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Title: PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization

Abstract

In this study, we show both experimentally and numerically on a series of model systems that in experiments involving transfer of magnetization from 1H to the quadrupolar nuclei under magic-angle-spinning (MAS), the PRESTO technique consistently outperforms traditionally used cross polarization (CP), affording more quantitative intensities, improved lineshapes, better overall sensitivity, and straightforward optimization. This advantage derives from the fact that PRESTO circumvents the convoluted and uncooperative spin dynamics during the CP transfer under MAS, by replacing the spin-locking of quadrupolar nuclei with a single central transition selective 90° pulse and using a symmetry-based recoupling sequence in the 1H channel. This is important in the context of dynamic nuclear polarization (DNP) NMR of quadrupolar nuclei, where the efficient transfer of enhanced 1H polarization is desired to obtain the highest sensitivity.

Authors:
 [1];  [1];  [2]
  1. Ames Lab., Ames, IA (United States)
  2. Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1221933
Report Number(s):
IS-J-8778
Journal ID: ISSN 1463-9076; PPCPFQ; PII: S0965977399002603
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP
Additional Journal Information:
Journal Volume: 17; Journal Issue: 35; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Perras, Frederic A., Kobayashi, Takeshi, and Pruski, Marek. PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization. United States: N. p., 2015. Web. doi:10.1039/c5cp04145g.
Perras, Frederic A., Kobayashi, Takeshi, & Pruski, Marek. PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization. United States. https://doi.org/10.1039/c5cp04145g
Perras, Frederic A., Kobayashi, Takeshi, and Pruski, Marek. Tue . "PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization". United States. https://doi.org/10.1039/c5cp04145g. https://www.osti.gov/servlets/purl/1221933.
@article{osti_1221933,
title = {PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization},
author = {Perras, Frederic A. and Kobayashi, Takeshi and Pruski, Marek},
abstractNote = {In this study, we show both experimentally and numerically on a series of model systems that in experiments involving transfer of magnetization from 1H to the quadrupolar nuclei under magic-angle-spinning (MAS), the PRESTO technique consistently outperforms traditionally used cross polarization (CP), affording more quantitative intensities, improved lineshapes, better overall sensitivity, and straightforward optimization. This advantage derives from the fact that PRESTO circumvents the convoluted and uncooperative spin dynamics during the CP transfer under MAS, by replacing the spin-locking of quadrupolar nuclei with a single central transition selective 90° pulse and using a symmetry-based recoupling sequence in the 1H channel. This is important in the context of dynamic nuclear polarization (DNP) NMR of quadrupolar nuclei, where the efficient transfer of enhanced 1H polarization is desired to obtain the highest sensitivity.},
doi = {10.1039/c5cp04145g},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 35,
volume = 17,
place = {United States},
year = {Tue Aug 04 00:00:00 EDT 2015},
month = {Tue Aug 04 00:00:00 EDT 2015}
}

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Cited by: 28 works
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Works referencing / citing this record:

DNP-NMR of surface hydrogen on silicon microparticles
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