.; Campbell, Charles T.
  • The Journal of Physical Chemistry, Vol. 93, Issue 13
  • DOI: 10.1021/j100350a040

Mechanistic aspects of carbon dioxide reforming of methane to synthesis gas over Ni catalysts
journal, January 1996

  • Zhang, Zhaolong; Verykios, Xenophon E.
  • Catalysis Letters, Vol. 38, Issue 3-4
  • DOI: 10.1007/BF00806565

Classification of chemical bonds based on topological analysis of electron localization functions
journal, October 1994

Electronic Structure of Magnesia−Ceria Model Catalysts, CO 2 Adsorption, and CO 2 Activation: A Synchrotron Radiation Photoelectron Spectroscopy Study
journal, April 2011

  • Staudt, Thorsten; Lykhach, Yaroslava; Tsud, Nataliya
  • The Journal of Physical Chemistry C, Vol. 115, Issue 17
  • DOI: 10.1021/jp200382y

Activation of noble metals on metal-carbide surfaces: novel catalysts for CO oxidation, desulfurization and hydrogenation reactions
journal, January 2012

  • Rodriguez, José A.; Illas, Francesc
  • Phys. Chem. Chem. Phys., Vol. 14, Issue 2
  • DOI: 10.1039/C1CP22738F

A Surface Science Investigation of Methanol Synthesis over a Zn-Deposited Polycrystalline Cu Surface
journal, April 1996

  • Nakamura, J.; Nakamura, I.; Uchijima, T.
  • Journal of Catalysis, Vol. 160, Issue 1
  • DOI: 10.1006/jcat.1996.0124

Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity
journal, July 1996

Electronic perturbations
journal, July 2012

CO2 hydrogenation on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane
journal, November 2013

Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol: Catalytic Performance and In Situ Characterization
journal, September 2015

  • Fiordaliso, Elisabetta M.; Sharafutdinov, Irek; Carvalho, Hudson W. P.
  • ACS Catalysis, Vol. 5, Issue 10
  • DOI: 10.1021/acscatal.5b01271

Modern Global Climate Change
journal, December 2003

CO 2 Activation and Methanol Synthesis on Novel Au/TiC and Cu/TiC Catalysts
journal, August 2012

  • Vidal, Alba B.; Feria, Leticia; Evans, Jaime
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 16
  • DOI: 10.1021/jz300989e

High-performance hybrid oxide catalyst of manganese and cobalt for low-pressure methanol synthesis
journal, March 2015

  • Li, Cheng-Shiuan; Melaet, Gérôme; Ralston, Walter T.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7538

A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts
journal, May 2012

  • Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J.
  • Journal of the American Chemical Society, Vol. 134, Issue 21
  • DOI: 10.1021/ja302070k

Carbon Dioxide Recycling: Emerging Large-Scale Technologies with Industrial Potential
journal, September 2011

  • Quadrelli, Elsje Alessandra; Centi, Gabriele; Duplan, Jean-Luc
  • ChemSusChem, Vol. 4, Issue 9
  • DOI: 10.1002/cssc.201100473

Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties
journal, January 1997

Promoting Strong Metal Support Interaction: Doping ZnO for Enhanced Activity of Cu/ZnO:M (M = Al, Ga, Mg) Catalysts
journal, April 2015

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012

Reactions of oxygen-containing molecules on transition metal carbides: Surface science insight into potential applications in catalysis and electrocatalysis
journal, September 2012

Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis
journal, August 1973

High Coverage CO Adsorption and Dissociation on the Orthorhombic Mo 2 C(100) Surface
journal, January 2014

  • Wang, Tao; Li, Yong-Wang; Wang, Jianguo
  • The Journal of Physical Chemistry C, Vol. 118, Issue 6
  • DOI: 10.1021/jp412067x

A universal method to synthesize nanoscale carbides as electrocatalyst supports towards oxygen reduction reaction
journal, January 2011

  • He, Guoqiang; Yan, Zaoxue; Ma, Xueming
  • Nanoscale, Vol. 3, Issue 9
  • DOI: 10.1039/c1nr10436e

Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄)
journal, January 2010

  • Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 33
  • DOI: 10.1039/c001484b

Methanol synthesis on a Cu(100) catalyst
journal, January 1991

  • Szanyi, J�nos; Goodman, D. Wayne
  • Catalysis Letters, Vol. 10, Issue 5-6
  • DOI: 10.1007/BF00769173

Metal carbides and nitrides as potential catalysts for hydroprocessing
journal, February 2003

CO oxidation over ZnO films on Pt(111) at near-atmospheric pressures
journal, May 2013

Formation of hydrocarbons via CO2 hydrogenation – A thermodynamic study
journal, June 2014

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate–alkoxide clusters
    journal, January 2018

    • VanGelder, L. E.; Forrestel, P. L.; Brennessel, W. W.
    • Chemical Communications, Vol. 54, Issue 50
    • DOI: 10.1039/c8cc01517a

    Structure of the catalytically active copper–ceria interfacial perimeter
    journal, February 2019

    Insight into catalytic reduction of CO 2 to methane with silanes using Brookhart's cationic Ir( iii ) pincer complex
    journal, January 2018

    • Fang, Shaoqin; Chen, Hongcai; Wei, Haiyan
    • RSC Advances, Vol. 8, Issue 17
    • DOI: 10.1039/c7ra13486j

    Methanol Oxidation in Alkaline Media with Pt-Au/fMWCNTs and Pt-Pd/fMWCNTs Electrocatalysts on an Exfoliated Graphite Electrode
    journal, October 2019

    New Set of Multicomponent Crystals as Efficient Heterogeneous Catalysts for the Synthesis of Cyclic Carbonates
    journal, March 2019

    Molecular adsorption and dissociation of CO2 on TiO2 anatase (001) activated by oxygen vacancies
    journal, July 2019

    • Varilla, L. A. Alcalá; Seriani, N.; Montoya, J. A.
    • Journal of Molecular Modeling, Vol. 25, Issue 8
    • DOI: 10.1007/s00894-019-4103-7

    Ruthenium(II)‐Catalyzed β ‐Methylation of Alcohols using Methanol as C 1 Source
    journal, March 2019

    A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2
    journal, October 2018

    • Duyar, Melis S.; Tsai, Charlie; Snider, Jonathan L.
    • Angewandte Chemie, Vol. 130, Issue 46
    • DOI: 10.1002/ange.201806583

    Nanoassemblies of ultrasmall clusters with remarkable activity in carbon dioxide conversion into C1 fuels
    journal, January 2019

    • Halder, Avik; Kioseoglou, Joseph; Yang, Bing
    • Nanoscale, Vol. 11, Issue 11
    • DOI: 10.1039/c8nr06664g

    Enhancing Metal-Support Interactions by Molybdenum Carbide: An Efficient Strategy toward the Chemoselective Hydrogenation of α,β-Unsaturated Aldehydes
    journal, March 2016

    • He, Sina; Shao, Zheng-Jiang; Shu, Yijin
    • Chemistry - A European Journal, Vol. 22, Issue 16
    • DOI: 10.1002/chem.201600323

    Effect of plasma-induced surface charging on catalytic processes: application to CO 2 activation
    journal, February 2018

    • Bal, Kristof M.; Huygh, Stijn; Bogaerts, Annemie
    • Plasma Sources Science and Technology, Vol. 27, Issue 2
    • DOI: 10.1088/1361-6595/aaa868

    Highly efficient binary copper−iron catalyst for photoelectrochemical carbon dioxide reduction toward methane
    journal, January 2020

    • Zhou, Baowen; Ou, Pengfei; Pant, Nick
    • Proceedings of the National Academy of Sciences, Vol. 117, Issue 3
    • DOI: 10.1073/pnas.1911159117

    Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
    journal, March 2017

    Incorporating nitrogen atoms into cobalt nanosheets as a strategy to boost catalytic activity toward CO2 hydrogenation
    journal, October 2017

    The Synergistic Effect of CuZnCeO x in Controlling the Formation of Methanol and CO from CO 2 Hydrogenation
    journal, August 2018

    Synthesis and Characterization of Catalysts Cu-ZnO Supported on Mesoporous Carbon FDU-15: Synthesis and Characterization of Cu-ZnO/FDU-15
    journal, February 2018

    • Ouyang, Chong; Wei, Hong; Li, Qiaoqiao
    • Journal of the Chinese Chemical Society, Vol. 65, Issue 6
    • DOI: 10.1002/jccs.201700409

    Structure–function relationship for CO 2 methanation over ceria supported Rh and Ni catalysts under atmospheric pressure conditions
    journal, January 2019

    • Martin, Natalia M.; Hemmingsson, Felix; Schaefer, Andreas
    • Catalysis Science & Technology, Vol. 9, Issue 7
    • DOI: 10.1039/c8cy02097c

    Design of Copper-Based Bimetallic Nanoparticles for Carbon Dioxide Adsorption and Activation
    journal, February 2018

    Hierarchical TiO 2 /Ni(OH) 2 composite fibers with enhanced photocatalytic CO 2 reduction performance
    journal, January 2018

    • Meng, Aiyun; Wu, Shuang; Cheng, Bei
    • Journal of Materials Chemistry A, Vol. 6, Issue 11
    • DOI: 10.1039/c7ta10073f

    Assessing the usefulness of transition metal carbides for hydrogenation reactions
    journal, January 2019

    • Prats, Hector; Piñero, Juan José; Viñes, Francesc
    • Chemical Communications, Vol. 55, Issue 85
    • DOI: 10.1039/c9cc06084g

    2D oxides on metal materials: concepts, status, and perspectives
    journal, January 2019

    • Barcaro, Giovanni; Fortunelli, Alessandro
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 22
    • DOI: 10.1039/c9cp00972h

    Promoting the Synthesis of Methanol: Understanding the Requirements for an Industrial Catalyst for the Conversion of CO 2
    journal, October 2016

    Serpentinization: Connecting Geochemistry, Ancient Metabolism and Industrial Hydrogenation
    journal, September 2018

    • Preiner, Martina; Xavier, Joana; Sousa, Filipa
    • Life, Vol. 8, Issue 4
    • DOI: 10.3390/life8040041

    Pyrolysis of metal–organic frameworks to hierarchical porous Cu/Zn-nanoparticle@carbon materials for efficient CO 2 hydrogenation
    journal, January 2017

    • Zhang, Jingzheng; An, Bing; Hong, Yahui
    • Materials Chemistry Frontiers, Vol. 1, Issue 11
    • DOI: 10.1039/c7qm00328e

    Selective hydrogenation of CO 2 over a Ce promoted Cu-based catalyst confined by SBA-15
    journal, January 2019

    • Hu, Xiaosong; Zhao, Chaoyue; Guan, Qingxin
    • Inorganic Chemistry Frontiers, Vol. 6, Issue 7
    • DOI: 10.1039/c9qi00397e

    La 2 O 3 ‐Modified LaTiO 2 N Photocatalyst with Spatially Separated Active Sites Achieving Enhanced CO 2 Reduction
    journal, July 2017

    • Lu, Lei; Wang, Bing; Wang, Shaomang
    • Advanced Functional Materials, Vol. 27, Issue 36
    • DOI: 10.1002/adfm.201702447

    Towards Solar Methanol: Past, Present, and Future
    journal, February 2019

    • Tountas, Athanasios A.; Peng, Xinyue; Tavasoli, Alexandra V.
    • Advanced Science, Vol. 6, Issue 8
    • DOI: 10.1002/advs.201801903

    Conversion of Carbon Dioxide into Oxazolidinones Mediated by Quaternary Ammonium Salts and DBU
    journal, August 2017

    Serpentinization: Connecting Geochemistry, Ancient Metabolism and Industrial Hydrogenation
    journal, September 2018

    • Preiner, Martina; Xavier, Joana; Sousa, Filipa
    • Life, Vol. 8, Issue 4
    • DOI: 10.3390/life8040041

    A review on photocatalytic CO 2 reduction using perovskite oxide nanomaterials
    journal, January 2018

    Applying low-temperature titration for determination of metallic sites on active oxide supported catalysts
    journal, January 2019

    • Liu, Zebang; Li, Jerry Pui Ho; Qi, Xiaomian
    • Catalysis Science & Technology, Vol. 9, Issue 8
    • DOI: 10.1039/c8cy02610f

    New Strategies for the Preparation of Sinter‐Resistant Metal‐Nanoparticle‐Based Catalysts
    journal, July 2019

    • Wang, Lingxiang; Wang, Liang; Meng, Xiangju
    • Advanced Materials, Vol. 31, Issue 50
    • DOI: 10.1002/adma.201901905

    Porous MoxCy/SiO2 Material for CO2 Hydrogenation
    journal, August 2019

    • García Blanco, Andrés A.; Furlong, Octavio J.; Stacchiola, Dario J.
    • Topics in Catalysis, Vol. 62, Issue 12-16
    • DOI: 10.1007/s11244-019-01195-w

    A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2
    journal, October 2018

    • Duyar, Melis S.; Tsai, Charlie; Snider, Jonathan L.
    • Angewandte Chemie International Edition, Vol. 57, Issue 46
    • DOI: 10.1002/anie.201806583

    The Methanol Economy: Methane and Carbon Dioxide Conversion
    journal, March 2018

    Iron Carbide@Carbon Nanocomposites: A Tool Box of Functional Materials
    journal, January 2019

    • Defilippi, Chiara; Mukadam, Mariam; Nicolae, Sabina
    • Materials, Vol. 12, Issue 2
    • DOI: 10.3390/ma12020323

    A novel Core–Shell structured CuIn@SiO 2 catalyst for CO 2 hydrogenation to methanol
    journal, December 2018

    • Shi, Zhisheng; Tan, Qingqing; Wu, Dongfang
    • AIChE Journal, Vol. 65, Issue 3
    • DOI: 10.1002/aic.16490

    The Roles of Oxide Growth and Sub-Surface Facets in Oxygen Evolution Activity of Iridium and Its Impact on Electrolysis
    journal, January 2019

    • Alia, Shaun M.; Ha, Mai-Anh; Anderson, Grace C.
    • Journal of The Electrochemical Society, Vol. 166, Issue 15
    • DOI: 10.1149/2.0771915jes

    Cu-Mo2C/MCM-41: An Efficient Catalyst for the Selective Synthesis of Methanol from CO2
    journal, May 2016

    Iron Carbide@Carbon Nanocomposites: A Tool Box of Functional Materials
    journal, January 2019

    • Defilippi, Chiara; Mukadam, Mariam; Nicolae, Sabina
    • Materials, Vol. 12, Issue 2
    • DOI: 10.3390/ma12020323
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: