Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer

Dell'Angela, M.; Anniyev, T.; Beye, M.; Coffee, R.; Föhlisch, A.; Gladh, J.; Kaya, S.; Katayama, T.; Krupin, O.; Nilsson, A.; Nordlund, D.; Schlotter, W. F.; Sellberg, J. A.; Sorgenfrei, F.; Turner, J. J.; Öström, H.; Ogasawara, H.; Wolf, M.; Wurth, W.

doi:10.1063/1.4914892

Title: Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer

Abstract

Vacuum space charge-induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.

Authors:

Dell'Angela, M. ^[1]; Anniyev, T. ^[2]; Beye, M. ^[3]; Coffee, R. ^[4]; Föhlisch, A. ^[5]; Gladh, J. ^[6]; Kaya, S. ^[7]; Katayama, T. ^[7]; Krupin, O. ^[8]; Nilsson, A. ^[9]; Nordlund, D. ^[10]; Schlotter, W. F. ^[11]; Sellberg, J. A. ^[12]; Sorgenfrei, F. ^[13]; Turner, J. J. ^[11]; Öström, H. ^[6]; Ogasawara, H. ^[14]; Wolf, M. ^[15]; Wurth, W. ^[13]

Univ. of Hamburg (Germany). Physics Dept., Center for Free-Electron Laser Science; Elettra-Sincrotrone Trieste, Trieste (Italy)
SLAC National Accelerator Laboratory, Menlo Park, CA (United States).SUNCAT Center for Interface Science and Catalysis.
SLAC National Accelerator Laboratory, Menlo Park, CA (United States).SUNCAT Center for Interface Science and Catalysis; Helmholtz-Zentrum Berlin fur Materialien und Energie, Berlin (Germany)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Helmholtz-Zentrum Berlin fur Materialien und Energie, Berlin (Germany); Universität Potsdam, (Germany). Institut für Physik und Astronomie.
Stockholm University (Sweden). Department of Physics, AlbaNova University Center.
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). SUNCAT Center for Interface Science and Catalysis.
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). Linac Coherent Light Source; European XFEL, Hamburg (Germany)
Stockholm Univ. (Sweden). Dept. of Physics, AlbaNova Univ. Center; SLAC National Accelerator Laboratory and SUNCAT Center for Interface Science and Catalysis, Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States). SSRL.
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). Linac Coherent Light Source.
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). SUNCAT Center for Interface Science and Catalysis; Stockholm Univ. (Sweden). Dept. of Physics, AlbaNova Univ. Center.
Univ. of Hamburg (Germany). Physics Dept., Center for Free-Electron Laser Science.
SUNCAT Center for Interface Science and Catalysis and SLAC National Accelerator, Menlo Park, CA (United States)
Fritz-Haber Institute, Berlin (Germany). Max Planck Society.

Publication Date:: Sun Mar 01 00:00:00 EST 2015

Research Org.:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1190016

Resource Type:: Accepted Manuscript

Journal Name:: Structural Dynamics

Additional Journal Information:: Journal Volume: 2; Journal Issue: 2; Journal ID: ISSN 2329-7778

Publisher:: American Crystallographic Association/AIP

Country of Publication:: United States

Language:: English

Subject:: 74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats


                    Dell'Angela, M., Anniyev, T., Beye, M., Coffee, R., Föhlisch, A., Gladh, J., Kaya, S., Katayama, T., Krupin, O., Nilsson, A., Nordlund, D., Schlotter, W. F., Sellberg, J. A., Sorgenfrei, F., Turner, J. J., Öström, H., Ogasawara, H., Wolf, M., and Wurth, W. Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer.  United States: N. p., 2015. 
Web.  doi:10.1063/1.4914892.

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                    Dell'Angela, M., Anniyev, T., Beye, M., Coffee, R., Föhlisch, A., Gladh, J., Kaya, S., Katayama, T., Krupin, O., Nilsson, A., Nordlund, D., Schlotter, W. F., Sellberg, J. A., Sorgenfrei, F., Turner, J. J., Öström, H., Ogasawara, H., Wolf, M., & Wurth, W. Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer.  United States.  https://doi.org/10.1063/1.4914892

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                    Dell'Angela, M., Anniyev, T., Beye, M., Coffee, R., Föhlisch, A., Gladh, J., Kaya, S., Katayama, T., Krupin, O., Nilsson, A., Nordlund, D., Schlotter, W. F., Sellberg, J. A., Sorgenfrei, F., Turner, J. J., Öström, H., Ogasawara, H., Wolf, M., and Wurth, W. Sun .  
"Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer".  United States.  https://doi.org/10.1063/1.4914892.  https://www.osti.gov/servlets/purl/1190016.

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@article{osti_1190016,

  title        = {Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer},

  author       = {Dell'Angela, M. and Anniyev, T. and Beye, M. and Coffee, R. and Föhlisch, A. and Gladh, J. and Kaya, S. and Katayama, T. and Krupin, O. and Nilsson, A. and Nordlund, D. and Schlotter, W. F. and Sellberg, J. A. and Sorgenfrei, F. and Turner, J. J. and Öström, H. and Ogasawara, H. and Wolf, M. and Wurth, W.},

  abstractNote = {Vacuum space charge-induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.},

  doi          = {10.1063/1.4914892},

  journal      = {Structural Dynamics},

  number       = 2,

  volume       = 2,

  place        = {United States},

  year         = {Sun Mar 01 00:00:00 EST 2015},

  month        = {Sun Mar 01 00:00:00 EST 2015}

}

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Science, Vol. 339, Issue 6125
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Works referencing / citing this record:

Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics
journal, October 2016

Oloff, Lars-Philip; Chainani, Ashish; Matsunami, Masaharu
Scientific Reports, Vol. 6, Issue 1
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Pump laser-induced space-charge effects in HHG-driven time- and angle-resolved photoelectron spectroscopy
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Oloff, L. -P.; Hanff, K.; Stange, A.
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Atom-specific activation in CO oxidation
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Schreck, Simon; Diesen, Elias; LaRue, Jerry
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Performance of photoelectron spin polarimeters with continuous and pulsed sources: from storage rings to free electron lasers
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Pincelli, T.; Grasselli, F.; Petrov, V. N.
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Atom-specific activation in CO oxidation
text, January 2018

Schreck, Simon; Diesen, Elias; LaRue, Jerry
Deutsches Elektronen-Synchrotron, DESY, Hamburg
DOI: 10.3204/pubdb-2019-00078

Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics
journal, October 2016

Oloff, Lars-Philip; Chainani, Ashish; Matsunami, Masaharu
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep35087

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Title: Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer

Abstract

Citation Formats

Real-Time Observation of Surface Bond Breaking with an X-ray Laser journal, March 2013

Probing the transition state region in catalytic CO oxidation on Ru journal, February 2015

Direct Observation of Surface Chemistry Using Ultrafast Soft-X-Ray Pulses journal, June 2001

Application of high harmonic radiation in surface science journal, February 2009

High-flux table-top soft x-ray source driven by sub-2-cycle, CEP stable, 185-μm 1-kHz pulses for carbon K-edge spectroscopy journal, January 2014

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Bright Coherent Ultrahigh Harmonics in the keV X-ray Regime from Mid-Infrared Femtosecond Lasers journal, June 2012

Ultrafast Melting of a Charge-Density Wave in the Mott Insulator 1 T − TaS 2 journal, October 2010

Clocking the Melting Transition of Charge and Lattice Order in 1 T − TaS 2 with Ultrafast Extreme-Ultraviolet Angle-Resolved Photoemission Spectroscopy journal, October 2011

Collapse of long-range charge order tracked by time-resolved photoemission at high momenta journal, March 2011

Towards time resolved core level photoelectron spectroscopy with femtosecond x-ray free-electron lasers journal, March 2008

Time-resolved x-ray photoelectron spectroscopy at FLASH journal, January 2012

Time-resolved HAXPES at SACLA: probe and pump pulse-induced space-charge effects journal, December 2014

Atomic-Scale Perspective of Ultrafast Charge Transfer at a Dye–Semiconductor Interface journal, July 2014

Vacuum space-charge effects in solid-state photoemission journal, January 2009

Space charge effect and mirror charge effect in photoemission spectroscopy journal, January 2005

Space charge effects in photoemission with a low repetition, high intensity femtosecond laser source journal, July 2006

Operation of a free-electron laser from the extreme ultraviolet to the water window journal, June 2007

First lasing and operation of an ångstrom-wavelength free-electron laser journal, August 2010

A compact X-ray free-electron laser emitting in the sub-ångström region journal, June 2012

Femtochemistry at Metal Surfaces: Nonadiabatic Reaction Dynamics journal, October 2006

The soft x-ray instrument for materials studies at the linac coherent light source x-ray free-electron laser journal, April 2012

Ultrafast soft X-ray emission spectroscopy of surface adsorbates using an X-ray free electron laser journal, April 2013

Surface core-level shifts of clean and oxygen-covered Ru(0001) journal, May 2001

Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103 journal, January 1985

Correction of non-linearity effects in detectors for electron spectroscopy journal, October 2004

Disentanglement of electron dynamics and space-charge effects in time-resolved photoemission from h -BN/Ni(111) journal, September 2011

Second and third harmonic measurements at the linac coherent light source journal, June 2011

Development and calibration of mirrors and gratings for the soft x-ray materials science beamline at the Linac Coherent Light Source free-electron laser journal, January 2012

Linac Coherent Light Source soft x-ray materials science instrument optical design and monochromator commissioning journal, September 2011

Observation of surface enhanced multiphoton photoemission from metal surfaces in the short pulse limit journal, June 1995

Quantum efficiency and thermal emittance of metal photocathodes journal, July 2009

Application of high harmonic radiation in surface science journal, February 2009

Femtochemistry at Metal Surfaces: Nonadiabatic Reaction Dynamics journal, October 2006

Atomic-Scale Perspective of Ultrafast Charge Transfer at a Dye–Semiconductor Interface journal, July 2014

Collapse of long-range charge order tracked by time-resolved photoemission at high momenta journal, March 2011

First lasing and operation of an ångstrom-wavelength free-electron laser journal, August 2010

A compact X-ray free-electron laser emitting in the sub-ångström region journal, June 2012

Space charge effects in photoemission with a low repetition, high intensity femtosecond laser source journal, July 2006

Observation of surface enhanced multiphoton photoemission from metal surfaces in the short pulse limit journal, June 1995

Towards time resolved core level photoelectron spectroscopy with femtosecond x-ray free-electron lasers journal, March 2008

Time-resolved HAXPES at SACLA: probe and pump pulse-induced space-charge effects journal, December 2014

Photoinduced Reconfiguration Cycle in a Molecular Adsorbate Layer Studied by Femtosecond Inner-Shell Photoelectron Spectroscopy journal, March 2011

Bright Coherent Ultrahigh Harmonics in the keV X-ray Regime from Mid-Infrared Femtosecond Lasers journal, June 2012

Real-Time Observation of Surface Bond Breaking with an X-ray Laser journal, March 2013

Probing the transition state region in catalytic CO oxidation on Ru journal, February 2015

53 W average power few-cycle fiber laser system generating soft x rays up to the water window journal, January 2014

The soft x-ray instrument for materials studies at the linac coherent light source x-ray free-electron laser text, January 2012

Ultrafast melting of a charge-density wave in the Mott insulator 1T-TaS2 text, January 2010

Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics journal, October 2016

Pump laser-induced space-charge effects in HHG-driven time- and angle-resolved photoelectron spectroscopy journal, June 2016

Atom-specific activation in CO oxidation journal, December 2018

Performance of photoelectron spin polarimeters with continuous and pulsed sources: from storage rings to free electron lasers journal, January 2017

Atom-specific activation in CO oxidation text, January 2018

Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics journal, October 2016

Real-Time Observation of Surface Bond Breaking with an X-ray Laser
journal, March 2013

Probing the transition state region in catalytic CO oxidation on Ru
journal, February 2015

Direct Observation of Surface Chemistry Using Ultrafast Soft-X-Ray Pulses
journal, June 2001

Application of high harmonic radiation in surface science
journal, February 2009

High-flux table-top soft x-ray source driven by sub-2-cycle, CEP stable, 185-μm 1-kHz pulses for carbon K-edge spectroscopy
journal, January 2014

High flux coherent super-continuum soft X-ray source driven by a single-stage, 10mJ, Ti:sapphire amplifier-pumped OPA
journal, January 2014

Bright Coherent Ultrahigh Harmonics in the keV X-ray Regime from Mid-Infrared Femtosecond Lasers
journal, June 2012

Ultrafast Melting of a Charge-Density Wave in the Mott Insulator $1 T − {TaS}_{2}$
journal, October 2010

Clocking the Melting Transition of Charge and Lattice Order in $1 T − {TaS}_{2}$ with Ultrafast Extreme-Ultraviolet Angle-Resolved Photoemission Spectroscopy
journal, October 2011

Collapse of long-range charge order tracked by time-resolved photoemission at high momenta
journal, March 2011

Towards time resolved core level photoelectron spectroscopy with femtosecond x-ray free-electron lasers
journal, March 2008

Time-resolved x-ray photoelectron spectroscopy at FLASH
journal, January 2012

Time-resolved HAXPES at SACLA: probe and pump pulse-induced space-charge effects
journal, December 2014

Atomic-Scale Perspective of Ultrafast Charge Transfer at a Dye–Semiconductor Interface
journal, July 2014

Vacuum space-charge effects in solid-state photoemission
journal, January 2009

Space charge effect and mirror charge effect in photoemission spectroscopy
journal, January 2005

Space charge effects in photoemission with a low repetition, high intensity femtosecond laser source
journal, July 2006

Operation of a free-electron laser from the extreme ultraviolet to the water window
journal, June 2007

First lasing and operation of an ångstrom-wavelength free-electron laser
journal, August 2010

A compact X-ray free-electron laser emitting in the sub-ångström region
journal, June 2012

Femtochemistry at Metal Surfaces: Nonadiabatic Reaction Dynamics
journal, October 2006

The soft x-ray instrument for materials studies at the linac coherent light source x-ray free-electron laser
journal, April 2012

Ultrafast soft X-ray emission spectroscopy of surface adsorbates using an X-ray free electron laser
journal, April 2013

Surface core-level shifts of clean and oxygen-covered Ru(0001)
journal, May 2001

Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103
journal, January 1985

Correction of non-linearity effects in detectors for electron spectroscopy
journal, October 2004

Disentanglement of electron dynamics and space-charge effects in time-resolved photoemission from $h$ -BN/Ni(111)
journal, September 2011

Second and third harmonic measurements at the linac coherent light source
journal, June 2011

Development and calibration of mirrors and gratings for the soft x-ray materials science beamline at the Linac Coherent Light Source free-electron laser
journal, January 2012

Linac Coherent Light Source soft x-ray materials science instrument optical design and monochromator commissioning
journal, September 2011

Observation of surface enhanced multiphoton photoemission from metal surfaces in the short pulse limit
journal, June 1995

Quantum efficiency and thermal emittance of metal photocathodes
journal, July 2009

Application of high harmonic radiation in surface science
journal, February 2009

Femtochemistry at Metal Surfaces: Nonadiabatic Reaction Dynamics
journal, October 2006

Atomic-Scale Perspective of Ultrafast Charge Transfer at a Dye–Semiconductor Interface
journal, July 2014

Collapse of long-range charge order tracked by time-resolved photoemission at high momenta
journal, March 2011

First lasing and operation of an ångstrom-wavelength free-electron laser
journal, August 2010

A compact X-ray free-electron laser emitting in the sub-ångström region
journal, June 2012

Space charge effects in photoemission with a low repetition, high intensity femtosecond laser source
journal, July 2006

Observation of surface enhanced multiphoton photoemission from metal surfaces in the short pulse limit
journal, June 1995

Towards time resolved core level photoelectron spectroscopy with femtosecond x-ray free-electron lasers
journal, March 2008

Time-resolved HAXPES at SACLA: probe and pump pulse-induced space-charge effects
journal, December 2014

Photoinduced Reconfiguration Cycle in a Molecular Adsorbate Layer Studied by Femtosecond Inner-Shell Photoelectron Spectroscopy
journal, March 2011

Bright Coherent Ultrahigh Harmonics in the keV X-ray Regime from Mid-Infrared Femtosecond Lasers
journal, June 2012

Real-Time Observation of Surface Bond Breaking with an X-ray Laser
journal, March 2013

Probing the transition state region in catalytic CO oxidation on Ru
journal, February 2015

53 W average power few-cycle fiber laser system generating soft x rays up to the water window
journal, January 2014

The soft x-ray instrument for materials studies at the linac coherent light source x-ray free-electron laser
text, January 2012

Ultrafast melting of a charge-density wave in the Mott insulator 1T-TaS2
text, January 2010

Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics
journal, October 2016

Pump laser-induced space-charge effects in HHG-driven time- and angle-resolved photoelectron spectroscopy
journal, June 2016

Atom-specific activation in CO oxidation
journal, December 2018

Performance of photoelectron spin polarimeters with continuous and pulsed sources: from storage rings to free electron lasers
journal, January 2017

Atom-specific activation in CO oxidation
text, January 2018

Time-resolved HAXPES using a microfocused XFEL beam: From vacuum space-charge effects to intrinsic charge-carrier recombination dynamics
journal, October 2016