Lattice dynamics of compounds
Abstract
We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe₂X₃ (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe₂S₃ (BaFe₂Se₃) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe₂S(Se)₃ is supported by the lattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe₂Se₃ below TN=255K leaves a fingerprint both in the A1g and B3g phonon mode linewidth and energy.
- Authors:
-
- Univ. of Belgrade, Belgrade (Serbia)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Emergent Superconductivity (CES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1193207
- Alternate Identifier(s):
- OSTI ID: 1180751
- Report Number(s):
- BNL-107988-2015-JA
Journal ID: ISSN 1098-0121; PRBMDO; R&D Project: PM016; KC0201050
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review. B, Condensed Matter and Materials Physics
- Additional Journal Information:
- Journal Volume: 91; Journal Issue: 6; Journal ID: ISSN 1098-0121
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Popović, Z. V., Šćepanović, M., Lazarević, N., Opačić, M., Radonjić, M. M., Tanasković, D., Lei, Hechang, and Petrovic, C. Lattice dynamics of BaFe2X3(X=S,Se) compounds. United States: N. p., 2015.
Web. doi:10.1103/PhysRevB.91.064303.
Popović, Z. V., Šćepanović, M., Lazarević, N., Opačić, M., Radonjić, M. M., Tanasković, D., Lei, Hechang, & Petrovic, C. Lattice dynamics of BaFe2X3(X=S,Se) compounds. United States. https://doi.org/10.1103/PhysRevB.91.064303
Popović, Z. V., Šćepanović, M., Lazarević, N., Opačić, M., Radonjić, M. M., Tanasković, D., Lei, Hechang, and Petrovic, C. Fri .
"Lattice dynamics of BaFe2X3(X=S,Se) compounds". United States. https://doi.org/10.1103/PhysRevB.91.064303. https://www.osti.gov/servlets/purl/1193207.
@article{osti_1193207,
title = {Lattice dynamics of BaFe2X3(X=S,Se) compounds},
author = {Popović, Z. V. and Šćepanović, M. and Lazarević, N. and Opačić, M. and Radonjić, M. M. and Tanasković, D. and Lei, Hechang and Petrovic, C.},
abstractNote = {We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe₂X₃ (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe₂S₃ (BaFe₂Se₃) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe₂S(Se)₃ is supported by the lattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe₂Se₃ below TN=255K leaves a fingerprint both in the A1g and B3g phonon mode linewidth and energy.},
doi = {10.1103/PhysRevB.91.064303},
journal = {Physical Review. B, Condensed Matter and Materials Physics},
number = 6,
volume = 91,
place = {United States},
year = {Fri Feb 27 00:00:00 EST 2015},
month = {Fri Feb 27 00:00:00 EST 2015}
}
Web of Science
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Works referencing / citing this record:
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