A low-cost solid–liquid separation process for enzymatically hydrolyzed corn stover slurries
Abstract
Solid-liquid separation of intermediate process slurries is required in some process configurations for the conversion of lignocellulosic biomass to transportation fuels. Thermochemically pretreated and enzymatically hydrolyzed corn stover slurries have proven difficult to filter due to formation of very low permeability cakes that are rich in lignin. Treatment of two different slurries with polyelectrolyte flocculant was demonstrated to increase mean particle size and filterability. Filtration flux was greatly improved, and thus scaled filter unit capacity was increased approximately 40-fold compared with unflocculated slurry. Although additional costs were accrued using polyelectrolyte, techno-economic analysis revealed that the increase in filter capacity significantly reduced overall production costs. Fuel production cost at 95% sugar recovery was reduced by $1.35 US per gallon gasoline equivalent for dilute-acid pretreated and enzymatically hydrolyzed slurries and $3.40 for slurries produced using an additional alkaline de-acetylation preprocessing step that is even more difficult to natively filter.
- Authors:
-
- National Renewable Energy Lab. (NREL), Golden, CO (United States). National Bioenergy Center
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1220661
- Alternate Identifier(s):
- OSTI ID: 1250317
- Report Number(s):
- NREL/JA-5100-63424
Journal ID: ISSN 0960-8524
- Grant/Contract Number:
- AC36-08GO28308; EE0005006
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Bioresource Technology
- Additional Journal Information:
- Journal Volume: 187; Journal Issue: C; Journal ID: ISSN 0960-8524
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; flocculation; solid-liquid separation; filtration; biofuels
Citation Formats
Sievers, David A., Lischeske, James J., Biddy, Mary J., and Stickel, Jonathan J. A low-cost solid–liquid separation process for enzymatically hydrolyzed corn stover slurries. United States: N. p., 2015.
Web. doi:10.1016/j.biortech.2015.03.087.
Sievers, David A., Lischeske, James J., Biddy, Mary J., & Stickel, Jonathan J. A low-cost solid–liquid separation process for enzymatically hydrolyzed corn stover slurries. United States. https://doi.org/10.1016/j.biortech.2015.03.087
Sievers, David A., Lischeske, James J., Biddy, Mary J., and Stickel, Jonathan J. Wed .
"A low-cost solid–liquid separation process for enzymatically hydrolyzed corn stover slurries". United States. https://doi.org/10.1016/j.biortech.2015.03.087. https://www.osti.gov/servlets/purl/1220661.
@article{osti_1220661,
title = {A low-cost solid–liquid separation process for enzymatically hydrolyzed corn stover slurries},
author = {Sievers, David A. and Lischeske, James J. and Biddy, Mary J. and Stickel, Jonathan J.},
abstractNote = {Solid-liquid separation of intermediate process slurries is required in some process configurations for the conversion of lignocellulosic biomass to transportation fuels. Thermochemically pretreated and enzymatically hydrolyzed corn stover slurries have proven difficult to filter due to formation of very low permeability cakes that are rich in lignin. Treatment of two different slurries with polyelectrolyte flocculant was demonstrated to increase mean particle size and filterability. Filtration flux was greatly improved, and thus scaled filter unit capacity was increased approximately 40-fold compared with unflocculated slurry. Although additional costs were accrued using polyelectrolyte, techno-economic analysis revealed that the increase in filter capacity significantly reduced overall production costs. Fuel production cost at 95% sugar recovery was reduced by $1.35 US per gallon gasoline equivalent for dilute-acid pretreated and enzymatically hydrolyzed slurries and $3.40 for slurries produced using an additional alkaline de-acetylation preprocessing step that is even more difficult to natively filter.},
doi = {10.1016/j.biortech.2015.03.087},
journal = {Bioresource Technology},
number = C,
volume = 187,
place = {United States},
year = {Wed Jul 01 00:00:00 EDT 2015},
month = {Wed Jul 01 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Conversion of Biomass into Chemicals over Metal Catalysts
journal, October 2013
- Besson, Michèle; Gallezot, Pierre; Pinel, Catherine
- Chemical Reviews, Vol. 114, Issue 3
Enhanced solid–liquid clarification of lignocellulosic slurries using polyelectrolyte flocculating agents
journal, January 2011
- Burke, Devon R.; Anderson, Jason; Gilcrease, Patrick C.
- Biomass and Bioenergy, Vol. 35, Issue 1
Improved ethanol yield and reduced Minimum Ethanol Selling Price (MESP) by modifying low severity dilute acid pretreatment with deacetylation and mechanical refining: 1) Experimental
journal, January 2012
- Chen, Xiaowen; Tao, Ling; Shekiro, Joseph
- Biotechnology for Biofuels, Vol. 5, Issue 1
Techno-economic analysis of autotrophic microalgae for fuel production
journal, October 2011
- Davis, Ryan; Aden, Andy; Pienkos, Philip T.
- Applied Energy, Vol. 88, Issue 10
Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons
report, October 2013
- Davis, R.; Tao, L.; Tan, E. C. D.
- NREL/TP-5100-60223
Development of a heterogeneous catalyst for lignocellulosic biomass conversion: Glucose dehydration by metal chlorides in a silica-supported ionic liquid layer
journal, September 2013
- Degirmenci, Volkan; Hensen, Emiel J. M.
- Environmental Progress & Sustainable Energy, Vol. 33, Issue 2
A Combined Pore Blockage and Cake Filtration Model for Protein Fouling during Microfiltration
journal, December 2000
- Ho, Chia-Chi; Zydney, Andrew L.
- Journal of Colloid and Interface Science, Vol. 232, Issue 2
Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover
report, March 2011
- Humbird, D.; Davis, R.; Tao, L.
Use of Filter Aids to Improve the Filterability of Enzymatically Hydrolyzed Biomass Suspensions
journal, October 2013
- Kinnarinen, Teemu; Golmaei, Mohammad; Häkkinen, Antti
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 42
Membrane separations for solid-liquid clarification within lignocellulosic biorefining processes
journal, July 2013
- Leberknight, Jennifer; Menkhaus, Todd J.
- Biotechnology Progress, Vol. 29, Issue 5
Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014
- Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
- Science, Vol. 344, Issue 6185, p. 1246843-1246843
Scale-down characterization of post-centrifuge flocculation processes for high-throughput process development: Characterization of Ultra Scale-Down Flocculation
journal, September 2014
- Espuny Garcia del Real, Georgina; Davies, Jim; Bracewell, Daniel G.
- Biotechnology and Bioengineering, Vol. 111, Issue 12
Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates
journal, June 2007
- Román-Leshkov, Yuriy; Barrett, Christopher J.; Liu, Zhen Y.
- Nature, Vol. 447, Issue 7147, p. 982-985
Performance and techno-economic assessment of several solid–liquid separation technologies for processing dilute-acid pretreated corn stover
journal, September 2014
- Sievers, David A.; Tao, Ling; Schell, Daniel J.
- Bioresource Technology, Vol. 167
Global bioenergy resources
journal, January 2014
- Slade, Raphael; Bauen, Ausilio; Gross, Robert
- Nature Climate Change, Vol. 4, Issue 2
Simultaneous saccharification and co-fermentation of paper sludge to ethanol by Saccharomyces cerevisiae RWB222. Part II: Investigation of discrepancies between predicted and observed performance at high solids concentration
journal, December 2009
- Zhang, Jiayi; Shao, Xiongjun; Lynd, Lee R.
- Biotechnology and Bioengineering, Vol. 104, Issue 5
Metabolic Engineering of a Pentose Metabolism Pathway in Ethanologenic Zymomonas mobilis
journal, January 1995
- Zhang, M.; Eddy, C.; Deanda, K.
- Science, Vol. 267, Issue 5195
Works referencing / citing this record:
Continuous succinic acid production by Actinobacillus succinogenes on xylose-enriched hydrolysate
journal, November 2015
- Bradfield, Michael F. A.; Mohagheghi, Ali; Salvachúa, Davinia
- Biotechnology for Biofuels, Vol. 8, Issue 1
Succinic acid production on xylose-enriched biorefinery streams by Actinobacillus succinogenes in batch fermentation
journal, February 2016
- Salvachúa, Davinia; Mohagheghi, Ali; Smith, Holly
- Biotechnology for Biofuels, Vol. 9, Issue 1
Continuous succinic acid production by Actinobacillus succinogenes on xylose-enriched hydrolysate
journal, November 2015
- Bradfield, Michael F. A.; Mohagheghi, Ali; Salvachúa, Davinia
- Biotechnology for Biofuels, Vol. 8, Issue 1
Succinic acid production on xylose-enriched biorefinery streams by Actinobacillus succinogenes in batch fermentation
journal, February 2016
- Salvachúa, Davinia; Mohagheghi, Ali; Smith, Holly
- Biotechnology for Biofuels, Vol. 9, Issue 1