Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe0.5Mn 0.5O3

Choi, Eun -Mi; Fix, Thomas; Kursumovic, Ahmed; Kinane, Christy J.; Arena, Darío; Sahonta, Suman -Lata; Bi, Zhenxing; Xiong, Jie; Yan, Li; Lee, Jun -Sik; Wang, Haiyan; Langridge, Sean; Kim, Young -Min; Borisevich, Albina Y.; MacLaren, Ian; Ramasse, Quentin M.; Blamire, Mark G.; Jia, Quanxi; MacManus-Driscoll, Judith L.

doi:10.1002/adfm.201401464

Title: Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe_0.5Mn _0.5O₃

Abstract

In this study, highly strained films of BiFe_0.5Mn_0.5O₃ (BFMO) grown at very low rates by pulsed laser deposition were demonstrated to exhibit both ferrimagnetism and ferroelectricity at room temperature and above. Magnetization measurements demonstrated ferrimagnetism (T_C ~ 600K), with a room temperature saturation moment (M_S) of up to 90 emu/cc (~0.58μ_B/f.u) on high quality (001) SrTiO₃. X-ray magnetic circular dichroism showed that the ferrimagnetism arose from antiferromagnetically coupled Fe³⁺ and Mn³⁺ . While scanning transmission electron microscope studies showed there was no long range ordering of Fe and Mn, the magnetic properties were found to be strongly dependent on the strain state in the films. The magnetism is explained to arise from one of three possible mechanisms with Bi polarization playing a key role. A signature of room temperature ferroelectricity in the films was measured by piezoresponse force microscopy and was confirmed using angular dark field scanning transmission electron microscopy. The demonstration of strain induced, high temperature multiferroism is a promising development for future spintronic and memory applications at room temperature and above.

Authors:

Choi, Eun -Mi ^[1]; Fix, Thomas ^[1]; Kursumovic, Ahmed ^[1]; Kinane, Christy J. ^[2]; Arena, Darío ^[3]; Sahonta, Suman -Lata ^[1]; Bi, Zhenxing ^[4]; Xiong, Jie ^[4]; Yan, Li ^[4]; Lee, Jun -Sik ^[5]; Wang, Haiyan ^[6]; Langridge, Sean ^[2]; Kim, Young -Min ^[7]; Borisevich, Albina Y. ^[8]; MacLaren, Ian ^[9]; Ramasse, Quentin M. ^[10]; Blamire, Mark G. ^[1]; Jia, Quanxi ^[4]; MacManus-Driscoll, Judith L. ^[1]

Univ. of Cambridge, Cambridge (United Kingdom). Dept. of Materials Science
Rutherford Appleton Lab., Didcot (United Kingdom). ISIS, Science and Technology Facilities Council
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource
Texas A & M Univ., College Station, TX (United States). Dept. of Electrical and Computer Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Korea Basic Science Institute, Daejeon (Republic of Korea). Division of Electron Microscopic Research
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Univ. of Glasgow, Glasgow (United Kingdom). SUPA School of Physics and Astronomy
SciTech Daresbury, Warrington (United Kingdom). SuperSTEM

Publication Date:: Tue Oct 14 00:00:00 EDT 2014

Research Org.:: Univ. of Cambridge (United Kingdom); Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Engineering and Physical Sciences Research Council; European Research Council (ERC)

OSTI Identifier:: 1212452

Alternate Identifier(s):: OSTI ID: 1265328

Grant/Contract Number:: AC52-06NA25396; AC02-98CH10886; DMR-1007969; DMR-1401266; AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Volume: 24; Journal Issue: 47; Journal ID: ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; multiferroic; ferrimagnetism; ferroelectric; BiFeO₃; BiMnO₃

Citation Formats


                    Choi, Eun -Mi, Fix, Thomas, Kursumovic, Ahmed, Kinane, Christy J., Arena, Darío, Sahonta, Suman -Lata, Bi, Zhenxing, Xiong, Jie, Yan, Li, Lee, Jun -Sik, Wang, Haiyan, Langridge, Sean, Kim, Young -Min, Borisevich, Albina Y., MacLaren, Ian, Ramasse, Quentin M., Blamire, Mark G., Jia, Quanxi, and MacManus-Driscoll, Judith L. Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe0.5Mn 0.5O3.  United States: N. p., 2014. 
Web.  doi:10.1002/adfm.201401464.

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                    Choi, Eun -Mi, Fix, Thomas, Kursumovic, Ahmed, Kinane, Christy J., Arena, Darío, Sahonta, Suman -Lata, Bi, Zhenxing, Xiong, Jie, Yan, Li, Lee, Jun -Sik, Wang, Haiyan, Langridge, Sean, Kim, Young -Min, Borisevich, Albina Y., MacLaren, Ian, Ramasse, Quentin M., Blamire, Mark G., Jia, Quanxi, & MacManus-Driscoll, Judith L. Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe0.5Mn 0.5O3.  United States.  https://doi.org/10.1002/adfm.201401464

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                    Choi, Eun -Mi, Fix, Thomas, Kursumovic, Ahmed, Kinane, Christy J., Arena, Darío, Sahonta, Suman -Lata, Bi, Zhenxing, Xiong, Jie, Yan, Li, Lee, Jun -Sik, Wang, Haiyan, Langridge, Sean, Kim, Young -Min, Borisevich, Albina Y., MacLaren, Ian, Ramasse, Quentin M., Blamire, Mark G., Jia, Quanxi, and MacManus-Driscoll, Judith L. Tue .  
"Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe0.5Mn 0.5O3".  United States.  https://doi.org/10.1002/adfm.201401464.  https://www.osti.gov/servlets/purl/1212452.

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@article{osti_1212452,

  title        = {Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe0.5Mn 0.5O3},

  author       = {Choi, Eun -Mi and Fix, Thomas and Kursumovic, Ahmed and Kinane, Christy J. and Arena, Darío and Sahonta, Suman -Lata and Bi, Zhenxing and Xiong, Jie and Yan, Li and Lee, Jun -Sik and Wang, Haiyan and Langridge, Sean and Kim, Young -Min and Borisevich, Albina Y. and MacLaren, Ian and Ramasse, Quentin M. and Blamire, Mark G. and Jia, Quanxi and MacManus-Driscoll, Judith L.},

  abstractNote = {In this study, highly strained films of BiFe0.5Mn0.5O3 (BFMO) grown at very low rates by pulsed laser deposition were demonstrated to exhibit both ferrimagnetism and ferroelectricity at room temperature and above. Magnetization measurements demonstrated ferrimagnetism (TC ~ 600K), with a room temperature saturation moment (MS) of up to 90 emu/cc (~0.58μB/f.u) on high quality (001) SrTiO3. X-ray magnetic circular dichroism showed that the ferrimagnetism arose from antiferromagnetically coupled Fe3+ and Mn3+ . While scanning transmission electron microscope studies showed there was no long range ordering of Fe and Mn, the magnetic properties were found to be strongly dependent on the strain state in the films. The magnetism is explained to arise from one of three possible mechanisms with Bi polarization playing a key role. A signature of room temperature ferroelectricity in the films was measured by piezoresponse force microscopy and was confirmed using angular dark field scanning transmission electron microscopy. The demonstration of strain induced, high temperature multiferroism is a promising development for future spintronic and memory applications at room temperature and above.},

  doi          = {10.1002/adfm.201401464},

  journal      = {Advanced Functional Materials},

  number       = 47,

  volume       = 24,

  place        = {United States},

  year         = {Tue Oct 14 00:00:00 EDT 2014},

  month        = {Tue Oct 14 00:00:00 EDT 2014}

}

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Title: Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe0.5Mn 0.5O3

Abstract

Citation Formats

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Improved leakage and ferroelectric properties of Mn and Ti codoped BiFeO3 thin films journal, March 2009

Metalorganic chemical vapor deposition of lead-free ferroelectric BiFeO3 films for memory applications journal, September 2005

Magnetic and structural properties of BiFe1−xMnxO3 journal, March 2007

A strong ferroelectric ferromagnet created by means of spin–lattice coupling journal, August 2010

A New Class of Room-Temperature Multiferroic Thin Films with Bismuth-Based Supercell Structure journal, November 2012

Multiferroic BiMnO3 thin films with double SrTiO3 buffer layers journal, August 2008

Tunnel junctions with multiferroic barriers journal, March 2007

Origin of Magnetization Reversal and Exchange Bias Phenomena in Solid Solutions of BiFeO 3 –BiMnO 3 : Intrinsic or Extrinsic? journal, January 2013

Structural and magnetic properties of epitaxial thin films of the ordered double perovskite La2CoMnO6 journal, December 2006

Anomalously large ferromagnetic Curie temperature of epitaxial Bi2CoMnO6 thin films journal, March 2008

Strong room temperature magnetism in highly resistive strained thin films of BiFe0.5Mn0.5O3 journal, January 2011

Multiferroism in orientational engineered (La, Mn) co-substituted BiFeO 3 thin films journal, June 2011

Implications of phase-segregation on structure, terahertz emission and magnetization of Bi(Fe 1-x Mn x )O 3 (0⩽x⩽0.5) thin films journal, December 2008

Magnetic Tunnel Junctions with Ferroelectric Barriers: Prediction of Four Resistance States from First Principles journal, January 2009

Evidence of the Griffiths phase in multiferroic BiMnO 3 and BiFe 0.5 Mn 0.5 O 3 films journal, May 2012

Ferroelectric, electrical and magnetic properties of Cr, Mn, Co, Ni, Cu added polycrystalline BiFeO3 films journal, August 2008

Multi-ferroic and magnetoelectric materials and interfaces journal, August 2011

Atomically Resolved Mapping of Polarization and Electric Fields Across Ferroelectric/Oxide Interfaces by Z-contrast Imaging journal, April 2011

Room temperature ferroelectric properties of Mn-substituted BiFeO3 thin films deposited on Pt electrodes using chemical solution deposition journal, June 2006

Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures journal, March 2003

Dielectric hysteresis in single crystal BiFeO3 journal, July 1970

Experimental difficulties and artefacts in multiferroic and magnetoelectric thin films of BiFeO 3 , Bi 0.6 Tb 0.3 La 0.1 FeO 3 and BiMnO 3 journal, March 2007

Evidence for the likely occurrence of magnetoferroelectricity in the simple perovskite, BiMnO3 journal, April 2002

Magnetocapacitance effect in multiferroic BiMnO 3 journal, May 2003

Magnetostructural Effect in the Multiferroic BiFeO 3 − BiMnO 3 Checkerboard from First Principles journal, January 2010

Structural, magnetic, and optical properties of BiFeO 3 and Bi 2 FeMnO 6 epitaxial thin films: An experimental and first-principles study journal, September 2008

High-Temperature Magnetic Insulating Phase in Ultrathin La 0.67 Sr 0.33 MnO 3 Films journal, October 2012

Multiple magnetic phases of La 2 CoMnO 6 − δ ( 0 <~ δ <~ 0 . 0 5 ) journal, January 2003

Experimental Confirmation of the X-Ray Magnetic Circular Dichroism Sum Rules for Iron and Cobalt journal, July 1995

Polarized neutron reflection as a probe of magnetic films and multilayers journal, August 1992

Competition between ferromagnetic and antiferromagnetic ground states in multiferroic BiMnO 3 at high pressures journal, July 2010

Spin filtering through ferromagnetic Bi Mn O 3 tunnel barriers journal, July 2005

A strong ferroelectric ferromagnet created by means of spin–lattice coupling journal, July 2011

Magnetic tunnel junctions with ferroelectric barriers: Prediction of four resistance states from first-principles text, January 2008

Room temperature ferromagnetism in BiFe 1− x Mn x O 3 thin film induced by spin-structure manipulation journal, May 2018

The Polar/Antipolar Phase Boundary of BiMnO 3 -BiFeO 3 -PbTiO 3 : Interplay among Crystal Structure, Point Defects, and Multiferroism journal, July 2018

High-temperature Magnetodielectric Bi ( Fe 0.5 Mn 0.5 ) O 3 Thin Films with Checkerboard-Ordered Oxygen Vacancies and Low Magnetic Damping journal, November 2018

Magnetic, electronic, and optical properties of double perovskite Bi 2 FeMnO 6 journal, March 2017

Interface-Coupled BiFeO 3 /BiMnO 3 Superlattices with Magnetic Transition Temperature up to 410 K journal, January 2016

Title: Room temperature ferrimagnetism and ferroelectricity in strained, thin films of BiFe_0.5Mn _0.5O₃

Effect of Mn doping on electric and magnetic properties of BiFeO3 thin films by chemical solution deposition
journal, September 2009

Temperature-induced magnetization reversal in ${BiFe}_{0.5} {Mn}_{0.5} O_{3}$ synthesized at high pressure
journal, September 2010

Atomic ordering in the LaFe0.5Mn0.5O3 solid solution film
journal, January 2001

Towards a magnetoelectric memory
journal, June 2008

Structure and Properties of Multiferroic Oxygen Hyperstoichiometric BiFe _{1− x} Mn _x O _3+δ
journal, November 2009

Structural transitions and enhanced ferroelectricity in Ca and Mn co-doped BiFeO ₃ thin films
journal, November 2011

Extracting the near surface stoichiometry of BiFe0.5Mn0.5O3 thin films; a finite element maximum entropy approach
journal, December 2012

Bi -relaxation behaviors in epitaxial multiferroic double-perovskite BiFe _0.5 Mn _0.5 O ₃ /CaRuO ₃ heterostructures
journal, August 2011

Why Are There so Few Magnetic Ferroelectrics?
journal, July 2000

Improved leakage and ferroelectric properties of Mn and Ti codoped BiFeO3 thin films
journal, March 2009

Metalorganic chemical vapor deposition of lead-free ferroelectric BiFeO3 films for memory applications
journal, September 2005

Magnetic and structural properties of BiFe1−xMnxO3
journal, March 2007

A strong ferroelectric ferromagnet created by means of spin–lattice coupling
journal, August 2010

A New Class of Room-Temperature Multiferroic Thin Films with Bismuth-Based Supercell Structure
journal, November 2012

Multiferroic BiMnO3 thin films with double SrTiO3 buffer layers
journal, August 2008

Tunnel junctions with multiferroic barriers
journal, March 2007

Origin of Magnetization Reversal and Exchange Bias Phenomena in Solid Solutions of BiFeO ₃ –BiMnO ₃ : Intrinsic or Extrinsic?
journal, January 2013

Structural and magnetic properties of epitaxial thin films of the ordered double perovskite La2CoMnO6
journal, December 2006

Anomalously large ferromagnetic Curie temperature of epitaxial Bi2CoMnO6 thin films
journal, March 2008

Strong room temperature magnetism in highly resistive strained thin films of BiFe0.5Mn0.5O3
journal, January 2011

Multiferroism in orientational engineered (La, Mn) co-substituted BiFeO ₃ thin films
journal, June 2011

Implications of phase-segregation on structure, terahertz emission and magnetization of Bi(Fe _1-x Mn _x )O ₃ (0⩽x⩽0.5) thin films
journal, December 2008

Magnetic Tunnel Junctions with Ferroelectric Barriers: Prediction of Four Resistance States from First Principles
journal, January 2009

Evidence of the Griffiths phase in multiferroic BiMnO ₃ and BiFe _0.5 Mn _0.5 O ₃ films
journal, May 2012

Ferroelectric, electrical and magnetic properties of Cr, Mn, Co, Ni, Cu added polycrystalline BiFeO3 films
journal, August 2008

Multi-ferroic and magnetoelectric materials and interfaces
journal, August 2011

Atomically Resolved Mapping of Polarization and Electric Fields Across Ferroelectric/Oxide Interfaces by Z-contrast Imaging
journal, April 2011

Room temperature ferroelectric properties of Mn-substituted BiFeO3 thin films deposited on Pt electrodes using chemical solution deposition
journal, June 2006

Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
journal, March 2003

Dielectric hysteresis in single crystal BiFeO3
journal, July 1970

Experimental difficulties and artefacts in multiferroic and magnetoelectric thin films of BiFeO ₃ , Bi _0.6 Tb _0.3 La _0.1 FeO ₃ and BiMnO ₃
journal, March 2007

Evidence for the likely occurrence of magnetoferroelectricity in the simple perovskite, BiMnO3
journal, April 2002

Magnetocapacitance effect in multiferroic ${BiMnO}_{3}$
journal, May 2003

Magnetostructural Effect in the Multiferroic ${BiFeO}_{3} − {BiMnO}_{3}$ Checkerboard from First Principles
journal, January 2010

Structural, magnetic, and optical properties of ${BiFeO}_{3}$ and ${Bi}_{2} {FeMnO}_{6}$ epitaxial thin films: An experimental and first-principles study
journal, September 2008

High-Temperature Magnetic Insulating Phase in Ultrathin ${La}_{0.67} {Sr}_{0.33} {MnO}_{3}$ Films
journal, October 2012

Multiple magnetic phases of ${La}_{2} {CoMnO}_{6 - δ}$ $(0 <~ δ <~ 0.05)$
journal, January 2003

Experimental Confirmation of the X-Ray Magnetic Circular Dichroism Sum Rules for Iron and Cobalt
journal, July 1995

Polarized neutron reflection as a probe of magnetic films and multilayers
journal, August 1992

Competition between ferromagnetic and antiferromagnetic ground states in multiferroic ${BiMnO}_{3}$ at high pressures
journal, July 2010

Spin filtering through ferromagnetic $Bi Mn O_{3}$ tunnel barriers
journal, July 2005

A strong ferroelectric ferromagnet created by means of spin–lattice coupling
journal, July 2011

Magnetic tunnel junctions with ferroelectric barriers: Prediction of four resistance states from first-principles
text, January 2008

Room temperature ferromagnetism in BiFe ₁₋ _x Mn _x O ₃ thin film induced by spin-structure manipulation
journal, May 2018

The Polar/Antipolar Phase Boundary of BiMnO ₃ -BiFeO ₃ -PbTiO ₃ : Interplay among Crystal Structure, Point Defects, and Multiferroism
journal, July 2018

High-temperature Magnetodielectric $Bi ({Fe}_{0.5} {Mn}_{0.5}) O_{3}$ Thin Films with Checkerboard-Ordered Oxygen Vacancies and Low Magnetic Damping
journal, November 2018

Magnetic, electronic, and optical properties of double perovskite Bi ₂ FeMnO ₆
journal, March 2017

Interface-Coupled BiFeO ₃ /BiMnO ₃ Superlattices with Magnetic Transition Temperature up to 410 K
journal, January 2016