Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode
Abstract
Using neutron reflectometry we have determined the thickness and chemistry of the solid-electrolyte interphase (SEI) layer grown on a silicon anode as a function of state of charge and during cycling. We show the chemistry of this SEI layer becomes more LiF like with increasing lithiation and more Li-C-O-F like with delithiation. More importantly the SEI layer thickness appears to increase (about 250 ) as the electrode becomes less lithiated and thins to 180 with increasing Li content (Li3.7Si). We attribute this breathing to the continual consumption of electrolyte with cycling.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1222554
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 119; Journal Issue: 35; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Veith, Gabriel M., Doucet, Mathieu, Baldwin, J. K., Sacci, Robert L., Fears, Tyler M., Wang, Yongqiang, and Browning, Jim. Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode. United States: N. p., 2015.
Web. doi:10.1021/acs.jpcc.5b06817.
Veith, Gabriel M., Doucet, Mathieu, Baldwin, J. K., Sacci, Robert L., Fears, Tyler M., Wang, Yongqiang, & Browning, Jim. Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode. United States. https://doi.org/10.1021/acs.jpcc.5b06817
Veith, Gabriel M., Doucet, Mathieu, Baldwin, J. K., Sacci, Robert L., Fears, Tyler M., Wang, Yongqiang, and Browning, Jim. Mon .
"Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode". United States. https://doi.org/10.1021/acs.jpcc.5b06817. https://www.osti.gov/servlets/purl/1222554.
@article{osti_1222554,
title = {Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode},
author = {Veith, Gabriel M. and Doucet, Mathieu and Baldwin, J. K. and Sacci, Robert L. and Fears, Tyler M. and Wang, Yongqiang and Browning, Jim},
abstractNote = {Using neutron reflectometry we have determined the thickness and chemistry of the solid-electrolyte interphase (SEI) layer grown on a silicon anode as a function of state of charge and during cycling. We show the chemistry of this SEI layer becomes more LiF like with increasing lithiation and more Li-C-O-F like with delithiation. More importantly the SEI layer thickness appears to increase (about 250 ) as the electrode becomes less lithiated and thins to 180 with increasing Li content (Li3.7Si). We attribute this breathing to the continual consumption of electrolyte with cycling.},
doi = {10.1021/acs.jpcc.5b06817},
journal = {Journal of Physical Chemistry. C},
number = 35,
volume = 119,
place = {United States},
year = {Mon Aug 17 00:00:00 EDT 2015},
month = {Mon Aug 17 00:00:00 EDT 2015}
}
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