Aqueous sulfate separation by crystallization of sulfate–water clusters
Abstract
An effective approach to separating sulfates from aqueous solutions is based on the crystallization of extended [SO4(H2O) 52-]n sulfate–water clusters with a bis(guanidinium) ligand. The ligand was generated in situ by hydrazone condensation in water, thus avoiding elaborate syntheses, tedious purifications, and organic solvents. Crystallization of sulfate–water clusters represents an alternative to the now established sulfate separation strategies that involve encapsulating the “naked” anion.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Texas at Austin, Austin, TX (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1213344
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 54; Journal Issue: 36; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Custelcean, Radu, Williams, Neil J., and Seipp, Charles A. Aqueous sulfate separation by crystallization of sulfate–water clusters. United States: N. p., 2015.
Web. doi:10.1002/anie.201506314.
Custelcean, Radu, Williams, Neil J., & Seipp, Charles A. Aqueous sulfate separation by crystallization of sulfate–water clusters. United States. https://doi.org/10.1002/anie.201506314
Custelcean, Radu, Williams, Neil J., and Seipp, Charles A. Fri .
"Aqueous sulfate separation by crystallization of sulfate–water clusters". United States. https://doi.org/10.1002/anie.201506314. https://www.osti.gov/servlets/purl/1213344.
@article{osti_1213344,
title = {Aqueous sulfate separation by crystallization of sulfate–water clusters},
author = {Custelcean, Radu and Williams, Neil J. and Seipp, Charles A.},
abstractNote = {An effective approach to separating sulfates from aqueous solutions is based on the crystallization of extended [SO4(H2O) 52-]n sulfate–water clusters with a bis(guanidinium) ligand. The ligand was generated in situ by hydrazone condensation in water, thus avoiding elaborate syntheses, tedious purifications, and organic solvents. Crystallization of sulfate–water clusters represents an alternative to the now established sulfate separation strategies that involve encapsulating the “naked” anion.},
doi = {10.1002/anie.201506314},
journal = {Angewandte Chemie (International Edition)},
number = 36,
volume = 54,
place = {United States},
year = {Fri Aug 07 00:00:00 EDT 2015},
month = {Fri Aug 07 00:00:00 EDT 2015}
}
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