Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃
Abstract
The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe₂(MoO₄)₃ electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na⁺ and Li⁺, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe₂(MoO₄)₃ and the one by one Na occupation (pseudo-continuous occupation) at 8d sites in partially sodiated Fe₂(MoO₄)₃ are obtained during the discharge processes of Li/Fe₂(MoO₄)₃ and Na/Fe₂(MoO₄)₃ cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.
- Authors:
-
- Fudan Univ., Shanghai (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Shanghai Univ., Shanghai (China)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1182528
- Alternate Identifier(s):
- OSTI ID: 1191276
- Report Number(s):
- BNL-107587-2015-JA
Journal ID: ISSN 2045-2322; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- SC00112704; AC02-98CH10886
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 5; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; national synchrotron light source
Citation Formats
Yue, Ji-Li, Zhou, Yong-Ning, Shi, Si-Qi, Shadike, Zulipiya, Huang, Xuan-Qi, Luo, Jun, Yang, Zhen-Zhong, Li, Hong, Gu, Lin, Yang, Xiao-Qing, and Fu, Zheng-Wen. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃. United States: N. p., 2015.
Web. doi:10.1038/srep08810.
Yue, Ji-Li, Zhou, Yong-Ning, Shi, Si-Qi, Shadike, Zulipiya, Huang, Xuan-Qi, Luo, Jun, Yang, Zhen-Zhong, Li, Hong, Gu, Lin, Yang, Xiao-Qing, & Fu, Zheng-Wen. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃. United States. https://doi.org/10.1038/srep08810
Yue, Ji-Li, Zhou, Yong-Ning, Shi, Si-Qi, Shadike, Zulipiya, Huang, Xuan-Qi, Luo, Jun, Yang, Zhen-Zhong, Li, Hong, Gu, Lin, Yang, Xiao-Qing, and Fu, Zheng-Wen. Fri .
"Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃". United States. https://doi.org/10.1038/srep08810. https://www.osti.gov/servlets/purl/1182528.
@article{osti_1182528,
title = {Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃},
author = {Yue, Ji-Li and Zhou, Yong-Ning and Shi, Si-Qi and Shadike, Zulipiya and Huang, Xuan-Qi and Luo, Jun and Yang, Zhen-Zhong and Li, Hong and Gu, Lin and Yang, Xiao-Qing and Fu, Zheng-Wen},
abstractNote = {The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe₂(MoO₄)₃ electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na⁺ and Li⁺, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe₂(MoO₄)₃ and the one by one Na occupation (pseudo-continuous occupation) at 8d sites in partially sodiated Fe₂(MoO₄)₃ are obtained during the discharge processes of Li/Fe₂(MoO₄)₃ and Na/Fe₂(MoO₄)₃ cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.},
doi = {10.1038/srep08810},
journal = {Scientific Reports},
number = ,
volume = 5,
place = {United States},
year = {Fri Mar 06 00:00:00 EST 2015},
month = {Fri Mar 06 00:00:00 EST 2015}
}
Web of Science
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